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The effects of moisture content in precursor powder for Bi-2223/Ag tape (Bi-2223/Ag 선재의 전구 분말에서 수분함량에 따른 효과)

  • 김성환;유재무;고재웅;김영국;김철진
    • Progress in Superconductivity
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    • v.4 no.2
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    • pp.162-167
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    • 2003
  • The critical current value of Bi-2223/Ag tape can be influenced by various factors. In particular, it was known that properties of precursor powders could affect the formation of Bi -2223 and grain growth rate of the same. Since, moistures and organic matters can easily contaminate the precursor powders of Bi-2223 tapes and degrade properties of superconductors, the precursor powders should be kept in optimal conditions to minimize contamination. In this study, the effect of moisture and organic matters has been investigated. A Bi-2223/Ag tape contaminated with a large amount of moisture and organic matter has been characterized by low critical current values and bubbling. It has been found that as the quantity of moisture increases, the Bi-2223 phases are formed at lower temperature and the amount of non-superconducting phase increases.

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superconducting properties of Bi-2223 tapes with various heat treatment condition (열처리 온도 및 분위기 변화에 따른 Bi-2223 초전도 선재에서의 특성변화)

  • 하동우;이동훈;하홍수;오상수;김홍대;양주생;윤진국;최정규;권영길
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07a
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    • pp.527-530
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    • 2002
  • A lot of efforts have been focused on the optimization of PIT parameters for Bi-2223/Ag wire. In this paper, initial annealing of Bi-2223/Ag wire to transform Bi-2212 orthorhombic from Bi-2212 tetragonal Precursor was investigated. This initial annealing step at low oxygen partial pressure were to transform Bi-2212 orthorhombic structure and to reduce the formation of second phases at superconducting wire. However Bi-2223 Phases were appeared at higher annealing temperature. Critical currents(Je) of Bi-2223/Ag tapes were sintered at low oxygen Partial pressure were higher than that of the wires sintered at atmosphere condition. In order to investigate the effect of rolling reduction ratio, Bi-2223/Ag HTS tapes were rolled with different reduction ratio. There were no clear difference of Je and filaments shape with various rolling reduction ratio.

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The effect of heat treatment mass flow on superconducting property of Bi-2223/Ag Tapes. (열처리 가스유량에 따른 Bi-2223/Ag 초전도 테이프의 특성에 미치는 영향)

  • 양주생;하동우;이동훈;최정규;황선역;오상수;김상철;김명호
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2003.10a
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    • pp.96-98
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    • 2003
  • Many of research efforts have been focused on the improvement of critical current density Jc of silver-sheathed Bi-2223 tapes for practical applications of material. Bi-2223 superconducting wires with 55 filaments were fabricated by stacking, drawing process with different heat-treatment histories. After rolling process, Bi-2223 tapes were heat-treatment at 780~826$^{\circ}C$ with variable mass flow rate of mixed gas. In this study, the effect of changes in the variable mass flow rate of mixed gas during the heat treatment of Bi-2223/Ag tapes has been investigated. Distinct differences were observed in the Bi-2223 phase and critical current as flow rate of mixed gas. We could achieve proper conditions of mass flow rate of mixed gas for Ag-alloy clad Bi-2223 superconducting tapes.

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Mechanical properties at Bi-2223 HTS tapes with various sheath materials (기지금속을 달리한 Bi-2223 초전도 선에서의 기계적 특성 변화)

  • Ha, Dong-Woo;Lee, Dong-Hoon;Yang, Joo-Sang;Kim, Sang-Chul;Hwang, Sun-Yuk;Ha, Hong-Soo;Oh, Sang-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.551-554
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    • 2004
  • Bi-2223 HTS tapes are used widely for application of superconducting power systems. However there are need the properties of high strength and low AC loss. Two kinds of Bi-2223 HTS tapes with different Ag sheath were used to know the effect of sheath alloying for the strength and the resistivity. The workability and reaction degree of superconducting phase at Bi-2223 HTS tapes were investigated. We designed conventional type-Ag/alloy and double sheathed mono filament type-Ag/alloy/alloy in order to increase the strength and resistivity of matrix in Bi-2223 HTS tapes. The effect of axial strain and thermal cycling on the critical current was investigated for the Bi-2223 HTS tapes. Because the workability of double sheath Bi-2223 HTS tape was lower than one sheath Bi-2223 HTS tape, it was need additional softening treatment. Bi-2223 formation reaction was decreased by Ag alloy matrix during sintering process. Two kinds of Bi-2223/Ag tapes with different Ag sheath were used to know the effect of sheath alloying for the tensile strain. Critical current is drastically decreased for Ag/alloy and Ag/alloy/alloy sheathed tapes at tensile strain above 0.24 % and 0.34 %, respectively. This result showed that mechanical strength was increased over than 40 % by introduce double sheath at mono filament stage.

