• Title/Summary/Keyword: 4IR

Search Result 3,552, Processing Time 0.031 seconds

Selective Deprotonation and Decarbonylation from Hydridocarbonyl-iridium(III) Compounds with Trimethylamine N-oxide

  • 천청식;오문현;원경식;조해연;신동찬
    • Bulletin of the Korean Chemical Society
    • /
    • v.20 no.1
    • /
    • pp.85-88
    • /
    • 1999
  • Me3NO selectively abstracts the proton from [IrH(CO)(PPh3)2L(A)]0.1+,2+ (1) (A: -CCPh, Cl-, CH3CN and L: CH3CN, Cl-, C1O4-) to give the trans-elimination products, Ir(CO)(PPh3)2(A) (2). The reductive elimination of H+ and Cl- from Ir(H)Cl2(CO)(PPh3)2 (lb) to give IrCl(CO)(PPh3)2 (2b) is first order in both lb and Me3NO. The rate law d[2b]/dt=kobs[lb]=k2[lb][Me3NO] suggests the formation of (PPh3)2(CI)2(CO)Ir-H-ON+Me3 in the rate determining step (k2) followed by the fast dissociation of both H-ON+Me3 and the trans ligand Cl-. The rate significantly varies with the cis liaand A and the trans ligand L and is slower with both A and L being Cl- than other ligands. Me3NO selectively eliminates CO from [Ir(H)2(CO)(PPh3)2L]0,+ (3) (L=CH3CN, C1O4-) to produce [Ir(H)2(PPh3)2L'(CH3CN)]+ (4) (L'=CH3CN, PPh3) in the presence of L. Me3NO does not readily remove either H+ or CO from cis, trans- and trans, trans-lr(H)(-CCPh)2(CO)(PPh3)2 and cis, trans-Ir(H)2Cl(CO)(PPh3)2. The choice whether hydridocarbonyls, 1 and 3 undergo the deprotonation or decarbonylation may be understood mostly in terms of thermodynamic stability of the products and partly by kinetic preference of Me3NO on proton and CO.

Convective Cloud RGB Product and Its Application to Tropical Cyclone Analysis Using Geostationary Satellite Observation

  • Kim, Yuha;Hong, Sungwook
    • Journal of the Korean earth science society
    • /
    • v.40 no.4
    • /
    • pp.406-413
    • /
    • 2019
  • Red-Green-Blue (RGB) imagery techniques are useful for both forecasters and public users because they are intuitively understood, have advantageous visualization, and do not lose observational information. This study presents a novel RGB convective cloud product and its application to tropical cyclone analysis using Communication, Oceanography, and Meteorology (COMS) satellite observations. The RGB convective cloud product was developed using the brightness temperature differences between WV ($6.75{\mu}m$) and IR1 ($10.8{\mu}m$), and IR2 ($12.0{\mu}m$) and IR1 ($10.8{\mu}m$) as well as the brightness temperature in the IR1 bands of the COMS, with the threshold values estimated from the Korea Meteorological Administration (KMA) radar observations and the EUMETSAT RGB recipe. To verify the accuracy of the convective cloud RGB product, the product was applied to the center positions analysis of two typhoons in 2013. Thus, the convective cloud RGB product threshold values were estimated for WV-IR1 (-20 K to 15 K), IR1 (210 K to 300 K), and IR1-IR2 (-4 K to 2 K). The product application in typhoon analysis shows relatively low bias and root mean square errors (RMSE)s of 23 and 28 km for DANAS in 2013, and 17 and 22 km for FRANCISCO in 2013, as compared to the best tracks data from the Regional Specialized Meteorological Center (RSMC) in Tokyo. Consequently, our proposed RGB convective cloud product has the advantages of high accuracy and excellent visualization for a variety of meteorological applications.

