• 제목/요약/키워드: 3%Si-Fe

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Sintering Process and it's Applications of Electric-stone Tourmaline (Tourmaline 전기석의 소결특성과 응용)

  • 소대화;전용우;박정철;장동훈;김정회
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2003.05a
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    • pp.778-781
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    • 2003
  • 투어멀린(Tourmaline)은 비대칭 쌍극자를 가진 유극성 결정체로 광물 중에서 영구적으로 전기분극의 특성을 띄고 있는 유일한 물질로써 일명 "전기석"이라고 알려져 있고, 자체의 미약전류(약 0,06mA)와 함께 음이온 및 원적외선의 발생으로 최근 들어 우리 주변에서 건강과 환경을 위한 관심고조의 대상인 육방정계의 압전성 및 초전성을 띄는 붕규산염(주요성분: Mg, Fe, B, Si, Ca)으로, 원석(면역지수 ~1000)에 비해 수백 배의 효력이 있는 투어말린 세라믹(면역지수 ~418,000)을 비롯하여 이것을 이용한 새로운 아이디어 신상품들이 계속 개발되고 있다. 뿐만 아니라, 물분자를 만나면 수소(H$^{+}$)와 수산기(OH$^{-}$)로 전기분해하여 친수기와 소수기 부분으로 구분하며, H$^{+}$와 OH$^{-}$는 각각 $H_2O$와 결합하여 활성이 강한 hydronium ion(H$_3$O$^{+}$ 과 계면활성 작용이 있는 hydroxyl ion(H$_3$O$_2$$^{-}$)을 생성하며, 물속에서 계속 불안정한 상태로 존재하는 수산기는 hydroxyl (-)ion을 형성하여 약 알카리성(pH~7.4)을 띄고 물의 클러스터 세분화와 미네랄을 공급해 줌으로 체내에 들어오면 살균, 항균능력이 있는 면역기능을 갖게 되며, 혈액을 정화하고 자율신경을 자극하여 교감신경의 흥분을 억제한. 이와 함께 전기분극을 띈 투어멀린 입자는 다른 물질에 비하여 경이적 수치의 원적외선을 발생하여 강력한 열 효과와 높은 침투력으로 인체의 혈액순환 촉진과 혈전용해 작용으로 건강과 활력에 도움을 주는 것으로 확인되어 많은 관심을 끌고 있다. 따라서 유익한 이용가치를 인정받고 있는 투어멀린을 유용한 타 물질과 혼합물을 구성하여 성형 또는 EPD 전착하여 소결한 뒤, 소결체의 특성을 분석하여 그 응용성을 개발, 확보하였다.

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Fabrication and Mechanical Properties of STS316L Porous Metal for Vacuum Injection Mold (진공사출금형용 STS316L 금속 다공체 제조 및 기계적 특성)

  • Kim, Se Hoon;Kim, Sang Min;Noh, Sang Ho;Kim, Jin Pyeong;Shin, Jae Hyuck;Sung, Si-Young;Jin, Jin Kwang;Kim, Taean
    • Journal of Powder Materials
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    • v.22 no.3
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    • pp.197-202
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    • 2015
  • In this study, porous stainless steel (STS316L) sintered body was fabricated by powder metallurgy method and its properties such as porosity, compressive yield strength, hardness, and permeability were evaluated. 67.5Fe-17Cr- 13Ni-2.5Mo (wt%) powder was produced by a water atomization. The atomized powder was classified into size with under $45{\mu}m$ and over $180{\mu}m$, and then they were compacted with various pressures and sintered at $1210^{\circ}C$ for 1 h in a vacuum atmosphere. The porosities of sintered bodies could be obtained in range of 20~53% by controlling the compaction pressure. Compressive yield strength and hardness were achieved up to 268 MPa and 94 Shore D, respectively. Air permeability was obtained up to $79l/min{\cdot}cm^2$. As a result, mechanical properties and air permeability of the optimized porous body having a porosity of 25~40% were very superior to that of Al alloy.

