• 제목/요약/키워드: 6LiF

검색결과 408건 처리시간 0.023초

TMP-BiP 호스트와 DJNBD-1 도펀트를 이용한 청색 OLED의 제작과 특성평가 (Fabrication and Characterization of Blue OLED using TMP-BiP Host and DJNBD-1 Dopant)

  • 장지근;안종명;신상배;장호정;공수철;신현관;공명선;이칠원
    • 반도체디스플레이기술학회지
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    • 제6권2호
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    • pp.19-23
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    • 2007
  • The blue emitting OLEDs using TMP-BiP[(4'-Benzoylferphenyl-4-yl)phenyl-methanone-Diethyl(biphenyl-4-ymethyl) phosphonate] host and DJNBD-1 dopant have been fabricated and characterized. In the device fabrication, 2-TNATA [4,4',4"-tris(2-naphthylphenyl-phenylamino)-triphenylamine] as a hole injection material and NPB [N,N'-bis(1-naphthyl)N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine] as a hole transport material were deposited on the ITO(indium tin oxide)/glass substrate by vacuum thermal evaporation method. Followed by the deposition, blue color emission layer was deposited using TMP-BiP as a host material and DJNBD-1 as a dopant. Finally, small molecule OLEDs with structure of $ITO/2-TNATA/NPB/TMP-BiP:DJNBD-l/Alq_3/LiF/Al$ were obtained by in-situ deposition of $Alq_3$, LiF and Al as the electron transport material, electron injection material and cathode, respectively. The effect of dopant into host material of the blue OLEDs was studied. The blue OLEDs with DJNBD-1 dopant showed that the maximum current and luminance were found to be about 34 mA and $8110\;cd/m^2$ at 11 V, respectively. In addition, the color coordinate was x=0.17, y=0.17 in CIE color chart, and the peak emission wavelength was 440 nm. The maximum current efficiency of 2.15 cd/A at 7 V was obtained in this experiment.

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균일침전법으로 제조한 플라즈마 디스플레이용 적색 형광체 (Y,Gd)$_2$O$_3$: Eu의 발광특성 (Photoluminescent properties of red phosphor (Y,Gd)$_2$O$_3$: Eu for plasma display panel synthesized by homogeneous precipitation method)

  • 김유혁;김좌연
    • 한국결정성장학회지
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    • 제10권6호
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    • pp.400-406
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    • 2000
  • 전구체인 (Y,Gd,Eu)(OH)$CO_3$.$H_2O$$900^{\circ}C$에서 열처리하여 얻은 분말을 플라즈마 디스플레이용 적색 형광체 $(Y,Gd)_2O_3$: Eu를 제조하기 위하여 이용하였다. 크기가 대략 1$\mu\textrm{m}$의 구형 형광체 $(Y,Gd)_2O_3$: Eu는 위의 분말에 소량의 융제를 첨가하여 $1350^{\circ}C$에서 2시간 소성하면 얻을 수 있다. 제조된 형광체의 발광 스펙트럼은 여기원이 254 nm와 147 nm인 파장에서 측정하였으며 최적인 활성제의 농도는 254 nm 하에서는 15 몰 %, 147 nm에서는 10 몰 %로 결정되었다. 또한 발광세기를 비교한 결과 BaCO$_3$, $AlF_3$$Li_3PO_4$$BaCO_3$가 가장 우수한 것으로 나타났다. 최적화된 형광체 $(Y,Gd)_2O_3$: Eu의 상대 휘도 및 색좌표는 상용품인 $Y_2O_3$: Eu 보다 개선되는 것으로 평가되고 있다.

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KTP 크리스탈을 이용한 PDT용 레이저 시스템 개발 (A Study on a KTP Crystal Laser System for a Cancer Using P.D.T.)

  • 김병문;남효덕;김병철
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.2
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    • pp.631-634
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    • 2004
  • The method that exists in Photodynamic Therapy uses Photosensibility drug strongly Influencing tumour accumulation together with photochemical laser effect and makes the structure of tumour be localized and become extinct. The intracavity transformation of the Nd :YAP main radiation 1079 nm was Raman converted in barium nitrate crystal and the Stokes frequency (1216 nm) was doubled using KTP or RTA crystals. The LiF or Cr:YAG crystals are used for the Q-switch. The radiation Parameters were obtained at 100 Hz pump repetition frequency. The average power at 608 nm radiation with LiF and KTP was 700 mW at multi-mode generation. The 3-6 single 10-15 ns pulses were generated during one cycle of pumping. The doubling efficiency with RTA was two times more than with KTP. The cells of Ehrlich adenocarcinoma (0.1 ml) were i.m. implanted in hind thighs of ICR white non-imbred mice. The cells were preliminarily diluted in medium 199 in the ratio of 1 to 5. HpD was intravenous administered in a dose of 10 mg/kg. The left clean-shaven hind leg was irradiated with laser light 21-27 hours after the administration of the preparation. The right non-Irradiated leg of each animal served as a control. The animals with the transplanted tumor that were not injected with HpD sewed as a control to estimate the complex effect (HpD+ irradiation). Before the administration of HpD and on 3 and 4 days after irradiation the tumor size was measured and the percent of the tumor growth inhibition was calculated. The results of animal treatments has shown high efficiency of PDT method for cancer treatment by means 0.608 m high power pulse solid state laser.

