• 제목/요약/키워드: 4D Cycling

검색결과 69건 처리시간 0.023초

Effect of Pre-Cycling Rate on the Passivating Ability of Surface Films on Li4Ti5O12 Electrodes

  • Jung, Jiwon;Hah, Hoe Jin;Lee, Tae jin;Lee, Jae Gil;Lee, Jeong Beom;Kim, Jongjung;Soon, Jiyong;Ryu, Ji Heon;Kim, Jae Jeong;Oh, Seung M.
    • Journal of Electrochemical Science and Technology
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    • 제8권1호
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    • pp.15-24
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    • 2017
  • A comparative study was performed on the passivating abilities of surface films generated on lithium titanate (LTO; $Li_4Ti_5O_{12}$) electrodes during pre-cycling at two different rates. The surface film deposited at a faster pre-cycling rate (i.e., 0.5 C) is irregularly shaped and unevenly covers the LTO electrode. Owing to the incomplete coverage of the protective film, this LTO electrode exhibits poor passivating ability. Additional electrolyte decomposition and concomitant film deposition occur during subsequent charge/discharge cycles. As a result of the thick surface film, severe cell polarization occurs and eventually causes cell failure. However, pre-cycling the Li/LTO cell at a slower rate (0.1 C) improves cell polarization and capacity retention; this occurs because the surface film uniformly covers the LTO electrode and provides strong passivation. Accordingly, there is no significant film deposition during subsequent charge/discharge cycling. Additionally, self-discharge is reduced during high-temperature storage.

루비듐 5S1/2-5P3/2-4D3/2, 5/2 전이선에서의 이중공명 광펌핑 분광 (Bouble Resonance Optical Pumping in the Transition 5S1/2-5P3/2-4D3/2, 5/2 of Rb Atoms)

  • 문한섭;이림;김중복
    • 한국광학회지
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    • 제16권4호
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    • pp.297-303
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    • 2005
  • 우리는 $^{87}Rb$ 원자의 $5S_{1/2}-5P_{3/2}-4D_{3/2,\;5/2}$ 전이선을 이용하여 레이저의 세기, 편광조합, 그리고 정렬상태에 따른 이중공명광펌핑(double resonance optical pumping; DROP) 스펙트럼을 조사하였다. $5P_{3/2}-4D_{5/2}$ 전이선에서 레이저의 세기에 따른 초미세 구조간의 DROP 신호의 변화가 크게 나타났고, 그 원인은 순환전이선의 낮은 광펌핑 효율 때문이었다. 두 레이저의 편광조합을 달리 했을 때 이중공명의 전이율이 변하고, 이러한 효과가DROP스펙트럼의 변화로 나타났다. 또한 두 레이저가 같은 방향으로 진행하는 경우와 반대 방향으로 진행하는 경우를 비교했을 때, 스펙트럼의 선폭은 각각 12.2 MHz 와 6.9 MHz로 측정되었다.

Detection of Fragment Length Polymorphism of the VNTR Loci D1S80 and D2S123 by PCR Amplification, PAGE and Silver Staining

  • Nam, Hyun-Suk;Kim, Eun-Hee;Yoon, Wan-Hee;Lee, Kong-Joo
    • BMB Reports
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    • 제28권4호
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    • pp.359-362
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    • 1995
  • The highly polymorphic variable number of tandem repeat (VNTR) loci in the human genome are informative markers for the genetic characterization of individuals in the paternity test and forensic science as well as for the study of human disease. In this study, VNTR loci D1S80 and D2S123 have been amplified by PCR and the amplified length polymorphic alleles were detected with a discontinuous vertical PAGE system and silver staining. For explicit DNA typing, PCR optimization, in which amplification efficiencies are similar over a wide range of allele sizes, non-specific amplifications are minimal, and new longer alleles have high amplification efficiency, has been performed by changing the PCR reaction buffer composition and thermal cycling conditions. It turned out that adding an appropriate amount of Tween 20 and NP40 to the PCR reaction buffer and raising the annealing temperature to $68^{\circ}C$ in thermal cycling made it possible for optimal VNTR loci amplification. A modified PAGE system for VNTR separation was established. Under these conditions, new longer alleles in the 01580 locus were discovered and 025123 pattern changes in colorectal tumors were observed. These technical tips are valuable for detecting various amplified fragment length polymorphisms.

