• Applied Chemistry for Engineering
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• v.9 no.4
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• pp.561-564
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• 1998

The radial distribution functions of a linear spheroidal type gas molecule $C_2H_4$ were calculated by using the Stockmayer molecular molel, which assumed the $C_2H_4$ molecule as simple quadrupolar molecule. To examine the validity of the calculated radial distribution of $C_2H_4$ gas, the density dependent pressures of $C_2H_4$ gas at several temperatures were calculated and compared with literarily known experimental pressure data of $C_2H_4$ gas. The temperatures examined was 50, 100 and $150^{\circ}C$ and the densities were up to $0.02/{\AA}^3$ (maximum pressure = 1500 atm). The radial distribution function expression used was derived by Yoon, Hacura, and Baglin (YHB) with Baker and Henderson's perturbation theory. The calculated results by a computer showed that the $C_2H_4$ pressures calculated agreed well with the experimental values within ${\pm}5%$ of error range. This indicated that the YHB radial distribution function expression is good enough to obtain various physical quantities sensitive to density such as pressure with resonable accuracy.

• Journal of KSNVE
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• v.7 no.1
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• pp.71-79
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• 1997

The objective of this study is to investigate experimentally the effect of surface conditions of the plate on the impinging jet noise. The experimental results about the spectrum, the sound pressure level and the directivity are pressented and discussed in relation with the surface conditions. Regardless of the surface conditions, the pure tones of high level are generated at the same frequency band and the overall sound power level of impinging jets is much higher than that of the free jet. However, the velocity dependence of the sound pressure level and the directivity are different between smooth surfaces and rough surfaces. The dependence of sound pressure level on the jet velocity shows that the smooth surface generates quadrupole-type sound like free jets. However, the perforated or the rough surface radiates sound power exactly proportional to the sixth power of the jet velocity, indicating that the source is fixed dipole type. The directivities of 1/3 octave band sound pressure level for both the free and impinging jet show the peak directivity at 115$^\circ$ upstream, probably due to the refraction associated with velocity gradient.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.5 no.2
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• pp.83-89
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• 1996

The objective of this study is to find experimentally the characteristics of the noise generated by the impinging jet on the normal plate, and also to compare the noise characteristics of the impinging jet with those of the free jet. The experiment is performed for the measurement of the noise specturm, the noise power, and the directivity for the free and impinging jets. From the experiment. it is found that the power of noises generated by the free jet as well as the impinging jet is proportional to the eighth power of the jet velocity through the circular converging nozzle, and that the noise power of the impinging jet is 15dB as high as one of the free jet when the plate distance is about within one to three times the nozzle diameter at the pressure ratio 1.39. The sound pressure level of the impinging jet depends upon the jet pressure and the plate distance. The plate distance with the maximum overall sound pressure level is increased with the jet pressure. The directivities with 1/3 octave band frequency for both the free jet and the impinging jet are greatly influenced by the convection effect.

• 한국전산유체공학회:학술대회논문집
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• 2008.03b
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• pp.638-641
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• 2008

Computational investigation was conducted to study the effects of the shape parameter of shroud on the performance of the outdoor unit of an air-conditioners. For this study the Design of Experiment(4-factor 3-level) was created and the an automatic program was composed using VBA to reduce the load of pre-process for CFD. The estimated mathematical equation was produced from this analysis and it was found that the gap between fan and shroud affects more heavily than the other parameters. As a result, the composition of the best parameters was verified that its flow rate was increased by 10 percents and sound pressure level was reduced by 1.2 dBA compare with the worst. And finally, a kind of Propeller fan with blades which were attached to the shroud, so-called 'ProBeller Fan' was introduced in this study.

