• Title/Summary/Keyword: 5 nm & 7 nm technology

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A Study on the Self-cleaning Surface Finishing Using PFOA Free Fluoric Polymer and Silica Nano-sol (PFOA Free 불소 고분자 및 실리카 나노졸을 이용한 self cleaning 표면 가공에 관한 연구)

  • Park, Sung-Min;Kwon, Il-Jun;Kim, Ran;Yeum, Jeong-Hyun;Yoon, Nam-Sik;Lee, Kyeung-Nam
    • Textile Coloration and Finishing
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    • v.21 no.6
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    • pp.1-11
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    • 2009
  • Super-hydrophobic surface, with a water contact angle greater than $150^{\circ}$, has a self cleaning effect termed 'lotus effect'. We introduced super-hydrophobicity onto aramid/rayon mixture fabric with dual-scale structure by assembling silica nano-sol. Mixture fabric was treated with silica nano-sol, fluoric polymer using various parameters such as particle size, concentration. Silica nano-sol size were measured using particle size analyzer. Morphological changes by particle size were observed using field emission scanning electron microscopy(FE-SEM), contact angle measurement equipment. The contact angle of water was about $134.0^{\circ}$, $137.0^{\circ}$, $143.0^{\circ}$, $139.5^{\circ}$ and $139.0^{\circ}$ for mixture fabric coated with 100.2nm, 313.7nm, 558.2nm, 628.5nm and 965.4nm silica nano-sol, compared with about $120.0^{\circ}$ for mixture fabric coated with fluoric polymer. When we mixed particle sizes of 100.2nm and 558.2nm by 7:3 volume ratio, the contact angle of water was about $146.2^{\circ}$. And we mixed particle sizes of 313.7nm and 558.2nm by 7:3 volume ratio, the contact angle of water was about $141.8^{\circ}$. Also we mixed particle sizes of 558.2nm and 965.4nm by 7:3 volume ratio, the best super-hydrophobicity was obtained. In this paper, we fabricated the water-repellent surfaces with various surface structures by using four types of silica nano-sol, and we found that the dual-scale structure was very important for the super-hydrophobicity.

Preparation of Resveratrol-loaded Poly($\varepsilon$-caprolactone) Nanoparticles by Oil-in-water Emulsion Solvent Evaporation Method

  • Kim, Bum-Keun;Lee, Jun-Soo;Oh, Ju-Kyoung;Park, Dong-June
    • Food Science and Biotechnology
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    • v.18 no.1
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    • pp.157-161
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    • 2009
  • Resveratrol-loaded poly($\varepsilon$-caprolactone) (PCL) nanoparticles were prepared by oil in water (O/W) emulsion solvent evaporation method. The morphology of the nanoparticles was evaluated using atomic force microscope (AFM), in which well-shaped and rigid nanoparticles were prepared. The mean particle size of nanoparticles prepared using only dichloromethane (DCM) ($523.5{\pm}36.7\;nm$) was larger than that prepared with a mixture of DCM and either ethanol (EtOH) ($494.5{\pm}29.2\;nm$) or acetone ($493.5{\pm}6.9\;nm$). The encapsulation efficiency of nanoparticles prepared only with DCM as dispersed phase ($78.3{\pm}7.7%$) was the highest of those prepared with solvent mixtures. An increase in the molecular weight of PCL led to an increase in encapsulation efficiency (from $78.3{\pm}7.7$ to $91.4{\pm}3.2%$). Pluronic F-127 produced the smallest mean size ($523.5{\pm}36.7\;nm$) with the narrowest particle size distribution. These results show that dispersed phase, molecular weight of wall materials, emulsion stabilizer could be important factors to affect the properties of nanoparticles.

Luminescence characterization of $YVO_4$: $Eu^{3+}$, $Bi^{3+}$ red phosphor by rapid microwave heating synthesis (급속 microwave 열처리 방법으로 합성한 $YVO_4$: $Eu^{3+}$, $Bi^{3+}$ 적색 형광체의 발광 특성)

  • Park, W.J.;Song, Y.H.;Moon, J.W.;Yoon, D.H.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.18 no.4
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    • pp.169-173
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    • 2008
  • $Eu^{3+}$ and $Bi^{3+}$ co-doped $YVO_4$ phosphors were produced by a microwave heating process. When the microwave heating method was synthesized,. the particle size was very small and the particles tended to agglomerate. However, as the heating time increased, the particle size increased and the agglomeration decreased. The emission spectrum exhibited a weak band for $^5D_0{\longrightarrow}^7F_1$ at 594.91 and 602.3 nm and strong sharp peaks at 616.7 and 620.0 nm due to the $^5D_0{\longrightarrow}^7F_2$ transition of $Eu^{3+}$. Microwave heating synthesis can provide a product without long time heating as well as good homogeneous distribution of activators.

