• Title/Summary/Keyword: 3D Reactor Kinetics

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A Study on the Treatment of a High-Strength Organic Wastewater by the Tube Type Fixed Biofilter Process (엔통형 고정상 생물막법에 의한 고농도 유기성 폐수처리에 관한 연구)

  • 손종렬;장명배;문경환
    • Journal of Environmental Health Sciences
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    • v.20 no.2
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    • pp.22-27
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    • 1994
  • This study is to discuss the factors influenced on the removal efficiency of a high-strength organic wastewaters investigated using the polypropyrene media which appropriate to attach microorganism in the tube type fixed biofilter reactor. The results obtained in the experiment were as follows: 1. The kinetics of reaction rate (k') were 0.125, 0.135, 0.155 varing initial COD 720, 1280, 1630 mg/l in batch reactor. 2. In the range of pH 4.0 ~12.0 was obtained the removal efficiency of COD higher than 85%. It was proved that variation of pH (4.0 ~12.0) was nothing to do with the removal efficiency of substrate in continuous reactor. 3. Temperature to obtain removal efficiency of COD higher than 85% was 10 ~ 40$\circ$C. Removal efficiency of COD was no less than those at high temperature. 4. In the continuous reactor, the volumetric loading of COD for removal efficiency higher than 95% had to be 0.5~1.5 kg COD/m$^3$.d below. And then the HRT was 8 hrs. 5. In comparison with the activated sludge process, the tube type fixed biofilter process was excellent in removal efficiency of substrate and sludge production rate.

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Biological Treatment of Ethylene Glycol in Polyester Weight-Loss Wastewater Using Jet-Loop Reactor (Jet-Loop Reactor를 이용한 Polyester 감량폐수중 Ethylene Glycol의 생물학적 처리)

  • 류원률;최장승;조무환
    • KSBB Journal
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    • v.14 no.1
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    • pp.119-123
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    • 1999
  • A jet-loop reactor was used for the biological treatment of ethylene glycol(EG) which is a main component of polyester weight-loss wastewater, and is difficult to be removed by physicochemical treatments. Volumetric oxygen coefficient(kLa) of jet-loop reactor was significantly larfgeer that of air-lift reactor. When organic loading rates of synthetic polyester weight-loss wastewater were 2.64 $kgOD_{Mn}/m^3$.day and 3.07 $kgCOD_{Cr}/m^3$.day, the effluent concentrations were measured as 154 $mgCOD_{Mn}/L$ and 156$mgCOD_{Cr}/L$, and removal efficiencies were found as 93%and 93.6%, respectively. The specific removal rate was proportionally increased from 0.25 to 1.60 $kgCOD_{Mn}$-removed/kgMLVSS.day as specific loading rate was increased from 0.25 to 1.72 $kgCOD_{Mn}$/kgMLVSS.day. Also, kinetics constants such as $K_s$, k, $K_d$, and Y were estimated as 89 mg/L, $0.05 hr^{-1}$, 0.1$day^{-1}$ and 0.78 respectively. When the organic loading rates of real polyester weight-loss wastewater were 2.64 $kgOD_{Mn}/m^3$. and 5.24 $kgCOD_{Cr}/m^3$. day, the effluent concentrations were measured as 150 $mgCOD_{Mn}$/L, and 306 $mgCOD_{Cr}$/L, and removal efficiencies were found as 93.2% and 93%, respectively. This study demonstrated that EG in the wastewater could be efficiently removed biologically using a jet-loop reactor.

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Simulation for the Flowing Water Purification with Spring Shape Inside Chamber (챔버 내측에 스프링형상을 갖는 유수형 자외선 살균장치 시뮬레이션)

  • Jung, Byung-Gyeon;Jeong, Byeong-Ho;Lee, Jin-Jong;Jung, Byeong-Soo
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.59 no.4
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    • pp.411-416
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    • 2010
  • Interest in application of ultraviolet light technology for primary disinfection of potable water in drinking water treatment plants has increased significantly in recent years. The efficacy of disinfection processes in water purification systems is governed by several key factors, including reactor hydraulics, disinfectant chemistry, and microbial inactivation kinetics. The objective of this work was to develop a computational fluid dynamics(CFD) model to predict velocity fields, mass transport, chlorine decay, and microbial inactivation in a continuous flow reactor. In this paper, It describe the how to design optimal UV disinfection device for ground water, BWT and rainwater. Spring shape instrument silver coated located in inner side of disinfection chamber. It make lead the active flowing movement target water and maximize disinfection performance. To search the optimal design method, it was performed computer simulation with 3D-CFD discrete ordinates model and manufactured prototype. Using proposed design method, performed simulation and proved satisfied performance.

