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Synthesis of $TiB_2-Al_2O_3$ Composite by Self-Propagating High Temperature Synthesis (SHS) and Its Pressureless Sintering (SHS법에 의한 $TiB_2-Al_2O_3$계 복합물의 합성 및 상압소결에 관한 연구)

  • 최상욱;조동수;김세용;남건태
    • Journal of the Korean Ceramic Society
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    • v.31 no.5
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    • pp.552-560
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    • 1994
  • A composite of TiB2-Al2O3 system was successfully prepared from a mixture of TiO2, B2O3, and Al by self-propagating high temperature synthesis (SHS) with a novel characteristic, utilizing the internal oxidation heat of aluminium metal of the mixture, instead of by a conventional technique, externally heating a mixture of Ti, B and Al2O3. From a mixture with B/Ti molar ratio of =2.0, pure two phases of TiB2 and $\alpha$-Al2O3 with good crystallinity and small, uniform sizes were formed. However, when the B/Ti molar ratio of the mixture goes to a value less than 2.0, in addition to the above main minerals, a small smounts of metastable phases such as TiB and Ti3B4 were formed. It was found that about 60%, the optimum green density of compacts gave their highest reaction rate and temperature during SHS process. TiB2-Al2O3 system composite with B/Ti molar ratio of =2.0 could be pressurelessly sintered even at 190$0^{\circ}C$ under Ar gas flows without any addition of sintering aids, showing their good properties such as 91.2% in relative density, 2750 kgf/$\textrm{mm}^2$ in Vickers hardness and 2620 kgf/$\textrm{cm}^2$ in flexural strength.

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Aqueous Chemistry of Boric Acid (보론산의 용액 화학)

  • Lee, Man Seung
    • Resources Recycling
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    • v.27 no.4
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    • pp.23-28
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    • 2018
  • Distribution data of boric acid in water is necessary to develop a hydrometallurgical process for the recovery of boron from primary and secondary resources containing boron. Boric acid exists as $B(OH)_3$ and $B(OH)_4{^-}$ when solution pH is less than 6 and higher than 12, respectively. In the solution pH range of 6-11, condensation reaction between $B(OH)_3$ and $B(OH)_4{^-}$ results in the formation of some polymers. The mole fraction of the boron polymers such as $B_3O_3(OH)_4{^-}$ and $B_4O_5(OH){_4}^{2-}$ is proportional to the concentration of boric acid.

THE EFFECT OF $HfB_{2}$ ON MAGNETIC PROPERTIES OF NANOCOMPOSITE $Fe_{2}Nd_{14}B/Fe_{3}B$ MAGNET

  • Yang, Choong-Jin;Kim, Chan-Wook;Park, Eyun-Byung
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.412-415
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    • 1995
  • By adding 1wt.% $HfB_{2}$ into $Nd_{3-4}Fe_{77-78.5}B_{18.5}$ alloys, the grain growth of $Fe_{3}B/Nd_{2}Fe_{14}B$ composite phases during annealing was found to be hindered by 40~50%. It is proposed that the addition of $HfB_{2}$ leads to the formation of fine dispersoids of $HfB_{2}$ in the $Fe_{3}B/Nd_{2}Fe_{14}B$ composite magnet. The maximum energy product($(B.H)_{max}$) as well as intrinsic coercivity($_{i}H_{c}$) for the $Nd_{3}Fe_{78.5}B_{18.5}\;+\;1wt.%\;HfB_{2}$ alloy were enhanced by more than 25% $(B.H)_{max}=10\;MGOe,\;_{i}H_{c}=2.5\;kOe)$ due to the addition of $HfB_{2}$ while remanent magntization($B_{r}$) was reduced slightly. Itis deduced that the formation of fine dispersoids will also play a role of magnetic domain pinning.

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Enhanced Exchange Coupling of $Nd_2Fe_{14}B/Fe_3B$ Magnet Via Magnetic Field Treatment

  • Choong Jin Yang;Con Byung Park
    • Journal of Magnetics
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    • v.1 no.1
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    • pp.31-36
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    • 1996
  • An externally applied magnetic field during heat treating the $Nd_2Fe_{14}B/Fe_3B$ based spring magnet was found to enhance the exchange coupling between the hard and soft magnetic grains. More than 30% increase in $M_r/M_s$ values for melt-spun $Nd_2Fe_{73.5}Co_3$$(Hf_{1-x}Ga_x)B_{18.5}$ (x=0, 0.5, 1) alloys was resulted from a uniform distribution of $Fe_3B, \alpha-Fe$ and $Nd_2Fe_{14}B$ phases, and also from a reduced grain size of those phases by 20%. The externally applied magnetic field induced a uniform distribution of fine grains. A study of Mossbauer effect also report that the enhancement of total magnetization of nanocomposite $Nd_2Fe_{14}B/Fe_3B$ alloys is attributed to an increased formation of $Fe_3$B after magnetic annealing.