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플립 칩 BGA 솔더 접합부의 열사이클링 해석 (Thermal Cycling Analysis of Flip-Chip BGA Solder Joints)

  • 유정희;김경섭
    • 마이크로전자및패키징학회지
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    • 제10권1호
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    • pp.45-50
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    • 2003
  • 시스템 보드에 플립 칩 BGA가 실장된 3차원 유한요소 해석 모델을 구성하여 열사이클시험 과정에서 발생되는 솔더 접합부의 피로수명을 예측하였다. 피로 모델은 Darveaux의 경험식에 기초하여 비선형 점소성 해석을 수행하였다. 해석은 4종류의 열사이클시험 조건과 패드구조, 솔더 볼의 조성과 크기의 변화에 따라 발생하는 크리프 수명을 평가하였다. 해석결과 $-65∼150^{\circ}C$의 열사이클시험 조건에서 가장 짧은 피로수명을 보였으며, $0∼100^{\circ}C$ 조건과 비교하면 약 3.5 배 정도 증가하였다. 동일한 시험조건에서 패드구조 변화에 따른 피로수명 차이는 SMD구조가 NSMD구조에 비해 약 5.7% 증가하였다 결과적으로 솔더 접합부에서 크리프 변형에너지 밀도가 높으면 피로수명은 짧아지는 것을 알 수 있었다

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Experimental investigation of infilled r/c frames with eccentric openings

  • Kakaletsis, D.;Karayannis, C.
    • Structural Engineering and Mechanics
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    • 제26권3호
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    • pp.231-250
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    • 2007
  • The influence of masonry infills with eccentric openings on the seismic performance of reinforced concrete (r/c) frames that were designed in accordance with current code provisions are investigated. Eight 1/3-scale, single-story, single-bay frame specimens were tested under cyclic horizontal loading up to a drift level of 4%. In all examined cases the shear strength of columns was higher than the cracking shear strength of solid infill. The parameters investigated include the shape and the location of the opening. Assessment of the behavior of the frames is also attempted, based on the observed failure modes, strength, stiffness, ductility, energy dissipation capacity and degradation from cycling loading. Based on these results there can be deduced that masonry infills with eccentrically located openings has been proven to be beneficial to the seismic capacity of the bare r/c frames in terms of strength, stiffness, ductility and energy dissipation. The location of the opening must be as near to the edge of the infill as possible in order to provide an improvement in the performance of the infilled frame.

국내 연안 퇴적물내 PCBs(Polychlorinated Biphenyls) 오염도 현황 (Concentrations of PCBs (Polychlorinated Biphenyls) in coastal sediments of Korea)

  • 김기환;이윤
    • 환경위생공학
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    • 제11권3호
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    • pp.9-12
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    • 1996
  • Polychlorinated biphenyl (PCBs) is one of major toxic pollutants in marine environments, This artificial chlorinated compound has been found in freshwater, seawater, soil, sediments and organismes living in various environments. Because of its toxicity and degradability, its uses in industrial processes have been banned after 1984 in Korea. Coastal area is an important environment for agriculture, industry, transportation, reduction of pollution loads through biogeochemical processes, cycling of nutrients and recreation. Input of pollutants from land and freshwater has been occurring through runoff, rivers and estuaries. Concentrations of PCBs were determined with GC-ECD. Concentrations of PCBs were in the range of 1.0 - 19.2 ng/g-dry weight of sediment(g-d.w.) at Ulsan, 4.5 -8,2 ng/g-d.w. at Onsan, 2.7 - 33.5 ng/g-d.w. at Masan and 4.0 - 60.7 ng/g-d.w. in Kwangyang, In Inchon area, PCBs were not detected in sediments. In sediments of Nakdong estuary, the distribution of PCBs' concentrations was 0.19 - 303 ng/g-d.w.

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Prediction of Carcass Fat, Protein, and Energy Content from Carcass Dry Matter and Specific Gravity of Broilers

  • Wiernusz, C.J.;Park, B.C.;Teeter, R.G.
    • Asian-Australasian Journal of Animal Sciences
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    • 제12권1호
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    • pp.42-48
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    • 1999
  • Three experiments were conducted to develop and test equations for predicting carcass composition. In the first study using 52 d-old Cobb ${\times}$ Cobb male broilers, twenty four carcasses were selected from 325 processed birds based upon visual appraisal for abdominal fat (low, medium, high) and assayed for specific gravity (SG), dry matter (DM), fat, protein, and ash. In experiment 2, 120 birds were fed rations containing 2 caloric densities (2,880 and $3,200kcal\;ME_n/kg$ diet) and assayed as described above on weeks 2,3,4,5, and 6. Carcass fat was elevated (p < 0.05) with increased caloric density. In both studies predictive variables were significantly correlated with chemically determined carcass fat, protein, and ash contents. Pooled across the 2 studies, data were used to form SG, DM, and or age based equations for predicting carcass composition. Results were tested in experiment 3, where 576 birds reared to 49-d consumed either 2,880, 3,200, or $3,574kcal\;ME_n/kg$ diet while exposed to constant $24^{\circ}C$ or cycling 24 to $35^{\circ}C$ ambient temperatures. Both dietary and environmental effects impacted (p < 0.05) carcass composition. The fat content analyzed chemically was enhanced from 12.4 to 15.7%, and predicted fat was also elevated from 13.4 to 14.8% with increasing caloric density. Heat distress reduced (p < 0.05) analyzed carcass protein (18.9 vs 18.3%) and predicted protein (18.2 vs 17.5%). Predicted equation values for carcass fat, protein, ash, and energy were correlated with the chemically analyzed values at r=0.96, 0.77, 0.86, and 0.79, respectively. Results suggest that prediction equations based on DM and SG may be used to estimate carcass fat, protein, ash, and energy contents of broilers consuming diets that differ in caloric density (2,800 to $3,574kcal\;ME_n/kg$) and for broilers exposed to either constant ($24^{\circ}C$) or cycling high (24 to $35^{\circ}C$) ambient temperatures during 49-d rearing period tested in the present study.