Development of Application Block Using Geobond and Ash from Sewage Sludge Incinerator II (하수슬러지 소각재와 무기바인더를 이용한 응용 블록 개발 II)

  • Lee, Hyun-joo
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.7
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    • pp.412-417
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    • 2015
  • This study investigated to recycle geobond and ash produced in thesewage sludge incinerator using reduction/stabilization. Nonsintering process was performed by binding cement (High Early Strength Portland cement, Micro cement), geobond and sand mixed with sewage sludge ash (SSA). Chemical ingradients of the sewage sludge ash was mainly composed of $SiO_2$, $Al_2O_3$, $Fe_2O_3$, CaO and others, which were similar to those of the each binders consisting High Early Strength Portland cement, Micro cement and geobond. Results showed that unconfined the long term compressive strength could be obtained components of sewage sludge ash. It exceeded more than double score 64.6 MPa of the Korean standard ($22.54MPa=229.7kg/cm^2$). Microstructure of solidified block for the different admixture was related to the compressive strength according to SEM analysis. Optimum mixing range of the sewage sludge ash to each binders were found to be 10~40% which can widly safely regulate the confined a long term compressive strength. The best binder of long term compressive strengh was revealed Geobond more than High Early Strength Portland cement and Micro cement. This study revealed the sewage sludge ash can be partial replacement of the inorganic binder & application block for recycling.

Graphite Spheroidization in Cast Iron by Addition of Misch Metal Hydrides (주철(鑄鐵)의 흑연(黑鉛)구상화에 미치는 Misch Metal Hydride의 첨가효과(添加效果))

  • Kim, Kwan-Hyu;Lee, Doh-Jae;Choi, Dap-Chun;Park, Choong-Nyeun
    • Journal of Korea Foundry Society
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    • v.8 no.3
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    • pp.322-328
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    • 1988
  • 3.9%C-2.0%Si-Fe 조성의 압분체(壓粉體)를 $1350^{\circ}$, Ar가스 분위기에서 50분간 용해한 용탕에 시판(市販) misch metal과 misch metal hydride인 MmH와 $MmH_2$를 각각 여러비율로 첨가(添加)한후 서냉(徐冷)및 급냉(急冷)한 시편의 흑연형상(黑鉛形狀)의 변화로부터 misch metal hydride의 구상화능(球狀化能)과 흑연구상화(黑鉛球狀化) 기구(機構) 로서의 기포설(氣泡說)의 타당성을 고찰한 결과 다음과 같은 결론을 얻었다. 1) Misch metal은 0.5% 이상, 그리고 misch metal hydride는 0.25% 이상 첨가한 때 구상흑연(球狀黑鉛)과 CV 흑연(黑鉛)이 나타났으며, misch metal hydride를 첨가한 때가 misch metal에 비하여 흑연립수(黑鉛粒數)가 더 많았다. 이와같이 misch metal hydride의 첨가량이 misch metal에 비하여 적었음에도 흑연립수(黑鉛粒數)가 더 많은 것을 보면 Mm으로부터 방출되는 다수(多數)의 수소기포(水素氣泡)가 구상흑연(球狀黑鉛)의 정출장소로 되는 것으로 해석되기 때문에 기포설(氣泡說)이 타당하다고 생각된다. 2) Misch metal 과 misch metal hydride의 첨가량(添加量)이 1.0%로 증가되면 두경우 모두 흑연립수(黑鉛粒數)가 감소하였다. 이는 용탕중에 개재된 수소기포(水素氣泡)의 실수율차이에 의한 잔류 수소기포수의 증가율둔화와 첨가량(添加量)의 증가에 따른 잔류 misch metal량의 상대적(相對的) 증가로 인한 다량의 잔류 misch metal이 응고과정에서 수소를 재흡수 용해하여 흑연입수를 결정하는 용탕중의 유효수소기포수(有效水素氣泡數)를 감소시켰기 때문으로 생각된다.