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Analysis of Water Soluble Vitamin B1, B2, and B3 Contents in Korean Traditional Holiday Foods (우리나라 명절 및 제사음식에 함유된 수용성 비타민 B1, B2 및 B3의 함량 분석)

  • Kim, Gi-Ppeum;Hwang, Young-Sun;Choung, Myoung-Gun
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.46 no.8
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    • pp.944-951
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    • 2017
  • This study aimed to determine and examine the contents of vitamins $B_1$, $B_2$, and $B_3$ using the high-performance liquid chromatography method in traditional holiday foods in Korea. All analyses were under the quality control chart of vitamins $B_1$, $B_2$, and $B_3$. The z-scores for vitamins $B_1$, $B_2$, and $B_3$ were 1.3, 0.0, and 0.6, respectively, in food analysis performance assessment scheme proficiency tests assuring reliability of analytical performance. Vitamin $B_1$, $B_2$, and $B_3$ contents were analyzed in a total of 31 samples. Vitamin $B_1$, $B_2$, and $B_3$ contents ranged from 0.000 to 0.973 mg/100 g, from 0.037 to 0.264 mg/100 g, and from 0.000 to 1.223 mg/100 g in Korean traditional holiday foods, respectively. The highest contents of vitamins $B_1$, $B_2$, and $B_3$ were 0.973 mg/100 g in Yukwon-jeon, 0.264 mg/100 g in Dongtae-jeon, and 1.223 mg/100 g in Yukwon-jeon sample, respectively. However, compared to vitamins $B_2$ and $B_3$, vitamin $B_1$ was not detected, generally. Therefore, these results can be used as basic data for a food composition table and improvement of national health for Koreans.

Effect of SiO2/B2O3 ratio on Li ion conductivity of a Li2O-B2O3-SiO2 glass electrolyte

  • Kim, Young Han;Yoon, Mi Young;Lee, Eun Jung;Hwang, Hae Jin
    • Journal of Ceramic Processing Research
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    • v.13 no.spc1
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    • pp.37-41
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    • 2012
  • A lithium ion conducting borosilicate glass was fabricated by a conventional melt quenching technique from a mixture of Li2CO3, B2O3 and SiO2 powders. The Li ion conductivity of the lithium borosilicate glasses was evaluated in terms of the SiO2/B2O3 ratio. In the Li2O-B2O3-SiO2 ternary glass, the glass forming region decreases with an increasing Li2O content. At the same Li2O, the crystallization tendency of the glass samples increases with the SiO2/B2O3 ratio, resulting in a reduced glass forming region in the Li2O-B2O3-SiO2 ternary glass. The electrical conductivity moderately depends on the SiO2/B2O3 ratio in the Li2O-B2O3-SiO2 ternary glass. The conductivity of the glasses slightly increases with the SiO2/B2O3 ratio. The observed phenomenon can be explained by the modification of the glass structure as a function of the SiO2 content.

THE STUDY ON THE NOISE IN THE VESSEL -Effect of the Noise Control by the Noise Arresting Rooms- (선박소음에 관한 연구 -방음실에 의한 소음제어효과실험-)

  • PARK Jung-Hee
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.9 no.3
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    • pp.215-221
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    • 1976
  • In this study, noise arresting effect of the noise control room from the transmission of surrounding noise was tested when the packing noise control rooms were set up in the test room in which the prerecorded noise from an engine room was reradiated at the same level as the original pressure. The inner space of control room A is $3.389m^3(1.19\times1.19\times2.14m)$ having walls furnished with plywood board 9mm in thickness and noise control room door$(60\times45cm) $ and illumination lamp are placed. In case of the control room B, noise absorption board(10mm fiber board which holds the corntype concavity with diameter of 5mm, depth 5mm, space 15mm) is adhered to the internal ceiling and styrol foam boards(20mm) to the walls. The other struction is same as the control room A. Type C is the same as B except wool board(Glass Fiber, 33mm) on the walls. Type D is same as type A except that the thickness of wall is 12mm and wood pyramid type cone$(5\times5\times13cm)$ is adhered to the ceiling ana walls(Fig. 1). When the recorded noise and vibrated noise were controlled in various levels. The noise pressure which passed through the control rooms was measured by sound level meter(Bruel & Kjar 2205, measuring range 37-140dB). In order to calculate the absorption rate in the control rooms the noise pressure was measured at different distances when the recorded noise pressure was radiated. The followings are the results obtained from the experiment. 1. When the noise pressure of the test room was 60dB, transmission rate of type A was $69.7\%$ and increased $3.3\%$ per 10dB. At the same condition, the rate was $53.9\%$ and increased $4.5\%$ per 10dB in type D. Type D was the most effective in noise arresting of the four and the effect was D,C,B and A in order(Fig.2). 2. When the oscillator sound and vessels noise were radiated in 1,000Hz, at one meter distance to the type A and D, the oscillator sound pressure were 77dB and 73dB, while the vessels noise pressure were 73.3dB and 66.2dB respectivley(Fig.3). 3. Refering to the influence of the frequency to the lower oscillator sound(1,000Hz) pressure, both type C and D were almost same at 140cm but type C was 0.3dB lower than type D at 20cm distance(Fig.4).