Simulation Method for the Flowing Water Purification with UV Lamp (자외선램프을 이용한 유수처리장치 설계 시뮬레이션)

  • Jeong, Byeong-Ho;Lee, Kang-Yeon
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.23 no.9
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    • pp.17-23
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    • 2009
  • Interest in application of ultraviolet light technology for primary disinfection of potable water in drinking water treatment plants has increased significantly in recent years. The efficacy of disinfection processes in water purification systems is governed by several key factors, including reactor hydraulics, disinfectant chemistry, and microbial inactivation kinetics. The objective of this work was to develop a computational fluid dynamics(CFD) model to predict velocity fields, mass transport, chlorine decay, and microbial inactivation in a continuous flow reactor. The CFD model was also used to evaluate disinfection efficiency in alternative reactor designs. In a typical operation, water enters the inlet of a UV lamp and flows through the annular space between the quartz sleeve and the outside chamber wall. The irradiated water leaves through the outlet nozzle. In this paper, it describe the how to design optimal ultraviolet disinfection device for ground water and rainwater. To search the optimal design method, it was performed computer simulation with 3D-CFD discrete ordinates model and manufactured prototype. Using proposed design method, performed simulation and proved satisfied performance.

Effect of Benzene, Acetone, and Methyl Mercaptan Vapor on Photocatalytic Decomposition of Toluene Vapor (톨루엔의 광촉매 분해시 벤젠, 아세톤 및 메틸메르캅탄 증기가 미치는 영향)

  • Kam, Sang-Kyu;Jeon, Jin-Woo;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.23 no.12
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    • pp.1971-1976
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    • 2014
  • In this study, the photocatalytic decomposition characteristics of single toluene, toluene mixed with benzene, toluene mixed with acetone, and toluene mixed methyl mercaptan (MM) by UV reactor installed with $TiO_2$-coated perforated plate were studied. The photocatalytic decomposition rate of single toluene, toluene mixed with benzene, toluene mixed with acetone, and toluene mixed with MM fitted well on Langmuir-Hinshelwood (L-H) kinetics equation. The maximum elimination capacity was obtained to be $628g/m^3{\cdot}d$ for single toluene, $499g/m^3{\cdot}d$ for toluene mixed with benzene, $318g/m^3{\cdot}d$ for toluene mixed with acetone, and $513g/m^3{\cdot}d$ for toluene mixed with MM, respectively. The negative effect in photocatalytic decomposition of toluene are found to be in the order of acetone>benzene>MM.

A Fundamental Study on the Methane Conversion of Agriculture, Forestry and Fisheries Wastes (농·축 ·수산 폐기물의 메탄전환에 관한 기초연구)

  • Hong, Soon-Seok;Park, Sang-Jeon;Hong, Chong-Joon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.6 no.1
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    • pp.31-42
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    • 1998
  • A fundamental study on methane conversion for the collection organic wastes of agriculture, forestry and fishers was performed in a laboratory scale. As a result, selected Run B sample were obtained 18.41 C/N Ratio and 168.96 mg/L TCOD; Under the biochemical methane potential test, theoretical and actual methane generation was 313.6 mg/L VS added and 234.2 mg/L VS added, respectively; However, methane conversion from Run B were occurred 74% by anaerobic digestion. By the first order reaction kinetics, kinetic constant were $0.2476d^{-1}$ for Run B. Three steps fill-up filter reactor was evaluated methane content 16% up to promote than blank reactor; TCOD and SCOD have reduced 44.7% and 44.2%, respectively.

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The effect of HRT, current density, and packing ratio on nitrate nitrogen removal efficiency and current efficiency in BRM-BER (고정상 담체를 충진한 BER에서 HRT, 전류밀도 및 담체 충진율 변화가 질산성 질소 제거효율과 전류이용효율에 미치는 영향)

