• Title/Summary/Keyword: 30B

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Synthesis and Thermal Degradation of Poly(oxydiethylene adipate urethane) Composites Containing Cloisite 30B and Melamine Phosphate (Cloisite 30B와 멜라민포스페이트를 함유한 Poly(oxydiethylene adipate urethane) Composites의 합성과 열분해 특성)

  • Shin, Seung-Wook;Lee, Sang-Ho
    • Polymer(Korea)
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    • v.36 no.5
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    • pp.643-650
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    • 2012
  • In order to improve the thermal stability of polyurethane, we synthesized poly(adipate urethane) (PAU) and three PAU composites, PAU/30B (2.7 wt% 30B), PAU/MP (2.2 wt% MP), PAU/30B/MP (2.2 wt% 30B and 2.2 wt% MP), from poly(oxydiethylene adipate)-diol (PAD), 4,4'-methylene diphenyl diisocyanate (MDI), Cloisite 30B (30B), and melamine phosphate (MP). 30B and MP were introduced into the reactant mixture at the initial stage of the esterification between adipic acid and diethylene glycol, so 30B and MP were evenly dispersed in the PAU composites for long period. At temperatures lower than $250^{\circ}C$, the PAU composites were degraded faster than pristine PAU, mainly due to the decomposition of 30B and MP. At higher temperatures, the 30B and MP enhanced the thermal stability of the PAU composites. Compared with the pristine PAU, the thermal decomposition rates of the PAU composites decreased by 13~17%. In air, the residual weights of PAU/30B, PAU/MP, and PAU/30B/MP were 2.4, 2.3, and 7.3 wt% at $700^{\circ}C$, respectively.

Effects of Cr, B, Ti and Si on Rolling Characteristics in Fe-30at.%A1 Alloy (Fe-30at.%A1 합금의 압연성에 미치는 Cr, B, Ti 및 Si 첨가효과)

  • Choi, Dap-Chun;Lee, Ji-Sung
    • Journal of Korea Foundry Society
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    • v.23 no.2
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    • pp.77-85
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    • 2003
  • Some alloying elements such as Cr, B, Ti and Si were added individually or as a mixture to Fe-30 at.%Al alloys. The alloys were melted using an arc furnace and then heat-treated for homogenization at 1000$^{\circ}C$ for 7 days and followed by rolling at 1000$^{\circ}C$. The alloying elements on rolling characteristics were investigated by the microstructures and fracture mode before and after rolling. The microstructures before rolling showed that all of the alloys had equiaxed grains. On the other hand, the microstructures of rolling plane as well as its perpendicular plane became elongated after rolling. The alloys such as Fe-30Al, Fe-30Al-3Ti, Fe-30Al-0.5B, Fe-30Al-5Cr and Fe-30Al-3Ti-0.5B revealed better rolling behaviour from the point that intergranular and cleavage fractures were not fundamentally occurred. But the addition of 5Ti or 3Si to Fe-Al alloys had detrimental effects. The Ti-added alloy system such as Fe-30Al-5Ti, Fe-30Al-5Ti-5Cr, Fe-30Al-3Ti-5Cr and Fe-30Al-5Ti-0.5B were cracked through grain and showed cleavage fracture. The Si-added alloy system such as Fe-30Al-5Si, Fe-27Al-3Si and Fe-27Al-5Cr-3Si were cracked along the grain boundary and showed intergranular fracture. $DO_3{\leftrightarrow}B_2$ transition temperature of Fe-30at.%Al alloy was 520$^{\circ}C$, whereas the addition of 3Ti and 3Ti+0.5B comparably increased the temperature to 797 and 773$^{\circ}C$, respectively.

Factors Affecting Opinions on Marriage of Unmarried Women in Their 30's in Korea: Based on 2012 Social Survey (한국 30대 미혼여성의 결혼견해 영향요인: 2012 사회조사 기반)

  • Lee, Sung-Hee;Gweon, Hyun-Soo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.1
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    • pp.606-616
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    • 2015
  • This study was conducted in order to identify factors affecting opinions on marriage of unmarried women in their 30's in Korea. Analysis of data on 529 unmarried women in their 30's, which were taken from the 2012 social survey, was analyzed. Data were analyzed using ${\chi}^2$ test, hierarchical logistic regression analysis as well as descriptive statistics by SPSS version 20.0. Results showed that age(Exp(b)=.90,p=.025), opinions on divorce(Exp(b)=3.81,p<.001) and remarriage(Exp(b)=3.09,p=.001), and value on marriage(Exp(b)=.80,p<.001) were independent predictors of opinions on marriage. Economic activity(Exp(b)=19.58,p=.003) was found to be an independent predictor of opinions on marriage for the 35-39 year old women differ from 30-34 year old women predictors. Findings of this study indicate a need for developing family and marriage value-centered education and the low-fertility policy for the 35-39year old actively working women considering factors affecting opinions on marriage.

