• 제목/요약/키워드: 6to4

검색결과 111,427건 처리시간 0.101초

$Zn_4SnSe_6$$Zn_4SnSe_6:Co^{2+}$단결정의 광학적 특성연구 (Optical Properties of Undoped and Doped$Zn_4SnSe_6$Single Crystals)

  • 이기형;김덕태;박광호;현승철;김형곤;김남오
    • 대한전기학회논문지:전기물성ㆍ응용부문C
    • /
    • 제52권1호
    • /
    • pp.1-5
    • /
    • 2003
  • Zn$_4$SnSe$_{6}$ and Zn$_4$SnSe$_{6}$ :Co$^{2+}$ single crystals were by the chemical transport reaction method. They crystallized in the monoclinic structure. The direct energy band gaps of the Zn$_4$SnSe$_{6}$ and Zn$_4$SnSe$_{6}$ :Co$^{2+}$single crystals at 289k were found to be 2.146eV and 2.042eV. Optical absorption due to impurity in the Zn$_4$SnSe$_{6}$ :Co$^{2+}$single crystal was observed and described as originating from the electron transition between energy levels of Co$^{2+}$ion sited at T$_{d}$ symmetry point.y point.

Ti-6Al-4V, Ti-4Fe, Ti-(1,2)Si합금의 고온산화 (High Temperature Oxidation of Ti-6Al-4V, Ti-4Fe, Ti-(1,2)Si Alloys)

  • 박기범;이동복
    • 한국표면공학회지
    • /
    • 제34권2호
    • /
    • pp.135-141
    • /
    • 2001
  • Arc-melted Ti-6Al-4V, Ti-4Fe and Ti-(1,2) Si alloys were oxidized at 700, 800, 900 and $1000^{\circ}C$ in air. The oxidation resistance of Ti-4Fe was comparable to that of Ti-6Al-4V, while the oxidation resistance of Ti-(1,2) Si was superior to that of Ti-6Al-4V. Ti-2Si displayed the best oxidation resistance among the four alloys, but failed after oxidation at $1000^{\circ}C$ for 17h. The oxide scale formed on Ti-6Al-4V, Ti-4Fe and Ti-(1,2)Si consisted of ($TiO_2$ and a small amount of $Al_2$$O_3$), ($TiO_2$ and a small amount of dissolved iron), and ($TiO_2$ plus a small concentration of amorphous $SiO_2$), respectively. The oxide grains of the surface scale of the four alloys were generally fine and round.

  • PDF

한방병원에 내원한 소아 골절환자에 대한 임상적 고찰 (A clinical study on pediatric patients with fracture that visited oriental medicine center)

  • 장규태;김장현;백현
    • 대한한방소아과학회지
    • /
    • 제18권1호
    • /
    • pp.1-9
    • /
    • 2004
  • Objectives: The purpose of this study was clinical review of pediatric patients with fracture that visited oriental medicine center. Methods: In retrospective study, the pediatric patients, who were visited to oriental medicine center due to fracture, were classified by sex, age, fracture site, date of accident, injury mechanism, time of treatment, kind of treatment. Results and Conclusion: Total 32 patients were visited due to fracture from April 2001 to March 2004. Male Patients were 27, female were 5. In distribution of age, 10 year-old and 11 year-old were 40.7% of totality. In distribution of month, May was 10(31.3%), June was 6(18.8%), and March was 4(12.5%). There are more patients with fracture in spring than other season. In distribution of fracture site, foot was 15(46.9%), hand was 7(21.9%), ankle was 4(12.5%), upper extremity was 3(9.4%), clavicle was 2(6.3%), tibia was 1(3.1%). In distribution of injury mechanism, slip down was 23(71.9%), impaction 5(15.6%), fall down 3(19.4%), crushing injury 1(13.1%). In distribution of injury motive, soccer was 8(25.0%), basketball 4(12.5%), skating 3(9.4%), cycling 2(6.3%), sliding 1(3.1%), Tae-kwon-do 1(3.1%), other sports 5(15.6%), collision 1(3.1%), walking 2(6.3%), hit 3(9.4%), etc. 2(6.3%). In distribution of treatment account, one time was 23(71.9%), twice 3(9.4%), three times 2(6.3%), four times 2(6.3%), five times 2(6.3%). In distribution of treatment time, 1 week was 26(81.3%), 2 weeks 4(12.5%), 3 weeks 2(6.3%). In distribution of treatment kind, acupuncture treatment was 18(56.3%), negative cupping 7(21.9%), splint 13(40.6%), and other treatment(coban taping, medical patch, and so on) 5(15.6%), transfer 14(43.8%).