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Development of Inorganic Binder Using Ash from Sewage Sludge Incinerator I (하수슬러지 소각재를 이용한 무기바인더 개발 I)

  • Lee, Hyun-Joo
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.12
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    • pp.843-850
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    • 2014
  • This study investigated to recycle ash produced in the sewage sludge incinerator using reduction/stabilization. Nonsintering process was performed by binding cement, geobond and sand mixed with sewage sludge ash (SSA). Results showed that unconfined compressive strength could be obtained components of sewage sludge ash. it exceeded more than double score of the 22.54 Mpa ($229.7kg/cm^2$) Korean standard. chemical ingradients of the sewage sludge ash was mainly composed of $SiO_2$, $Al_2O_3$, $Fe_2O_3$, CaO and others, which were similar to those of the each binders consisting cement and geobond. microstructure of solidified speceimen for the different admixture was related to the compressive strength according to SEM analysis. optimum mixing range of the sewage sludge ash to inorganic binder was found to be 10~40% which can widly safely regulate the confined compressive strength. This study revealed the sewage sludge ash can be partial replacement of the inorganic binder for recycling.

Fabrication and magnetic properties of Co-Zn ferrite thin films prepared by a sol-gel process (Sol-gel 법에 의한 Co-Zn Ferrite 박막의 제호와 자기 특성에 관한 연구)

  • 김철성;안성용;이승화;양계준;류연국
    • Journal of the Korean Magnetics Society
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    • v.11 no.4
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    • pp.168-172
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    • 2001
  • Co-Zn ferrite thin films grown on thermally oxidized silicon wafers were fabricated by a sol-gel method. Magnetic and structural properties of Co-Zn thin films were investigated by using x-ray diffractometer (XRD), atomic force microscopy (AFM), auger electron spectroscopy (AES) and a vibrating sample magnetometer (VSM). Co-Zn ferrite thin films annealed at 400 $^{\circ}C$ presented have only a single phase spinel structure without any preferred crystallite orientation. Their surface roughness of Co-Zn ferrite thin films was shown as less than 3 nm and the grain size was about 40 nm for annealing temperatures over 600 $^{\circ}C$. A moderate saturation magnetization of Co-Zn ferrite thin films for recording media was obtained in this study and there is no significant difference of their magnetic property with those external fields of parallel and perpendicular to planes of the films. The maximum value of the coercivity was obtained as 1,900 Oe for Co-Zn ferrite thin film annealed at 600 $^{\circ}C$.

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Impacts of Soil Microbial Populations on Soil Chemical and Biological Properties under Tropical Dry Evergreen Forest, Coromandel Coast, India

  • Sudhakaran, M.;Ramamoorthy, D.;Swamynathan, B.;Ramya, J.
    • Journal of Forest and Environmental Science
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    • v.30 no.4
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    • pp.370-377
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    • 2014
  • There are very few studies about soil chemical and biological properties under tropical dry evergreen forest Coromandel Coast, India. The present study was conducted in six tropical dry evergreen forests sites such as Oorani, Puthupet, Vadaagram, Kotthatai, Sendrakillai and Palvathunnan. We measured the quantity of soil chemical, biological properties and selected soil microorganisms for investigating the impacts of soil microbial populations on soil chemical and biological properties. The result showed that total N, P, Ca, S, Fe, Mn, Cu, Co, exchangeable K, Olson P, extractable Ca and phosphobacterial population were higher in the soil from Kothattai forest site. Organic carbon, total Mg, extractable Na, soil respiration, ${\beta}$-glucosidase activity, bacterial population, fungi population and actinomycetes population were higher in the soil from Palvathunn forest site. Total K, $NH_4{^+}$-N, $NO_3{^-}$-N, exchangeable K, extractable Ca, extractable Na, azotobacter population, bacillus population and rhizobacteria population were higher in the soil from Sendrakillai. Beijerinckia population, rhizobacteria and soluble sodium were higher in Puthupet forest soil. Total Si, total Na and exchangeable K were higher in soil from Oorani forest site. Total Mo and exchangeable K were higher in the soil from Vadaagaram forest site. The results showed that organic carbon, total N, $NH_4{^+}$-N, $NO_3{^-}$-N, extractable P, extractable Ca, soil respiration and ${\beta}$-glucosidase were significantly correlated with soil microbial populations. Therefore soil microorganisms are important factor for maintaining soil quality in tropical dry evergreen forest.

