• Title/Summary/Keyword: 6/8 structure

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A Study on Magnetic Properties of $Ni_{1-x}Zn_{x}Fe_{2}O_{4}(0{\leq}x{\leq}1)$ Ferrrite ($Ni_{1-x}Zn_{x}Fe_{2}O_{4}(0{\leq}x{\leq}1)$ Ferrrite의 자기적 성질 연구)

  • 조익한;양재석;김응찬;강신규
    • Journal of the Korean Magnetics Society
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    • v.6 no.6
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    • pp.397-404
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    • 1996
  • The magnetic properties of $Ni_{1-x}Zn_{x}Fe_{2}O_{4}$ have been studied by X-ray diffractometry and $M\"{o}ssbauer$ Spectroscopy at room temperature. The X-ray diffraction study show that spinel structure is formed in all x, lattice constants linearly increased from $8.3111{$\AA$}~8.4184{$\AA$}({\pm}0.0003)$ with increasing x from 0 to 1, and oxygen parameter increase with increasing x. $M\"{o}ssbauer$ spectrum shows that $Ni_{1-x}Zn_{x}Fe_{2}O_{4}(x=0)$ has two antiparallel magnetic structure due to $Fe^{3+}$ octahedral site and $Fe^{3+}$ tetrahedral site. $Ni_{1-x}Zn_{x}Fe_{2}O_{4}$ with $0.2{\leq}x{\leq}0.6$ has magnetic structure of Yafet and Kittel, in particularly, specimen with x=0.6 shows relaxation effect. Specimen with $x{\geq}0.8$ show paramagnetic quadrupole splitting. The isomer shift is independent of x, but quadrupole splittings decrease with increasing x in the range of $0.8{\leq}x{\leq}1$, and nuclear magnetic fields decrease with in¬creasing x in the range of $0{\leq}x{\leq}0.6$. The magnetic properties of $Ni_{1-x}Zn_{x}Fe_{2}O_{4}$ change from ferrimagnetics to pararnagnetics with increasing x.

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Mammalian Sialyltransferase Superfamily : Structure and Function

  • Lee, Young-Choon
    • Proceedings of the Korean Society of Life Science Conference
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    • 2002.12a
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    • pp.13-19
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    • 2002
  • To elucidate the regulatory mechanism for expression of sialyl-glycoconjugates and their biological functions, ninetheen sialyltransferase cDNAs including eleven by our group or co-works have been cloned and characterized so far. The cloned sialyltransferases are classified into four families according to the carbohydrate linkages they synthesize: ${\alpha}2,3-sialyltransferase$ (ST3Gal I-VI), ${\alpha}$ 2,6-sialyltransferase (ST6Gal I), GalNAc ${\alpha}$ 2,6-sialyltransferase (ST6GalNAc I-VI), and ${\alpha}2,8-sialyltransferase$ (ST8Sia I-VI). Each of the sialyltransferase genes is differentially expressed in a tissue-, cell type-, and stage-specific manner. These enzymes differ in their substrate specificity and various biochemical parameters. However, enzymatic analysis conducted in vitro with recombinant enzyme revealed that one linkage can be synthesized by multiple enzymes. We present here an overview of structure and function of sialyltransferases performed by our group and co-works. Genomic structures and transcriptional regulation of two kinds of human sialyltransferase gene are also presented.

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Sintering Property of Ti-Te LTCC Materials with SnO Additions (SnO 첨가에 따른 Ti-Te LTCC 재료의 소결 특성)

