• Journal of the Korean Chemical Society
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• v.51 no.4
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• pp.339-345
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• 2007

Urea reacts with PtCl2, H2[PtCl6]·6H2O, H2[IrCl6] and Ni(CH3CO2)2 in aqueous solution at high temperature (60-80 °C) yielding [PtCl2(Urea)]·2H2O (1), (NH4)2[PtCl6] (2), (NH4)2[IrCl6]·H2O (3) and [Ni2(OH)2(NCO)2(H2O)2] (4) complexes, respectively. In complex 1, urea coordinates to Pt(II) as a neutral bidentate ligand via amido nitrogen atoms. In complexes 2, 3 and 4 it seems that the coordinated urea molecules decompose during the reaction at high temperature and a variety of reaction products are obtained. All complexes were isolated in moderate yields as dark green (1), yellow (2), pale brown (3) and faint green (4) precipitates, respectively. The reaction products were characterized by their microanalysis, IR, 1H and 13C NMR spectra as well as thermal analysis. General mechanisms describing the formation of these complexes were suggested.

• Korean Journal of Weed Science
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• v.10 no.4
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• pp.277-284
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• 1990

The response of rice (Oryza sativa L.) cultivars to mixtures of 2, 4-D(2, 4-dichlorophenoxyacetic acid) and other herbicides was investigated to determine if there was an interaction between them. When 2, 4-D was applied, shoot growth of Taipei 309 was more affected than that of IR28 at all concentrations used. In contrast, when thiobencarb (S-[(4-chlorophenyl)methyl]diethylcarbamothioate), butachlor [N-(buthoxymethyl) -2-chloro-N-(2, 6-diethylphenyl) acetamide], and glyphosate [N-(phosphonomethyl)glycine] were applied, the shoot growth of Taipei 309 was less affected than that of IR28 at all herbicide concentrations. Combination of 2, 4-D and the lowest thiobencarb concentration was antagonistic for shoot length for both cultivars, but at higher concentrations, it was synergistic. Synergism for shoot fresh weight between 2, 4-D and thiobencarb was observed with IR28 at all concentrations but, for Taipei 309, synergism was observed only at lower 2, 4-D concentrations. Mixing 2. 4-D with butachlor resulted in greater inhibition in shoot length and fresh weight of IR28 than Taipei 309 at all concentrations indicating a synergistic interaction. With combinations of 2, 4-D and glyphosate, an antagonistic interaction for shoot length was observed for both cultivars. A synergistic interaction for shoot fresh weight was observed with IR28 when combinations of the highest concentration of glyphosate and 2, 4-D were applied but there was an antagonistic interaction with Taipei 309.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.18 no.12
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• pp.2857-2863
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• 2014

IR-UWB has been developed as a standard of indoor ranging technology, because it has robust and good transmission characteristics in indoor environments and it can be operated with low power. In this paper, a IR-UWB packet analyzer is designed and implemented based on IEEE 802.15.4a, which is useful in developing IR-UWB real time location system with resolution of a few ten centimeters. A sniffer device of the packet analyzer monitors IR-UWB wireless networks, captures MAC packet frames, and transmits packet frames to the packet analyzing computer. The packet analyzing program in a computer analyzes received MAC packet frames and displays parsed packet information for developing engineers. Developed packet analyzer is used to analyze IEEE 802.15.4a MAC protocol, and also it can be used in other IEEE 802 series MAC protocol by modifying some functions.