A DSP System for On-line Monitoring in Laser Welding Using a IR and UV Sensors (IR 및 UV센서를 이용한 레이저 용접시의 실시간 모니터링 DSP 시스템)

  • Yoon Choong-Sup
    • Journal of Welding and Joining
    • /
    • v.23 no.4
    • /
    • pp.53-58
    • /
    • 2005
  • We designed a weld monitoring system with UV and IR sensors using a embedded DSP controller for implementing a distribution system; running stand alone and communication with outside by industrial standard protocols. Also this system provided a USB port in order to be acquiring data in PC. The user interface program in PC visualized the IR and W data in time, frequency and state space. A correlation of IR and UV signals showed closely related to weld quality. A rapid change of geometry can be found through a moving average filter. And the average value of IR signal at an interval represented a welding width and depth. Through these results, we proposed a monitoring algorithm for a integer type DSP.

Enhanced Extraction of Traversable Region by Combining Scene Clustering with 3D World Modeling based on CCD/IR Image (CCD/IR 영상 기반의 3D 월드모델링과 클러스터링의 통합을 통한 주행영역 추출 성능 개선)

  • Kim, Jun
    • Journal of the Korea Institute of Military Science and Technology
    • /
    • v.11 no.4
    • /
    • pp.107-115
    • /
    • 2008
  • Accurate extraction of traversable region is a critical issue for autonomous navigation of unmanned ground vehicle(UGV). This paper introduces enhanced extraction of traversable region by combining scene clustering with 3D world modeling using CCD(Charge-Coupled Device)/IR(Infra Red) image. Scene clustering is developed with K-means algorithm based on CCD and IR image. 3D world modeling is developed by fusing CCD and IR stereo image. Enhanced extraction of traversable regions is obtained by combining feature of extraction with a clustering method and a geometric characteristic of terrain derived by 3D world modeling.

Fabrication of 3D Feed Horn IR Antenna for IR Detector

  • Kim, Kun-Tae;Han, Yong-Hee;Shin, Hyun-Joon;Sung Moon;Park, Jung-Ho
    • KIEE International Transactions on Electrophysics and Applications
    • /
    • v.4C no.4
    • /
    • pp.170-175
    • /
    • 2004
  • A three dimensional feed horn 10${\mu}{\textrm}{m}$ wavelength infrared antenna has been suggested, fabricated and characterized. It was applied to an infrared detector for efficient collecting of IR radiation and for reducing background noise. The horn antenna size was designed for maximum antenna directivity. The 3D feed horn antenna mold was fabricated using rotating and tilted illumination while the antenna plate was constructed by way of electroplating. Antenna characteristics were measured by coupling with a microbolometer. Measurement results indicated that the directivity of the antenna is 16.1㏈ and the background noise is reduced by approximately two times.

Pt Thickness Dependence of Oscillatory Interlayer Exchange Coupling in [CoFe/Pt/CoFe]/IrMn Multilayers with Perpendicular Anisotropy

  • Lee, Sang-Suk;Choi, Jong-Gu;Kim, Sun-Wook;Hwang, Do-Guwn;Rhee, Jang-Roh
    • Journal of Magnetics
    • /
    • v.10 no.2
    • /
    • pp.44-47
    • /
    • 2005
  • The oscillatory interlayer exchange coupling (IEC) has been shown in pinned $[CoFe/Pt(t_{pt})/CoFe]/IrMn$ multi-layers with perpendicular anisotropy. The period of oscillation corresponds to about 2 monolayers of Pt. The oscillatory behavior of IEC depending on the nonmagnetic metallic Pt thickness is thought to be related the antiferromagnetic ordering induced by IrMn layer. Oscillatory IEC as function of insulating NiO thickness has been observed in $[Pt/CoFe]_4/NiO(t_{NiO})/[CoFe/Pt]_4$ multilayers. The effect of N (number of bilayer repeats) upon the magnetic property of [Pt/CoFe]N/IrMn is also studied.

