• Bulletin of the Korean Chemical Society
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• 제18권10호
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• pp.1090-1093
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• 1997

The solvent effects on the isotropic NMR shifts in conformationally rigid ligands such as quinuclidine, pyridine, and 4-aminopyridine coordinated to the paramagnetic polyoxometalate, [SiW11CoⅡO39]6- (SiW11Co), are reported. For these complexes the ligand exchange is slow on the NMR time scale and pure 1H NMR signals have been observed at room temperature. The signals for the SiW11Co complexes are shifted upfield whe dimethyl sulfoxide-d6 (DMSO) is added to a D2O solution. The isotropic shifts are separated into contact and pseudocontact contributions by assuming that the contact shifts are proportional to the isotropic shifts of the same ligands coordinated to [SiW11NiⅡO39]6-. It is shown that both the contact and pseudocontact shifts decrease (the absolute values of the pseudocontact shifts increase), when D2O is replaced by DMSO. It is suggested that D2O, a strong hydrogen bond donor, withdraws electron density from [SiW11CoⅡO39]6-, increasing the acidity of the cobalt ion toward the axial ligand. When D2O is replaced by DMSO, the acidity of the cobalt ion in SiW11Co decreases, weakening the Co-N bond. Then both the contact and pseudocontact shifts are expected to decrease in agreement with the observed solvent effects.

• Tribology and Lubricants
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• 제25권5호
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• pp.342-347
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• 2009

This paper presents EHL analysis for rough surfaces with directional roughness. Three different types of surfaces with pure longitudinal roughness, pure transversal roughness and isotropic roughness are generated. For the surfaces with longitudinal and transversal roughness, two cases are analyzed; one is a case of asperity peak on a spherical contact center, the other one is of valley on a spherical contact center. As a results, the surface with pure transversal roughness gives higher pressure and smaller minimum film thickness than the surface with pure longitudinal roughness, and the surface with isotropic roughness has similar EHL behavior with the surface with pure transversal roughness.

• Structural Engineering and Mechanics
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• 제19권6호
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• pp.707-720
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• 2005

The bending stress formula that taking into account the transverse deformation is developed for plane-curved, untwisted isotropic beams subjected to loadings that result in deformations in the plane of curvature. In order to account the transverse Poisson contraction effect, a new constitutive relation between force resultants, moment resultants, mid-plane strains and deformed curvatures for a curved plate is derived in a $6{\times}6$ matrix form. This constitutive relation will provide the fundamental basis to the analyses of curved structures composing of isotropic or anisotropic materials. Then, the bending stress formula of a curved isotropic beam can be deduced from this newly developed curved plate theory. The stress predictions by the present analysis are compared to those by the analysis that neglected the Poisson contraction effect. The results show that the Poisson effect becomes more significant as the Poisson ratio and the curvature are getting larger.

• 대한토목학회논문집
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• 제31권5A호
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• pp.389-397
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• 2011

본 논문에서는 이방향 휨인장강도 시험 시 시험체에 작용하는 등방성 휨인장거동의 구현여부를 실험적으로 증명하기 위해 시험체의 변형률 측정 실험과, 시험체에 등방성 휨인장응력이 작용할 수 있도록 시험법 개선을 위한 연구를 수행하였다. 또한, 개선된 시험법을 적용하여 이방향 휨인장강도와 4점 휨인장강도 시험에 의한 일방향 휨인장강도를 측정하여 비교하였다. 실험 결과, 시험체에 발생하는 등방성 휨인장응력은 시험체의 표면 조건과 뒤틀림 정도에 많은 영향을 받는 것으로 나타났으나, 시험법 개선으로 인해 시험체에 등방성 휨인장응력상태를 확보할 수 있었다. 개선된 이방향 휨인장강도 시험에 의한 이방향 휨인장강도가 일방향 휨인장강도 보다 32% 더 큰 것으로 나타났으며, 분산성은 동일한 것으로 나타났다.

