• Title/Summary/Keyword: 2-diamine

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IAA Synthesis and Polyamine Metabolism in Higher Plants: Effects of IAA on the Activity of Diamine Oxidase in Seedlings of Soybean (고등식물에서 IAA합성과 Polyamine 대사에 관한 연구: 대두의 유식물에서 IAA가 Diamine Oxidase의 활성에 미치는 영향)

  • 김도균
    • Journal of Plant Biology
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    • v.35 no.3
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    • pp.265-271
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    • 1992
  • Vie investigated the effect of indole acetic acid (IAA) on diamine oxidase (DAO; EC 1.4.3.6) in the seedling of soybean (Glycine max L. forma Paldalkong). DAO activity was not detected in the resting soybean seeds. During germination it appeared in the elongating zone on day 3, increased up to day 4 and decreased thereafter. Endogenous IAA content has been shown the same pattern as DAO activity. However, cadaverine content was reduced on day 4. To investigate the effect of IAA on DAO activity, the segments of hypocotyl on day 3 were soaked in various concentration of IAA. The activity increased at low concentrations ($10^{-7}-10^{-6}M$) of 1M as compared to that of control but not at high concentrations ($10^{-5}-10^{-4}M$) of IAA. Differing from DAO activity, cadaverine content increased as concentrations of IAA increased. On the other hand, ethylene was induced by IAA at high concentrations. To study the effect of ethylene on DAO activity, we cotreated IAA and 2,S-Norbonadiene (NDE). In this case, DAO activity was not affected.fected.

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Synthesis and Hydrolysis-Resistance Characterization of Waterborne Polyurethane (Waterborne Polyurethane의 합성 및 내가수분해 특성 연구)

  • Jeong, Booyoung;Cheon, Jungmi;Chun, Jaehwan
    • Journal of Adhesion and Interface
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    • v.13 no.3
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    • pp.116-120
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    • 2012
  • In this study, waterborne polyurethane was prepared from polyester polyol, $H_{12}MDI$, DMPA and sulfopropylated polypropyleneglycol-${\alpha}$,${\omega}$-diamine (SP). The $T_g$ of waterborne polyurethane was increased as the SP content increased, while it was decreased at the NCO/OH ratio of 1.8. Also the hydrolysis-resistance and tensile strength were increased as the SP content increased. The tensile strength decrement of WPU-SP was 2~5% with the exception of WPU-SP-1.

New Fluorescent Blue OLED Host and Dopant Materials Based on the Spirobenzofluorene

  • Lee, In-Ho;Gong, Myoung-Seon
    • Bulletin of the Korean Chemical Society
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    • v.32 no.5
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    • pp.1475-1482
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    • 2011
  • New spiro[benzo[c]fluorene-7,9'-fluorene] (SBFF)-based blue host materials, 9-phenyl-SBFF (BH-4P) and 5,9-diphenyl-SBFF (BH-6DP), were successfully prepared by spiro-formation of 9-phenyl-7H-benzo[c]fluoren-7-one with 2-bromobiphenyl via lithiation and reaction of 5,9-dibromo-SBFF with phenylboronic acid through the Suzuki reaction, respectively. Diphenyl-[4-(2-[1,1;4,1]terphenyl-4-yl-vinyl)-phenyl]-amine (BD-1) and N,N-diphenyl-N',N'-diphenyl-SBFF-5,9-diamine (BD-6DPA) were used as dopant materials. Blue OLEDs with the configuration ITO/N,N'-bis-[4-(di-m-tolylamino)phenyl]-N,N'-diphenylbiphenyl-4,4'-diamine (DNTPD)/bis[N-(1-naphthyl)-N-phenyl]benzidine (NPB)/host:5% dopant/SFC-137/Al-LiF were prepared from the two host materials doped with BD-1 and BD-6DPA dopants and the devices composed of BH-4P and BH-6DP doped with BD-6DPA showed blue EL spectra at 458 and 463 nm at 7 V and luminance efficiencies of 4.58 and 4.88 cd/A, respectively.

Effects of EDTA on morphology of hydroxyapatite prepared by hydrothermal method (수열합성법에 의해 합성된 수산화아파타이트 결정의 입자 형상에 관한 EDTA의 영향)

  • Choi, Bong-Seok;Kim, Dong-Hyun;Kim, Tae-Wan;Park, Hong-Chae;Yoon, Seog-Young
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.2
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    • pp.75-81
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    • 2011
  • Hydroxyapatite (HAP) crystals with hexagonal structure have been successfully synthesized by using EDTA(ethylene diamine tetraacetic acid) as chelate under hydrothermal condition. The as-prepared HAp powders were characterized by XRD and SEM. The XRD result indicated that the products were preferentially oriented along c-axis. The SEM photographs showed that the morphology of the HAp crystals was well controlled by the reaction parameters such as temperature, pH value, and the molar ratio of EDTA/Ca.

