• Korean Chemical Engineering Research
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• 제46권2호
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• pp.301-309
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• 2008

본 연구에서는 레졸수지 합성에서 부가반응 실험변수인 F/P 몰비, 촉매 wt% 및 반응온도가 페놀치환체에 미치는 영향을 2단 실험계획법을 사용하여 실험하고 실험 결과를 삼원변량분석법(ANOVA, SPSS)을 사용하여 해석하였다. 페놀치환체는 반응시간 300분에서 F/P 몰비가 높을수록, 반응온도가 낮을수록, 촉매량이 적을수록 증가하는 경향을 보였고 ortho 지향성이 있음을 확인하였다. 레졸형 페놀수지의 합성에서 페놀계 치환체의 해리반응과 메틸렌글리콜 형태의 포름알데하이드의 분율을 고려하는 Zavitsas류의 속도론 모델을 단순화시킨 기초반응 모델을 제시하고 Zavitsas류의 속도론 모델과 비교하였다. 기초반응 모델은 평균적으로 2.79%의 오차를 보였으며 Zavitsas류 모델의 오차인 3.27%와 비슷한 값을 보이는 것을 확인하였다. 따라서 본 논문에서 제시한 기초반응 모델은 레졸합성의 부가반응 속도론 연구에 적용 가능하다고 판단된다.

• Biotechnology and Bioprocess Engineering:BBE
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• 제5권2호
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• pp.118-122
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• 2000

A comlementary call line CR2 is curretly used to propagte the Disabled Infectious Single Cycle Herpes Simplex Virus Typee2 (DISC HSV-2) on a small Iaboratory scale upto 15 L. These cultures are initiated by passaging the cells from roller bottle cultures. Whilst this is suitable for the laboratory scale it is totally impractical for use in seeding an industrial manufacturing scaled version of the culture. It is paramount to have a robust system for passaging cells from a small microcarrierier culture system to a larger one by a serial subculturing regime. Here we report on the successes we have had in our laboratory in scaling up out production system for the DISC HSV-2 from small 1-L cultures to a 50-L vessel with the maintenance of the viral productivity. Ease of use, reproducibility and the need to minimise overall production time were factors which were taken into consideration whils developing our procedures. We were aware of the need to keep a production train simple and as short as possible as this was the amall scale study for an envisaged manufacturing process.

• Journal of Ceramic Processing Research
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• 제19권5호
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• pp.413-418
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• 2018

All-solid-state lithium batteries (ASSBs) using inorganic sulfide-based solid electrolytes are considered prospective alternatives to existing liquid electrolyte-based batteries owing to benefits such as non-flammability. However, it is difficult to form a favorable solid-solid interface among electrode constituents because all the constituents are solid particles. It is important to form an effective electron conduction network in composite cathode while increasing utilization of active materials and not blocking the lithium ion path, resulting in excellent cell performance. In this study, a mixture of fibrous VGCF and spherical nano-sized Super P was used to improve rate performance by fabricating valid conduction paths in composite cathodes. Then, composite cathodes of ASSBs containing 70% and 80% active materials ($LiNi_{0.6}Co_{0.2}Mn_{0.2}O_2$) were prepared by a solution-based process to achieve uniform dispersion of the electrode components in the slurry. We investigated the influence of binary carbon additives in the cathode of all-solid-state batteries to improve rate performance by constructing an effective electron conduction network.

• 한국수자원학회논문집
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• 제37권11호
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• pp.897-913
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• 2004

