• Journal of the Korean Chemical Society
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• v.31 no.4
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• pp.334-343
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• 1987

The Chemical reactions between $NiL_m{^{2+}}\{$Ni(rac-1[14]7-diene)^{2+},\;Ni(meso-1[14]7-diene)^{2+},\;Ni(1[14]4-diene)^{2+},\;{\alpha}-Ni(rac-[14]-decane)^{2+},\;{\beta}-Ni(rac-[14]-decane)^{2+},\;and\;Ni(meso-[14]-decane)^{2+}$}\and\ CN^-$ ion were studied by the spectrophotometric method. The equilibrium constants (K_1$) for the 1:1 complex ion, $[NiL_m(CN)]^+\;with\;NiL_m{^{2+}}\;and\;CN^-$ ion were determined in the range of 3 to $25^{\circ}C$. The $K_1\;for\;Ni(rac-1[14]7-diene)^{2+},\;Ni(meso-1[14]7-diene)^{2+},\;Ni(1[14]4-diene)^{2+},\;{\alpha}-Ni(rac-[14]-decane)^{2+},\;{beta}-Ni(rac-[14]-decane)^{2+},\;and\;Ni(meso-[14]-decane)^{2+}\;at\;15^{\circ}C$ was 4.7, 5.3, 6.2, 7.5, 9.4, and 9.8, respectively. The values of $K_1$ decreased with increasing temperature. From the temperature effect on equilibrium constant ($K_1$), thermodynamic parameters $({\Delta}H^{\circ},\;{\Delta}S^{\circ},\;{\Delta}G^{\circ})$ for reaction were evaluated and the reaction of $NiL_m{^{2+}}\;and\;CN^-$ ion was exothermic. $NiL_m{^{2+}\;reacts\;with\;CN^-$ ion to give $Ni(CN)_4{^{2-}}$ ion and macrocyclic ligand $(L_m)$. The kinetics of formation of the $Ni(CN)_4{^{2-}}$ ion of varying the $[CN^-],\;[HCN],\;and\;[OH^-]$ have been investigated at 3∼$25^{\circ}C\;and\;0.5M\;NaClO_4$. Maintaining a constant $[CN^-],\;k_{obs}/[CN^-]^2$ increases linearly with increasing [HCN]. In the presence of large quantities of $[OH^-],\;k_{obs}/[CN^-]^2$ also increases linearly with $[OH^-]$. From the temperature effect on kinetic constant (k_{obs})$, parameter of activation $({\Delta}H^{\neq},\;{\Delta}S^{\neq})$ of reaction of $NiL_m{^{2+}}\;with\;CN^-$ ion were determined. For the $Ni(rac-1[14]7-diene)^{2+},\;Ni(meso-1[14]7-diene)^{2+},\;{\alpha}-Ni(rac-[14]-decane)^{2+},\;{\beta}-Ni(rac-[14]-decane)^{2+},\;and\;Ni(meso-[14]-decane)^{2+}\;series\;{\Delta}H^{\neq}$ gradually decrease as the d-d transition energy, $ν(cm^{-1})$ decrease. And the reaction of the five $NiL_m{^{2+}}\;with\;CN^-$ ion take place by way of equal paths.

• Proceedings of the KIEE Conference
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• 1987.07b
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• pp.907-910
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• 1987

This paper describes the design and implementation of M10CN software management system which manages the current state of M10CN software. This system provides the fast search of information in the software and the exact state of the software in the M10CN exchange.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.34 no.4
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• pp.1171-1180
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• 2014

The NRCS-CN method is generally used to estimate effective rainfalls in a basin. However, since the curve number which plays a critical role in the NRCS-CN method was originally developed for US watersheds, it is limited to be directly applied to other basins outside the United States. Therefore various modifications have been suggested to revise the NRCS-CN for specific watershed condition. This study introduced the weighted average method and the slope-based CN to estimate effective rainfalls available for Korean watersheds and compared with the observed direct runoff. The overall results achieved from this study indicated that the adjusted slope-based CN considerably increases effective rainfalls in general and makes the duration of effective storm longer. Based on the statistical error analysis performed for various modifications of NRCS-CN, the weighted average method with the adjusted slope-based CN has highest precision with the observed direct runoff. In addition, after analyzing the relation between the initial loss estimated from rainfall-runoff observations and the potential maximum retention from GIS-based data, it turns out that the assumption of linear relationship between the initial loss and the potential maximum retention is not available for Korean watersheds.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.06a
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• pp.216-216
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• 2009

This paper describes a novel processing technique for the fabrication of polymer-derived SiCN (silicone carbonitride) microstructures for extreme microelectromechanical system (MEMS) applications. A polydimethylsiloxane (PDMS) mold was formed on an SU-8 pattern using a standard UV photolithographic process. Next, the liquid precursor, polysilazane, was injected into the PDMS mold to fabricate free-standing SiCN microstructures. Finally, the solid polymer SiCN microstructure was cross-linked using hot isostatic pressure at $400^{\circ}C$ and 205 bar. The optimal pyrolysis and annealing conditions to form a ceramic microstructure capable of withstanding temperatures over $1400^{\circ}C$ were determined. Using the optimal process conditions, the fabricated SiCN ceramic microstructure possessed excellent characteristics includingshear strength (15.2 N), insulation resistance ($2.163{\times}10^{14}\;{\Omega}$, and BDV (1.2 kV, minimum). Since the fabricated ceramic SiCN microstructure has improved electrical and physical characteristics compared to bulk Si wafers, it may be applied to harsh environments and high-power MEMS applications such as heat exchangers and combustion chambers.