Color-stabilized organic light-emitting devices by using N, N'-bis-(1- naphthyl)-N, N'-diphenyl-1,1-biphenyl-4,4'-diamine/5,6,11,12 - tetraphenylnaphthacene multiple quantum well structures

  • Yoon, Y.B.;Kim, T.W.;Yang, H.W.;Lee, H.G.;Kim, J.H.;Kim, Y.G.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1378-1380
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    • 2005
  • The efficiency and the optical properties of the yellow organic light-emitting devices (OLEDs) were significantly affected by the existence of the multiple quantum well (MQW) structures consisting of N, N'- bis-(1-naphthyl)-N, N'-diphenyl-1,1-biphenyl-4,4'- diamine(NPB)/5,6,11,12 - tetraphenylnaphthacene (rubrene). The maximum efficiency and the luminance of OLEDs with 3-periods of the NPB/rubrene MQWs at 41.6 $mA/cm^2$ were 3.66 cd/A and 1524 $cd/m^2$, respectively, and their Commission Internationale de l'Eclairage chromaticity coordinates were (0.34, 0.55), which indicates a yellow color. These results indicate that the efficiencies of the OLEDs by using MQW emitting layers can be improved.

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Cobalt(III) Complexes Containing Ethylenediamine-Triacetate and Aliphatic Diamine (I). The Reaction of Etylenediamine-tetraacetatocobaltate(Ⅲ) with Trimethylenediamine in Aqueous Solution (지방족디아민과 에틸렌디아민-트리아세테이트를 포함하는 코발트 (Ⅲ) 錯物에 관한 연구 (제1보). 수용액 중에서 [Co(EDTA)]- 錯物에 트리메틸렌디아민의 반응)

  • Myung-Ki Doh;Dong-Soo Kim
    • Journal of the Korean Chemical Society
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    • v.22 no.1
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    • pp.25-29
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    • 1978
  • Cobalt(III) complex containing ethylenediamine-triacetate and trimethylenediamine has been isolated from the reaction of ethylenediamine-tetraacetatocobaltate(III) with trimethylene-diamine in aqueous solution by Dowex 50W-X8, cation exchange resin in $H^+$ form. The ethylenediamine-triacetate($EDTRA^{3-}$) ligand coordinates to the cobalt(III) ion as a quadridentate with a free acetate branch. It has been observed that the complex has trans(O-O) (1) structure via the elemental analysis, UV, IR and NMR data.

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Dyeability of Oxidative Permanent Hair Coloring Agents and the Damage of Hair (산화형 영구염모제 종류에 따른 염색성과 모발의 손상)

  • Jeong, Nam Young;Lim, Sun Nye;Choi, Chang Nam
    • Textile Coloration and Finishing
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    • v.24 no.4
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    • pp.305-312
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    • 2012
  • In this study, we investigated the effects of oxidative permanent hair coloring agents on the dyeability and the damage of human hair. p-phenylenediamine and toluene-2.5-diamine sulfate were used as a hair coloring agent precursers. The degree of dyeability was checked by the change of CIELAB $L^*$ value according to dyeing time. And the damage of hair was evaluated by the tensile strength and morphological change of hair in SEM. When the hair was dyed, the CIELAB $L^*$ value was decreased with dyeing time regardless of the type of precursers. But when the hair was dyed after nutritional treatment, the CIELAB $L^*$ value showed lower level. This means that the nutritional treatment covers the scale of hair and protects the hair from the chemicals.

Synthesis and Characterization of Copoly(amide-imide) Derivatives and Ultrafiltration Membrane Performances I - Preparation of Copoly(amide-imide)s by One-step Method -

  • Jeon, Jong-young;Shin, Bong-Seob
    • Korean Membrane Journal
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    • v.3 no.1
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    • pp.9-16
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    • 2001
  • The diamide-diamine having carboxylic acid was prepared by direct condensation of 1,2,4-benzenetricarboxylic acid with bits[4- (3-aminophenoxy ) phenyl] sulfone and bits(4-aminouhenyl)-1,4- diisopropylbenzene in medium consisting of triphenylphosphite, LiCl, and N-methyl-2-pyrrolidone. Copoly (amide-imide) derivatives with high molecular weight could be synthesized by one-step polycondensation of prepared diamide-diamine having carboxylic acid and various dianhydride compounds. Depending on the chemical structure and composition of polymer backbones, the viscosities of polymers were found to range between 0.87∼ 1.57 dL/B. All the polymers showed good thermal stability up to 320$\^{C}$ and the 10% weight loss temperature was observed in the range of 450∼540$\^{C}$ in a thermogravimetric traces. The glass transition was recorded in the temperature range of 200 ∼ 270$\^{C}$. All the polymers showed an amorphous nature on a differential scanning calorimetric thermograms. These polymers generally had good mechanical properties and readily soluble in various polar solvents. Further, it was proved that their properties could be determined from the composition.

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Synthesis of Salens and Their Cobalt Complexes from Meso-1,2-Diamine and Their Anti-Cancer Property (메소-1,2-디아민을 이용한 Salen-코발트 착화합물의 합성과 항암효과)

  • Koh, Dong-Soo
    • Journal of Applied Biological Chemistry
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    • v.53 no.2
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    • pp.108-111
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    • 2010
  • New salens (3) and their Cobalt complexes (4) were prepared from meso-1,2-bis(ortho-hydroxyphenyl)-1,2-diaminoethane (1) and substituted salicylic aldehydes (2). In contrast to symmetric structure of salen ligand (3), salen-Co(III) complexes (4) showed dissymmetric molecular structure due to participation of three hydroxyl groups in complex formation. One of the salens (3b) revealed decrease in Cyclin D1 expression, which represents anti-cancer property.