• Title/Summary/Keyword: 210Pb

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An Assessment of the Long-Term Concentration of Heavy Metals and Associated Risk in Ambient PM-10 (PM-10 내 중금속의 장기간 평균농도 및 위해도 평가)

  • 이혜문;김동술;이진홍
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.5
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    • pp.555-566
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    • 1996
  • In order to assess the long-term airborne concentrations of 6 metals such as Cr, Cd, Pb, Zn, K, and Na and the associated health resk, a great number of PM-10 samples were collected and analyzed in Kyung Hee University-Suwon Campus for three years from 1991 to 1993. The 3-year average concentration of Pb in respirable particulate matters was 142.6 ng/m$^{3}$ while that of Zn was 1,210.5ng/m$^{3}$. The corresponding hazard index from Pb Zn for the ingalation route was estimated to be 9.5.times.10$^{-2}$ and 3.5.times.10$^{-2}$ , respectively. Therefore, it can be said that there was no adverse chronic health effects by airborne Pb and Zn. However, the 2-year average concentration of Cr(6) was estimated to be 1.3ng/m$^{3}$ shile the 3-year average concentration of Cd was 3.1ng/m$^{3}$. The total cancer risk by these two metals for the inhalation route was estimated to be about 7.2.times.10$^{-6}$ . This order-of-magnitude risk estimate suggests that the ingalation risk in the study area from all carcinogenic metals including As and Ni (subsulfide) might exceed the acceptable risk criteria of 10$^{-5}$ -10$^{-6}$ by U.S.EPA.For a better risk assessment in the future, alveolar deposition of PM-10 in the study area were also discussed and an assessment was done.

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Amperometric Electronic Tongue Based on Metal Oxide Containing Carbon Paste Electrode Array (금속 산화물을 포함한 탄소반죽 전극 어레이로 제작한 전자 혀)

  • Han Jong Ho;Kim Dong Sun;Kim Jong Sik;Yoon In Jun;Cha Geun Sig;Nam Hakhyun
    • Journal of the Korean Electrochemical Society
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    • v.7 no.4
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    • pp.206-210
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    • 2004
  • All array of carbon paste-based electrodes was prepared by screen printing the carbon paste modified with metal oxides $(TiO_2,\;RuO_2,\;PbO_2,\;Ni(OH)_2)$ and Prussian blue (PB). An electronic tongue system was assembled with the carbon-paste electrode array, and applied to discriminate the tastes of various commercial beverages and foods by measuring the chronoamperometric responses to the samples diluted in 0.1M carbonate buffer (pH 9.6). The results were analyzed with principal component analysis(PCA) method and plotted on two dimensional PCA coordinate; it was apparent that the amperometric electronic tongue system could discriminate the types of various foods and beverages.

Distributions and Pollution History of Heavy Metals in Nakdong Estuary Sediments (낙동강 하구역 퇴적물 중금속의 분포와 오염의 역사 추정)

  • Cho, Jin-Hyung;Park, Nam-Joon;Kim, Kee-Hyun
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.5 no.4
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    • pp.285-294
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    • 2000
  • In order to determine the horizontal and vertical distributions of metals and prospect the recent metal pollution history in Nakdong Estuary, we took surface and core sediments. Maximum value of organic matter occurs at the upstream site located 4 km from Nakdong barrage, and the concentration of trace metals (Zn, Cu, and Pb etc.) decrease seaward in the estuary. The sedimentation rates, based on $^{210}$Pb$_{ex}$ and $^{137}$Cs activities, were 0.34 cm/yr in inside of barrage (core 1) and 0.25 cm/yr in Changrim (core 4). Sediment mixing layer does not exist in core 1, where anoxic condition is known to be prevail. The topmost sediment layer of core 4 (<3.5 cm) is severely mixed. At sites 1 and 4, concentrations of Cu slowly increased during the period of 1920-1970, rapidly increased during 1970-1990, and followed by slight decrease after 1990. Zn contents increased in early 1960s and peaked in 1993, and followed by decrease after 1990s. Pb has increased continuously since early 1970s. At the downstream of the barrage, Cu and Zn have increased in the topmost layer. The trend of increase of Cu is evident after 1950 (11 cm in sediment depth). Overall trend of heavy metal concentration clearly indicates the pollution has been increasing after the construction of the barrage.

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Pollution of Heavy Metals and Sedimentation Rate in the Sediments of Suyeong Bay, Pusan (수영만 퇴적물의 퇴적속도와 중금속 오염)

