• Journal of Korean Society of Environmental Engineers
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• v.22 no.10
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• pp.1825-1832
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• 2000

Column experiments were conducted by using soil columns, to investigate feasibility and efficiency of in-situ ozone enhanced remediation for diesel-contaminated soil. The injection of gaseous ozone into soil column revealed the enhanced decomposition of ozone due to the catalytic reaction between ozone and metal (e.g., Fe, Mn etc.) oxides as evidenced by as much as 25 times shorter half-life of ozone in a sand packed column than in a glass beads packed column. Substantial retardation in the transport of and the consumption of ozone were observed in the diesel contaminated field soil and sand packed columns. After 16 hrs ozonation, 80% of the initial mass of diesel (as diesel range organic) concentration of $800{\pm}50mg/kg$, was removed under the conditions of the flow rate of 50mL/min and $6mg-O_3/min$. Whereas, less than 30% of diesel was removed in the case of air injection. Analysis of the residual TPH(total petroleum hydrocarbon) and selected 8 aliphatics of diesel compounds in the inlet and the outlet of the column confirmed that diesel nonselectively reacted with ozone and then shifted to lower carbon numbered molecules. Water content also was found to be an important parameter in employing ozone to the hydrocarbon-contaminated soil.

• Textile Coloration and Finishing
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• v.5 no.4
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• pp.29-41
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• 1993

In order to surface Hydrophobilization of Poly(ethylene terephthalate) (PET) fiber samples were treated in the atmosphere of CF$_{4}$ or $C_{2}$F$_{6}$glow discharge. The sample used in this study was PET film which is 75$\mu$m thick made by Teijin, O-Type(Japan). The cleaned samples were placed in plasma reactor made of pyrex glass cylinder, and plasma processing was carried out by glow discharge of CF$_{4}$ or $C_{2}$F$_{6}$ gas, being continuously fed by gas flow and continuously pumped out by a vacuum system. Electric power source for generate plasma state was sustained alternating current(60Hz) and voltage was sustained 600 volt. The duration of plasma treatment varied from 15 to 120 seconds except special case, the monomer gase pressure varied from 0.02 to 0.3 Torr and power range was 10 to 90 watts. The hydrophobic features of changed PET surface were evaluated by contact angle measurement and surface chemical characteristics were analyzed by ESCA. Results can be summerized as follows. 1. The most favorable setting position of substrate was the center area between the two electrodes. 2. $C_{2}$F$_{6}$ discharge current was lower than that of CF$_{4}$ when same voltage was sustained. Treated efficiency between CF$_{4}$ and $C_{2}$F$_{6}$ did not revealed significant differences under same electric power(wattage). 3. When monomer pressure is very low below 0.02 torr, as though substrate is exposed to CF$_{4}$ or $C_{2}$F$_{6}$ plasma, it tend to be hydrophilic through a little of fluorine bond and a great deal of oxidizing reaction. 4. There brought good hydrophobilization when monomer pressure was more 0.1 torr and duration of glow discharge treatment was over 45 seconds. When monomer pressure was too high, discharge current became low. Although prolong the duration, there was no more high hydrophobilization. 5. According to ESCA analysis, there were a little CF bond and a prevailing CF$_{2}$ bond in CF$_{4}$-treated substrate. There were CF$_{3}$, a little CF and a prevailing CF$_{2}$ bond in $C_{2}$F$_{6}$-treated substrate.d substrate.

• Economic and Environmental Geology
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• v.42 no.4
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• pp.315-333
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• 2009

In this study, the hydrochemical and the isotopic characteristics of major streams in the Daejeon area were investigated during rainy and dry seasons. The stream water shows the electrical conductivity of the range of $37{\sim}527{\mu}s$/cm, and pH $6.21{\sim}9.83$. The chemical composition of stream waters can be grouped as three types: the upper streams of Ca(Mg)-$HCO_3$ type, Ca(Mg)-$SO_4(Cl)$ type of middle streams flowing through urban area, and Na(Ca)-$HCO_3$(Cl, $SO_4$) type of the down streams. Based on in-situ investigation, the high pH of stream waters flowing through urban area is likely to be caused by the inflow of a synthetic detergent discharging from the apartment complex. The electrical conductivity of stream waters at a dry season is higher than those of at a rainy season. We suggest that the hydro-chemical composition of stream waters in the Daejeon area was affected by the discharging water from the sewage treatment facilities and anthropogenic contaminants as well as the interaction with soil and rocks. ${\delta}D$ and ${\delta}^{18}O$ values of the stream waters show the relationship of ${\delta}D=6.45{\delta}^{18}O-7.4$, which is plotted at a lower area than global meteoric water line(GMWL) of Craig(1961). It is likely that this isotopic range results from the evaporation effect of stram waters and the change of an air mass. The isotope value shows an increasing trend from upper stream to lower stream, that reflects the isotopic altitude effect. The relationship between ${\delta}^{13}C$ and $EpCO_2$ indicates that the carbon as bicarbonate in stream water is mainly originated from $CO_2$ in the air and organic materials. The increasing trend of ${\delta}^{13}C$ value from upper stream waters to lower stream waters can be attributed to the following reasons: (1) an increasing dissolution of $CO_2$ gas from a contaminated air in downtown area of the Daejeon, and (2) the increment of an inorganic carbon of groundwater inflowed into stream by base flow. Based on the relationship between ${\delta}^{34}S$ and $SO_4$ of stream waters, the stream waters can be divided into four groups. $SO_4$ content increases as a following order: upper and middle Gab stream${\delta}^{34}S$ value decreases as above order. ${\delta}^{34}S$ value indicates that sulfur of stream waters is mainly originated from atmosphere, and is additionally supplied by pyrite source according to the increase of sulfate content. The sulfur isotope analysis of a synthetic detergent and sewage water as a potential source of the sulfur in stream waters is furtherly needed.