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Properties of Bi-2223/Ag HTS tapes using different content of precursors (조성이 다른 전구체 분말에 따른 Bi-2223/Ag 초전도 테이프의 특성 변화)

  • Ha, Dong-Woo;Yang, Joo-Saeng;Ha, Hong-Soo;Oh, Sang-Soo;Hwang, Sun-Yuk;Lee, Dong-Hoon;Choi, Jung-Kyu;Lee, En-Yong;Kwon, Young-Kil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05a
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    • pp.69-72
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    • 2003
  • Bi-2223 superconducting wires were fabricated by stacking, drawing process with different precursor powders and different heat-treatment histories. The precursor powders were 2 kinds of Pb content. And a part of the tapes were experienced pre-annealing process which caused tetragonal structure of Bi-2212 phase to orthorhombic structure of it was during drawing process. We confirmed the transformation of Bi-2212 phase from tetragonal structure to orthorhombic structure and reduction of second phases. XRD and DC magnetization analysis were performed in order to investigate the fraction of Bi-2223 phase in Bi-2223/Ag HTS tape. We could achieve best Ic of 70 A class at the Bi-2223/Ag tape using low Pb content of precursor powder and experienced pre-annealing process. DC magnetization analysis was useful to investigate the fraction of Bi-2223 phase in the Bi-2223/Ag tape.

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Mechanical Characteristics of Bi-2223 Wire for High-Tc Superconducting Cable (고온 초전도 케이블용 Bi-2223 선재의 기계적 특성)

  • 백승명;김영석;정순용;김상현
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.11
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    • pp.1028-1034
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    • 1998
  • Bi-2223 superconductor is known as one of the candidates for practical superconducting wires. Ag-sheathed Bi-2223 superconducting wires were fabricated using the powder-in-tube(PIT) method. When the 19-filaments wire was immersed in liquid nitrogen(77K), maximum critical current density Jc of 62 A/$mm_2$ at 0T was achieved. The critical current density has been shown to depend on the mechanical properties such as tensile stress and bending strain in Ag-sheathed Bi-2223 superconducting wires. The tensile strain for Jc degradation onset was in the range of 0.12~0.3%. In the case of 19-filaments wire, the bending strain is estimated to be smaller than 0.3% for the reasonable Jc value. The observed degradation of the critical current density due to strain effect is inevitable and can be attributed to the formation of microcracks within the superconducting core.

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The change of critical current with crack formation in a Bi-2223/Ag tape (크랙에 의한 Bi-2223/Ag 테이프의 임계전류 변화)

  • 박을주;설승윤
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2002.02a
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    • pp.249-252
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    • 2002
  • The change of critical current with a crack formation in a Bi-2223/Ag tape was studied by experimental and numerical analyses. Critical current of Bi-2223/Ag tape was measured with a continuous DC-power supply. The current-voltage relation of a Bi-2223/Ag tape is measured by the four point method. Numerical method is used to solve two dimensional heat conduction equation. By comparing the experimental and numerical results, the validity of numerical method is verified.

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Fault Current Characteristics of a Bi-2223 Tape (Bi-2223테이프의 사고전류 특성)

  • 류경우;차귀수
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2001.02a
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    • pp.65-67
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    • 2001
  • Temperature and resistance of a Bi-2223 tape for fault currents up to 10 $I_{c}$ were measured in two types of samples taking into account real applications. The results indicate that the Bi-2223 tape is safe from burn-out for fault currents with a few cycles up to 10 I$_{c}$. For fault currents of over an order of magnitude higher than the nominal current, the temperature of the Bi-2223 tape depends strongly on fault durations.s.

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