MTF Evaluation and Clinical Application according to the Characteristic Kernels in the Computed Tomogrsphy (Kernel 특성에 따른 MTF 평가 및 임상적 적용에 관한 연구)

  • Yoo, Beong-Gyu;Lee, Jong-Seok;Kweon, Dae-Cheol
    • Progress in Medical Physics
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    • v.18 no.2
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    • pp.55-64
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    • 2007
  • Our objective was to evaluate the clinical feasibility of spatial domain filtering as an alternative to additional image reconstruction using different kernels in CT. Kernels were grouped as H30 (head medium smooth), B30 (body medium smooth), S80 (special) and U95 (ultra sharp). Derived from thin coilimated source images, four sets of images were generated using phantom kernels. MTF (50%, 10%, 2%) measured with H30 (3.25, 5.68, 7.45 Ip/cm) B30 (3.84, 6.25, 7.72 Ip/cm), S80 (4.69, 9.49, 12.34 Ip/cm), and U95 (14.19, 20.31, 24.67 Ip/cm). Spatial resolution for the U95 kernel (0.6 mm) was 33.3% greater than that of the H30 and B30 (0.8 mm) kernels. Initially scanned kernels images were rated for subjective image qualify, using a five-point scale. Image scanned with a convolution kernel led to an increase in noise (U95), whereas the results for CT attenuation coefficient were comparable. CT images increase the diagnostic accuracy in head (H30), abdomen (B30), temporal bone and lung (U95) kernels may be controlled by adjusting CT various algorithms, which should be adjusted to take into account the kernels of the CT undergoing the examination.

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Design and Fabrication of SMD Type Backward Wave 3dB Coupler for PCS Basestation (PCS 기지국용 표면실장형 후진파 3dB 커플러의 설계 및 제작)

  • 박인식;김종규;신동호
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.35D no.6
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    • pp.1-7
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    • 1998
  • In this paper, SMD type backward wave 3dB coupler for PCS basestation application was designed, fabricated and measured. We designed that it could be replaced for commercial basestation system and it was 0.56 $\times$ 0.35 inches size. The test results show that coupler is well operated within frequency range of 1.75 ~ 1.98GHz, which is defined on PCS system. The coupler reveals insertion loss 0.295dB, isolation -30.31dB, amplitude balance 0.05dB, phase balance 0.02$^{\circ}$, input and output impedance matching -30.38dB, -39.72dB, respectively.

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Quality characteristics and processing of rice cake (Backsulgi) with rice flour containing Lactobacillus plantarum CGKW3 by spray-drying (유산균 포집 쌀가루를 이용한 백설기의 제조 및 품질특성)

  • Lee, Dae-Hoon;Park, Hye-Mi;Hong, Joo-Heon
    • Food Science and Preservation
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    • v.23 no.7
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    • pp.953-959
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    • 2016
  • The quality characteristics and processing of rice cake (Backsulgi) with rice flour containing Lactobacillus plantarum CGKW3 by spray-drying (LP-B) were investigated. The LP-B was applied at ratios of 10, 20, and 30 (w/w), and the moisture contents and pH were 33.39%~36.70% and 5.81~5.46, respectively. The L value of LP-B increased as the rice flour decreased, while the a and b value increased as the LP-B increased. The texture profiles showed that Backsulgi prepared with LP-B mixture had higher hardness, cohesiveness, springiness and chewiness than 100% rice flour. The pH of LP-B Backsulgi (LP-B20 and LP-B30) did not differ during 6 days at room temperature. The total bacteria in Backsulgi prepared LP-B20 and LP-B30 Backsulgi was $10^4CFU/g$ after 2 days of storage at room temperature. The shelf life of Backsulgi prepared with LP-B20 and LP-B30 were extended by about 2 days when compared with the control at room temperature. Sensory evaluation showed that Backsulgi without LP-B20 had higher scores in terms of appearance, color, flavor, taste, texture, hardness and overall acceptability than Backsulgi without 100% rice flour. In conclusion, the results demonstrate that LP-B20 may prove quite useful as a Backsulgi flour with desirable properties.

