• Journal of Photoscience
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• 제9권2호
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• pp.344-346
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• 2002

Eight intact bacteriochlorophyll (BChl)-d homologs and isomers were isolated from a strain of green sulfur bacterium Chlorobium vibrioforme. All the molecular structures of the BChl-d components were fully determined by a combination of mass spectrometry and $^1$H-NMR spectroscopy. The aggregation behavior of the isomerically pure BChls-d in hydrophobic organic solvents was examined with respect to the stereoisomeric configuration at the C3$^1$ position as well as the bulkiness of the C8 and C12 side-chains by using electronic- absorption spectroscopy.

• 한국통신학회논문지
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• 제25권4B호
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• pp.734-742
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• 2000

기존의 거리영상을 이용한 모델베이스기반 3차원 물체인식에서는 주로 거리영상 분할과정을 통한 면정합이나 그래프매칭 등의 방법을 이용하였으나, 이러한 방법은 인간의 인식체계와는 동떨어져 있는 경우가 대부분이다. 본 논문에서는 인간의 인식체계와 유사한 체적기반의 수퍼쿼드릭(superquadric) 물체표현과 이를 확장한 물체인식과정을 보인다. 먼저 3차원 물체에 대한 체적특성을 수퍼쿼드릭 계수를 이용한 부품기반 수퍼쿼드릭 모델(PBSM ; part-based superquadirc model) 로 기술하며, 면 특성 및 체적소간의 접합관계 등을 함께 이용하여 물체의 일부 가려짐이나 시점에 의한 비선형적인 형상변화(nonlinear shape change)에도 강건하도록 한다. 입력되는 물체로부터 추출된 수퍼쿼드릭 계수와 모델물체의 계수들간의 매칭을 거쳐 인식에 이른다. 본 논문에서는 실험결과를 통하여 이러한 병합된 방법이 임의의 기계조립 부품의 위치와 자세를 판정하고 인식하는데 유용함을 입증하였다.

• 한국정밀공학회지
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• 제24권12호
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• pp.136-142
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• 2007

Precise fabrication of three-dimensional (3D) self-standing microstructures on thin glass plates via two-photon induced polymerization (TPP) has been an important issue for innovative 3D nanodevices and microdevices. However, there are still issues remaining to be solved, such as building 3D microstructures on opaque materials via TPP and being able to implant them as functional parts onto practical systems. To settle these issues simply and effectively, we propose a contact print lithography (CPL) method using an ultraviolet (UV)-curable polymer layer. We report some of the possibilities and potential of CPL by presenting our results for transplanting 3D microstructures onto large-area substrates and also our examination of some of the effects of the process parameters on successful transplantation.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.374-375
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• 2006

Three-dimensional artificial crystals with periodicity corresponding to terahertz wave lengths were fabricated by self-assembling monosized metal spherical particles. The metal crystals were weakly sintered to utilize them as templates. The metal templates were inverted to air spheres crystal embedded in dielectric resin though infiltration and etching. The resulting resin inverted crystals clearly presented the photonic stop gaps within terahertz wave region and the frequencies of the gaps were confirmed to agree well with calculation by plane wave expansion method.

• Current Optics and Photonics
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• 제7권6호
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• pp.608-637
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• 2023

The initial motivation in colloid science and engineering was driven by the fact that colloids can serve as excellent models to study atomic and molecular behavior at the mesoscale or microscale. The thermal behaviors of actual atoms and molecules are similar to those of colloids at the mesoscale or microscale, with the primary distinction being the slower dynamics of the latter. While atoms and molecules are challenging to observe directly in situ, colloidal motions can be easily monitored in situ using simple and versatile optical microscopic imaging. This foundational approach in colloid research persisted until the 1980s, and began to be extensively implemented in optics and photonics research in the 1990s. This shift in research direction was brought by an interplay of several factors. In 1987, Yablonovitch and John modernized the concept of photonic crystals (initially conceptualized by Lord Rayleigh in 1887). Around this time, mesoscale dielectric colloids, which were predominantly in a suspended state, began to be self-assembled into three-dimensional (3D) crystals. For photonic crystals operating at optical frequencies (visible to near-infrared), mesoscale crystal units are needed. At that time, no manufacturing process could achieve this, except through colloidal self-assembly. This convergence of the thirst for advances in optics and photonics and the interest in the expanding field of colloids led to a significant shift in the research paradigm of colloids. Initially limited to polymers and ceramics, colloidal elements subsequently expanded to include semiconductors, metals, and DNA after the year 2000. As a result, the application of colloids extended beyond dielectric-based photonic crystals to encompass plasmonics, metamaterials, and metasurfaces, shaping the present field of colloidal optics and photonics. In this review we aim to introduce the research trajectory of colloidal optics and photonics over the past three decades; To elucidate the utility of colloids in photonic crystals, plasmonics, and metamaterials; And to present the challenges that must be overcome and potential research prospects for the future.

• Rapid Communication in Photoscience
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• 제3권3호
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• pp.42-47
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• 2014

Development of molecular and supramolecular systems showing efficient photoinduced energy or electron transfer are of current research interest due to their applications in various chemical and biological processes. Various polypyridine metal complexes including Ru(II), Ru(III), Os(II), Pt(II), Fe(II), Re(I), Ir(III) and so on as a metal center introduce for expanding some more understanding of molecular-scale photoelectronics. Their complexes are concisely classified by the types of relay ligands as follows; (a) metal-direct ligand-metal system; dinuclear or trinuclear systems, (b) metal-nonconjugated ligand-metal system and metal-nonconjugated ligand system having flexible/rigid ligand, (c) metal-conjugated ligand-metal system, and (d) conjugated ligand-metal-conjugated ligand system and metal-self assembly ligand-metal system. It is pointed out that the role played by the relay ligands is important in constructing the metal complexes.