• 한국전자파학회논문지
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• 제22권4호
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• pp.407-415
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• 2011

본 논문에서는 등방성(isotropic) 특성과 작은 분산 오차(low dispersion error)를 갖는 3차원 등방성 시간 영역 유한 차분법(ID-FDTD: Isotropic Dispersion Finite Difference Time Domain) 방법의 stability condition과 광대역 해석 특성에 대해 논의하였다. 3차원 ID-FDTD 방법은 기존의 Yee FDTD 방법의 비등방성 특성과 큰 분산 오차를 개선하기 위해 제안되었다. 기존 연구에서는 3차원 ID-FDTD 방법의 stability condition을 수치적으로 계산하였지만, 이에 대한 검증이 충분히 이뤄지지 않은 상태이다. 이에 본 논문에서는 단일 주파수와 광대역 주파수 신호를 입력원으로 한 모의 실험 환경에서 3차원 ID-FDTD 방법의 stability condition 검증을 수행하였다. 또한 광대역 특성에 대해 3차원 ID-FDTD 방법과 유사한 알고리즘들을 비교 분석해 해보았고, 마지막으로 3D ID-FDTD을 적용하여 대형 크기 구 모델에 대해 radar cross section(RCS) 해석을 수행함으로써, 실질적 해석을 통한 알고리즘 검증 및 분석을 마무리 하였다.

• Coupled systems mechanics
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• 제9권4호
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• pp.343-358
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• 2020

The present research deals with the time-harmonic deformation in transversely isotropic magneto thermoelastic solid with two temperature (2T), rotation due to inclined load and laser pulse. Generalized theory of thermoelasticity has been formulated for this mathematical model. The entire thermo-elastic medium is rotating with uniform angular velocity and subjected to thermally insulated and isothermal boundaries. The inclined load is supposed to be a linear combination of a normal load and a tangential load. The Fourier transform techniques have been used to find the solution to the problem. The displacement components, stress components, and conductive temperature distribution with the horizontal distance are computed in the transformed domain and further calculated in the physical domain using numerical inversion techniques. The effect of angle of inclination of normal and tangential load for Green Lindsay Model and time-harmonic source for Lord Shulman model is depicted graphically on the resulting quantities.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회B
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• pp.2396-2400
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• 2008

The motion of small heavy particles in homogeneous isotropic turbulence in the present of gravity is investigated using Direct Numerical Simulations (DNS) at moderate Reynolds number. The Lagrangian velocity and acceleration statistics of particles and of flow for a wide range of Stokes number, defined as the ratio of the particle response time to Kolmogorov time scale of turbulence, were obtained for the direction of the gravity and normal direction, respectively. It is found that particles lose their correction faster than the case without gravity. Then, a significant increase in the average settling velocity was observed for a certain range of Stokes number. Our focus is placed on gravitational effect on very small particles. Our simulations show that as the Stokes number reduces to zero, their mean settling velocity approaches the terminal velocity in still fluid.

• 한국전자파학회지:전자파기술
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• 제6권1호
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• pp.3-9
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• 1995

An isotropic electric-field probe, capable of characterizing and quantifying electromagnetic field, was fabricated. The probe consists of three short dipole antennas, a beam-lead Schottky diode and the high resistive transmission line. In order to get the isotropic response three mutually orthogonal dipoles are configured to form the probe. The probe's short dipole elements allow measurements of electric fields from 300MHz to 2GHz with a flatness of .+-. 2.9dB. The mutually orthogonal dipole configration shows a .+-. 1.2dB deviation in the isotropic response with respect to angle.

• 한국지진공학회:학술대회논문집
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• 한국지진공학회 2006년도 학술발표회 논문집
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• pp.345-350
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• 2006

If a structure is founded on the ground saturated with pore water, then the ground should be modeled as a saturated two-phase porous medium for accurate earthquake response analysis. In this study, a 3-dimensional transmitting boundary is developed for modeling of far field using u-U formulation for water-saturated transversely isotropic layered stratum. The developed transmitting boundary is verified by comparing the dynamic stiffness of rigid square foundation on water-saturated isotropic layered stratum with the case of using equivalent single-phase medium model.

• Coupled systems mechanics
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• 제2권3호
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• pp.271-288
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• 2013

In the present study an elastic-plastic strain analysis is carried out for fibrous composites by using numerical modeling. Application of homogeneous transversely-isotropic model was chosen based on problem solution of a square plate with a circular hole under uniaxial tension. The results obtained in this study correspond to the solution of fiber model trial problem, as well as to analytical solution. Further, numerical algorithm and software has been developed, based on simplified theory of small elastic strains for transversely-isotropic bodies, and FEM. The influence of holes and cracks on stress state of complicated configuration transversely-isotropic bodies has been studied. Strain curves and plasticity zones that are formed in vicinity of the concentrators has been provided. Numerical values of effective mechanical parameters calculated for unidirectional composites at different ratios of fiber volume content and matrix. Content volume proportions of fibers and matrix defined for fibrous composite material that enables to behave as elastic-plastic body or as a brittle material. The influences of the fibrous structure on stress concentration in vicinity of holes on boron/aluminum D16, used as an example.