• 대한화학회지
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• 제36권3호
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• pp.366-375
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• 1992

카르밤산 화합물의 가아민 분해반응을 이론적으로 고찰하였다. AM1 이론적 계산 결과로서의 반응성은 결합의 형성-파괴효과 및 입체효과에 의하여 결정되는데, 결합의 형성에서 유리한 $B_{AC}2$ 반응메카니즘으로 진행되는데 결과를 줌으로써 실험과 잘 일치하였다. 특히 이론적으로 열적 forbidden인 2 + 2 반응의 구조적 특성을 가지더라도 반응에 관여하는 총 전자수가 6개인 5전자 4중심 반응의 경우 1단계 연속반응으로 진행됨을 밝혔다. 또한 각 반응경로의 활성화 장벽에 대한 차이를 정량적으로 고찰해 보면 전이상태에서 $\sigma$-결합이 깨어지는 것과 $\pi$-결합이 깨어지는 차이는 17kcal/mol이며, 6-각 고리형 구조가 갖는 입체 효과의 차이는 5kcal/mol임을 알았다.

• 방송공학회논문지
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• 제24권2호
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• pp.234-242
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• 2019

본 논문에서는 일정 크기로 자른 영상의 가운데 픽셀이 SIFT 특징점인지를 판별함으로써 SIFT 특징점을 추출하는 딥 뉴럴 네트워크(Deep Neural Network)를 제안한다. 이 네트워크의 데이터 세트는 DIV2K 데이터 세트를 $33{\times}33$ 크기로 잘라서 구성하고, 흑백 영상으로 판별하는 SIFT와는 달리 RGB 영상을 사용한다. 그라운드 트루스(ground truth)는 옥타브(scale, octave)를 0, 시그마(sigma)는 1.6, 간격(intervals)은 3으로 설정하여 추출한 RobHess SIFT 특징들로 구성한다. VGG-16을 기반으로 컨볼루션 층을 13개에서 23개와 33개로 점점 깊은 네트워크를 구성하고, 영상의 스케일을 증가시키는 방법을 바꿔가며 실험을 수행한다. 출력 층의 활성화 함수로 시그모이드(sigmoid) 함수를 사용한 결과와 소프트맥스(softmax) 함수를 사용한 결과를 비교하여 분석한다. 실험결과 제안한 네트워크가 99% 이상의 추출 정확도를 가질 뿐 아니라 왜곡된 영상에 대해서도 높은 추출 반복성을 가진다는 것을 보인다.

• Design & Manufacturing
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• 제11권2호
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• pp.1-8
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• 2017

In this study, we applied microcellular foaming injection molding process to improve the performance of system air-conditioner drain fan which had been produced by injection molding process and studied the optimization of process conditions through 6-sigma process and response surface method (RSM) to reduce weight and deformation of products. Additive type, melt temperature, mold temperature, and injection screw shape were selected as the factor affecting the weight and deformation of the products by carrying out analysis of trivial many through ANOVA and design of experiment (DOE) method. Among the effect factor, we set the addictive type to Long G/F and screw shape to foaming screw which had the highest level of weight reduction and deformation reduction. The amount of foaming agent gas was set at 60 ml, which was the limit beyond which the weight of product did not decrease any more. For melt temperature and mold temperature, we studied the conditions where both weight and deformation were minimized using the RSM. As a result, we set the melt temperature to $250^{\circ}C$, fixed mold temperature to $20^{\circ}C$, and moving mold temperature to $40^{\circ}C$. The improvement effect was analyzed by appling the selected optimal conditions to the production process using the microcellular foaming injection molding. The results showed that the mean weight of product was measured to be 1,420g which was 19% lower than that measured in the current process. The standard deviations of the weights were found to be similar to those in the current process and it showed a low dispersion. The mean deformation was measured to be 0.9237mm, which represented a 57% reduction compared to the mean deformation in the current process, and the standard deviation decreased from 0.3298mm to 0.1398mm. Moreover, we analyzed the process capability for deformation, and the results showed that the short-term process capability increased from 2.73 to 6.60 which was even higher than targeted level of 6.0.