Characterization of (Y,Gd) $BO_3$:Eu Phosphors Prepared by Urea Hydrolysis Method

  • Park, Jung-Min;Kim, Chang-Hae;Jung, Ha-Kyun;Park, Hee-Dong;Park, Yoon-Chang
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.792-794
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    • 2002
  • Uniform cylinder-shaped precursors for (Y,Gd)$BO_3$:Eu phosphors were prepared by urea hydrolysis reaction. After heating the precursors at lower temperature than general synthetic methods, the phosphor powders were well dispersed and held their original shapes. Their emissions under vacuum-ultraviolet (VUV) excitation appeared with the peaks at 593nm due to magnetic dipole transition from $^5D_0$ to $^7F_1$, 612nm and 627nm due to electric dipole transition from $^5D_0$ to $^7F_2$

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Experiments of a Novel Magnetic Levitation Stage for Wide Area Movements

  • Jeon, Jeong-Woo;Caraiani, Mitica;Oh, Hyeon-Seok;Kim, Sung-Shin
    • Journal of Electrical Engineering and Technology
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    • v.7 no.4
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    • pp.558-563
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    • 2012
  • In this paper, a novel planar type magnetic levitation system without other assistant devices is proposed and it can move with 6 degree of freedom (X, Y, Z, ${\theta}_X$, ${\theta}_Y$, ${\theta}_Z$) in wafer size as well as in nano scale positioning.The mover is composed with 2-D Halbach permanent magnet array and the stator is composed with $10{\times}10$ coil arrays.It was composed in laboratory and tested with short stroke (4 [mm]) and long stroke (160 [mm])movements. The errors of short movement test is [X, Y, Z, ${\theta}_X$, ${\theta}_Y$, ${\theta}_Z$]${\leq}$ [${\pm}200nm$, ${\pm}200nm$, ${\pm}250nm$, ${\pm}3urad$, ${\pm}2urad$, ${\pm}1urad$]The errors of long stroke movement test is [X, Y, Z, ${\theta}_X$, ${\theta}_Y$, ${\theta}_Z$]${\leq}$ [${\pm}200nm$, ${\pm}200nm$, ${\pm}250nm$, ${\pm}1.5urad$, ${\pm}2urad$, ${\pm}0.5urad$].

Encapsulation Method of OLED with Organic-inorganic Protective Thin Films Sealed with Flat Glass (평판 유리로 봉인된 유-무기 보호 박막을 갖는 OLED 봉지 방법)

  • Park, Min-Kyung;Ju, Sung-Hoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.5
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    • pp.381-386
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    • 2012
  • To study encapsulation method for large-area organic light emitting diodes (OLEDs), red emitting OLEDs were fabricated, on which $Alq_3$ as organic buffer layer and LiF and Al as inorganic protective layers were deposited to protect the damage of OLED by epoxy. And then the OLEDs were attached to flat glass by printing method using epoxy. The basic structure of OLED doped with rubrene of 1 vol.% as emitting layer is ITO(150 nm) / 2-TNATA(50 nm) / ${\alpha}$-NPD(30 nm) / $Alq_3$:Rubrene(30 nm) / $Alq_3$(30 nm) / LiF(0.7 nm) / Al(100 nm). In case of depositing $Alq_3$, LiF and Al and then attaching of flat glass onto OLED, current density, luminance, efficiency and driving voltage were not changed and lifetime was increased according to thickness of Al as inorganic protective layers. The lifetime of OLED/$Alq_3$/LiF/Al_4/glass structure was 139 hours increased by 15.8 times more than bare OLED of 8.8 hours and 1.6 times more than edge sealed OLED of 54.5 hours.

Generation of Femtosecond Pulses in a Passively Mode-Locked 100 MHz Cr4+:YAG Laser (수동 모드 잠금된 100 MHz Cr4+:YAG 레이저에서의 펨토초 펄스 발생)

  • Cho, Won-Bae;Rotermund Fabian;Kim, Jong-Doo;Jeon, Min-Yong;Suh, Ho-Suhng
    • Korean Journal of Optics and Photonics
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    • v.16 no.6
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    • pp.535-541
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    • 2005
  • We report on the development of a passively mode-locked near-infrared femtosecond laser with Cr:YAG crystal that operates near room temperature. The laser wavelength could easily be tuned by using only the internal prism pair over 110 nm from 1400 nm to 1510 nm in cw and over about 30 nm in mode-locked operation, respectively Maximum cw output powers of 810 mW were obtained with $1.5 \%$ output coupler for absorbed pump powers of 7.6 W. For compensation of the internal group velocity dispersion, an IR graded prism pair was used. The Cr:YAG laser delivered nearly Fourier-transform limited pulses with a pulse duration as short as 64 fs at 100 MHz repetition rate. In the mode-locked regime, the laser was operating at 1510 nm with a spectral bandwidth of 44 nm. In order to avoid unstable mode-locking and power instabilities, self-built tubes were inserted into the beam path in the resonator and purged with N2 gas. Finally, output powers of the Cr:YAG laser were optimized to 250 mW fer long time stable mode-locked operation.