  • PDF

1,4-Dihydropyridine-5-Formyl 유도체의 합성 (Synthesis of 1,4-Dihydropyridine-5-Formyl Derivatives)

  • 홍유화;서정진
    • 약학회지
    • /
    • 제33권5호
    • /
    • pp.290-295
    • /
    • 1989
  • 2,6-Dimethyl-4-(3'-nitrophenyl)-1,4-dihydropyridine-3-carboxylic acid methyl ester (1) was formylated to 2,6-dimethy-4-(3'-nitrophenyl)-5-formyl-1,4-dihydropyridine-3-carboxylic acid methyl ester (2) in 76% yield. At the elevated temperature, 2,6-dimethyl-4-(3'-nitrophenyl)-1,4-dihydropyridine-3,5-dicarboxylic acid 3-monomethyl ester (3) was also converted into compound 2 in 46% yield. The compound 2 was reduced to 2,6-dimethyl-4-(3'-nitrophenyl)-5-hydroxymethyl-1,4-dihydropyridine-3-carboxylic acid methyl ester (4) in 91% yield. Compound 2 was reacted with triethyl phosphonoacetate to give 2,6-dimethyl-4-(3'-nitrophenyl)-5-(2-ethoxycarbonyl ethenyl)-1,4-dihydropyridine-3-carboxylic acid methyl ester (5) in 50% yield. Reaction between compound 2 and amines (methyl amine, ethylamine, methoxylamine, hydroxyl amine, phenyl hydrazine and 1-amino-4-methyl piperazine) gave six schiff bases 7a, 7b, 7c, 7e, 7f in 81%, 91%, 82%, 81%, 50% and 84% yield, respectively.

  • PDF

4.16kV 및 6.6kV 전동기 고정자 권선의 절연열화 판정기준 (Judgement Criterion of Insulation Deterioration in 4.16kV and 6.6kV Motor Stator Windings)

  • 김희동
    • 전기학회논문지
    • /
    • 제58권4호
    • /
    • pp.788-794
    • /
    • 2009
  • To assess the condition of stator insulation, nondestructive tests were performed on twenty five coil groups and twenty six motors. The stator windings has nominal ratings of 6.6kV and are classified into five coil groups ;one group with healthy insulation and four groups with four different types of artificial defects. After completing nondestructive tests, the AC voltage applied to the stator windings was gradually increasing until insulation failure in order to obtain the breakdown voltage. No.1, No.2 and No.6 of 6.6kV motors failed near rated voltage of 14kV, 8.7kV and 14kV, respectively. The breakdown voltage of three motors was lower that expected for good quality coils(14.2kV) in 6.6kV motors. No.3 and No.6 of 4.16kV motors failed near rated voltage of 5.6kV and 4.2kV, respectively. Almost all of failures were located in a line-end coil at the exit from the core slot. The breakdown voltages and the types of defects showed strong relation to the stator insulation tests such as in the case of AC current, dissipation factor(tan${\delta}$) and partial discharge magnitude.