  • YANG Han-Soeb;KIM Seong-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.27 no.5
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    • pp.643-658
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    • 1994
  • The sedimentary records of anthropogenic metal loads in the Suyeong Bay, Pusan were determined by combining the Pb-210 dating technique with the measurements of heavy metals in the sediment cores. The sedimentation rates of sediment particles ranged from $0.12\;to\;0.20\;g/m^2/yr\;or\;2.4{\sim}4.0\;mm/yr$ in accumulation rates. The lowest sedimentation rate was observed at station S3 which was characterized by a bottom with relatively low organic matter contents(e.g. TIL and TOC). Heavy metals showed generally higher concentrations at station S1 and S2 near the mouth of the Suyeong River than at station S3 and the outmost station S4. The contents of copper, lead and zinc in the sediment cores especially from station S1 and S2 began to increase around 1930, and were at their highest levels in the $1960{\sim}1970$ period as a result of increasing industrial activities. Concentrations of these heavy metals have slightly decreased since 1970, probably due to regulation of pollution discharge. The natural background levels of copper, lead and zinc in the sediments of this bay ranged $18{\pm}4ppm,\;28{\pm}6ppm\;and\;74{\pm}9ppm$, respectively, by averaging the contents in the sediment depths corresponding to periods between about 1900 and 1920 at the four stations. The total amounts of anthropogenic loads deposited in the sediments since about 1930 were estimated to be $9{\sim}291{mu}g/cm^2$ for lead, $165{\sim}1122{mu}g/cm^2$ for zinc and $20{\sim}208{mu}g/cm^2$ for copper. These values were remarkably high at stations S1 and S2 relative to the other two stations. At stations S1 and S2, the anthropogenic loads of lead, copper and zinc constituted $29{\sim}30\%,\;32{\sim}42\%\;and\;28{\sim}35\%$ of the total sedimentary inventories at the present day, respectively. These metal contents have a good correlation(r>0.7) with each other and cadmium measurements also show a positive linear relation with nickel or total organic nitrogen.

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Properties and Formaldehyde Emission of Particleboards Fabricated with Waste Wood Charcoal (폐목재 탄화물로 제조한 파티클보드의 물성과 포름알데히드 방출량)

  • Park, Sang-Bum;Lee, Sang-Min;Park, Jong-Young;Kang, Eun-Chang
    • Journal of the Korea Furniture Society
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    • v.18 no.3
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    • pp.205-210
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    • 2007
  • Particleboard(PB) is one of the most commonly used wood-based composite materials, which can be prepared by utilizing any kind of low grade wooden materials like waste wood which contains formaldehyde itself. Therefore, PB have been of considerable interest, in issues regarding the formaldehyde emission problems. Wood wastes are carbonized by the carbonization kiln at $800^{\circ}C$. Charcoal has been known as a formaldehyde adsorber. Thus, in this study, we fabricated PBs with carbonized waste particles cores, to examine the possibility of developing less formaldehyde emitting boards. The physical and mechanical properties were evaluated by Korean Standard (KS F 3104). The moisture content of PBs ranged from 6.76 to 8.36%. Internal bond strengths decreased with the increase in the content of carbonized core particles. Formaldehyde emission showed minimum value at 25% of carbonized core particles, but the emission values increased when the amount of carbonized cote particles increased. When 25% of carbonized core particles was used, PBs met KS F 3104 standard properties.

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Heavy Metal Contents and Food Safety Assessment of Processed Seaweeds and Cultured Lavers (국내 가공 해조류와 미가공 김의 중금속 함량 및 식품 안전성평가)

  • Yang, Won Ho;Lee, Hyo Jin;Lee, Sang Yong;Kim, Seong Gil;Kim, Gi Beum
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.19 no.3
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    • pp.203-210
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    • 2016
  • In this study, nine heavy metals were analyzed in seaweeds collected from market and laver culture farm of Korea and a food safety assessment were also carried out for these heavy metals. The level of heavy metal concentrations in seaweeds was in the following order: Fe>As>Zn>Cu>Cd>Pb>Cr>Ni>Hg. Except for zinc and cadmium, seven heavy metals were significantly higher in cultured laver than in processed laver. Significant correlation was observed Cr-Fe in cultured laver and Cu-Zn, Cd-Cu, Cd-Zn and Pb-Ni in processed laver and Cu-Cr, Cu-Zn, Cd-Cr and Ni-Fe in sea tangle and Zn-Fe, Cr-Fe, Cr-Zn, Cd-Ni, Cu-Cd and Cu-Pb in processed sea mustard. Considering differences in heavy metal concentration between processed laver and cultured laver and in correlation among heavy metals, removal efficiency of heavy metals may be attributed to seaweed treatment process. The average weekly intakes of Cu, Cd, Zn, Fe and Hg via seaweeds consumption were about 0.1~7.6% of PTWI (Provisional Tolerable Weekly Intakes). Therefore, it was found that heavy metals in the seaweeds were very safe for consumption.

Environmental Contamination of the Abandoned Chonju Il Mine in the Chonbuk Area (전주 일광산 주변의 환경 오염에 관한 연구 -겨울철 중금속오염을 중심으로-)