지금까지 국내에서는 도시하수, 공장폐수 등의 점오염원에 국한하여 수질관리를 시행하여 부분적으로 밖에 효과를 얻지 못하였다. 따라서 오염원에 대한 최적관리를 위해서는 유역의 토지특성 및 토양 형태에 따른 비점오염원에 대한 관리가 매우 중요하다. 본 연구에서는 유역의 특성별로 발생하는 오염원을 산정하기 위해 분포형 모형을 적용하였으며, 상세한 유역특성 자료를 구축하기 위해 GIS 기법을 응용하였다. 본 연구에서는 분포형 수질관리모형으로 연속 강우 사상에 대해 유역에서 발생하는 유출량 및 첨두유량, 유사량, 비점오염 부하량 등을 산정할 수 있는 AnnAGNPS 모형을 적용하였고, 모형내의 부모듈을 이용하여 입력자료를 생성 및 가공하여 적용하였다. 대상유역은 팔당호 유역권에 포함되는 복하천 유역을 선정하였으며, 1999년과 2000년 호우기의 각각 2개의 강우 사상을 적용하였다. 우선 강우시 유역에서 발생하는 유출량을 모의하고, 이를 복하교 지점의 실측유량자료와 비교, 보정하여 모형의 입력 매개변수를 조정하였으며, 이후 토사발생량과 오염부하량을 모의하였다 토사발생량의 경우는 실측값이 미비하여 비교분석은 못하였으나, 오염부하량의 경우 환경부에서 측정한 수질농도 자료를 이용하여 비교, 분석값을 제시하였다.

• Computers and Concrete
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• 제33권6호
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• pp.631-642
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• 2024

The present study concerns the corrosion mitigation of electrochemical chloride extraction (ECE) in concrete structure. Concrete specimen was fabricated with 5.0% chloride in cast, while the other specimen was exposed to 4.0M NaCl solution for 1 year to accelerate corrosion of steel. Then, the ECE was applied to the concrete specimen with 1000 mA/m² of the current density for 2, 4 and 8 weeks, respectively. During the ECE, the corrosion current density and corrosion potential were regularly monitored. As a result, the ECE was very effective in mitigating the degree of corrosion on the steel surface. The corrosion current density was significantly reduced from thousands to decades mA/m², while the corrosion potential was mostly shifted to positive direction. Assuming that the corrosion starts at 1.0 mA/m² of the corrosion current density or/and -275 mV vs SCE of the corrosion potential, the ECE could not fully achieve the repassivation of the steel, although its degree was lowered more or less depending on the duration of the treatment and type of chloride contamination. A visual examination confirmed that an increase in the duration of the treatment could lower the rust formation, but never fully removed all rust stains.

• 한국환경과학회지
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• 제12권2호
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• pp.93-100
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• 2003

In most mountainous parts of the temperate zone of Japan along the Pacific Ocean, some climatic climax forests, whose main dominant species is Fagus crenate, F. japonica or Quercus mongolica var. grosseserrata, are distributed. In the riparian regions of the zone, however, there appear summer green forests composed of the different species from the climatic climax forests. Climate plays an important role in determining the overall distribution of vegetation, but some environmental factors, i.e., topography, soil type, soil moisture content, etc. have a great influence on vegetation formation. Riparian forests seem to be controlled by various geomorphologic disturbances, such as landslide, soil erosion and accumulation. The study aims to present the relationships among vegetation, soils and landforms in the process of determining riparian forests dominated by Fraxinus platypoda and Pterocarya rhoifolia establishment in the mountainous region of central Japan. The study area extends an area of 302 ha with a range of elevation between 925 m and 1,681 m at the Chichibu mountains. The landforms were corditied at sampling grids (25 $\times$ 25 m, n = 4,843) using a hierarchical system, and a brief description of the forest soil classification was also given. The mutual relationship analysis indicated that forest soils and landforms play a significant role in determining the geomorphological process of riparian forest, and shaping the ultimate pattern of vegetation. At the study area, riparian forests were mainly found on the $B_E$ forest soil type and steep slopes ( > 30$^{\circ}$) at convex slopes along the streams. On the other hand, the direction of slopes did not have a significant impact on the establishment of the riparian forests. A mosaic of patchy distribution of those riparian forests on the slightly wetter $B_E$ forest soil type was one of the characteristic features of the study area. This particular soil which contained large talus gravels was found on the land formed by erosion and deposition of landslide.

