• Bulletin of the Korean Chemical Society
• /
• 제5권1호
• /
• pp.32-37
• /
• 1984

The photoreaction of 2, 3-benzo-1, 1-diphenyl (or dimethyl)-1-sila-2-cyclobutene (9 or 10) with an aldehyde or ketone results in 1:1 cycloadduct of [4 + 2] type. In the reactions of 2, 3-benzo-1, 1-dimethyl-1-sila-2-cyclobutene (10) with acetone and butanone, another 1:1 adducts (13) were also formed, respectively. The following facts indicate that the formation of adduct involves an attack of a triplet carbonyl compound on the silicon of the benzosilacyclobutene, an $S_H2$ process. (1) Even when the reaction of 9 with acetophenone was carried out under conditions such that more than 99% of incident light was absorbed only by acetophenone using the filter solution of aq. cupric sulfate, the same adduct was still formed. (2) When the reaction of 9 with acetone was carried out under oxygen atmosphere, only trace amount of adduct was formed.

• 비파괴검사학회지
• /
• 제23권4호
• /
• pp.349-355
• /
• 2003

후방복사 레일리 표면파를 사용하여 부식피로에 의한 재료손상을 평가하였다. $25^{\circ}C$, 3.5 wt.% NaCl 수용액에서 TMCP 강재에 대하여 하중의 크기를 변화시키면서 부식피로 시험을 수행하였다. 각각의 시험편에 대해서 입사각에 따른 후방복사 초음파의 진폭변화를 측정하였다. 후방복사 프로파일이 최대가 되는 입사각으로부터 레일리 표면 탄성파의 속도를 결정하였는데, 부식피로 시험에서 파손수명이 길었던 시험편에서의 표면탄성파의 속도가 더 느렸다. 이 사실은 시험편 표면에 발생한 부식손상이 주로 부식환경에 놓인 시간에 의존함을 의미한다 본 연구에서 얻어진 결과는 후방복사된 레일리 표면 탄성파가 노후 재료의 부식손상을 비파괴적으로 평가하는데 유용한 도구임을 보여주었다.

• Korean Circulation Journal
• /
• 제53권5호
• /
• pp.313-327
• /
• 2023

Background and Objectives: Pulmonary arterial hypertension (PAH) is a rare but fatal disease. Recent advances in PAH-specific drugs have improved its outcomes, although the healthcare burden of novel therapeutics may lead to a discrepancy in outcomes between developing and developed countries. We analyzed how the epidemiology and clinical features of PAH has changed through the rapidly advancing healthcare infrastructure in South Korea. Methods: PAH was defined according to a newly devised 3-component algorithm. Using a nationwide health insurance claims database, we delineated annual trends in the prevalence, incidence, medication prescription pattern, and 5-year survival of PAH in Korea. Cumulative survival and potential predictors of mortality were also assessed among 2,151 incident PAH cases. Results: Between 2002 or 2004 and 2018, the prevalence and incidence of PAH increased 75-fold (0.4 to 29.9 per million people) and 12-fold (0.5 to 6.3 per million person-years), respectively. The proportion of patients on combination PAH-specific drug therapy has also steadily increased up to 29.0% in 2018. Among 2,151 incident PAH cases (median [interquartile range] age, 50 [37-62] years; 67.2% female), the 5-year survival rate and median survival duration were 71.8% and 13.1 years, respectively. Independent predictors of mortality were age, sex, etiology of PAH, diabetes, dyslipidemia, and chronic kidney disease. Conclusions: This nationwide study delineated that the prevalence and incidence of PAH have grown rapidly in Korea since the early 2000s. The use of combination therapy has also increased, and the 5-year survival rate of PAH in Korea was similar to those in western countries.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
• /
• pp.296-296
• /
• 2014