• Journal of the Korean Magnetics Society
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• v.17 no.1
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• pp.30-33
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• 2007

The $FeIn_2S_4$ exhibits an inverse spinel which Fe ions are occupied to the octahedral(B) site, while In ions are occupied to both the tetrahedral(A) and the octahedral(B) site. The $N\'{e}el$ temperature($T_N$) is determined to be 13 K. The effective moment of $FeIn_2S_4$ found to be $5.094{\mu}_B$ from the fit of Curie-Weiss inverse susceptibility for the temperature range over $T_N$, implying angular momentum contribution. The angular momentum contribution is shown in $M\"{o}ssbauer$ spectra for the antiferromagnetic ordering region($T{\leq}\;13K$), too. A weak $Fe^{2+}(B)-S^2-Fe^{2+}(B)$ interaction is responsible for a low $N\'{e}el$ temperature($T_N$) in $FeIn_2S_4$ system. The temperature dependence of electric quadrupole interaction is explained by z-axial crystalline field energy.

• Journal of the Korean Magnetics Society
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• v.16 no.1
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• pp.6-10
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• 2006

The sulphur spinel $FeCr_{2-x}M_xS_4$(M=Ga, In) have been studied with Mossbauer spectroscopy, x-ray diffraction (XRD), and vibrating sample magnetometer. The XRB patterns for samples $FeCr_{2-x}M_xS_4$(M=Ga, In: x=0.1, 0.3) reveal a single phase, which the Ga and In ions are partially occupied to the tetrahedral (A) site. The Neel temperature for the Ga substituted samples increases from 180 to 188 K, with increase from x=0.1 to 0.3. While, it decreases from 173 to 160 K, for the In substituted samples of the x=0.1 and 0.3, respectively. The Mossbauer spectra were collected from 4.2 K to room temperature. We have analyzed the Mossbauer spectra using eight Lorentzian lines fitting method for the $FeCr_{2-x}In_xS_4$(x=0.1) at 4.2 K, yielding the 1311owing results; $H_{hf}=146.0kOe,\;{\Delta}E_Q=1.88mm/s,\;\theta=36^{\circ},\;\phi=0^{\circ},\;\eta=0.6$, and R=1.9. The Ga ions enter into the both sites octahedral (B) and tetrahedral (A), simultaneously the same amounts of Fe ions migrate from the A to the B site, this result is an agreement with XRD results, too. The ${\Delta}E_Q$ of the A and B site in Mossbauer spectra of the samples $FeCr_{2-x}Ga_xS_4$(x=0.3) are 0.83 and 2.94mm/s, respectively. While they are 0.56 and 2.36mm/s for the $FeCr_{2-x}In_xS_4$(x=0.3). It is noticeable that the ${\Delta}E_Q$ for the Ga doped samples are larger than that of the corresponding In doped samples, in spite of the larger ionic radius for In ions. The bond lengths of Cr-S, for the Ga and In doped samples (x=0.3) are found to be 2.41 and $2.43\;{\AA}$, respectively. We interpret that the larger covalence effect from the smaller bond length induces a large asymmetric charge distribution. Finally, it gives a large quadrupole interaction.

• Journal of the Korean Magnetics Society
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• v.15 no.2
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• pp.137-141
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• 2005

The CMR properties and magnetic properties of sulphospinels $Zn_xFe_{1-x}Cr_2S_4$ have been explored by X-ray diffraction, magnetoresistance measurement, and $M\ddot{o}ssbauer$ spectroscopy. The crystal structures in the range of x=0.05, 0.1, 0.2 are cubic at room temperature. Magnetoresistance measurement indicates that these system is semiconducting below about 160 K. The temperature of maximum magnetoresistance is almost consistent with Curie temperature. The Zn substitutions for Fe occur to increase the Jahn-Teller relaxation and the electric quadrupole shift. CMR properties could be explained with Jahn-Teller effect, and half-metallic electronic structure, which is different from both the double exchange interactions of manganite La-Ca-Mn-O system and the triple exchange interactions of chalcogenide $Cu_xFe_{1-x}Cr_2S_4$.