• Membrane and Water Treatment
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• v.11 no.3
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• pp.217-222
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• 2020

An electrochemical oxidation process was applied to remove cyanide (CN^-) from real plating wastewater. CN^- removal efficiencies were investigated under various operating factors: current density and electrolyte concentration. Electrolyte concentration positively affected the removal of both CN^- and Chemical Oxygen Demand (COD). As the electrolyte concentration increased from 302 to 2,077 mg Cl^-/L, removal efficiency of CN^- and COD increased from 49.07% to 98.30% and from 23.53% to 49.50%, respectively, at 10 mA/㎠. Current density affected the removal efficiency in a different way. As current density increased at a fixed electrolyte concentration, CN^- removal efficiency increased while COD removal efficiency decreased, this is probably due to lowered current efficiency caused by water electrolysis.

• Journal of Radiation Protection and Research
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• v.21 no.3
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• pp.167-173
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• 1996

The calibration method for the detection efficiency of solid state track detector to alpha is presented, and the detection efficiency of CN-85 and LEXAN to alpha is measured by this method. The results are 97% and 57% in CN-85 and LEXAN, respectively. The reason for a better result in CN-85 in not only the high sensitivity but also the low energy dependency with comparing for LEXAN. The peak detection efficiency is 3MeV and 1.8MeV in CN-85 and LEXAN, respectively.

• Food Science of Animal Resources
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• v.25 no.3
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• pp.328-332
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• 2005

The effect of k-casein (k-CN) variant on milk production traits (milk yield, fat yield, protein yield, fat percentage and protein percentage) was estimated for 568 Holstein cows in the first lactation. The k-CN valiant were determined by PCR-RFLP (restriction fragment length polymorphism) technique at the DNA level. Single trait linear model was used for the statistical analysis of the data. Result of this study indicated that k-CN variant affected significantly milk yield (P<0.05) and protein yield (P<0.01). Animals with the BB variant produced 622kg milk more and had protein yield higher by 32kg compared with animals with the AA variant No associations between the k-CN variants and other milk production trait were found. Therefore, milk and protein yield may be improved through milk protein typing by increasing the frequencies of k-CN B variant in dairy cattle population. In cheese making, it will be also preferable to have milk with the B variant of k-CN, which gives higher yield having a better quality than the A variant milk.

• Journal of Mechanical Science and Technology
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• v.16 no.7
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• pp.927-934
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• 2002

The HANARO ( High-flux Advanced Neutron Application Reactor) has been operated since 1995. The Cold Neutron (CN) hole was implanted in the reflector tank from the design stage. Before a vacuum chamber and a moderator cell for the cold neutron source are installed into the CN hole, it is necessary to measure exactly the size of the inside diameter and thickness of the CN hole to prevent the interference problem. Due to inaccessibility and high radiation field in the CN hole, a mechanical measurement method is not permitted. The immersed ultrasonic technique is considered as the best way to measure the thickness and the diameter of the CN hole. The 4-Axis manipulator was designed and fabricated for locating the ultrasonic sensors. The transducer of an ultrasonic sensor having 10 MHz frequency leads to high resolution as much as 0.03mm. The inside diameter and thickness of 550 points of the CN hole were measured using 2 channel ultrasonic sensors. The results show that the thickness and inside diameter of the CN hole is in the range of 3.3∼6.7mm and 156∼ 165mm, respectively. This data will be a good reference for the design of the cold neutron source facility.

• Journal of the Korean Chemical Society
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• v.29 no.1
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• pp.38-44
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• 1985

Photoreaction path for the monocyanochromium (Ⅲ) ion was inferred from the experimentally observed product ratio and theoretical analysis. The angular overlap model was used to analyze the d-orbital of various intermediates along a selected reaction coordinate and to determine quartet state energy level. A loss of equatorial ammine leads to pentacoordinated square pyramid with CN- ligand in an equatorial position. The SP(CNeq) intermediate undergoes a rearrangement by the N-Cr-CN bending. This process leads to a trigonal bipyramidal intermediate in which the CN- ligand is located in equatorial position. The subsequent association with a solvent molecule should probably proceed by lateral attack an one edge of the equatorial triangle. The assumption adopted above was consistent with experimental results.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.34 no.2
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• pp.493-503
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• 2014

The NRCS-CN method is generally applied for estimating effective rainfalls in practice, in which the basin-averaged CN is normally used. In order to develop a more appropriate method for estimating effective rainfalls in a basin, this study compared estimated effective rainfalls from two distinct methods with the observed direct runoff. The first method is to estimate the basin-representative effective rainfall using the basin-averaged CN (hereafter, effective rainfall I), whereas the second method to estimate the basin-averaged effective rainfall through areal-averaging sub-area effective rainfalls corresponding to the soil type and landuse type (hereafter, effective rainfall II). The overall results indicated that the effective rainfall II was higher than the effective rainfall I and closer to the observed direct runoff. The study also performed error analyses to verify that the effective rainfall II can be applied in practice in a basin as more accurate estimate of basin-representative effective rainfall.