We investigate experimentally and theoretically the splitting of surface plasmon (SP) resonance peaks under TE- and TM-polarized illumination. The SP structure at infrared wavelength is fabricated with a 2-dimensional square periodic array of circular holes penetrating through Au (gold) film. In brief, the processing steps to fabricate the SP structure are as follows. (i) A standard optical lithography was performed to produce to a periodic array of photoresist (PR) circular cylinders. (ii) After the PR pattern, e-beam evaporation was used to deposit a 50-nm thick layer of Au. (iii) A lift-off processing with acetone to remove the PR layer, leading to final structure (pitch, $p=2.2{\mu}m$; aperture size, $d=1.1{\mu}m$) as shown in Fig. 1(a). The transmission is measured using a Nicolet Fourier-transform infrared spectroscopy (FTIR) at the incident angle from $0^{\circ}$ to $36^{\circ}$ with a step of $4^{\circ}$ both in TE and TM polarization. Measured first and second order SP resonances at interface between Au and GaAs exhibit the splitting into two branches under TM-polarized light as shown in Fig. 1(b). However, as the incidence angle under TE polarization is increased, the $1^{st}$ order SP resonance peak blue-shifts slightly while the splitting of $2^{nd}$ order SP resonance peak tends to be larger (not shown here). For the purpose of understanding our experimental results qualitatively, SP resonance peak wavelengths can be calculated from momentum matching condition (black circle depicted in Fig. 2(b)), $k_{sp}=k_{\parallel}{\pm}iG_x{\pm}jG_y$, where $k_{sp}$ is the SP wavevector, $k_{\parallel}$ is the in-plane component of incident light wavevector, i and j are SP coupling order, and G is the grating momentum wavevector. Moreover, for better understanding we performed 3D full field electromagnetic simulations of SP structure using a finite integration technique (CST Microwave Studio). Fig. 1(b) shows an excellent agreement between the experimental, calculated and CST-simulated splitting of SP resonance peaks with various incidence angles under TM-polarized illumination (TE results are not shown here). The simulated z-component electric field (Ez) distribution at incident angle, $4^{\circ}$ and $16^{\circ}$ under TM polarization and at the corresponding SP resonance wavelength is shown in Fig. 1(c). The analysis and comparison of theoretical results with experiment indicates a good agreement of the splitting behavior of the surface plasmon resonance modes at oblique incidence both in TE and TM polarization.

• 대한방사선기술학회지:방사선기술과학
• /
• 제40권1호
• /
• pp.93-99
• /
• 2017

Monte Carlo 시뮬레이션을 이용하여 MV X, ${\gamma}$선에서의 선량증가 효과를 평가하였다. MCNPX code를 이용하여 ICRU 평판형(Slab) 모의피폭체를 전산모사하였으며, 입사 광자의 에너지, 선량증가 물질의 종류 및 농도에 따른 영향을 분석하였다. 선량증가 물질은 금(aurum), 가돌리늄(gadolinium), 요오드(iodine), 산화철(iron oxide)에 대해 비교 평가하였으며, 입사에너지는 선형가속기에서 발생된 4, 6, 10, 15 MV X선의 스펙트럼과 Co 60의 ${\gamma}$선원을 사용하였다. 모의피폭체 내에 7, 18, 30 mg/g 농도의 물질을 삽입하였으며, 선량증가 효과의 정량적 평가를 위해 선량증가비를 산출하였다. X선의 입사에너지가 낮을수록, 선량증가 물질의 농도가 높을수록 높은 선량증가비를 나타내었으며, 최대 선량증가비는 금 1.079, 가돌리늄 1.062, 요오드 1.049, 산화철 1.035를 보여 금, 가돌리늄, 요오드, 산화철 입자 순으로 높은 선량증가 효과를 보였다. 이러한 결과는 In-vivo, vitro 연구의 기초자료로 활용할 수 있을 것으로 사료된다.

• 한국해양환경ㆍ에너지학회지
• /
• 제12권3호
• /
• pp.188-196
• /
• 2009

본 연구에서는 천해역 파랑추산모델인 SWAN(Simulating WAves Nearshore) 모델을 이용하여 파향에 따른 낙동강 하구역의 파랑분포 수치모의를 수행하고 탁월 파향 변화에 따른 낙동강 하구역 파랑 분포 특성을 정량적으로 분석하고자 하였다. 그 결과를 요약하면 다음과 같다. 천해역인 낙동강 하구역에서의 파랑분포는 S계열의 파향이 우세한 경우 파고비가 가장 높게 분포하였으며 다음으로 SSE, SSW, SE, SW계열의 순으로 파고분포가 높은 것으로 나타났다. S 및 SSW, SSE 파향이 탁월한 경우 사주섬 전면의 극천해역까지 파랑에너지가 전달되어 높은 파고가 발생하는 것으로 나타났다. 또한 파향별 파형경사의 단면 분포 계산결과에 따르면 해저경사가 완만한 가덕도 동측해역(낙동강 하구역 남서측)에서 파고비는 0.4~0.6이었으며, 다대포 서측해역(낙동강 하구역 남동측)에서 파고비는 0.5~0.6으로서 파고비의 감소폭이 가덕도 동측해역(낙동강 하구역 남서측)보다 크게 나타났다.

