• Title/Summary/Keyword: 2A11

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Photochemistry of 1-(o-Hydroxyphenyl)-2-pentamethyldisilanylethyne : Photoreaction in a Concentrated Benzene Solution and Photoreaction with Methanol or Acetone

  • Park, Seong Gi
    • Bulletin of the Korean Chemical Society
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    • v.22 no.11
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    • pp.1202-1206
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    • 2001
  • Irradiation of 1-(o-hydroxyphenyl)-2-pentamethyldisilanylethyne 1 in a concentrated benzene solution has provided photodimer product 7 along with other reported photoproducts. Irradiation of 1 in methanol yields 1-(o-hydroxyphenyl)-2-trimethylsilylethyne 2 and its reduction product 13, via silacyclopropene intermediate 10, and the reduction product 8 and two methanol addition products, 11 and 12, via o-hydroxyphenylethyne. Photolysis of 1 with acetone in deaerated methylene chloride affords site specific and regioselective 1 : 1 adduct 16 via silacyclopropene intermediate 10.

Analysis of Toughening Mechanism of Ceramic Composites by Acoustic Emission (AE(Acoustic Emission)에 의한 세라믹 복합재료의 고인성화 기구 분석)

  • 장병국
    • Journal of the Korean Ceramic Society
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    • v.34 no.11
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    • pp.1129-1138
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    • 1997
  • Al2O3/20 vol%YAG composite containing equiaxed grains and Al2O3/20 vol%LaAl11O18 composite containing elongated grains were fabricated using Al2O3-Y2O3 composition and Al2O3-La2O3 composition, respectively, by hot-pressing. In order to investigate the influence of microstructural control of second phase on toughening effect of toughened ceramic composites, AE (acoustic emission) measurements have been coupled with fracture toughness experiments(SENB and SEPB method). A separation of the fracture toughness and analysis of toughening mechanism was possible using the AE technique. The fracture toughness of hot-pressed materials was estimated to be 3.2 MPam0.5 for monolithic alumina, 4.7 MPam0.5 for Al2O3/20 vol%YAG composite and 6.2 MPam0.5 for Al2O3/20 vol%LaAl11O18 composite. In monolithic Al2O3, toughening does not occur as a result of either microcracking or grain bridging, whereas, composites exhibit toughening effects by both microcracking in the frontal zone and gain bridging in the wake zone, resulting in an improvement of fracture toughness as compared with monolithic Al2O3. The fracture toughness of Al2O3/20 vol%LaAl11O18 composite is higher than that of Al2O3/20 vol%YAG composite. It may be attributed to the elongated microstructure of Al2O3/20 vol%LaAl11O18 composite, resulting relatively greater bridging effect.

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CNN based IEEE 802.11 WLAN frame format detection (CNN 기반의 IEEE 802.11 WLAN 프레임 포맷 검출)

  • Kim, Minjae;Ahn, Heungseop;Choi, Seungwon
    • Journal of Korea Society of Digital Industry and Information Management
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    • v.16 no.2
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    • pp.27-33
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    • 2020
  • Backward compatibility is one of the key issues for radio equipment supporting IEEE 802.11, the typical wireless local area networks (WLANs) communication protocol. For a successful packet decoding with the backward compatibility, the frame format detection is a core precondition. This paper presents a novel frame format detection method based on a deep learning procedure for WLANs affiliated with IEEE 802.11. Considering that the detection performance of conventional methods is degraded mainly due to the poor performances in the symbol synchronization and/or channel estimation in low signal-to-noise-ratio environments, we propose a novel detection method based on convolutional neural network (CNN) that replaces the entire conventional detection procedures. The proposed deep learning network provides a robust detection directly from the receive data. Through extensive computer simulations performed in the multipath fading channel environments (modeled by Project IEEE 802.11 Task Group ac), the proposed method exhibits superb improvement in the frame format detection compared to the conventional method.