• 한국항공우주학회지
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• 제35권11호
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• pp.1036-1042
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• 2007

비행조종컴퓨터 하드웨어 개발은 상용 툴 및 전용 개발치구가 전무하여 전 근대적인 방법으로 개발하고 있어 개발 기간을 단축하기가 용이하지 않다. 모델링 및 시뮬레이션과 가상현실 기술을 이용하여 비행조종컴퓨터 하드웨어 개발에 적용하는 프로세스 개선 툴이 필요하게 되었다. 본 논문에서는 비행조종컴퓨터 입/출력 신호 흐름, 입력 신호의 고장모니터 및 고장 관리 알고리즘, 논리 회로의 작동, 회로기판 조립체의 형상 및 장착 등과 같은 비행조종컴퓨터의 설계특성을 가상의 공간에 시각화 하고 모사할 수 있는 프로세스 개선 툴을 제안한다. 프로세스 개선 툴 사용자는 open flight format의 3차원 모델링 데이터를 이용하여 구성된 비행조종컴퓨터 모델을 사용하여 회로기판 조립체까지 분해/조립을 할 수 있으며 다양한 비행조종컴퓨터 설계 형상을 시뮬레이션 할 수 있다.

• Bulletin of the Korean Chemical Society
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• 제26권3호
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• pp.418-422
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• 2005

By introducing spin-coating method to the evaporation induced self-assembly (EISA) process, a simple and reproducible route in controlling the mesophase of silica thin films has been developed for the first time in this work. When a comparatively solvent-rich Si-sol (The atomic ratio of TEOS : F127 : HCl : $H_2O$ : EtOH = 1 : 0.006 : 0.2 : 9.2 : 30) was used as coating solution, the mesophase of resultant silica films was selectively controlled by adjusting the spin-on speed. The cubic mesophase has been obtained from the coating at a low rpm, such as 600 rpm, while the 2-D hexagonal mesophase is formed at a high rpm, such as 2,500 rpm. At a medium coating speed, a mixture of cubic and hexagonal mesophase has been found in the fabricated films. The present results confirm that the evaporation rate of volatile components at initial step is critical for the determination of mesopore structures during the EISA process.

• 한국재료학회지
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• 제27권10호
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• pp.534-543
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• 2017

$Gd_2O_3:Eu^{3+}$ red phosphors were prepared by template method from crystalline cellulose impregnated by metal salt. The crystallite size and photoluminescence(PL) property of $Gd_2O_3:Eu^{3+}$ red phosphors were controlled by varying the calcination temperature and $Eu^{3+}$ mol ratio. The nano dispersion of $Gd_2O_3:Eu^{3+}$ was also conducted with a bead mill wet process. Dependent on the time of bead milling, $Gd_2O_3:Eu^{3+}$ nanosol of around 100 nm (median particle size : $D_{50}$) was produced. As the bead milling process proceeded, the luminescent efficiency decreased due to the low crystallinity of the $Gd_2O_3:Eu^{3+}$ nanoparticles. In spite of the low PL property of $Gd_2O_3:Eu^{3+}$ nanosol, it was observed that the photoluminescent property was recovered after re-calcination. In addition, in the dispersed nanosol treated at $85^{\circ}C$, a self assembly phenomenon between particles appeared, and the particles changed from spherical to rod-shaped. These results indicate that particle growth occurs due to mutual assembly of $Gd(OH)_3$ particles, which is the hydration of $Gd_2O_3$ particles, in aqueous solvent at $85^{\circ}C$.

• International Journal of Oral Biology
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• 제31권3호
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• pp.93-98
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• 2006

Biosynthetic processing of fibrillar procollagens is essential for producing mature collagen monomers that polymerize into fibrils by a self-assembly process. The metalloproteinase ADAMTS-2 is the major enzyme that processes the N-propeptide of type I procollagen in the skin and also of type II and type III procollagens. Mutations in the ADAMTS-2 gene cause dermatospraxis in animals and Ehlers-Danlos syndrome VIIC in humans, both of which are characterized by the accumulation of type I pN-collagen and the formation of abnormal collagen fibrils in the skin. Despite its importance in procollagen processing, little is known about the regulation of ADAMTS-2 expression. Here, we demonstrate that ADAMTS-2 can be regulated by 1,25-dihydroxyvitamin D3, an inducer of type I procollagen synthesis. This steroid hormone induced ADAMTS-2 mRNA ${\sim}3-fold$ in MG-63 human osteosarcoma cells and MC3T3-E1 murine osteoblastic cells. This induction was dose- and time-dependent in MG-63 cells. In contrast, secreted ADAMTS-2 protein was increased only 1.4-fold with 1,25-dihydroxyvitamin D3. Finally, 1,25-dihydroxyvitamin D3 in the presence of ascorbate increased levels of secreted ADAMTS-2 1.9-fold over ascorbate treatment alone, which did not appreciably change ADAMTS-2 expression. These data indicate that the regulation of ADAMTS-2 is coupled with the synthesis of type I procollagen through 1,25-dihydroxyvitamin D3 signaling and may involve translational or posttranslational control.