• Clinical and Experimental Pediatrics
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• 제62권12호
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• pp.444-449
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• 2019

Background: Sixty percent of infants with severe neonatal hypoxic-ischemic encephalopathy die, while most survivors have permanent disabilities. Treatment for neonatal hypoxic-ischemic encephalopathy is limited to therapeutic hypothermia, but it does not offer complete protection. Here, we investigated whether hypoxia-inducible factor (HIF) promotes cell survival and suggested neuroprotective strategies. Purpose: HIF-1α deficient mice have increased brain injury after neonatal hypoxia-ischemia (HI), and the role of HIF-2α in HI is not well characterized. Copper-zinc superoxide dismutase (SOD)1 overexpression is not beneficial in neonatal HI. The expression of HIF-1α and HIF-2α was measured in SOD1 overexpressing mice and compared to wild-type littermates to see if alteration in expression explains this lack of benefit. Methods: On postnatal day 9, C57Bl/6 mice were subjected to HI, and protein expression was measured by western blotting in the ipsilateral cortex of wild-type and SOD1 overexpressing mice to quantify HIF-1α and HIF-2α. Spectrin expression was also measured to characterize the mechanism of cell death. Results: HIF-1α protein expression did not significantly change after HI injury in the SOD1 overexpressing or wild-type mouse cortex. However, HIF-2α protein expression increased 30 minutes after HI injury in the wild-type and SOD1 overexpressing mouse cortex and decreased to baseline value at 24 hours after HI injury. Spectrin 145/150 expression did not significantly change after HI injury in the SOD1 overexpressing or wild-type mouse cortex. However, spectrin 120 expression increased in both wild-type and SOD1 overexpressing mouse at 4 hours after HI, which decreased by 24 hours, indicating a greater role of apoptotic cell death. Conclusion: HIF-1α and HIF-2α may promote cell survival in neonatal HI in a cell-specific and regional fashion. Our findings suggest that early HIF-2α upregulation precedes apoptotic cell death and limits necrotic cell death. However, the influence of SOD was not clarified; it remains an intriguing factor in neonatal HI.

• International Journal of Internet, Broadcasting and Communication
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• 제7권2호
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• pp.73-78
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• 2015

Touch panel is mainly applied to pressure type touch panel but it occur a low recognition rate and error during long-term use. So, it is partly applied to capacitive touch panel to compensate for these problems but it also can occur a same problems via pollutions. Touch technology has developed a various method but it is not used because of high costs and difficult installation process. So, in this paper, we proposed an input method of touchless panel using IrDA matrix. This method is conducted using an IrDA Matrix composed of depth sensor. It is possible to offer a various contents for multi user. The proposed technology need a development of a high sensitivity sensing method and high-speed processing method of position information for Seamless operation control. And, it is required high-precision drive technology. Also, we proposed a Seamless user recognition for interactive contents service through a touchless panel using IrDA matrix.

• Carbon letters
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• 제11권2호
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• pp.107-111
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• 2010

We prepared the amine epoxy adducts (AEA)/thin multiwalled carbon nanotubes (TWCNTs) composite particles using nonsolvent based methods including dry mechano-chemical bonding(MCB) process and supercritical fluid (SCF) process. The resulting TWCNTs/AEA composite particles have been used as curing agents for urethane modified bispheol A type epoxy resin. The thermal, thermomechanical properties of the epoxy resins cured with TWCNTs/AEA composite particles were measured by DMA and the dispersion of CNT was characterized by SEM. Because of high degree of CNT dispersion, thermal and mechanical properties of the epoxy resin cured with TWCNTs/AEA composite particles prepared by SCF process are better than those cured with mechano-chemically prepared TWCNTs/AEA composite particles.

• 한국전기전자재료학회논문지
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• 제11권10호
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• pp.940-945
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• 1998

In this paper, we obtained the data, which is required in training the neural network and diagnosing the degradation degree, by introducing the AE detection that is effective method in ordinary degradation diagnosis on activation. Aa the results of generalization tests by appling neural network to the unknown AE patterns obtained from two kinds of specimen, firstly as to evaluate an objective performance of neural network, the recognition ration for no-void specimen and 1[mm] -void specimen are appeared to be 98.9% and 92.5%, respectively. Also, in the evaluation of the adaptability of neural network with a new type of 0.2[mm] -void specimen, it is confirmed that the result appears to be 64% of recognition ratio at 94% of confidence interval coefficient in expectation output 0.2. On the other hand, the recognition capability of the neural network was confirmed by data from no-void and 1[mm] void specimen. The results prove the promising possibility of the application of ANN to discriminate specific void affecting as main degradation source at partial discharge condition in insulator containing multi-void by accummulated data base.