• Journal of Food Hygiene and Safety
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• v.19 no.1
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• pp.12-18
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• 2004

Ofloxacin, norfloxacin, ciprofloxacin, and enrofloxacin in chicken muscle were seperated by liquid extraction and determined with high performance liquid chromatography (HPLC) with fluorescence detector. Analysis was carried out using following conditions; Cl8 column (250${\times}$4.6 mm i.d. 5 ${\mu}{\textrm}{m}$ particle size), mobile phase composed of D.W. (containing 0.4% triethylamine and phospholic acid): methanol : acetonitrile (800:100:100, v/v/v), isocratic pump at a flow rate of 1.0 $m\ell$/min and 50 ${mu}ell$ of injection volume, fluorescence detector with EX278 nm/EM.456 nm. The calibration curves of four fluoroquinolones showed linearity (${\gamma}$$^2$$\geq$0.999) at concenration range of 0.025-0.6 $\mu\textrm{g}$/ml. The recoveries in fortified chicken muscle represented more than 80% with low coefficient of variation (〈10%) for concentration range of four fluoroquinolones. The detection limits for ofloxacin, norfloxacin, ciprofloxacin, and enrofloxacin were 23.5, 3.4, 3.0 and 2.5 ng/g in chicken muscle, respectively. We also monitored fluoroquinolones residue in muscle of chickens (broiler 1:227, Korean native chicken 219, laying chicken 77) using EEC-4-plate screening and HPLC conformation methods. Ten(broiler 5, Korean native chicken 5) out of the fifteen samples which were positively detected by EEC-plate screening method from 1,523 chicken meat were confirmed with ciprofloxacin and enrofloxacin by HPLC. The ranges of residual concentration were 0-0.12 ppm for ciprofloxacin and 0.01-6.79 ppm for enrofloxacin. In conclusion, our method could be applied effectively to determine four fluoroquinolones residues in chicken meat, and further survey for fluoroquinolones residue in chicken meat are needed for more effective control of fluoroquinolones used in livestock.

• Journal of Environmental Impact Assessment
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• v.27 no.6
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• pp.548-561
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• 2018

The objectives of this study were to construct a three-dimensional (3D) hydrodynamic and water quality model (EFDC) for the river reach between the Daecheong dam and the Sejong weir, which are directly affected by Gap and Miho streams located in the middle of the Geum River, and to evaluate the trophic status and water quality improvement effect according to the flow control and pollutant load reduction scenarios. The EFDC model was calibrated with the field data including waterlevel, temperature and water quality collected from September, 2012 to April, 2013. The model showed a good agreement with the field data and adequately replicated the spatial and temporal variations of water surface elevation, temperature and water quality. Especially, it was confirmed that spatial distributions of nutrients and algae biomass have wide variation of transverse direction. Also, from the analysis of algal growth limiting factor, it was found that phosphorous loadings from Gap and Miho streams to Sejong weir induce eutrophication and algal bloom. The scenario of pollutant load reduction from Gap and Miho streams showed a significant effect on the improvement of water quality; 4.7~18.2% for Chl-a, 5.4~21.9% for TP at Cheongwon-1 site, and 4.2~ 17.3% for Chl-a and 4.7~19.4% for TP at Yeongi site. In addition, the eutrophication index value, identifying the tropic status of the river, was improved. Meanwhile, flow control of Daecheong Dam and Sejong weir showed little effect on the improvement of water quality; 1.5~2.4% for Chl-a, 2.5~ 3.8% for TP at Cheongwon-1 site, and 1.2~2.1% for Chl-a and 0.9~1.5% for TP at Yeongi site. Therefore, improvement of the water quality in Gap and Miho streams is essential and a prerequirement to meet the target water quality level of the study area.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.32 no.1
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• pp.37-44
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• 2019