• Journal of the Korean Magnetics Society
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• v.8 no.3
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• pp.118-124
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• 1998

$Ni_{0.65}Zn_{0.35}Cu_{0.1}Fe{1.9}O_4$ has been studied with Mossbauer spectroscopy and X-ray diffraction. The crystal structure is found to be a cubic spinel with the lattice constant $a_0=8.390{\AA}$. Mossbauer spectra of $Ni_{0.65}Zn_{0.35}Cu_{0.1}Fe{1.9}O_4$ has been taken at various temperatures ranging from 12 K to 705 K. The isomer shift indicates that iron ions are ferric at tetrahedral [A] and octahedral sites [B], respectively. The Neel temperature is determined to be $T_N=705\;K$. As the temperature increases toward $T_N$ a systematic line broadening effect in the Mossbauer spectrum is observed and interpreted to originate from different temperature dependencies of the magnetic hyperfine fields at various iron sites. The quadrupole splitting just on $T_N$ is 0.41 mm/s whereas the quadrupole shift below $T_N$ vanishes. This implies that the orientation of the magnetic hyperfine field with respect to be principal axes of the electric field gradient is random.

• Journal of the Korean earth science society
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• v.28 no.7
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• pp.847-856
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• 2007

The Planetary nebula NGC 6881 displays quadrupole morphology and it also has a jet feature in its image. We investigated the line profiles of the optical region spectral emission lines, using the Hamilton Echelle Spectrograph (HES) at the Lick observatory. The HES data obtained in this study was the radiation coming from the inner region within the diameter of 4 second of arc. Expansion velocity was obtained, based on the strong emission line profiles of e.g. H, Hel, Hell, [OIII], [NII], [ArIII], [SII], and [SIII}, using the IRAF and StarLink/Dipso reduction packages. The HI recombination lines showed one single peak profile, while the He and forbidden strong lines displayed double peaks. The results of this study show that the outflow velocity of gas increases radially outwards due to the central stellar radiation pressure. It was concluded that three central rings appeared in the HST image are the result of a combined structure of bipolar cones (seen in e.g. HI lines) and a ring (seen in He, [SIII] lines) in projection.

• Journal of the Korean Magnetics Society
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• v.14 no.2
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• pp.76-82
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• 2004

Crystallographic and magnetic properties for Brownmillerite-type oxides $Ca_{1-x}$Sr$_{x}$FeO$_{2.5}$ (x = 0, 0.3, 0.5, 0.7, 1.0) were investigated using x-ray diffraction (XRD) and Mossbauer spectroscopy. Polycrystalline samples were prepared by conventional solid-state reaction method. Information on exact crystalline structures, lattice parameters, bond lengths and bond angles were obtained by refining their XRD profiles using a Rietveld method. The crystal structures were found to be all orthorhombic with space group Icmm (x = 0, 0.3) and Icmm (x = 0.5, 0.7, 1.0) The lattice parameters increased monotonically with increasing Sr concentration. Both the tetrahedral and the octahedral sites were considerably distorted and elongated along b-axis. While bond lengths and bond angles O-Fe-O tend to increase minutely with the increase of Sr content, bond angles Fe-O-Fe decreased accordingly. The Mossbauer spectra showed two sets of sharp sextets originating from ferric ions occupying the tetrahedral and the octahedral sites under the magnetic transition temperature T$_{N}$. Regardless of the compositions x, the electric quadrupole splittings were -0.3 mm/s and 0.4 mm/s for the octahedral and the tetrahedral site, respectively. Above T$_{N}$, the Mossbauer spectra showed the paramagnetic doublets whose electric quadrupole splittings were about 1.6 mm/s, irrespective of compositions x. T$_{N}$ was found to decrease monotonically with the increase of Sr concentration. Ratios of absorption area for the two sites were almost 1:1 up to as high as 0.95 T$_{N}$ for all x. The result of the Debye temperature indicated that the inter-atomic binding force for the Fe atoms in the tetrahedral site was stronger than that for the octahedral site.hedral site.