The Physio-Chemical Characteristics of Aerosol in Urban Area During Snowfall (강설시 도심지역 에어러솔의 물리.화학적 특성)

  • 김민수;이동인;유철환
    • Journal of Environmental Science International
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    • v.10 no.3
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    • pp.201-208
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    • 2001
  • To investigate the physio-chemical components and properties of aerosol particles in urban area sampling of aerosol particles was carried out in the campus of Hokkaido University, Sapporo, Japan, during snowfall. Aerosol particles were collected on millipore filter papers using a low volume air sampler. Their shapes, sizes and chemical components were analyzed by a SEM(Scanning Electron Microscope) and an EDX(Energy Dispersive X-ray). As a results, ice crystals of dendrite and column types were predominantly shown at mature and developing stage of snowfall intensity. The denerite and sector plate types of ice crystals were mainly originated from the sea but column types were come from soil. Scavenging effect by snowfall was greatly also shown at dendrite type ice crystals that embryo was fully developd. Al, Si elements were shown at high frequencies as compared with others. Na, Cl components were especially shown at high frequencies under the sea-breeze wind during snowfall. Anthropogenic aerosol particles had shown with irregular shapes and sizes, relatively. Mainly 3-7$\mu$m aerosol particles were abundant and coarse particles also could be seen during snowfall. Ca, Zn, Fe components mainly caused by spike tires from vehicles in winter season were dominant before snowfall, however the element S mainly caused by human activity was rich after snowfall. The pH values of snow in Sapporo city were higher than those at coastal area. The concentration of chemical components in aerosol particles was also affected by surface winds. Aerosol particles in urban area, Sapporo were mainly affected by human activities like vehicles and combustion with wind system. And their types were related with snowfall intensity.

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The Scientific Analysis of Floor Tile Excavated from the Beobgwangsa Temple Site in the Pohang (포항 법광사지 출토 녹유전의 자연 과학적 조사)

  • Moon Whan-Suk;Han Min-Su;Hwang Jin-Ju;Kim Ho-Sang
    • KOMUNHWA
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    • no.60
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    • pp.101-120
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    • 2002
  • The floor tile on a coated green-glass was excavated from the Beobgwangsa Temple Site in the Pohang City. We analyzed using the MXRD, ICP-AES, EDXRF, TG/DTA and TIMS. As a result of microscope analysis, it was composed of quartz, feldspar and clay particl

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Pore-Controlled Synthesis of Mesoporous Silica Particles by Spray Pyrolysis from Aqueous Silicic Acid (규산 수용액으로부터 분무열분해법에 의한 기공 특성이 제어된 메조기공의 다공성 실리카 분말 합성)

  • Chang, Han Kwon;Lee, Jin Woo;Oh, Kyoung Joon;Jang, Hee Dong;Kil, Dae Sup;Choi, Jeong Woo
    • Particle and aerosol research
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    • v.8 no.2
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    • pp.89-95
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    • 2012
  • Spherical mesoporous silica particles, of which main pore diameter was 3.8 nm, were successfully prepared by spray pyrolysis from aqueous silicic acid. The effect of precursor concentration, reaction temperature, and the addition of urea and PEG on the particle diameter and pore properties such as pore diameter, total pore volume, and specific surface area were investigated by using FE-SEM, particle size analyzer, and nitrogen absorption-desorption analysis. With an increase of the precursor concentration from 0.2 M to 0.7 M, the average particle diameter, total pore volume, and specific surface area of the porous silica particles increased from 0.56 to $0.96\;{\mu}m$, 0.434 to $0.486\;cm^3/g$, 467.8 to $610.4\;m^2/g$, respectively. Within the temperature range $(600\;^{\circ}C{\sim}800\;^{\circ}C)$, there was no significant difference in the pore diameter, total pore volume, and specific surface area. In addition, the addition of urea as an expansion aid led to slight increases in particle diameter, pore diameter, and specific surface area. However, when the polyethylene glycol (PEG) as an organic template was used, the total pore volume of porous particles increased dramatically.