A bond-based peridynamic model has been reported dynamic fracture characteristic of brittle materials through a simple constitutive model. In the model, each bond is assumed to be a simple spring operating independently. As a result, this simple bond interaction modeling restricts the material behavior having a fixed Poisson's ratio of 1/4 and not being capable of expressing shear deformation. We consider a state-based peridynamics as a generalized peridynamic model. Constitutive models in the state-based peridynamics are corresponding to those in continuum theory. In state-based peridynamics, thus, the response of a material particle depends collectively on deformation of all bonds connected to other particles. So, a state-based peridynamic theory can represent the volume and shear changes of the material. In this paper, the perfect plasticity is considered to express plastic deformation of material by the state-based peridynamic constitutive model with perfect plastic flow rule. The elastic-plastic behavior of the material is verified through the stress-strain curves of the flat plate example. Furthermore, we simulate the high-speed impact on 3D granite model with a nonlocal contact modeling. It is observed that the damage patterns obtained by peridynamics are similar to experimental observations.

• Investigative Magnetic Resonance Imaging
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• v.17 no.4
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• pp.275-285
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• 2013

Purpose : The objective of this study was to investigate effects of different smoothing kernel sizes on brain tissue-masked susceptibility-weighted images (SWI) obtained from normal elderly subjects using voxel-based analyses. Materials and Methods: Twenty healthy human volunteers (mean $age{\pm}SD$ = $67.8{\pm}6.09$ years, 14 females and 6 males) were studied after informed consent. A fully first-order flow-compensated three-dimensional (3D) gradient-echo sequence ran to obtain axial magnitude and phase images to generate SWI data. In addition, sagittal 3D T1-weighted images were acquired with the magnetization-prepared rapid acquisition of gradient-echo sequence for brain tissue segmentation and imaging registration. Both paramagnetically (PSWI) and diamagnetically (NSWI) phase-masked SWI data were obtained with masking out non-brain tissues. Finally, both tissue-masked PSWI and NSWI data were smoothed using different smoothing kernel sizes that were isotropic 0, 2, 4, and 8 mm Gaussian kernels. The voxel-based comparisons were performed using a paired t-test between PSWI and NSWI for each smoothing kernel size. Results: The significance of comparisons increased with increasing smoothing kernel sizes. Signals from NSWI were greater than those from PSWI. The smoothing kernel size of four was optimal to use voxel-based comparisons. The bilaterally different areas were found on multiple brain regions. Conclusion: The paramagnetic (positive) phase mask led to reduce signals from high susceptibility areas. To minimize partial volume effects and contributions of large vessels, the voxel-based analysis on SWI with masked non-brain components should be utilized.

• Tunnel and Underground Space
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• v.28 no.5
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• pp.400-425
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• 2018

This study presents the research results and current status of the DECOVALEX-2019 project Task B. Task B named 'Fault slip modelling' is aiming at developing a numerical method to simulate the coupled hydro-mechanical behavior of fault, including slip or reactivation, induced by water injection. The first research step of Task B is a benchmark simulation which is designed for the modelling teams to familiarize themselves with the problem and to set up their own codes to reproduce the hydro-mechanical coupling between the fault hydraulic transmissivity and the mechanically-induced displacement. We reproduced the coupled hydro-mechanical process of fault slip using TOUGH-FLAC simulator. The fluid flow along a fault was modelled with solid elements and governed by Darcy's law with the cubic law in TOUGH2, whereas the mechanical behavior of a single fault was represented by creating interface elements between two separating rock blocks in FLAC3D. A methodology to formulate the hydro-mechanical coupling relations of two different hydraulic aperture models and link the solid element of TOUGH2 and the interface element of FLAC3D was suggested. In addition, we developed a coupling module to update the changes in geometric features (mesh) and hydrological properties of fault caused by water injection at every calculation step for TOUGH-FLAC simulator. Then, the transient responses of the fault, including elastic deformation, reactivation, progressive evolutions of pathway, pressure distribution and water injection rate, to stepwise pressurization were examined during the simulations. The results of the simulations suggest that the developed model can provide a reasonable prediction of the hydro-mechanical behavior related to fault reactivation. The numerical model will be enhanced by continuing collaboration and interaction with other research teams of DECOLVAEX-2019 Task B and validated using the field data from fault activation experiments in a further study.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.6
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• pp.721-728
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• 2016