A Spatial-domain Fourier Transform Infrared Spectrometer: Application for Analyte Measurement in Cell Culture Media

  • Jung, Byung-Jo
    • Journal of the Optical Society of Korea
    • /
    • v.9 no.4
    • /
    • pp.151-156
    • /
    • 2005
  • A spatial-domain Fourier Transform (FT) infrared (IR) spectrometer coupled with a PtSi Schottky­barrier IR detector plane was developed in the spectral range of $2.0-2.5{\mu}m$ for noninvasive measurement of analyte concentrations in cell culture media during cell culture processing. A key optical component of the spectrometer is a Savart plate which is a birefringent polarizer generating coherent two rays for interfering. The spectral resolution of the spectrometer was determined as $71cm^{-1}$ (${\~}0.05{\mu}m$ at $2.5{\mu}m$). Clear IR fringe patterns were imaged on the IR detector plane. The feasibility of the spectrometer for our application was investigated by measuring absorbance spectra of glucose and fetal bovine serum (FBS) which are important compounds in cell culture media. Experiment results show that the spectral quality of glucose and FBS was comparable with the standard spectra acquired with a commercial FT-IR spectrometer, presenting the feasibility of the spectrometer to perform analyte measurement in cell culture media.

Feeding of Juvenile Purple Washington Clam, Saxidomus purpuratus (Sowerby): Effects of Algal Concentration and Temperature

  • Lee, Chang-Hoon;Choi, Yong-Suk;Bang, Jong-Deuk;Jo, Soo-Gun
    • Journal of Aquaculture
    • /
    • v.15 no.4
    • /
    • pp.253-260
    • /
    • 2002
  • To find the optimal rearing conditions for Saxidomus purpuratus juvenile, filtering activity was estimated as functions of algal concentration and temperature by measuring the rates of clearance (CR) and ingestion (IR), when S. purpuratus was feeding. The clams were fed on unialgal diet of Isochrysis galbana at 6 algal concentrations (4.6$\times$$10^4$~2.6$\times$$10^6$ cells/ml) and at 6 temperatures (5, 10, 15, 20, 25, and 30^{\circ}C ). Algal concentration significantly affected the CR and the IR at all temperatures. At lower algal concentrations, CR increased, but decreased beyond a particular concentration. The maximum CR ($CR_{max}$) at 5, 10, 15, 20, 25, and 30^{\circ}C were 0.30, 1.73, 5.95, 15.17, 21.12, and 0.33 $l/g/h$, respectively. Below the level of 5.6$\times$10$^{5}$ cells/ml, IR increased as algal concentration increased, but was saturated at higher concentrations. To maintain high growth rate of S. purpuratus, I. galbana should be supplied with more than 5.6$\times$10$^{5}$ cells/ml. The maximum IR ($IR_{max}$) at 5, 10, 15, 20, 25 and30^{\circ}C were $2.2$\times$10^8, $1.5\times$10^9, 3.4$\times$10^9, 4.9$\times$10^9, 5.3$\times$10^9, and 1.0$\times$10^8$ cells/g/h, respectively. As for temperature, both $CR_max$ and $IR_max$ increased remarkably with raising temperature from 5 to 25^{\circ}C, but rapidly decreased at 30^{\circ}C. Between 15 and 25^{\circ}C $CR_{max} and IR_{max}$ were higher and most stable, At this temperature range, the $Q_{10}/s for CR_{max} and IR_{max}$ were 3.5 and 1.6, respectively. Therefore the optimal thermal range for the juvenile is 15~$25^{\circ}C$. The annual variation in IR$_{max}$ predicted by natural seawater temperature shows that inactive period (with lower $IR_max$) lasts for 5 months (from December to April). To ensure higher growth of juvenile during this inactive period at hatcheries, rearing temperature should be elevated to $15^{\circ}C$.>.

