• 제목/요약/키워드: 355 nm

검색결과 190건 처리시간 0.022초

A Study of the Diffusion and Rise of Stack Plumes at Coastal Region by Using LIDAR Observation Data

  • Yoon, Ill-Hee
    • International Union of Geodesy and Geophysics Korean Journal of Geophysical Research
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    • 제26권1호
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    • pp.43-58
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    • 1998
  • The Kwinana Shoreline Fumigation Experiment (KSFE) took place at Fremantle, WA, Australia between January 23 and February 8, 1995. The CSIRO DAR LIDAR measured plume sections from near the Kwinana Power Station (KPS) stacks to up to about 5 km downstream. It also measured boundary layer aerosols and the structure of the boundary layer on some occasions. Both stages A and C of KPS were used as tracers at different times. The heart of the LIDAR system is a Neodymium-doped Yttrium-aluminum-garnet (Nd:YAG) laser operating at a fundamental wavelength of 1064 nm, with harmonics of 532 nm and 355 nm. For these experiments the third harmonic was used because the UV wavelength at 355 nm is eye safe beyond about 50 m. The laser fires a pulse of light 6 ns in duration (about 1.8 m long) and with an energy (at the third harmonic) of about 70 mJ. This pulse subsequently scattered and absorbed by both air molecules and particles in the atmosphere. A small fraction of the laser beam is scattered back to the LIDAR, collected by a telescope and detected by a photo-multiplier tube. The intensity of the signal as a function of time is a measure of the particle concentration as a function of distance along the line of the laser shot. The smoke plume was clearly identifiable in the scans both before and after fumigation in the thermal internal boundary layer (TIBL). Both power station plumes were detected. Over the 9 days of operation, 1,568 plumes scans (214 series) were performed. Essentially all of these will provide instantaneous plume heights and widths, and there are many periods of continuous operation over several hours when it should be possible to compile hourly average plume statistics as well. The results of four days LIDAR observations of the dispersion of smoke plume in the TIBL at a coastal site are presented for the case of stages A and C.

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구름에서의 다중산란효과 계산 및 이를 이용한 구름 물리변수 원격 추출 방법 연구 (Calculation of Multiple Scattering in Water Cloud and Application in Remote Measurement of Cloud Physical Properties)

  • 김덕현;박선호;최성철
    • 한국광학회지
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    • 제25권1호
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    • pp.1-7
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    • 2014
  • 구름에서의 다중산란 효과는 Mie 산란현상을 이용하는 탄성산란 라이다에서 그 해를 구하는데 있어서, 매우 중요한 오차요인으로 작용하기 때문에 이 효과를 보정하는 것은 그 자체만으로도 매우 중요하다. 이를 위하여 구름에서 다중산란되는 현상을 Monte Carlo 방법으로 계산하였으며, 이 결과를 적용하여 물방울 구름의 총량과 유효입자크기를 추출하는 방법을 제안하였다. 구름의 유효입자 크기가 $2.5{\mu}m$ 이하일 경우엔 355 nm나 1064 nm에서 얻은 두 파장의 소광계수로 쉽게 그 값들을 구할 수 있음을 알 수 있었다. 크기가 큰 경우엔 라이다 신호의 안정화된 선형편광도가 유효입자크기, 총량, 그리고 소광계수와 관련이 있음을 알 수 있었으며, 이 관계를 통하여 큰 입자의 경우에도 라만 라이다와 편광 라이다를 이용한다면 유효입자크기와 총량을 구할 수 있다는 것을 알 수 있었다.

PTMSP-Borosilicate 복합막에 의한 수소-질소 기체 분리에 관한 연구 (Separation of Hydrogen-Nitrogen Gases by PTMSP-Borosilicate Composite Membranes)

  • 이석호;강태범
    • 멤브레인
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    • 제24권6호
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    • pp.438-447
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    • 2014
  • 무정형의 괴상의 다공성 borosilicate는 trimethylborate (TMB)/ tetraethylorthosilicate (TEOS) 몰비 0.01~0.10 겔체를 $700{\sim}800^{\circ}C$ 온도범위에서 열처리 하였을 때 얻어졌다. BET와 SEM 관찰에 의하면 $700{\sim}800^{\circ}C$에서 얻어진 borosilicate의 표면적은 $251.12{\sim}355.62m^2/g$이고, 기공직경은 3.5~4.9 nm이며, 입자크기는 30~60 nm이었다. TGA측정에 의하면 borosilicate가 poly[1-(trimethylsilyl)propyne](PTMSP)에 첨가되었을 때 PTMSP-borosilicate 복합막의 열적 안정성은 향상 되었다. SEM관찰에 의하면 borosilicate는 $1{\mu}m$ 크기로 복합막 내에 분산되어 있었다. 기체투과실험에 의하면 PTMSP에 borosilicate 함량이 증가하면 자유부피, 공동, 기공률이 증가하여 기체투과가 용해확산에 의한 것보다 분자체거름, 표면확산, Knudsen 확산에 의해 일어나는 경우가 점차 증가함으로 해서 $H_2$$N_2$의 투과도는 증가하고 선택도($H_2/N_2$)는 감소하였다.