Photoluminescence and Concentration Quenching Properties of BaMoO4:Tb3+ Phosphors (BaMoO4:Tb3+ 형광체의 발광과 농도 소광 특성)

  • Cho, Shinho;Kim, Jindae;Hwang, Donghyun;Cho, Seon-Woog
    • Korean Journal of Materials Research
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    • v.26 no.2
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    • pp.67-72
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    • 2016
  • $BaMoO_4:Tb^{3+}$ phosphor powders were synthesized with different concentrations of $Tb^{3+}$ ions using the solid-state reaction method. XRD patterns showed that all the phosphors, irrespective of the concentration of $Tb^{3+}$ ions, had tetragonal systems with two main (112) and (004) diffraction peaks. The excitation spectra of the $Tb^{3+}$-doped $BaMoO_4$ phosphors consisted of an intense broad band centered at 290 nm in the range of 230-330 nm and two weak bands. The former broad band corresponded to the $4f^8{\rightarrow}4f^75d^1$ transition of $Tb^{3+}$ ions; the latter two weak bands were ascribed to the $^7F_2{\rightarrow}^5D_3$ (471 nm) and $^7F_6{\rightarrow}^5D_4$ (492 nm) transitions of $Tb^{3+}$. The main emission band, when excited at 290 nm, showed a strong green band at 550 nm arising from the $^5D_4{\rightarrow}^7F_5$ transition of $Tb^{3+}$ ions. As the concentration of $Tb^{3+}$ increased from 1 to 10 mol%, the intensities of all the emission lines gradually increased, approached maxima at 10 mol% of $Tb^{3+}$ ions, and then showed a decreasing tendency with further increase in the $Tb^{3+}$ ions due to the concentration quenching effect. The critical distance between neighboring $Tb^{3+}$ ions for concentration quenching was calculated and found to be $12.3{\AA}$, which indicates that dipole-dipole interaction was the main mechanism for the concentration quenching of the $^5D_4{\rightarrow}^7F_5$ transition of $Tb^{3+}$ in the $BaMoO_4:Tb^{3+}$ phosphors.

Luminescence characteristics of bismuth and europium co-doped yttrium oxide red phosphor for white light emitting diodes (Bi와 Eu이 도핑된 yttrium oxide의 white LED용 적색 형광체 발광 특성)

  • Park, W.J.;Jung, M.K.;Yoon, S.G.;Yoon, D.H.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.16 no.3
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    • pp.112-115
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    • 2006
  • The red emission properties of $Bi^{3+}$ co-doped $Y_2O_3:Eu^{3+}$ prepared by the solid-state reaction was investigated, in order to verify its potential to act as the red emitting phosphor of white LEDs. The emission spectrum consisted of a weak band at 581, 587, 5931 and 599 nm, with maximum sharp peaks occurring at about 611 nm due to the $^5D_0{\rightarrow}^7F_2$ transition of $Eu^{3+}$, while the excitation spectrum exhibited a broad band between 290 and 430 mm with peaks occurring in the range of $310{\sim}390nm$. Also, SEM image of the sample containing 0.43 mol% $H_3BO_3$ and 2.08 mol% $BaCl_2{\cdot}2H_2O$ phosphor particles grew to achieve diameters of $700{\sim}800nm$.

Semi-analytical Numerical Analysis of the Core-size and Electric-field Intensity Dependency of the Light Emission Wavelength of CdSe/ZnS Quantum Dots

  • Lee, Honyeon
    • Journal of the Semiconductor & Display Technology
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    • v.20 no.3
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    • pp.11-17
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    • 2021
  • I performed a semi-analytical numerical analysis of the effects of core size and electric field intensity on the light emission wavelength of CdSe/ZnS quantum dots (QDs). The analysis used a quantum mechanical approach; I solved the Schrödinger equation describing the electron-hole pairs of QDs. The numerical solutions are described using a basis set composed of the eigenstates of the Schrödinger equation; they are thus equivalent to analytical solutions. This semi-analytical numerical method made it simple and reliable to evaluate the dependency of QD characteristics on the QD core size and electric field intensity. As the QD core diameter changed from 9.9 to 2.5 nm, the light emission wavelength of CdSe core-only QDs varied from 262.9 to 643.8 nm, and that of CdSe/ZnS core/shell QDs from 279.9 to 697.2 nm. On application of an electric field of 8 × 105 V/cm, the emission wavelengths of green-emitting CdSe and CdSe/ZnS QDs increased by 7.7 and 3.8 nm, respectively. This semi-analytical numerical analysis will aid the choice of QD size and material, and promote the development of improved QD light-emitting devices.