2-Wavelength Organic Light-Emitting Diodes Using Bebq2 Selectively Doped with (pq)2Ir(acac) (Bebq2에 (pq)2Ir(acac)가 선택 도핑된 2-파장 유기발광다이오드)

  • Kim, Min-Young;Ji, Hyun-Jin;Jang, Ji-Geun
    • Korean Journal of Materials Research
    • /
    • v.21 no.4
    • /
    • pp.212-215
    • /
    • 2011
  • New organic light-emitting diodes with structure of indium-tin-oxide[ITO]/N,N'-diphenyl-N, N'-bis-[4-(phenyl-m-tolvlamino)-phenyl]-biphenyl-4,4'-diamine[DNTPD]/1,1-bis-(di-4-poly-aminophenyl) cyclohexane[TAPC]/bis(10-hydroxy-benzo(h)quinolinato)beryllium[Bebq2]/Bebq2:iridium(III)bis(2-phenylquinoline-N,C2')acetylacetonate[(pq)2Ir(acac)]/ET-137[electron transport material from SFC Co]/LiF/Al using the selective doping of 5%-(pq)2Ir(acac) in a single Bebq2 host in the two wavelength (green, orange) emitter formation were proposed and characterized. In the experiments, with a 300${\AA}$-thick undoped emitter of Bebq2, two kinds of devices with the doped emitter thicknesses of 20${\AA}$ and 40${\AA}$ in the Bebq2:(pq)2Ir(acac) were fabricated. The device with a 20${\AA}$-thick doped emitter is referred to as "D-1" and the device with a 4${\AA}$-thick doped emitter is referred to as "D-2". Under an applied voltage of 9V, the luminance of D-1 and D-2 were 7780 $cd/m^2$ and 6620 $cd/m^2$, respectively. The electroluminescent spectrum of each fabricated device showed peak emissions at the same two wavelengths: 508 nm and 596 nm. However, the relative intensity of 596 nm to 508 nm at those wavelengths was higher in the D-2 than in the D-1. The D-1 and D-2 devices showed maximum current efficiencies of 5.2 cd/A and 6.0 cd/A, and color coordinates of (0.31, 0.50) and (0.37, 0.48) on the Commission Internationale de I'Eclairage[CIE] chart, respectively.

1,4-Dicyanobutene Bridged Binuclear Iridium (I, III) Complexes and Their Catalytic Activities

  • Park, Hwa-Kun;Chin, Chong-Shik
    • Bulletin of the Korean Chemical Society
    • /
    • v.8 no.3
    • /
    • pp.185-189
    • /
    • 1987
  • Reactions of $Ir(ClO)_4(CO)(PPh_3)_2$ with dicyano olefins, cis-NCCH = CH$CH_2$$CH_2$CN (cDC1B), trans-NCCH = CH$CH_2$$CH_2$CN (tDC1B), trans-NC$CH_2$CH = CH$CH_2$CN (tDC2B), and NC$CH_2$$CH_2$$CH_2$$CH_2$CN (DCB) produce binuclear dicationic iridium (I) complexes, $[(CO)(PPh_3)_2Ir-NC-A-CN-Ir(PPh_3)_2(CO)](ClO_4)_2$ (NC-A-CN = cDC1B (1a), tDC1B (1b), tDC2B (1c), DCB (1d)). Complexes 1a-1d react with hydrogen to give binuclear dicationic tetrahydrido iridium (Ⅲ ) complexes, $[(CO)(PPh_3)_2(H)_2Ir-NC-A-CN-Ir(H)_2(PPh_3)_2(CO)](ClO_4)_2$ (NC-A-CN = cDC1B (2a), tDC1B (2b), tDC2B (2c), DCB (2d)). Complexes 2a and 2b catalyze the hydrogenation of cDC1B and tDC1B, respectively to give DCB, while the complex 2c is catalytically active for the isomerization of tDC2B to give cDC1B and tDC1B and the hydrogenation of tDC2B to give DCB at $100^{\circ}C$.