• 한국건설관리학회논문집
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• 제11권6호
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• pp.89-99
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• 2010

군 내무생활관, 독신자 숙소 등은 동일한 평면이 반복되면서 대량으로 건설되는 대표적인 공공건축물이다. 이들 건축물들은 향후 군 구조개편시 부대의 이동, 재편에 따라 건축물의 해체 및 재사용 등이 요구되는 경우도 있다. 이러한 이유로 2005년 이래 군 건축물에 대해 철골조 기반의 공업화 건축공법인 모듈러 공법의 도입이 이루어져 왔다. 군 건축물에 모듈러 공법을 적용함에 있어 가장 중요한 요소는 표준화를 통한 공사비 절감, 건축물의 해체 및 재사용의 용이성 등이나 기존의 모듈러 군시설들은 이러한 요구를 만족시키지 못하였다. 본 연구는 향후 많은 수요가 예측되며 표준화된 모델을 적용하기 용이한 군독신자 숙소를 대상으로 식스-시그마 방법론을 이용한 모듈러 건축 시스템을 제안한다. 식스-시그마방법론을 적용하면 개발 단계에서 고객 요구사항을 주요 설계요소인 CTQ에 반영할 수 있고 이를 기반으로 설계 컨셉의 도출이 가능하다. 분석 결과 공사비 절감은 면적당 골조 중량, 재사용 용이성은 공장제작 비율의 지표로 나타낼 수 있음을 확인하였다. 본 연구에서 제안된 BOQ시스템은 기존의 모듈러 시스템에 비해 공장제작비율은 약 80% 향상되고, 면적당 골조의 중량은 기존 모듈러 시스템에 비해 62% 절감되어 충분한 경쟁력을 가지고 있는 것으로 평가되었다.

• 품질경영학회지
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• 제46권4호
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• pp.843-862
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• 2018

Purpose: The purpose of this study was to develop quality innovation techniques specialized for the small and medium-sized businesses. which account for the majority of Korean companies, were having a hard time utilizing the widely recognized quality innovation techniques due to resource constraints. Methods: First, we do review the existing Single PPM and 6 Sigma. And investigate the utilization of these methods including Toyota Production System. Second, we devised a four-step problem-solving methodology based on recent trends in quality innovation such as Simple, Speedy, and Smart. Third, we do survey on frequently used tools for quality innovation. Many opinion leaders including quality consultants and professors answered and gave us valuable comments about our selected quality tools. Finally, we do specify and map tools to each step of PASS. Results: In 2017, 167 companies participated in the quality innovation support business for small businesses according to the Korea Chamber of Commerce & Industry. We conducted performance checks on 167 companies that had completed the "PASS" projects. For the purpose of evaluating improvement performance, the survey was carried out using a structured questionnaire during the field visit of these companies mentioned above. For the reference, 165 out of 167 companies (98.8 % response rate) responded to the questionnaire and conducted performance analysis based on it. According to the survey, 97.6 percent of the respondents were very satisfied with their overall satisfaction with the quality innovation support projects for small and medium sized enterprises in 2017. Also, 93.3 % of the respondents were satisfied with the results of level of the target achievement. As a result, 160 companies (97.0 % of the participating companies) hope to partic ipate in the quality improvement project using "PASS" once again. Conclusion: In this paper, we introduce the new quality innovation methodology, which is named as 'PASS', It could support the long-range business plan of the small and medium-sized businesses to achieve total customer satisfaction resulting in increased market share and improved profit margin. The most small companies can use this "PASS" technique more easily, quickly and most efficiently than their existing known quality innovation techniques such as Six Sigma and Single PPM, etc.

• 한국결정성장학회지
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• 제6권1호
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• pp.32-43
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• 1996

$CdIn_{2}Te_{4}$ 단결정을 Bridgman방법으로 성장하였다. 성장된 $CdIn_{2}Te_{4}$ 단결정은 분말법으로 X-ray diffraction을 측정하여 tetragonal로 성장되었음을 알 수 있었고 격자상수는 Nelson-Riley 보정식을 이용하여 외삽법으로 구한 결과 $a_{0}$는 $6.215{\AA}$, $c_{0}$는 $12.390{\AA}$이었다. $CdIn_{2}Te_{4}$ 결정이 단결정임을 알아보기 위해 Laue 배면 반사법으로 측정하였는데 c축에 수평한면은 (110), c축에 수직한 면은 (001)으로 성장되었음을 알 수 있었다. 또한 van der Pauw방법으로 Hall 효과를 측정하여 운반자 농도와 이동도를 구하였으며, c축에 수직한 시료의 carrier density는 $8.75{\times}10^{23}electrons/m^{3},\;mobility는\;3.41{\times}10^{-2}m^{2}/V.s$였으며 c축에 평행한 시료의 carrier density는 $8.61{\times}10^{23}electrons/m^{3},\;mobility는\;2.42{\times}10^{-2}m^{2}/V.s$였다. 또한 Hall 계수가 양의 값이여서 $CdIn_{2}Te_{4}$ 단결정은 p형 반도체임을 알 수 있었다.