  • Kim, Jae-Sik;Choi, Eui-Sun;Ryu, Ki-Won;Lee, Young-Hie
    • Proceedings of the KIEE Conference
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    • 2008.10a
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    • pp.169-170
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    • 2008
  • In this study, low temperature sintering property of the $0.6TiTe_3O_8-0.4MgTiO_3$ ceramics with sintering adds were investigated for LTCC application which enable to cofiring with Ag electrode. $TiTe_3O_8$ mixed with $MgTiO_3$ to improve the temperature property. In the X-ray diffraction patterns, the columbite structure of $TiTe_3O_8$ phase and ilmenite structure of $MgTiO_3$ phase were coexisted in all specimens. In the case of SnO addition, the bulk density and dielectric constant were increased but quality factor was decreased with amount of SnO additions. The TCRF of the $0.6TiTe_3O_8-0.4MgTiO_3$+xwt%SnO ceramics were shifted to negative direction. The dielectric constant, quality factor and TCRF of the $0.6TiTe_3O_8-0.4MgTiO_3$ ceramics with 2.5wt% addition of SnO sintered at $830^{\circ}C$ for 1hr were 29.86, 35,800 GHz, -0.58 ppm/$^{\circ}C$, respectively.

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Antineoplastic Natural Products and the Analogues(IX). A Review of the Series

  • Ahn, Byung-Zun;Kim, Shin-Il;Ryu, Sung-Ho;Kang, Kyu-Sang;Lee, You-Hui
    • Korean Journal of Pharmacognosy
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    • v.17 no.2
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    • pp.168-177
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    • 1986
  • Bioassay-directed isolation has yielded some cytotoxic substances against L1210 cell from the Korean traditional medicine. These include 5,2'-dihydroxy-6,7,8,6'-teramethoxyflavone $(IV,\;scutellaria\;root,\;ED_{50}\;=\;1.7\;{mu}g/ml)$, 7-geranyloxycoumarin $(XXXII,\;poncirus\;fruit,\;10.2\;{mu}g/ml) $and panaxydol $(I,\;white\;ginseng,\;0.03\;{mu}g/ml)$. IV, XXXII and their derivatives were synthesized in the purpose of in vivo tests and for observation of structure-activity relations. Among the flavone derivatives, 5,2',6'-trihydroxy-6,7,8-trimethoxy flavone (XVIII), 5-hydroxy-6,7,8-trimethoxy-6'-benzyloxyflavone (XVII) and 5,8-dihydroxy-6,7-dimethoxyflavone (X) showed the cytotoxicity which has no correlation to the flavone structures. Of the coumarins synthesized, 7,8-dihydroxycoumarin (XXVI), 6-7-dihydroxycoumarin (XXIX) and 6-hydroxy-5,7-dimethoxycoumarin (XXXI) showed considerable activities. Acetylated XXXI has moderate activity $(ED_{50}=17.2\;{mu}g/ml)$. Monobydroxycoumarins or their methyl and allyl ether were inactive. IV inhibits the growth of the solid form of S-180 by 70% at 40 mg/kg and shows T/C of 166% on the ascitic S-180 at 40 mg/kg. It strongly inhibits the activity of the membrane bounded ATPase from L1210 cell. The most cytotoxic fraction of the antitumor materials studied is the one from the trichosanthes root showing $ED_{50}=0. 0003\;{mu}g/ml$ against L1210 cell. This fraction, obtained from ethyl acetate extract, showed T/C of 130 and 135%, on ICR mice bearing S-180 and $BDF_1$ mice bearing L1210 at 10 mg/kg and 7.5 mg/kg, respectively.

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Ecological Management of Sangnim Woods in Hamyang-gun, Korea by Analysis of Ecological Structure (함양 상림의 환경생태적 구조 분석 및 생태적 관리방안1)