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가시광 수중 무선통신을 위한 이종접합 유기물 반도체 기반 고감도 포토트랜지스터 연구 (Photo-Transistors Based on Bulk-Heterojunction Organic Semiconductors for Underwater Visible-Light Communications)

  • 이정민;서성용;임영수;백강준
    • 한국전기전자재료학회논문지
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    • 제36권2호
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    • pp.143-150
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    • 2023
  • Underwater wireless communication is a challenging issue for realizing the smart aqua-farm and various marine activities for exploring the ocean and environmental monitoring. In comparison to acoustic and radio frequency technologies, the visible light communication is the most promising method to transmit data with a higher speed in complex underwater environments. To send data at a speedier rate, high-performance photodetectors are essentially required to receive blue and/or cyan-blue light that are transmitted from the light sources in a light-fidelity (Li-Fi) system. Here, we fabricated high-performance organic phototransistors (OPTs) based on P-type donor polymer (PTO2) and N-type acceptor small molecule (IT-4F) blend semiconductors. Bulk-heterojunction (BHJ) PTO2:IT-4F photo-active layer has a broad absorption spectrum in the range of 450~550 nm wavelength. Solution-processed OPTs showed a high photo-responsivity >1,000 mA/W, a large photo-sensitivity >103, a fast response time, and reproducible light-On/Off switching characteristics even under a weak incident light. BHJ organic semiconductors absorbed photons and generated excitons, and efficiently dissociated to electron and hole carriers at the donor-acceptor interface. Printed and flexible OPTs can be widely used as Li-Fi receivers and image sensors for underwater communication and underwater internet of things (UIoTs).

Combination of 18F-Fluorodeoxyglucose PET/CT Radiomics and Clinical Features for Predicting Epidermal Growth Factor Receptor Mutations in Lung Adenocarcinoma

  • Shen Li;Yadi Li;Min Zhao;Pengyuan Wang;Jun Xin
    • Korean Journal of Radiology
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    • 제23권9호
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    • pp.921-930
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    • 2022
  • Objective: To identify epidermal growth factor receptor (EGFR) mutations in lung adenocarcinoma based on 18F-fluorodeoxyglucose (FDG) PET/CT radiomics and clinical features and to distinguish EGFR exon 19 deletion (19 del) and exon 21 L858R missense (21 L858R) mutations using FDG PET/CT radiomics. Materials and Methods: We retrospectively analyzed 179 patients with lung adenocarcinoma. They were randomly assigned to training (n = 125) and testing (n = 54) cohorts in a 7:3 ratio. A total of 2632 radiomics features were extracted from the tumor region of interest from the PET (1316) and CT (1316) images. Six PET/CT radiomics features that remained after the feature selection step were used to calculate the radiomics model score (rad-score). Subsequently, a combined clinical and radiomics model was constructed based on sex, smoking history, tumor diameter, and rad-score. The performance of the combined model in identifying EGFR mutations was assessed using a receiver operating characteristic (ROC) curve. Furthermore, in a subsample of 99 patients, a PET/CT radiomics model for distinguishing 19 del and 21 L858R EGFR mutational subtypes was established, and its performance was evaluated. Results: The area under the ROC curve (AUROC) and accuracy of the combined clinical and PET/CT radiomics models were 0.882 and 81.6%, respectively, in the training cohort and 0.837 and 74.1%, respectively, in the testing cohort. The AUROC and accuracy of the radiomics model for distinguishing between 19 del and 21 L858R EGFR mutational subtypes were 0.708 and 66.7%, respectively, in the training cohort and 0.652 and 56.7%, respectively, in the testing cohort. Conclusion: The combined clinical and PET/CT radiomics model could identify the EGFR mutational status in lung adenocarcinoma with moderate accuracy. However, distinguishing between EGFR 19 del and 21 L858R mutational subtypes was more challenging using PET/CT radiomics.