다파장 라만 라이다 관측을 통한 황사의 이동 고도 분포에 따른 광학적 특성 변화 규명 (Retrieval of the Variation of Optical Characteristics of Asian Dust Plume according to their Vertical Distributions using Multi-wavelength Raman LIDAR System)

  • 신성균;박영산;최병철;이권호;신동호;김영준;노영민
    • 대한원격탐사학회지
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    • 제30권5호
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    • pp.597-605
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    • 2014
  • 광주과학기술원의 다파장 라만 라이다를 이용한 에어로졸 연속관측이 2009년부터 2011년까지 3년간 수행되었다. 장기 연속 관측을 통해 얻어진 라이다 신호들의 분석을 통해 편광소멸도를 산출해 내었고, 편광소멸도를 통하여 황사 층을 구분해 내었다. 구분된 황사의 층의 광학적 특징들이 관측 고도에 따라 다르다는 것을 신호의 분석으로부터 밝혀졌다. 이러한 광학적 특징의 차이를 규명하기 위하여, HYSPLIT 모델을 이용하여 각각 관측된 황사 층들의 유입 경로와 이동 중 고도를 분석하였다. 이러한 황사의 관측 고도에 따른 광학적 특성의 변화는 황사가 장거리 이동 중 통과한 오염물질 발생 지역에서 발생한 오염물질과의 혼합으로부터 기인한 것으로 사료된다. 특히 오염물질 발생 지역을 지날 때의 황사 층의 고도는 황사의 광학적 특성 변화에 가장 큰 영향을 미치는 것으로 판단된다. 3년간 라이다 관측 시스템으로 관측한 황사 중, 중국산업지역 및 인구밀집도가 높은 지역 등과 같은 인위적 기원의 오염물질 발생 지역을 통과할 때의 고도가 1 km 이하 일 때, $0.12{\pm}0.01$의 낮은 편광소멸도, 355 nm와 532 nm 파장에서 각각 $67{\pm}9sr$, $68{\pm}9sr$의 낮은 라이다비, $1.05{\pm}0.57$의 낮은 옹스트롬 지수(${\AA}ngstr\ddot{o}m$ expon) 보였으며, 이는 오염물질이 갖는 광학적 특성 값과 유사하다. 이와 반면 황사가 3 km 이상의 높은 고도로 오염물질 발생 지역을 통과한 경우는 $0.21{\pm}0.09$의 편광소멸도, 355 nm와 532 nm 파장에서 각각 $48{\pm}5sr$, $46{\pm}4sr$의 라이다 비, $0.57{\pm}0.24$의 옹스토롬 지수를 보이며 이는 순수황사의 광학적 특성과 유사하다. 이는 황사가 중국 오염물질 발생지역을 통과할 때의 고도가 혼합상태의 황사 전체의 광학적 특성에 큰 영향을 미치는 것으로 판단되며, 낮은 고도에서는 오염물질과의 혼합의 정도가 증가하여, 오염물질의 광학적 특성이 우세하게 나타나는 반면, 높은 고도에서는 오염물질과 황사의 혼합이 상대적으로 적게 일어난다고 사료된다.

Photoluminescence Excitation Spectroscopy Studies of Anodically Etched and Oxidized Porous Zn

  • Chang, Sung-Sik;Lee, Hyung-Jik
    • 한국세라믹학회지
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    • 제41권5호
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    • pp.359-363
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    • 2004
  • Photoluminescence excitation (PLE) spectroscopy studies were performed for anodically etched porous Zn, which exhibited a PL in the blue/violet spectral range peaking at 420 nm (2.95 eV), and oxidzed porous Zn at 380$^{\circ}C$ for 10 min and 12 h. A broad absorption band was observed at 4.07 eV (305 nm), 3.49 (355 nm) for anodically etched porous Zn. In contrast, both the oxidized porous Zn and sintered ZnO exhibited an almost identical one broad absorption band at 3.85 eV (322 nm), when PLE spectra were measured at 378 nm (3.28 eV). The oxidized porous Zn and sintered ZnO, which displayed both UV and green luminescence band, showed an additional absorption band at 389 nm (3.19 eV) and 467 nm (2.66 eV). In contrast, no significant absorption band was detected for a 10-min oxidized porous Zn, which only displayed one UV luminescence void of deep-level luminescence. These absorption bands determined by PLE studies enabled a clear understanding of an emission mechanism for the UV and green luminescence from ZnO.