  • Whang, Gye-Dae;Lee, Sang-Keun;Sung, Hae-Chang
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.4
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    • pp.433-442
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    • 2010
  • BER at different packing ratios of bio-ring media(BRM) was tested to investigate the effect of varying hydraulic retention time (HRT) and current density on the nitrate removal and current efficiency. In the preliminary batch mode experiment of BERs, current density was applied at 2.0 A/$m^2$, 4.0 A/$m^2$, 4.8 A/$m^2$, which correspond to the designation of reactor #1, #2, #3, respectively. The reactor #2 showed a highest nitrate removal rate of 162.0 mg $NO_3{^-}$-N/L/d, and the kinetics of nitrate removal rate was defined as the Zero order reaction. In the primary experiment of BERs, four BERs packed with BRM were operated in varying HRT and current, and the packing ratios of reactor #1, #2, #3 and #4 were 0%, 8%, 16%, 24%. respectively. This results of the experiments indicated that the nitrate removal rate and current efficiency were increased significantly cause of growing of autotrophic denitrification microorganisms on the surface of cathode and media by increasing of the current density and decreasing of HRT. However, The decreasing of nitrate removal rate and current efficiencies were observed in the condition of HRT of 5.25 hr and 4.8 A/$m^2$ of current density. With more increasing current density and decreasing of HRT, the hydrogen inhibition occurred at the surface of cathode. Moreover, nitrate removal rate by autotrophic denitrification microorganisms attached on the media surface was observed to be limited by no longer increasing dissolved hydrogen concentration of each reactor. In conclusion, the highest nitrate nitrogen removal and current efficiency could be achieved when the BER was operated at the conditions of 7 hr HRT, current density of 4.0 A/$m^2$, and 16% packing ratio. And it was found that the amount of nitrate removal by microorganisms attached on the surface of cathode and media (BRM) was 178.2 mg/L and 52.2 mg/L respectively. and the amount of nitrate removal per MLVSS was 0.435 g $NO_3{^-}$-N/g $MLVSS{\cdot}d$ and 0.336 $NO_3{^-}$-N/g $MLVSS{\cdot}d$.

The Kinetics of Radical Copolyerization of ${\alpha}$-Methylstyrene with Acrylonitrile in a CSTR (연속반응기에서 ${\alpha}$-Methylstyrene과 Acrylonitrile 라디칼 공중합 속도론)

  • Kim, Nam-Seok;Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.19 no.1
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    • pp.33-42
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    • 2002
  • Copolymerization of ${\alpha}$-Methylstyrene(AMS) with Acrylonitrile(AN) was carried out with benzoylperoxide(BPO) as an initiator in toluene at $80^{\circ}C$ in a continuous stirred tank reactor. Reaction volume and residence time were 0.6 liters and 3 hours, respectively. The monomer reactivity ratios, $r_{AMS}$ and $r_{AN}$ determined by both the Kele$T{\"{u}}d\"{o}s$ method and the Fineman-Ross method were $r_{AMS}$=0.16(0.14), $r_{AN}$=0.04(0.06). The cross-termination factor ${\Phi}$ of the copolymer over the entire AMS composition ranged from 0.75 to 0.92. The ${\Phi}$ factors of poly(AMS-co-AN) were increased with increasing AMS content. The simulated conversions and copolymerization rates were compared with the experimental results. It was observed that the average time to reach dynamic steady-state was three times the residence time.

TWO-Point Reactor Kinetics for Large D$_2$O Reflected Systems (다량의 중수반사체 계통에 대한 2-점노 운동방정식)

  • Noh, T.W.;Oh, S.K.;Kim, S.Y.;Kim, D.H.
    • Nuclear Engineering and Technology
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    • v.19 no.3
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    • pp.192-197
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    • 1987
  • Two-point kinetic equations for a compact-core-with-bulky-D$_2$O-reflector system were developed. A unique feature of the system is that certain fission gammas create retarded photoneutrons in the D$_2$O reflector by (r, n) reaction. Coupling effect between the core and the reflector was investigated by simulating power transients with various ramp reactivity insertions. Special attention was paid to the phenomenon associated with spatial separation of photoneutrons and their precursors. Simulations show that accuracy of the two-point model is comparable with that of space-dependent approach. Also it is found that the explicily expressed photoneutron terms in the reflector equation slow down the power transient compared to non-photoneutron expressions. Detectors for reactor power control purpose prefer to be deployed in the core zone to be able to accurately perdict transient power.

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An analysis of the influence on the formation kinetics of methane hydrate (메탄 하이드레이트 생성 속도에 미치는 영향 분석)

  • Lee Young Chul;Cho Byoung Hak;Baek Young Soon;Lee Woo Jin
    • Journal of the Korean Institute of Gas
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    • v.5 no.3 s.15
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    • pp.55-62
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    • 2001
  • This paper describes about the formation of methane hydrate that is artificially made in jacket-type stirred reactor and is observed the change of hydrate shape during the course of reaction. The combustion of manufactured methane hydrate is showed the probability of a storage and transport of gas. And the influence of various experimental conditions of temperature, pressure and stirring rate on the manufacture of methane hydrate is measured. The growth rate and the induction time of methane hydrate is observed according to the conditions. Especially it is important to investigate the effect of temperature and pressure on the growth of hydrate such as the nuclear creation and the structure formation of hydrate in order to study the storage and transport of gas.

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