A Low-Cost Digital PWM-Controlled LED Driver with PFC and Low Light Flicker

  • Li, Yi;Lim, Jae-Woo;Kim, Hee-Jun
    • Journal of Electrical Engineering and Technology
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    • 제10권6호
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    • pp.2334-2342
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    • 2015
  • This paper proposes an LED driving circuit with a digital controller, power factor correct (PFC) function, and low light flicker. The key topology of the proposed circuit is a conventional Flyback combined with a pre-stage. As a result, there will be less light flicker than with other one-stage PFC circuits. A digital controller, implemented using a low-cost microcontroller, dsPIC30F2020, will meet PFC and low light flicker. The experimental results validate the functionality of the proposed circuit.

CONSTANT-SIGN SOLUTIONS OF p-LAPLACIAN TYPE OPERATORS ON TIME SCALES VIA VARIATIONAL METHODS

  • Zhang, Li;Ge, Weigao
    • 대한수학회보
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    • 제49권6호
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    • pp.1131-1145
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    • 2012
  • The purpose of this paper is to use an appropriate variational framework to discuss the boundary value problem with p-Laplacian type operators $$\{({\alpha}(t,x^{\Delta}(t)))^{\Delta}-a(t){\phi}_p(x^{\sigma}(t))+f({\sigma}(t),x^{\sigma}(t))=0,\;{\Delta}-a.e.\;t{\in}I\\x^{\sigma}(0)=0,\\{\beta}_1x^{\sigma}(1)+{\beta}_2x^{\Delta}({\sigma}(1))=0,$$ where ${\beta}_1$, ${\beta}_2$ > 0, $I=[0,1]^{k^2}$, ${\alpha}({\cdot},x({\cdot}))$ is an operator of $p$-Laplacian type, $\mathbb{T}$ is a time scale. Some sufficient conditions for the existence of constant-sign solutions are obtained.

Chiral 2-Amino Alcohol Derivatives Catalyze the Enantioselective α-Chlorination of β-Ketoesters

  • Zhang, Baohua;Guo, Ruixia;Liu, Sijie;Shi, Lanxiang;Li, Xiaoyun
    • Bulletin of the Korean Chemical Society
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    • 제35권6호
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    • pp.1759-1762
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    • 2014
  • The enantioselective ${\alpha}$-chlorination of cyclic ${\beta}$-ketoesters catalyzed by chiral 2-aminoalcohol derivatives (2f) has been developed. For the optically active ${\alpha}$-chlorinated products, the isolated yields are in the range of 85-94% and the enantiomeric excesses are up to 84% ee.

Eu(III)-Pyridine Dicarboxylic Acid 착물에 관한 전기화학적 거동 및 형광분광학적 연구 (Electrochemical and Spectrofluorometric Studies of Europium(III)-Pyridine Dicarboxylic Acid Complexes)

  • 김용렬;채원석
    • 한국응용과학기술학회지
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    • 제18권1호
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    • pp.12-19
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    • 2001
  • Eu(III) exhibits one electron-transfer reduction at $E_{1/2}$ = -0.564 V(vs. Ag/AgCl) and the hypersensitive peak at 615 ㎚ corresponding to $^{5}D_{0}{\rightarrow}^{7}F_{2}$ transition in 0.1 M $LiClO_{4}$ aqueous solution. Upon the addition of 2,6-pyridine dicarboxylic acid(PDA) to the Eu(III) aqueous soultion, the reduction potential shifts negatively and the PDA, and the Eu(III)-PDA complex emits great fluorescence than free-Eu(III) ion at 615 nm. The results are interpreted in term of the electrochemical and spectrofluorometric studies.

Roof collapse of shallow tunnel in layered Hoek-Brown rock media

  • Yang, X.L.;Li, K.F.
    • Geomechanics and Engineering
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    • 제11권6호
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    • pp.867-877
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    • 2016
  • Collapse shape of tunnel roof in layered Hoek-Brown rock media is investigated within the framework of upper bound theorem. The traditional collapse mechanism for homogeneous stratum is no longer suitable for the present analysis of roof stability, and it would be necessary to propose a curve failure mode to describe the velocity discontinuity surface in layered media. What is discussed in the paper is that the failure mechanism of tunnel roofs, consisting of two different functions, is proposed for layered rock media. Then it is employed to investigate the impending roof failure. Based on the nonlinear Hoek-Brown failure criterion, the collapse volume of roof blocks are derived with the upper bound theorem and variational principle. Numerical calculations and parametric analysis are carried out to illustrate the effects of different parameters on the shape of failure mechanism, which is of overriding significance to the stability analysis of tunnel roof in layered rock media.