Mass Spectrometric Study of Carbon Cluster Formation in Laser Ablation of Graphite at 355 nm

  • Koo, Young-Mi;Choi, Young-Ku;Lee, Kee-Hag;Jung, Kwang-Woo
    • Bulletin of the Korean Chemical Society
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    • 제23권2호
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    • pp.309-314
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    • 2002
  • The ablation dynamics and cluster formation of $C_n^+$ ions ejected from 355 nm laser ablation of a graphite target in vacuum are investigated using a reflectron time-of-flight (RTOF) mass spectrometer. At low laser fluence, odd-numbered cluster ions with $3{\leq}n{\leq}15$ are predominantly produced. Increasing the laser fluence shifts the maximum size distribution towards small cluster ions, implying the fragmentation of larger clusters within the hot plume. The temporal evolution of $C_n^+$ ions was measured by varying the delay time of the ion extraction pulse with respect to the laser irradiation, providing significant information on the characteristics of the ablated plume. Above a laser fluence of $0.2J/cm^2$ , large cluster ions ($n{\geq}30$) are produced at relatively long delay times, indicating that atoms or small carbon clusters aggregate during plume propagation. The dependence of the intensity of ablated $C_n^+$ ions on delay time after laser irradiation shows that the most probable velocity of each cluster ion decreases with cluster size.

변형률 속도 효과를 고려한 355 nm UV 레이저 구리재질의 싱글 펄스 전산해석 (Computational Analysis of 355 nm UV Laser Single-Pulsed Machining of Copper Material Considering the Strain Rate Effect)

  • 이정한;오재용;박상후;신보성
    • 한국기계가공학회지
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    • 제9권3호
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    • pp.56-61
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    • 2010
  • Recently, UV pulse laser is widely used in micro machining of the research, development and industry field of IT, NT and BT products because the laser short wavelength provides not only micro drilling, micro cutting and micro grooving which has a very fine line width, but also high absorption coefficient which allows a lot of type of materials to be machined more easily. To analyze the dynamic deformation during a very short processing time, which is nearly about several tens nanoseconds, the commercial Finite Element Analysis (FEA) code, LS-DYNA 3D, was employed for the computitional simulation of the UV laser micro machining behavior for thin copper material in this paper. A finite element model considering high strain rate effect is especially suggested to investigate the micro phenomena which are only dominated by mechanically pressure impact in disregard of thermally heat transfer. From these computational results, some of dynamic deformation behaviors such as dent deformation shapes, strains and stresses distributions were observed and compared with previous experimental works. These will help us to understand micro interaction between UV laser beam and material.

355nm UV 레이저를 이용한 마이크로 렌즈 어레이 쾌속 제작에 관한 연구 (A Study on Rapid Fabrication of Micro Lens Array using 355nm UV Laser Irradiation)

  • 제순규;박상후;최춘기;신보성
    • 소성∙가공
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    • 제18권4호
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    • pp.310-316
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    • 2009
  • Micro lens array(MLA) is widely used in information technology(IT) industry fields for various applications such as a projection display, an optical power regulator, a micro mass spectrometer and for medical appliances. Recently, MLA have been fabricated and developed by using a reflow method having the processes of micro etching, electroplating, micro machining and laser local heating. Laser thermal relaxation method is introduced in marking of microdots on the surface of densified glass. In this paper, we have proposed a new direct fabrication process using UV laser local thermal-expansion(UV-LLTE) and investigated the optimal processing conditions of MLA on the surface of negative photo-resist material. We have also studied the 3D shape of the micro lens obtained by UV laser irradiation and the optimal process conditions. And then, we made chrome mold by electroplating. After that, we made MLA using chrome mold by hot embossing processing. Finally, we have measured the opto-physical properties of micro lens and then have also tested the possibility of MLA applications.

SOLVING BIOANALYTICAL PROBLEMS BY THE METHOD OF MATRIX-ASSISTED LASER DESORPTION IONIZATION MASS SPECTROMETRY (MALDI-MS)

  • Zhao, Shankai;Zhong, Feng;Zhu, Zhihua
    • 분석과학
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    • 제8권4호
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    • pp.865-868
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    • 1995
  • The method of matrix-assisted laser desorption ionization mass spectrometry has been used to solve some bioanalytical problems, which is difficult to analyse by general methods. For the selection of proper laser wavelength and matrices, eight matriees was used with laser wavelength of 226 and 355nm. The result shows that with wavelength of 355nm better results could be obtained with most of the matrices. The molecular weight of eytochrome C, which was seperated by gel electrophoresis and electro-blotted onto NC membrane is determined by MALDI. The accuracy is better than 0.1%, which is much higher than that of SDS-PAGE. Protein mixture extracted from crude peanut oil is directly determined by MALDI. The molecuiar weight of its three components are determined, and the result also demonstrated that these proteins are in free manner. As proteins arc in 2S bond, with the traditional method, SDS-PAGE, it is not able to decide whether protein exists in combination mode or in free manner. In the technique of two phase aquesous solution, which is used for separating biomaterials, water soluble polymers stained with dyes are used in this technique. By the use of MALDI the number or the dye molecules react with the polymer PEG molecule are determined, and that is difficult to determined by other methods.

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