• Journal of Radiation Protection and Research
• /
• 제23권1호
• /
• pp.59-63
• /
• 1998

$Mg_2SiO_4$:Tb(MSO-S) TLD의 사용에서 부정확한 선량평가의 원인이 될 수 있는 광감수성과 방향 의존성을 조사하였다. 200 lux의 형광등과 백열등 하에서 8시간씩 노출한 경우 각각 약 11 mR과 3 mR의 조사선량에 해당하는 광감수성이 나타났다 그리고 수직입사($0^{\circ}$)에 대한 ${\pm}80^{\circ}$ 의 각도로 입사하는 경우의 열형광강도 비가 MSO-S는 약 0.8, badge형의 MSO-L은 약 0.15로서 방향의존성이 비교적 크게 나타났다.

• 한국임상수의학회지
• /
• 제21권3호
• /
• pp.276-279
• /
• 2004

Ninety-nine dogs diagnosed as tracheal collapse were reviewed for 2002-2003 year at Veterinary Medical Teaching Hospital, Seoul National University with clinical records and radiographs. Dogs were ranged in age from 1 to 15 years old (average 8.23 years old) and in weight from 1.2kg to 10.3kg (average 3.3kg). The population included 58 females (6 spayed) and 41 males (8 castrated). It is highly predominant in Yorkshire terrier (64, 64.6%) followed by Pomeranian (10, 10.1 %), Poodle and Chihuahua (8, 8.1%), Maltese (4, 4.0%), mixed breed (3, 3.0%), Cocker Spaniel and Pug (1, 1.0%). The incident rate of female dogs (59%) exhibited relatively higher than that of male dogs (41%). The most prevalent occurrence location was thoracic inlet (60%) of all and carina region (15%), intrathoracic trachea (14%) and cervical trachea (11 %) showed similar rate. Conclusively, tracheal collapse was observed in completely matured or old small breed dogs, largely Yorkshire terrier, on thoracic inlet primarily regardless of gender. These tendencies were apparently similar to previous reports.

• 한국기계가공학회지
• /
• 제14권4호
• /
• pp.43-48
• /
• 2015

A focal length-correcting lens called the F-theta lens is required to compensate for the different focus on spot size due to the deflected incident laser beam. The F-theta lens was designed by the ray tracing method and fabricated by a 3D printer with polymer-based material. The designed F-theta lens is able to compensate for the focus on spot size by an incidence angle of 0 to 2 degrees. Based on the analysis of the simulation, there was almost no aberration in the $0^{\circ}C$ incidence angle, and the maximum of $50{\mu}m$ of aberration was observed at the incidence angle of $2^{\circ}$. Diffraction-encircled energy was analyzed to characterize the designed optics, and an image simulation was performed to confirm the actual image resolution.

• Journal of Photoscience
• /
• 제6권1호
• /
• pp.1-3
• /
• 1999

Solar ultraviolet-A (UV-A) irradiances indicent on a horizontal surface at Taegu of Korea during 1995-1998 were calculated with 5 min averages of measurements taken every 30 seconds by a broadband UV- A sensor. The maximum and minimum of monthly averages of daily UV-A dose were 499.37 KJ m-2 day-1 inJuly and 171.09 KJ m--2 day-1 in December for 4 years of the observation period. The maxima of daily UV-A dose and instandaneous UV-A were observed as 846.46KJ m-2 day-1 June 7, 1998 and 37.22 W m-2 at 12 : 15, July 16, 1998, respectively. Increasing trends in annual maxima of daily UV-A dose and instantaneous UV-A were averaged to 6.4% and 6.7% , respectively, per year during 1995-1998 at Taegu, Korea.