• 한국전기전자재료학회논문지
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• 제14권6호
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• pp.475-480
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• 2001

Glasses in he system CuO-P$_2$O$_{5}$ -Nb$_2$O$_{5}$ -Nb$_2$O$_{5}$ -V$_2$O$_{5}$ were prepared by a press-quenching method on the copper plate. the glass-ceramics from these glasses were obtained by post-heat treatment, and the crystallization behavior and DC conductivities were determined. The conductivities of the glasses were range from 10$^{-6}$ s.$cm^{-1}$ / at room temperature ,but the conductivities of the glass-ceramics were 10$^{-3}$ s.$cm^{-1}$ / increased by 10$^3$ order. The crystalline product in the glass-ceramics was CuV$_2$O$_{6}$ . the crystal growth of CuV$_2$O$_{6}$ phase increased with heat-treatment conditions. The linear relationship between il($\sigma$T) and T$^{-1}$ suggested that the electrical conduction in the present glass-ceramics would be due to a small polaron hopping(SPH) mechanism.

• 정보처리학회논문지:소프트웨어 및 데이터공학
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• 제2권5호
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• pp.303-310
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• 2013

애자일 소프트웨어 개발 방법은 경량 소프트웨어 개발 방법으로 소프트웨어 개발에서 팀워크가 중요한 역할을 한다. 본 논문에서는 애자일 개발에서 공동 작업을 할 때 팀워크, 팀 관리, 프로젝트 관리를 효율적으로 수행할 수 있는 작업과 인적자원을 분배하는 방안을 제시한다. 제안모델은 작업과 인적자원 분배를 위한 수학적 모델을 재시하고 6-시그마의 우선순위를 적용해서 작업에 가장 합당한 인력을 할당한다. 그리고 개발인력 관계모델을 이용하여 작업에 할당된 인력의 적절성을 검증한다. 제안된 방법은 인원배치의 효율성을 통한 팀워크를 개선함으로써 SW개발 생산성을 높였다.

• Nuclear Engineering and Technology
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• 제49권6호
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• pp.1287-1300
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• 2017

Based on the observation that ignoring the angle dependency of multigroup resonance cross sections within a fuel pellet would result in nontrivial underestimation of the spatial self-shielding of flux, a parametrized spectral superhomogenization (SPH) factor library (PSSL) method is developed as a practical means of resolving the problem. Region-wise spectral SPH factors are calculated by the normal and transport corrected SPH iterations after ultrafine group slowing down calculations over various light water reactor pin-cell configurations. The parametrization is done with fuel temperature, U-238 number density, fuel radius, moderator source represented by ${\Sigma}_{mod}V_{mod}$, and the number density ratio of resonance nuclides to that of U-238 in a form of resonance interference correction factors. The parametrization is successful in that the root mean square errors of the interpolated SPH factors over the fuel regions of various pin-cells are within 0.1%. The improvement in reactivity error of the PSSL method is shown to be superior to that by the original SPH method in that the reactivity bias of -200 pcm to -300 pcm vanishes almost completely. It is demonstrated that the environment effect takes only about 4% in the reactivity improvement so that the pin-cell based PSSL method is effective in the assembly problems.

• Archives of Pharmacal Research
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• 제15권1호
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• pp.52-57
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• 1992

The molecular structure of a natural compound was determined by single crystal X-ray diffraction analysis. The compound was isolated by methanol extraction and repeated chromatography from the stem of Paulownia tomentosa. Yellow prismatic crystals of the compound, which were recrystallized from tetrahydrofuran, are triclinic, with a = 7.310 (6), b = 10.753(6), c = 11.586(5) ${\AA}.\;\alpha= 93.30(6),\;\beta=105.62(10),\;\gamma=109.49(7)^\circ,\;D_x=1.514,\;D_m=1.51 g/cm^3$, space group P1 and Z = 2. The structure was solved by direct method, and refined by least-squares procedure to the final R-value of 0.032 for 1271 independent reflections $(F\le3\sigma{(F))}$. The compound is one of new furanquinone analogue. The molecule has a nearly planar conformation with an intramolecular hydrogen bond. In the crystal, the planar molecules are arranged as a prallel sheet-like pattern, and these stackings are stabilized by the O-H...O type intermolecular hydrogen bonds. The other intermolecular contacts appear to be the normal van der Waals interactions.