• Bulletin of the Korean Chemical Society
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• v.16 no.6
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• pp.524-528
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• 1995

The reaction of [IrCl(cod)]2 with ppol ligand, Ph2PCH2CH2CH2P(Ph)CH2CH2CH=CH2, in ethanol gives an iridium complex, whose structure is converted from an ionic form, [Ir(cod)(ppol)]Cl·2C2H5OH (1),in polar solvents (ethanol, methanol and acetonitrile), to a molecular form, [IrCl(cod)(ppol)], in non-polar solvents (benzene and toluene). The cationic complexes, [Ir(cod)(ppol)]AsF6·1/2C2H5OH and [Ir(cod)(ppol)]PF6·1/2CH3CN, were prepared to compare with the ionic form by 31P NMR spectroscopy. When carbon monoxide is introduced to 1, cod is replaced by CO to give the 5-coordinated complex, [IrCl(CO)(ppol)]. Hydrogenation of 1-octene was not successful in the presence of 1. In order to verify the reason for 1 not behaving as a good catalyst for hydrogenation, electrophilic reactions with HCl, I2 and HBF4·etherate were performed, which yielded the oxidative addition product, [IrHCl2(ppol)], the substitution product, [IrI(cod)(ppol)], and another cationic product, [Ir(cod)(ppol)]BF4, respectively. Thus, the iridium complex is not sufficiently basic to activate hydrogen atoms or the olefin of the ppol ligand.

• Elastomers and Composites
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• v.56 no.4
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• pp.223-233
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• 2021

In this study, epoxidized liquid isoprene rubber (E-LqIR) was used as a processing aid in a silica-filled natural rubber compound to improve the fuel efficiency, abrasion resistance, and oil migration problems of truck and bus radial tire tread. The wear resistance, fuel efficiency, and extraction resistance of the compound were evaluated according to the molecular weight of E-LqIR. Results of the evaluation showed that the E-LqIR compound had a lower chemical crosslink density than that of a treated distillate aromatic extract (TDAE) oil compound because of the sulfur consumption of E-LqIR. However, the filler-rubber interaction improved because of the reaction of E-LqIR with silica and crosslink with the base rubber by sulfur. As the molecular weight of E-LqIR increased, crosslink with sulfur was facilitated, and the filler-rubber interaction improved, resulting in improved abrasion resistance. The fuel efficiency performance of the E-LqIR compound was poorer than that of the TDAE oil compound because of the low chemical crosslink density and hysteresis loss at the free chain end of E-LqIR. However, the fuel efficiency performance improved as the molecular weight of E-LqIR increased.

• Korean Journal of Agricultural Science
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• v.50 no.3
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• pp.365-371
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• 2023

This experiment was carried out to breed a medium maturing variety of Italian ryegrass (Lolium multiflorum Lam.) in Grassland and Forage Crops Division, National Institute of Animal Science, Rural Development Administration (RDA), Cheonan from 2019 to 2020. An Italian ryegrass variety, IR 604 is a tetraploid variety with green in leaf color and has half-erect growth habit in late autumn and erect growth habit in early spring, IR 604 was on May 17 in heading date as a medium maturing variety. Also, IR 604 was longer by 11 cm in flag leaf length and longer by 1.3 cm in plant height than those of the control variety, Kowinner, respectively. IR 604 was also thicker by 1.0 mm in stem thickness and strong in winter hardness. Dry matter (DM) yield (11,036 kg/ha) of IR 604 was 16.6% higher than that of Kowinner. Total digestible nutrient (TDN), crude protein (CP) and relative feed value (RFV) of IR 604 were 60.4, 13.8% and 100.6 which are 1.4, 3.3%, 7.7 higher than those of Kowinner, respectively. Acid detergent fiber (ADF) and neutral detergent fiber (NDF) of IR 604 were 35.5 and 56.7% which are 1.3 and 3.6% lower than those of Kowinner, respectively.

• Asia-Pacific Journal of Business Venturing and Entrepreneurship
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• v.9 no.4
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• pp.97-109
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• 2014

The purpose of this study is, as to verify the effect of IR announcements, the IR activity to look at the usefulness. In previous study, they found that the IR announcement leads to reductions in information asymmetry, effect to positive stock price. This study examine the abnormal returns between group by corporate characteristics. The data used in this study are daily stock market returns taken from the KOSDAQ listed company with IR announcements during the 2005-2012 year(8 year). We find that follows. First, the capital market is accepted IR activity as the positive information. Second, abnormal returns of small company is higher than big size that. We show the difference of abnormal returns between the venture company and general company, the venture company's high. The abnormal returns of corporate with high ownership is above the group of low ownership. Additionally, consider interaction by firm characteristics, we show the interaction between firm size and business type. The result of two-way ANOVA is that venture corporate with big size are more abnormal returns than others. Also, we demonstrate that firm location is the factor of difference on information effect in venture firm.