  • 한봉호;김종엽;조현서
    • Korean Journal of Environment and Ecology
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    • v.17 no.4
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    • pp.324-336
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    • 2004
  • This study was achieved to present ecological administration plan by analyzing vegetation structure and condition rating class(environmental damage degree) of Sangnim Woods Natural Monument in Hamyang-gun, Korea. In vegetation structure part, actual vegetation was classified by 22 patterns and Quercus serrata Carpinus tschonoskii community(31.8%), Quercus serrata community(14.6%) ranged extensively. Main plant community was 8 types, and is fractionated by 13 plant communities according to stratigraphy development degree it is Quercus serrata community, Quercus serrata Carpinus tschonoskii community, Quercus aliena community, Quercus acutissima community, Carpinus tschonoskii community, Carpinus tschonoskii Quercus serrata community, Zelkova serrata-Quercus serrata community, and Planted area with korean landscape woody plants. Age of old growth trees that diameter of breast height over 38cm was 61∼77years. In condition rating class, area of class 3 was 51,960$m^2$(32.8%), area of class 4 was 6,583$m^2$(3.5%), and area of class 5 was 4,086$m^2$(2.6%) and gross area of class 3∼6 need artificial restoration was 61,619$m^2$(38.9%). Considering actual vegetation, plant community structure, and condition rating class biotope was classified by total 14 types. While distribution area of Queens spp. old growth forest of shrub damaged(51,246$m^2$, 32.4%) and deciduous broad leaved old growth forest of simple-layer structure(19,906$m^2$, 12.6%) is large and that of deciduous broad-leaved old growth forest of multi-layer structure(2,085$m^2$, 1.3%) and Queens spp. old growth forest of multi-layer structure may have to manage with user control by administration plan for stabilization of Sangnim Woods ecosystem for long-term. Also, both vegetation of shrub damaged and simple-layer structure as negative restoration area should be restored for ecological succession and both grassland and planted area with korean woody plants as positive restoration area should be revegetated by using ecological planting model of native vegetation structure in Sangnim Woods.

[ $C_{16}H_{19}O_2N_3CuCl_2\;{\cdot}\;H_2O$ ] ($C_{16}H_{19}O_2N_3CuCl_2\;{\cdot}\;H_2O$의 결정 구조)

  • Kim Moon-Jib;Kim Young-Soo;Choi Ki-Young
    • Korean Journal of Crystallography
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    • v.15 no.2
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    • pp.99-103
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    • 2004
  • The structure of $C_{16}H_{19}O_2N_3CuCl_2\;{\cdot}\;H_2O$ has been determined by X-ray diffraction methods. The crystal system is triclinic, space group Pl, unit cell constants. $a=7.6202(9)\; \AA,\; b=8.5943(7) \AA,\; c= 8.6272(6) \AA,\; \alpha= 67.518(6)^{\circ}.\; \beta= 68.043(8)^{\circ},\; \gamma=74.370(8)^{\circ},\; V=478.89(8)\; \AA^3,\; T=295K,\; Z=1,\; D_c=1.504Mgm^{-3}$The intensity data were collected on an Enraf-Nonius CAD-4 Diffractometer with graphite monochromated $MoK\alpha$ radiation $(\alpha=0.7107\;\AA)$. The molecular structure was solved by direct method.』 and refined by full-matrix least squares to a final $R=2.47\%$ for 1659 unique observed $F_0>4\sigma(F_0)$ reflections and 234 parameters.

Crystal Structure of Ca1.29Bi0.14VO4

  • Kim, Myung-Seab;Lah, Myoung-Soo;Kim, Ho-Kun
    • Bulletin of the Korean Chemical Society
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    • v.23 no.1
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    • pp.98-102
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    • 2002
  • The structure of a single crystal, grown by a slow cooling a melt of $Ca_{1.29}Bi_{0.14}VO_4$ composition, was analyzed. The crystals belong to the rhombohedral space group R3c and the dimensions of the unit cells are a = 10.848(1)${\AA}$, c = 38.048(6)${\AA}$, V = 3877.6(8)${\AA}^3$ for the pale yellow crystal, and a = 10.857(1), c = 38.063(6)${\AA}$, V = 3885.6(8)${\AA}^3$ for the yellow crystal, respectively. Unit cell dimensions of the crystal were larger than those of the host crystal, $Ca_3(VO_4)_2$, owing to the Bi that replaced Ca in the unit cell. Ca in the unit cell formed six, eight and nine coordinated polyhedra with O atoms and Bi replacing Ca entered the eight or nine coordinated Ca sites with different crystallographic environments in the unit cell. All the V in the unit cell formed four coordinated tetrahedra with O atoms, however V-O bond lengths in the tetrahedra were different from one another.