97% of water on earth exists in the form of seawater. Therefore, the use of marine resources is one of the most important research issues at present. The use of seawater is expanding in various fields (seawater desalination, cooling water for nuclear power plants, deep seawater utilization, etc.). Seawater intake systems utilizing sand filters in order to take in clean seawater are being actively employed. For the intake pipe used in this system, assuring equal intake flows through the respective holes is very important to improve the efficiency of the intake and filtering process. In this study, we analyzed the efficiency of the dual structure perforated pipe used in the seawater intake system using 3D numerical simulations and the inflow rate according to the gap of the up holes. In the case of decreasing gaps in the up holes toward the pipe end, the variation of the total inflow rate was small in comparison with the other cases. However, the standard deviation of the inflow rate through the up holes was the lowest in this case. Also, stable flow occurred, which can improve the efficiency of the intake process. In the future, a sensitivity analysis of the various conditions should be performed based on the results of this study, in order to determine the factors influencing the efficiency, which can then be utilized to derive optimal designs suitable for specific environments.

• Proceedings of the Korean Society for Agricultural Machinery Conference
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• 2017.04a
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• pp.58-58
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• 2017

점적 호스의 원통형 미로 구조물내의 유동특성을 분석하기 위해 금속판에 동일한 구조의 미로가 가공된 시험부를 활용하여 압력과 유량의 변화에 대한 실험을 CFD 해석하였다. 해석은 미로의 길이에 따른 유량 특성을 정밀하게 분석하기 위해 전체 미로에 구간별 총 8개의 배출구를 배치하고 밸브 조절을 통해 구간별 압력에 따른 유량을 측정함으로서 실험에 의한 압력과 유량의 관계를 검증하고 새로운 경질 미로를 설계하는데 응용하고자 한다. 경질 미로의 이론적인 해석에서 정밀도가 실험을 대신할 가능성이 있는지에 관심을 두었다. 점적관수의 경질 미로는 디자인을 달리함으로써 성능이 높고 미세한 스케일이 침착되지 않는 고성능의 점적관수 장치의 개발이 가능할 것으로 판단하였다. 미로 입구의 공급 유체 압력(Gauge pressure)을 0.5, 1.5, 2.5, 3.0 bar로 나누어 공급하였으며, 8개의 구간별 유출되는 유량은 전자저울에서 측정하였다. 향후 최적 미로의 새로운 설계를 위해 미로구조 전체를 CFD 해석하였고 그 결과를 실험치와 비교 분석하였다. 또한 경질 미로내 각 구간별 세부적인 유동구조를 분석하였고 해석결과와 실험결과를 통해 향후 새로운 경질 구조의 개발이 가능 할 것으로 판단되었다. 경질 미로의 입구압력에 따른 미로의 길이 #1과 #2에 대한 CFD 분석에서는 전체적으로 경질 미로에 압력이 증가할수록 미로의 유체 속도가 증가됨을 알 수 있었으며 이것은 #2에서도 거의 같은 양상을 나타내었다. 미로 통로에서는 와류로 인한 이물질의 멈춤 현상이 발생하지 않을 만큼 흐름이 원활함을 알 수 있었다. 미로의 길이 #3과 #4에 대한 CFD 분석과 미로의 길이 #5와 #6에 대한 CFD 분석에서는 압력이 증가하고 미로의 길이가 길어질수록 속도에도 영향을 미치고 있는 것으로 나타났으며 미로와 미로 사이의 넒은 통로에서는 유속이 크게 떨어지고 있음을 알 수 있었다. 따라서 이 부분에는 유체속의 이물질이 침착할 수 있는 가능성이 있으며 통로가 좁은 곳에서는 유속이 증가되는 것으로 나타났다. #7과 #8은 미로의 상하단으로 유출되는 부분의 차이이므로 실질적으로 해석의 결과는 차이가 없었다. 경질 미로에 대한 압력에 따른 미로의 길이별 유출량은 지수적인 반비례 현상을 나타내어 앞서 실험한 연구의 결과와 1~2% 오차 범위에서 잘 일치하였다. 따라서 점적 호스의 경질 미로에 대한 설계는 이론적인 해석을 통하여 새로운 디자인이 가능할 것으로 판단되었다. 경질 미로의 미로의 길이에 따른 CFD 분석의 결과는 실험적인 유출량의 값과 거의 일치하였다. 미로와 미로 사이의 넒은 통로에서는 유속이 크게 떨어져 이물질들이 침착될 가능성이 있었으며 실질적으로 넓게 설계하는 것이 유리하지 않을 것으로 판단되었다. 경질 미로에 대한 압력에 따른 미로의 길이별 유출량은 지수적으로 반비례 하였으며 점적 호스의 경질 미로에 대한 새로운 설계는 이론적인 해석을 통하여 가능할 것으로 판단되었다.