• Korean Journal of Agricultural Science
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• v.16 no.2
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• pp.129-137
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• 1989

This experiment was undertaken to clarify derivation of resistance of Tongil type of rice varieties to rice blast in Korea and to classify Tongil type of rice varieties on the basis of their rice blast reactions in th blast nursery test. 1. The resistance of Tongil, Josaengtongil, Yeongnamjosaeng, Hwanggeumbyeo, Honamjosaeng, Noupung, Milyang 21, Milyang 22, Milyang 23, Raekyung, Manseogbyeo, Yongmunbyeo and Yongjubyeo to rice blast was derived from IR 8 or IR 24. 2. The resistance of Milyang 20, Nampungbyeo and Milyang 42, and Samseongbyeo, Seogwangbyeo, Pungsanbyeo and Shingwangbyeo to the rice blast was derived from IR 946 and IR 1539, and IR 1545, respectively. 3. The resistance of Palgwangbyeo, Sujeongbyeo, Hangangchalbyeo, Baegunchalbyeo, Samgangbyeo and Weonpungbyeo, and Taebaegbyeo and Chupungbyeo, and Kayabyeo to the rice blast was derived from IR 2061(IR 29), IR 747 and IR 32, respectively. 4. Cheongcheongbyeo, and Jungweonbyeo and Namyeongbyeo, and Changseongbyeo to the rice blast was derived from IR 2035, IR 5533, and HR 2797 and HR 1671, respectively. 5. Tongil type of rice varieties was classified into Tongil group, Milyang 30 group, Baegyangbyeo group and Taebaegbyeo group.

• Transactions on Electrical and Electronic Materials
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• v.12 no.2
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• pp.80-83
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• 2011

We have fabricated phosphorescent white organic light-emitting devices (WOLEDs) with a spin-coated poly(Nvinylcarbazole) [PVK] host layer. Iridium(III) bis[(4,6-difluorophenyl)-pyridinato-N,$C^{2'}$]picolinate (FIrpic), tris(2-phenylpyridine)iridium(III) [$Ir(ppy)_3$], and tris(2-phenyl-1-quinoline)iridium(III) [$Ir(phq)_3$], were used as the blue, green, and red guest materials, respectively. The PVK was mixed with FIrpic, $Ir(ppy)_3$, and $Ir(phq)_3$ molecules in a chlorobenzene solution and spin-coated in order to prepare the emission layer; 3-(4-biphenylyl)-4-phenyl-5-(4-tertbutylphenyl)-1,2,4-triazole (TAZ) was used as an electron transport material. The resultant device structure was ITO/PVK:FIrpic:$Ir(ppy)_3:Ir(phq)_3$/TAZ/LiF/Al. The electroluminescence, efficiency, and electrical conduction characteristics of the WOLEDs based on the doped PVK host layer were investigated. The maximum current efficiency of the three wavelength WOLED with the doped PVK host was 19.2 cd/A.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.34 no.3A
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• pp.205-212
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• 2009

A novel channel estimation scheme is proposed for coherent Impulse Radio Ultra Wideband (IR-UWB) system based on IEEE 802.15.4a specification. By extracting and utilizing the information on the frequency synchronization, the proposed channel estimation algorithm improves the receiver performance even under the restricted number of preamble symbols in IEEE 802.15.4a signal format. Simulation results over the IEEE 802.15.4a channel models show the performance gain with the proposed algorithm compared to ordinary channel estimation method.