자원순환형 소각열 이용시스템에 관한 평가 (Evaluation on Utilizing Systems of Incineration Heat as Resource cycling Type)

  • 정용현
    • 한국환경과학회지
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    • 제12권4호
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    • pp.503-510
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    • 2003
  • How to plan the energy system is one of the keys f3r constructing the Environment -Friendly City. for this reason, a great number of surveys for utilizing unused energy have conducted by a planner. In regard to unused energy, the heat from incineration plants classify as a unused energy having high-exergy-energy. From this point of view, It is studied about the plant systems providing heat to district heating & cooling(D.H.C) and producing electric power. It is divided four system models as system I (10K [kgf/cm$^2$) vapor as outlet of boiler, supply far 10K vapor and return to 60$^{\circ}C$ as supply condition of district heating), system II (30 K vapor as outlet of boiler, supply for 5t vapor and return to 60f as supply condition of district heating), system 111 (30 K vapor as outlet of boiler, supply for 85$^{\circ}C$ hot water and return to 60$^{\circ}C$ as supply condition of district heating), system IV (30 K vapor as outlet of boiler, supply for 47$^{\circ}C$ hot water and return to 40t as supply condition of district heating). The results from the upper condition of four system, System II got a proper on economical benefits and system IV calculated as benefiting on energy saving effects, and suggest indifference curve as the total evaluation method of both economical benefits and energy saving.

PdHx 박막의 광투과도 (Optical Transmittance of PdHx Thin Film)

  • 조영신
    • 한국수소및신에너지학회논문집
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    • 제12권3호
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    • pp.201-209
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    • 2001
  • The change of optical transmittance of $PdH_x$ thin film due to hydrogen concentration change was measured at room temperature. Pd film($312{\AA}$ thick) was made by thermal evaporation on glass substrate. Hydrogen absorption and desorption cycling effect on optical transmittance was measured 4 times in the pressure range between 0 and 640 torr. Ratio of optical transmittance to the change of ln pressure(torr) increases with increasing number of hydrogen A-D cyclings in the ${\beta}$ phase.

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Combination of Potassium Pentagamavunon-0 and Doxorubicin Induces Apoptosis and Cell Cycle Arrest and Inhibits Metastasis in Breast Cancer Cells

  • Putri, Herwandhani;Jenie, Riris Istighfari;Handayani, Sri;Kastian, Ria Fajarwati;Meiyanto, Edy
    • Asian Pacific Journal of Cancer Prevention
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    • 제17권5호
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    • pp.2683-2688
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    • 2016
  • A salt compound of a curcumin analogue, potassium pentagamavunon-0 (K PGV-0) has been synthesized to improve solubility of pentagamavunon-0 which has been proven to have anti-proliferative effects on several cancer cells. The purpose of this study was to investigate cytotoxic activity and metastasis inhibition by K PGV-0 alone and in combination with achemotherapeutic agent, doxorubicin (dox), in breast cancer cells. Based on MTT assay analysis, K PGV-0 showed cytotoxic activity in T47D and 4T1 cell lines with $IC_{50}$ values of $94.9{\mu}M$ and $49.0{\pm}0.2{\mu}M$, respectively. In general, K PGV-0+dox demonstrated synergistic effects and decreased cell viability up to 84.7% in T47D cells and 62.6% in 4T1 cells. Cell cycle modulation and apoptosis induction were examined by flow cytometry. K PGV-0 and K PGV-0+dox caused cell accumulation in G2/M phase and apoptosis induction. Regarding cancer metastasis, while K PGV-0 alone did not show any inhibition of 4T1 cell migration, K PGV-0+dox exerted inhibition. K PGV-0 and its combination with dox inhibited the activity of MMP-9 which has a pivotal role in extracellular matrix degradation. These results show that a combination of K PGV-0 and doxorubicin inhibits cancer cell growth through cell cycling, apoptosis induction, and inhibition of cell migration and MMP-9 activity. Therefore, K PGV-0 may have potential for development as a co-chemotherapeutic agent.