Structure analysis of polymeric micelles using SANS (중성자 소각 산란(Small Angle Neutron Scattering)을 이용한 모델 고분자 미셀의 구조 분석)

  • Tae, Gi-Yoong
    • Journal of the Korean Vacuum Society
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    • v.14 no.3
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    • pp.115-118
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    • 2005
  • Structure analysis of model polymeric micelles, both for non-asosciative and associative cases is done by small angle neutron scattering method. Aggregation number of the hydrophobic cores and the lyotropic ordering transitions of aqueous solutions of poly(ethylene glycol)(PEG) (6 K or 10 K g/mol) end-capped with perfluoroalkyl groups $(-(CH_2)_2C_OnF_{2n+1}$ (n =6,8, or 10) are characterized. Aggregation number is mainly determined by the hydrophobe end group only, and is insensitive to polymer concentration or temperature. Also, there is no difference between non-associative micelles and associative micelles in terms of aggregation number. The model systems order into a BCC structure with increasing concentration.

A Low-power DIF Radix-4 FFT Processor for OFDM Systems Using CORDIC Algorithm (CORDIC을 이용한 OFDM용 저전력 DIF Radix-4 FFT 프로세서)

  • Jang, Young-Beom;Choi, Dong-Kyu;Kim, Do-Han
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.45 no.3
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    • pp.103-110
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    • 2008
  • In this paper, an efficient butterfly structure for 8K/2K-Point Radix-4 FFT algorithm using CORDIC(coordinate rotation digital computer) is proposed. It is shown that CORDIC can be efficiently used in twiddle factor calculation of the Radix-4 FFT algorithm. The Verilog-HDL coding results for the proposed CORDIC butterfly structure show 36.9% cell area reduction comparison with those of the conventional multiplier butterfly structure. Furthermore, the 8K/2K-point Radix-4 pipeline structure using the proposed butterfly and delay commutators is compared with other conventional structures. Implementation coding results show 11.6% cell area reduction. Due to its efficient processing scheme, the proposed FFT structure can be widely used in large size of FFT like OFDM Modem.

Meiobenthic Community Structure in Mud Flat and Sand Flat in Yeochari, Ganghwado (강화도 여차리 니질갯벌과 사질갯벌에 서식하는 중형저서동물의 군집구조)

  • Kim, Dong Sung;Min, Won Gi;Je, Jong Geel
    • Journal of Wetlands Research
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    • v.6 no.1
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    • pp.43-55
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    • 2004
  • Meiobenthic community structure was studied in intertidal mud flat and sand flat of Yeochari in Ganghwado in May and August, 1998. Sixteen groups of meiofauna were found at all study sites in the Yeochari tidal flats. Nematodes were the most dominant animal group among the meiofaunal groups as a whole. Sarcomastigophorans, harpacticoid copepods, nauplius larvae of crustaceans and ciliophorans which were also important components of the meiofaunal community. All of these five faunal groups comprised more than 90% of total meiofauna. The maximum total density of meiobenthos was $5.8{\times}10^6ind./m^2$ at the station of sand flat in August and the minimum density was $4.0{\times}10^6ind./m^2$ at same station in May. Biomass of meiobenthos was $1.5g/m^2$(May), $2.3g/m^2$(August) at mud flat and $1.7g/m^2$(May), $2.6g/m^2$(August) at sand flat. At the station of mud flat in May, the highest density was observed within 1cm in depth of upper sediment and steeply decreased increasing depth of sediment. At the sand flat station in August, the highest density was also observed within 1cm in depth of upper sediment and decreased with depth, while the concentration of the animals at the surface was not conspicuous as the mud flat. The value of N/C(nematodes/benthic harpacticoids) ratio was the highest at the station of sand flat in May and the lowest at the sand flat in August.

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