Synthesis of Polyester-diol and Exfoliation of Nanoclay through Esterification between Adipic Acid and Diethylene Glycol (Adipic Acid와 Diethylene Glycol의 에스테르 반응을 통한 나노점토의 박리와 폴리에스테르형 디올의 합성)

  • Kim, Byung-Ju;Lee, Sang-Ho
    • Elastomers and Composites
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    • v.44 no.4
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    • pp.447-454
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    • 2009
  • We synthesized polyester-diol containing Cloisite 30B which is exfoliated during the synthesis. First, esterification was conducted with excess adipic acids and two 2-hydroxyethyl groups of the tertiary ammonium tethered to Cloisite 30B silicate layer. Due to the small molecular size of adipic acid ($d{\approx}3.0\;{\AA}$, $L{\approx}9.3\;{\AA}$), it penetrated into the interlayer of Cloisite 30B, reacted with the 2-hydroxyethyl groups, and produced the tertiary ammonium that has the two ethyl-ester adipic acid groups, one methyl group, and one hydrogenated alkyl group. Through the esterification, the molecular size of the tertiary ammonium increased and as the result, the basal space of Cloisite 30B increased from $18.4\;{\AA}$ to more than $58.3\;{\AA}$. The produced ethyl-ester adipic acid and unreacted adipic acid reacted with excess diethylene glycol ([COOH]/[OH]${\approx}0.6$) to be polyester-diol. The COOH conversion calculated from the acid value of the reactant mixture was 94%. The number average molecular weight and PDI of the produced polyester-diol were 830 g/mol and 1.2, respectively.

Enhanced Tolerance of Chinese Cabbage Seedlings Mediated by Bacillus aryabhattai H26-2 and B. siamensis H30-3 against High Temperature Stress and Fungal Infections

  • Lee, Young Hee;Jang, Su Jeong;Han, Joon-Hee;Bae, Jin Su;Shin, Hyunsuk;Park, Hee Jin;Sang, Mee Kyung;Han, Song Hee;Kim, Kyoung Su;Han, Sang-Wook;Hong, Jeum Kyu
    • The Plant Pathology Journal
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    • v.34 no.6
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    • pp.555-566
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    • 2018
  • Two rhizobacteria Bacillus aryabhattai H26-2 and B. siamensis H30-3 were evaluated whether they are involved in stress tolerance against drought and high temperature as well as fungal infections in Chinese cabbage plants. Chinese cabbage seedlings cv. Ryeokgwang (spring cultivar) has shown better growth compared to cv. Buram-3-ho (autumn cultivar) under high temperature conditions in a greenhouse, whilst there was no difference in drought stress tolerance of the two cultivars. In vitro growth of B. aryabhattai H26-2 and B. siamensis H30-3 were differentially regulated under PEG 6000-induced drought stress at different growing temperatures (30, 40 and $50^{\circ}C$). Pretreatment with B. aryabhattai H26-2 and B. siamensis H30-3 enhanced the tolerance of Chinese cabbage seedlings to high temperature, but not to drought stress. It turns out that only B. siamensis H30-3 showed in vitro antifungal activities and in planta crop protection against two fungal pathogens Alternaria brassicicola and Colletotrichum higginsianum causing black spots and anthracnose on Chinese cabbage plants cv. Ryeokgwang, respectively. B. siamensis H30-3 brings several genes involved in production of cyclic lipopeptides in its genome and secreted hydrolytic enzymes like chitinase, protease and cellulase. B. siamensis H30-3 was found to produce siderophore, a high affinity iron-chelating compound. Expressions of BrChi1 and BrGST1 genes were up-regulated in Chinese cabbage leaves by B. siamensis H30-3. These findings suggest that integration of B. aryabhattai H26-2 and B. siamensis H30-3 in Chinese cabbage production system may increase productivity through improved plant growth under high temperature and crop protection against fungal pathogens.

Shape Memory Characteristics and Mechanical Properties of Rapidly Solidified $Ti_{50}Ni_{20}Cu_{30}$ Alloy Strips (급냉응고된 $Ti_{50}Ni_{20}Cu_{30}$ 합금 스트립의 형상기억특성과 기계적특성)

  • Kim, Yoen-Wook
    • Journal of Korea Foundry Society
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    • v.29 no.5
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    • pp.187-191
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    • 2009
  • Microstructures and shape memory characteristics of $Ti_{50}Ni_{20}Cu_{30}$ alloy strips fabricated by arc melt overflow have been investigated by means of XRD, optical microscopy and DSC. The microstructure of as-cast strips exhibited columnar grains normal to the strip surface. X-ray diffraction analysis showed that one-step martensitic transformation of B2-B19 occurred in the alloy strips. According to the DSC analysis, it was known that the martensitic transformation temperature ($M_s$) of B2 $\rightarrow$ B19 in $Ti_{50}Ni_{20}Cu_{30}$ strip is $57^{\circ}C$. During thermal cyclic deformation with the applied stress of 60 MPa, transformation hysteresis and elongation associated with the B2-B19 transformation were observed to be $3.7^{\circ}C$ and 1.6%, respectively. The as-cast strip of $Ti_{50}Ni_{20}Cu_{30}$ alloy also showed a superelasticity and its stress hysteresis was as small as 14 MPa. These mechanical properties and shape memory characteristics of the alloy strips were ascribed to B2-B19 transformation and the controlled microstructures produced by rapid solidification of the arc melt overflow process.