Analysis of cellular communication network factor (CCN) 4 and CCN6 expression in the endometrium during the estrous cycle and at the maternal-conceptus interface in pigs

  • Inkyu, Yoo;Soohyung, Lee;Yugyeong, Cheon;Hakhyun, Ka
    • 한국동물생명공학회지
    • /
    • 제37권4호
    • /
    • pp.255-265
    • /
    • 2022
  • The cellular communication network factor (CCN) family proteins regulate many biological events such as angiogenesis, tumor growth, placentation, implantation, and embryogenesis. The expression and function of CCN1, CCN2, and CCN3 at the maternal-conceptus interface are established in humans and rodents, but little is known about the role of CCN4 to CCN6 in the reproductive organs in any other species. Several studies in transcriptome analysis in pigs have shown that the expression of CCN4 and CCN6 increases in the endometrium during early pregnancy. However, their expression, regulation, and function in the endometrium throughout the estrous cycle and pregnancy have not been fully understood in pigs. Thus, we determined the expression, localization, and regulation of CCN4 and CCN6 during the estrous cycle and at the maternal-conceptus interface in pigs. We found that the levels of CCN4, but not CCN6, changed during the estrous cycle. The levels of CCN4 were greater during mid- to late pregnancy than in the early stage, and the levels of CCN6 were greatest on Day 15 of pregnancy. CCN4 and CCN6 were detected in conceptus tissues during early pregnancy and in chorioallantoic tissues during the later stage of pregnancy. CCN4 mRNA was mainly localized to epithelial cells, CCN6 mRNAs to epithelial and stromal cells in the endometrium. In endometrial explant cultures, CCN4 expression was increased by progesterone, and CCN6 expression by interferon-𝛾. These results suggest that CCN4 and CCN6 may play roles in the establishment and maintenance of pregnancy by regulating the endometrial epithelial cell functions in pigs.

티오크잔틸이움 이온과 디메돈의 반응메카니즘에 관한 연구 (Mechanistic Studies on the Reaction of Thioxanthylium Ion with Dimedone)

  • 안광현;김경태
    • 대한화학회지
    • /
    • 제26권2호
    • /
    • pp.107-113
    • /
    • 1982
  • 티안트렌양이온 자유라디칼의 아세토니트릴 용액에 의해 티오크잔틴이 산화되어 생성된 티오크잔틸이움 이온에 디메돈을 넣어주면 9-(4,4-dimethylcyclohexane-2,6-dionyl)thioxanthylium 과염소산염(2)이 생성되나 순서를 바꾸어 넣어주면 초기에 9-(4,4-dimethylcyclohexane-2,6-dionyl)thioxanthene (1)이 생성되며 이것은 계속 반응하여 2를 만든다. 화합물 2는 물이 섞인 아세톤에서 쉽게 탈 수소화되어 9-(4,4-dimethylcyclohexane-2,6-dionylidene)thioxanthene (3)이 된다. 그러나 물이 섞인 아세토니트릴용액중에서 관찰된 219, 289, 348 nm의 isobestic point는 3이 2와 평형상태로 존재함을 말한다. 3의 380nm 근처에 있는 흡수띠의 위치와 강도는 용매에 따라 변하는데 이것은 용매-용질 사이의 상호작용으로 설명한다.

  • PDF

Synthesis of Organic Carbonates with Alkyl/aryl 4,5-dichloro-6-oxopyridazine-1(6H)-carboxylates and ROH/AlCl3 under Ambient Condition

