• Title/Summary/Keyword: 28S

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Optical Properties of Mid-infrared Transparent ZnS Ceramics with Different Molar Ratio of S/Zn (S/Zn의 몰비에 따른 중적외선 투과용 ZnS 세라믹스의 소결과 광학적 특성)

  • Yeo, Seo-Yeong;Park, Buem-Keun;Kim, Chang-Il;Paik, Jong-Hoo
    • Journal of Sensor Science and Technology
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    • v.28 no.4
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    • pp.256-261
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    • 2019
  • In this study, mid-infrared transparent zinc sulfide (ZnS) ceramics were fabricated through hydrothermal synthesis with different molar ratios of S/Zn (S/Zn = 0.8, 1.0, 1.2, 1.4, and 1.6). The ZnS ceramics were sintered at a relatively low temperature of $850^{\circ}C$ to prevent the occurrence of the hexagonal phase featuring optical anisotropy. The phase composition, microstructure, and optical properties of the ZnS ceramics were subsequently investigated by employing X-ray diffraction, scanning electron microscopy, and Fouriertransform infrared spectroscopy. The results obtained indicate that the ZnS nanoparticles feature the cubic phase, without the hexagonal phase. Moreover, with increasing S, the crystallinity and particle size of the ZnS nanoparticles increased. The crystallinity and density of the ZnS ceramics improved when the molar ratio of S was higher than the molar ratio of Zn, thereby enhancing the transmittance. Furthermore, the ZnS ceramic with an S/Zn value of 1.2 was found to exhibit the highest transmittance of approximately 69% owing to the reduced occurrence of the hexagonal phase and a high density of 99.8%.

Effects of Initial Defoliation Stage and Defoliation Interval on the Growth of White Clover Cultivars Differing in Leaf Size (최초예취시간 및 예취간격이 엽의 크기가 다른 White Clover 품종들의 생장에 미치는 영향)

  • 강진호
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.37 no.3
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    • pp.264-273
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    • 1992
  • Availability of white clover (Trifolium repens L.) has been limited due to its poor introduction to swards and lack of persistence under improper grazing management. This experiment was conducted to determine the effects of initial defoliation stage and defoliation interval on the growth of white clover varieties. Individual plants of Regal (large leaf), Louisiana S.1 (medium-large leaf), Grasslands Huia (medium-small leaf) and S184 (small leaf) were grown in containers (4.5 $\times$ 13.5 cm) containing a 1:2:1 soil:sand:Promix until reaching to the stage of 1, 4, or 8 trifoliolates, and then clipped to remove all fully expanded leaves every 7 or 28 days (d). For analysis of morphological parameters, plants were sampled on the final harvest date (0 d), and 7, 14, 21, and 28 d after the final harvest date. Harvested dry weight (dw) of all varieties declined as defoliation interval declined or initial defoliation was made earlier. That of Regal was the highest as initial defoliation was delayed. On the 7 d regrowth shoot and root dw were increased as initial defoliation was delayed or interval lengthened, whereas on the 28 d regrowth the trend was alleviated. Root dw and biomass of Regal were higher than the other varieties during the whole regrowing period, when the increase of biomass resulted from that of shoot dw. Leaf areas and petiole lengths of all varieties declined under 7 d defoliation interval. The area and the length declined with earlier initial defoliation on the 7 d regrowth but not on the 28 d regrowth. Stolon length and growing tips of S184 were the highest and increased more steeply during regrowth, while those of Regal were the lowest and did slightly. It is concluded that the continuous defoliation and the first defoliation at earlier growth stage have detrimental effects on growth of white clover, although larger leaf types are more productive but less persistent in a sward than smaller leaf types.

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