  • 조규성;정덕호
    • Journal of Environmental Science International
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    • v.7 no.5
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    • pp.623-631
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    • 1998
  • Pyrite contained in wasted ore dumps induces a strong acid environment when it contacts oxygenated rainfall. Present research was designed to evaluate the pollution of an area that is supposedly contaminated by pyrite of ore wasted dumps form in Chonju Il Mine. Measured are the pH and selected heavy metal elements in the supposedly polluted hydrologic system. The samples include three types : those collected from the stream waters; those from the stream sediments; and those from the rice field soil scattered over the area. The dispersion path of the pollution source was also traced. The pH of the hydrologic system ranged from 3.44 to 5.46, which clearly indicates that the area is on the acid environment. The pH tends to rise as the distance from the minehead increases. The content of heavy metal elements dissolved in the stream water varies as follows; Mn=69.73~1.99ppm, Cd=0.02~0.03ppm, Zn=0.77~1.18ppm, Cu=0.04~0.13ppm, Pb=0.22~0.32ppm. The stream water in this state may induce serious heavy metal pollution to the agricultural land and the water for human life especially in the villages down the stream. The content of heavy metal elements dissolved in the stream sediment varies as follows; Mn=245.0~4685.0ppm, Cd=10.0~15.0ppm, Zn=105.0~210.0ppm, Cu=65.0~155.0ppm, Pb=90.0~150.0ppm. The content of heavy metal elements dissolved in the rice field soil varies as follows; Mn=185.0~260.0ppm, Cd=10.0~15.0ppm, Zn=135.0~180.0ppm, Cu=65.0~90.0ppm, Pb=100.0~130.0ppm. The pollution index in the stream sediment and the rice field sell is 1.36~2.03, which shows that pollution had already begun all over the area where the samples were collected.

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Ecological impact of fast industrialization inferred from a sediment core in Seocheon, West Coast of Korean Peninsula

  • Choi, Rack Yeon;Kim, Heung-Tae;Yang, Ji-Woong;Kim, Jae Geun
    • Journal of Ecology and Environment
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    • v.44 no.4
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    • pp.212-221
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    • 2020
  • Background: Rapid industrialization has caused various impacts on nature, including heavy metal pollution. However, the impacts of industrialization vary depending on the types of industrializing activity and surrounding environment. South Korea is a proper region because the rapid socio-economical changes have been occurred since the late nineteenth century. Therefore, in this study, we estimate the anthropogenic impacts on an ecosystem from a sediment core of Yonghwasil-mot, an irrigation reservoir on the western coast of Korea, in terms of heavy metal concentrations, nutrient influx, and pollen composition. Results: The sediment accumulation rate (SAR) determined by 210Pb geochronology showed two abrupt peaks in the 1930s and 1950s, presumably because of smelting activity and the Korean War, respectively. The following gradual increase in SAR may reflect the urbanization of recent decades. The average concentrations of arsenic (As), copper (Cu), and lead (Pb) during the twentieth century were > 48% compared to those before the nineteenth century, supporting the influence of smelting activity. However, at the beginning of the twenty-first century, the As, Cu, and Pb concentrations decreased by 19% compared to levels in the twentieth century, which is coincident with the closure of the smelter in 1989 and government policy banning leaded gasoline since 1993. The pollen assemblage and nutrient input records exhibit changes in vegetation cover and water level of the reservoir corresponding to anthropogenic deforestation and reforestation, as well as to land-use alteration. Conclusions: Our results show that the rapid socio-economic development since the twentieth century clearly affected the vegetation cover, land use, and metal pollutions.

A Study on Distribution of Radon Concentration at Atmospheric in Seoul (서울 대기중 라돈농도의 분포에 관한 연구)

  • ;;;T. Iida
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.04a
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    • pp.279-281
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    • 2000
  • 발암성 물질로 알려진 라돈($^{222}Rn$)은 원래 불활성기체로 자연계에 널리 존재하는 자연방사능으로 암석이나 토양 같은 지각물질에서 발생하는 우라늄($^{238}U$) 붕괴계열인 라듐($^{226}Ra$)의 붕괴과정에서 생성되는 방사성 가스이다. 라돈($^{222}R$)은 $\alpha$붕괴에 의하여 $^{218}Po$, $^{214}Po$등의 자핵종(Radon daughter)을 생성하며, 최종적으로 납($^{210}Pb$)으로 변한다 라돈이 폐에 흡입되면 붕괴하면서 $\alpha$방사선을 방출하는데, 이것이 인체의 세포를 죽이거나 염색체를 손상시킬 수 있으며, 폐암의 발생 위험률을 높이는 것으로 보고되었다. (중략)

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Separation of Thallium Stable Isotopes with Lasers (레이저를 이용한 탈륨 안정 동위원소 분리)

  • Jung, Do-Young;Ko, Kwang-Hoon;Im, Kwon;Park, Sang-Eon;Kim, Jae-Woo;Kim, Chul-Joong
    • Proceedings of the Optical Society of Korea Conference
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    • 2003.07a
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    • pp.174-175
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    • 2003
  • 안정 동위원소는 원자력, 정밀전자, 제약 및 의료 분야 등에서 다양하게 사용되고 있다(그림1 참고). 원자로의 핵반응 조절을 위해 chemical shim으로 사용되는 B-10과 low activation 내부식성 재료인 감손 아연(Zn depleted in Zn-64)은 원자력 분야에서 사용되는 대표적인 안정 동위원소이다. 정밀 전자 분야에서 low alpha lead (LAL: Pb-210이 제거된 납)는 고집적 반도체 패킹 시 soft error를 줄이는 솔더 물질로 사용되고 있고, Si-28 은 열전도도가 높은 새로운 반도체 소재로 부각되고 있다. (중략)

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