  • Sung, Gi Hyeon;Kim, Bo Ram;Ryu, Ki Eun;Kim, Jeum-Jong;Yoon, Yong-Jin
    • Bulletin of the Korean Chemical Society
    • /
    • 제35권9호
    • /
    • pp.2758-2764
    • /
    • 2014
  • We demonstrated the synthesis of organic carbonates using alkyl/aryl 4,5-dichloro-6-oxopyridazine-1(6H)-carboxylates and alcohol in the presence of aluminum chloride. Alkyl/aryl 4,5-dichloro-6-oxopyridazine-1(6H)-carboxylates were reacted with alcohol in the presence of $AlCl_3$ in toluene at room temperature to afford the corresponding unsymmetric and symmetric organic carbonates in good to excellent yields. These are efficient and convenient processes. Alkyl/aryl 4,5-dichloro-6-oxopyridazine-1(6H)-carboxylates are solid, stable and non-toxic $CO_2/CO_2R$(Ar) source. It is noteworthy that the reaction is carry out under an ambient and acidic conditions, the easy-to prepare and readily available starting materials and the quantitative isolation of reusable 4,5-dichloropyridazin-3(2H)-one.

금식 또는 Vitamin$B_6$ 보충급식이 흰쥐의 Vitamin B6 대사에 미치는 영향 (The Effect of Fasting and Vitamin B6 Repletion on Vitamin$B_6$ Metabolism in Rats)

  • Cho, Youn-Ok
    • Journal of Nutrition and Health
    • /
    • 제28권5호
    • /
    • pp.426-434
    • /
    • 1995
  • The purpose of this study were to investigate the effect of fasting and vitamin B6 repletion on tissue concentration of pyridoxal 5-phosphate and urinary excreteion of 4-pyridoxic acid in vitamin B6 deficient rats. Sixty six rats(6 per group) were fed either a vitamin B6 deficient diet (-B6) or a control diet (+B6) for 6 weeks and then rats were repleted with +B6 diet for 2 weeks. Rats were fasted for 1 and 3 days and for 3 days after repletion. Pyridoxal 5-phosphate (PLP) concentration in plasma, liver, skeletal muscle, and heart muscle and urinary 4-pyridoxic acid (4-PA) excretion were compared. Fasting resulted in a significant increase in PLP concentration in the plasma, liver and heart muscle of rats fed the -B6 diet. Skeletal muscle PLP concentration was significantly decreased in +B6 rats but not in -B6 rats. Following vitamin B6 repletion, PLP concentration in the plasma, liver and heart muscle in previously -B6 rats was similar to the respective concentration in +B6 rats while PLP concentration in the skeletal muscle of previously -B6 rats increased, but it was not reached to that of +B6 rats. At day 1 and 2 of the fast, urinary 4-PT excretion increased in both +B6 and -B6 rats although there was no supply of vitamin B6 due to fasting. These results suggest that vitami B6 is redistributed as PLP when there is a caloric deficit and PLP is supplied by an endogenous source, possibly PLP bound to skeletal muscle glycogen phosphorylase.

  • PDF

IPv6 프로토콜 LAN 설계 및 구축 (A Design and Implementation of IPv6 LAN)

  • 김상범;김두석
    • 대한전자공학회:학술대회논문집
    • /
    • 대한전자공학회 2000년도 추계종합학술대회 논문집(1)
    • /
    • pp.481-484
    • /
    • 2000
  • In this paper, we describe the design and implementation of IPv6 LAN. The legacy protocol for Internet is IPv4(IP version 4). The ability of IPv4 is not enough for modern real time multimedia communication services. So IPv6(IP version 6) protocol was suggested to resolve the problems of IPv4. We implemented IPv6 LAN using sTLA(sub Top Level Aggregation identifier) address and KOREN(KOrea Research and Experimental Network). Our IPv6 LAN is connected with 6TAP(Chicago), WIDE(Tokyo), and SingAREN(Singapore). We used a dedicated router, Windows 2000 PC host FreeBSD PC host, Solaris 7 workstation and Solaris 8 workstation for IPv6 NDP(Neighbor Discovery Protocol) protocol test. To support all data services including voice and video, IP protocol should be enhanced because the characteristics of modern network services are requiring QoS(Quality of Service) functions, auto-configuration, security, mobility and so on. So a new IP protocol, IPv6, has been developing to meet the requirements. In this paper, we introduce the implementation method and configuration information of IPv6 LAN.

  • PDF