Design and Comparison of the Pipelined IFFT/FFT modules for IEEE 802.11a OFDM System (IEEE 802.11a OFDM System을 위한 파이프라인 구조 IFFT/FFT 모듈의 설계와 비교)

  • 이창훈;김주현;강봉순
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.8 no.3
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    • pp.570-576
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    • 2004
  • In this paper, we design the IFFT/FFT (Inverse fast Fourier Transform/Fast Fourier Transform) modules for IEEE 802.11a-1999, which is a standard of the High-speed Wireless LAN using the OFDM (Orthogonal Frequency Division Multiplexing). The designed IFFT/FFT is the 64-point FFT to be compatible with IEEE 802.11a and the pipelined architecture which needs neither serial-to-parallel nor parallel-to-serial converter. We compare four types of IFFT/FFT modules for the hardware complexity and operation : R22SDF (Radix-2 Single-path Delay feedback), the R2SDF (Radix-2 Single-path Delay feedback), R2SDF (Radix-4 Single-path Delay Feedback), and R4SDC (Radix-4 Single-path Delay Commutator). In order to minimize the error, we design the IFFT/FFT module to operate with additional decimal parts after butterfly operation. In case of the R22SDF, the IFFT/FFT module has 44,747 gate counts excluding RAMs and the minimized error rate as compared with other types. And we know that the R22SDF has a small hardware structure as compared with other types.

Condensation heat transfer characteristics of alternative refrigerants for CFC-11, CFC-12 for enhanced tubes (열전달 촉진관에서 CFC-11 및 CFC-12 대체냉매의 응축 열전달 특성 연구)

  • 조성준;황수민;정동수;김종보
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.10 no.5
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    • pp.569-580
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    • 1998
  • In this study, condensation heat transfer coefficients(HTCs) of a plain tube, low fin tube, and Turbo-C enhanced tube for CFC-11, HCFC-123, CFC-12, HFC-l34a are measured and compared against each other. All data are taken at the vapor temperature of 39$^{\circ}C$ with a wall subcooling temperature 3~8$^{\circ}C$. Test results show that HTCs of a low vapor pressure refrigerant, HFC-123, for a plain, low fin, and Turbo-C tubes are 10.5~20.5%, 8.2~12.2%, 16.5~19.2% lower than those of CFC-11, respectively. On the other hand, HTCs of a medium vapor refrigerant, HFC-l34a, for a plain, low fin, and Turbo-C tubes are 20.6~31.8%, 0.0~8.0%, 13.2~20.9% higher than those of CFC-12, respectively. For all refrigerants tested, HTCs of Turbo-C tube are the highest among the three tubes showing almost 8 times increase in HTCs as compared to those of a plain tube. Nusselt's prediction equation for a plain tube yielded 12% deviation for all plain tube data while Realty and Katz's prediction equation for a low fin tube yielded 20% deviation for all low tube data.

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Busy-tone PHY Module with IEEE 802.11 Design and Implementation in NS-2 (NS-2에서 IEEE 802.11의 Busy-tone PHY 모듈 설계 및 구현)

  • Yoo, Dae-Hun;Choi, Woong-Chul
    • Journal of the Korea Society of Computer and Information
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    • v.13 no.7
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    • pp.189-197
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    • 2008
  • ENS-2 simulator is the most widely-used simulator in the research of wired/wireless communication. Since an IEEE 802.11 module has been implemented in NS-2. much research using this module has been done for various MAC layer functions. The most important problem in terms of performance is the hidden terminal problem. To solve this problem, the solutions using a busy-tone such as BTMA, DBTMA, etc. have been proposed. In order to be able to use a busy-tone, channels using the frequency bandwidth except the frequency bandwidth of the data channel is required for the collision prevention, and a MAC layer has to be able to menage such multiple channels. In this research, we implement a module that can use a busy-tone in NS-2, implement a modified RI-BTMA by applying the implemented module, and verify its performance.

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A Study on the Progression and Prevalence of Myopia according to Age for the Last Five Years : from 2008 to 2012 (최근 5년간 연령에 따른 근시 유병률 진행에 관한 연구 : 2008년에서 2012년 중심으로)