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Performance Analysis of OFDM M-ary QAM System with One Tap Equalizer in Rummler Fading Channel (룸머 페이딩 환경 하에서 단일 탭 등화기를 사용한 OFDM M-ary QAM 시스템의 성능 분석)

  • 심재옥;김언곤
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.6 no.2
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    • pp.175-180
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    • 2002
  • In this paper, the system performace with the convolution rode using a Viterbi decoding and the one tap LMS(Least Meam Square) equalizer applied to the OFDM(Orthogonal Frequency Division Multiplexing) system, is analyzed through computer simulation. DMRS(Digital Microwave Radio System)is modeled as Rummler fading channel. In Simulation result, we known that the coding system improved about 3.6dB~10.5dB when BER is 10 $^3$and b is 0.1~0.2 in case of 16QAM(Qurdrature Amplitude Modulation). Also, we known that was improved about 19.7dB when the b is 0.1 and was demanded about 10.5dB when the b is 0.2 in case of 64QAM. we known that the soft decision improved about 2~0.9dB when the b is 0.1~0.2 in case of 16QAM and about 3.3~7.8dB in case of 64QAM. In the equalizer system, efficiency improved from the case of that Eb/No is more than 13dB.

Purification of Xylogone sphaerospora ${\beta}$-mannanase and Growth Activity of Bifidobacterium spp. by Konjac Glucomannan Hydrolysates (Xylogone sphaerospora 유래 ${\beta}$-mannanase 정제 및 Konjac Glucomannan 가수분해 올리고당의 중합도별 Bifidobacterium spp.에 대한 증식활성)

  • Lee, Hee-Jung;Park, Gwi-Gun
    • Applied Biological Chemistry
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    • v.51 no.3
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    • pp.159-163
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    • 2008
  • Xylogone sphaerospora ${\beta}$-mannanase was purified by Sephadex G-100 column chromatography. The specific activity of the purified enzyme was 8.44 units/ml protein, representing an 56.27-folds purification of the original crude extract. The final preparation thus obtained showed a single band on SDS-polyacrylamide gel electrophoresis. The molecular weight was determined to be 42kDa. Konjac glucomannan was hydrolyzed by the purified ${\beta}$-mannanase, and then the hydrolysates was separated by activated carbon column chromatography. The main hydrolysates were composed of D.P. (Degree of Polymerization) 3 and 4 glucomannooligosaccharides. For elucidate the structure of D.P 3 and 4 glucomannooligosaccharides, sequential enzymatic action was performed. D.P 3 and 4 were identified as M-G-M and M-M-G-M (G- and M- represent glucosidic and mannosidic link-ages). To investigate the effects of konjac glucomannooligosaccharides on in vitro growth of Bifido-bacterium longum, B. bifidum, B. infantis, B. adolescentis, B. animalis, B. auglutum and B. breve. Bifidobacterium spp. were cultivated individually on the modified-MRS medium containing carbon source such as D.P. 3 and D.P. 4 glucomannooligosaccharides, respectively. B. longum and B. bifidum grew up 3.9-fold and 2.8-fold more effectively by the treatment of D.P. 4 glucomannooligosaccharides, compared to those of standard MRS medium. Especially, D.P. 4 was more effective than D.P. 3 glucomannooligosaccharide on the growth of Bifidobacterium spp.

Synthesis of Histamine $H_2$-receptor antagonists - Synthesis of 5,6-dihydro[2,1-b]thiazole derivatives - (Histamine $H_2$-수용체길항제의 합성 - 5,6-Dihydroimidazo[2,1-b]thiazole 유도체의 합성 -)

  • 박상우;이강노
    • YAKHAK HOEJI
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    • v.35 no.5
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    • pp.368-371
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    • 1991
  • For the development of new antiulcer agents 5, 6-dihydroimidazo[2, 1-b]- thiazoles substituted at the 3-position are sythesized. Thus, the reaction of 3-chloromethyl-5, 6-dihydroimidazo[2, 1-b]thiazole(2) with thiourea and subsequently with 3-chloro-propionitrile gives 3-[3-[5, 6-dihydroimidazo[2, 1-b]thiazolyl]methylthio]propionitrile(4), which by partial alcoholysis with methanol is converted into methyl-3-[3-[5, 6-dihydro-imidazo[2, 1-b]thiazoyl]methylthio]propionimidate(5) . This compound(5) is treated finally with sulfamide or sulfonamides. 3-[3-[5, 6-dihydroimidazo[2, 1-b]thiazoyl]methylthiol-N$^{2}$-sulfamoyl-propionamidine(6) inhibited gastric acid secretion (45%) when administered intraduodenally (100 mg/kg) to pylorus-ligated rats.

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