  • Lee, Wan-Seok;Ye, Ki-Hun;Shin, Bum-Joo
    • Journal of Korean Ophthalmic Optics Society
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    • v.19 no.1
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    • pp.121-133
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    • 2014
  • Purpose: In this study, we analyzed the progression and prevalence of myopia according to age for the last five years. Methods: We have done a comparative analysis of the progression and prevalence of myopia with the Korean National Health and Nutrition Examination Survey document from 2008 to 2012. Results: According to classification of myopia by age group for the last five years, the prevalence of low myopia was 25.5% for 5-11ages group, 25.1% for 12-18ages, 27.3% for 19-29ages, 30.7% for 30-39ages, 29.6% for 40-49ages, 19.2% for 50-59ages, 11.8% for 60-69ages, and 20.2% for over 70ages respectively. The prevalence of moderate myopia was 21.7% for 5-11ages group, 43.6% for 12-18ages, 36.2% for 19-29ages, 30.0% for 30-39ages, 20.4% for 40-49ages, 9.9% for 50-59ages, 5.2% for 60-69ages, and 7.6% for over 70ages respectively. The prevalence of high myopia was 2.1% for 5-11ages group, 11.7% for 12-18ages, 11.5% for 19-29ages, 6.9% for 30-39ages, 5.6% for 40-49ages, 1.9% for 50-59ages, 1.5% for 60-69ages, and 1.0% for over 70ages respectively. Conclusions: We must recognize an importance to the increase of the progression and prevalence of myopia, so it is necessary to provide a social interest in prevention of deteriorating vision and eye health welfare.

Design of a broadband(2㎓-5.8㎓) FET Switch Using Impedance Transformation Network (임피던스 변환회로를 이용한 광대역(2㎓-5.8㎓) FET 스위치 설계)

  • 노희정
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.18 no.4
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    • pp.155-159
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    • 2004
  • This paper describes the design and the simulation of a single pole double throw(SPDT) FET switch for wireless LAN(IEEE802.11a & IEEE802.11b) applications using drain impedance transformation network with Microstrip transmission line. At the receiving path insertion losses were from 0.8(㏈) to 1.462(㏈) between 2(㎓) and 4(㎓), from l.26(㏈) to 2.3(㏈) between 4.7(㎓) and 6.7(㎓) and the isolations were under 30(㏈) between 2(㎓) and 6.7(㎓). At the transmitting path insertion loss were from 1.18(㏈) to 2.87(㏈) between 2(㎓) and 4(㎓) from 0.625(㏈) to 1.2(㏈) between 4.7(㎓) and 6.7(㎓) and the isolations were under 30(㏈) between 2(㎓) and 6.7(㎓).

Synthesis and Crystal Structure of the Cadmium(II) Complex with Thiocyanate and 1,2-Diaminocyclohexane Ligands (Thiocyanat 및 1,2-Diaminocyclohexane 리간드로 구성된 카드뮴(II) 착물의 합성 및 결정구조)

  • 김인회;서승욱;김종혁;김진규;서일환
    • Korean Journal of Crystallography
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    • v.12 no.4
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    • pp.207-211
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    • 2001
  • The crystal structure of the title complex, Cd(SCN)₂{CH/sub 6/H/sub 10/(NH₂)₂}₂(1) has been analyzed by X-ray single crystallography. The complex 1 crystallizes in the monoclinic system P2₁/ space group with a=11.842(2), b=7.926(2), c=11.291(2) Å, β=106.73(3)°V=1014.8(4)Ų, Z=2, R₁=0.0518 and ωR₂=0.1315 for 1775 independent reflections. The central Cd(II) atom of this com-plex has a slightly distorted octahedral coordination geometry, with the 1,2-Diaminocyclohexane ligands functioning as an N,N'-bidentate and the thiocyanate ligands bonding through the sulfur atom in a trans arrangement.

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Synthesis and Phytotoxic Activities of (8S, 9S, 11R)-(-)-Monocerin and (9S, 11R)-(+)-Fusarentin 4, 5-dimethyl ether ((8S, 9S, 11R)-(-)-Monocerin and (9S, 11R)-(+)-Fusarentin 4, 5-dimethyl ether의 합성과 생리활성)

  • Ko, Byoung-Seob
    • Applied Biological Chemistry
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    • v.37 no.5
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    • pp.402-408
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    • 1994
  • For the examination of the role of monocerin(1) on the biological activity, (8S, 9S, 11R)-(-)-monocerin(20) and (9S, 11R)-(+)-fusarentin 4, 5-dimethyl ether(19) were synthesized by a condensation of the benzylic anion of ethyl 2, 3, 4-trimethoxy-6-methylbenzoate(16) with modifyed (R)-ethyl 3-hydroxyhexanoate (9). In a key step, bioreduction with active dried baker's yeast in organic solvent system was employed to get a chiral aldehyde 12. Their phytotoxic activities were tested on rice seedlings and lettuce seeds.

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