• Title/Summary/Keyword: 2-Halo-1,3-diene

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Efficient Synthetic Method of Z-Selective 2-Halo-1,3-dienes from Reactions of Allenols Possessing Ethoxycarbonyl and Vinyl Group with Indium Trihalide

  • Eom, Da-Han;Kim, Sung-Hong;Lee, Phil-Ho
    • Bulletin of the Korean Chemical Society
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    • v.31 no.3
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    • pp.645-649
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    • 2010
  • An efficient synthetic method of Z-selective 3-ethoxycarbonyl-2-halo-1,3-dienes and 3-vinyl-2-halo-1,3-dienes was developed from the reaction of allenols having ethoxycarbonyl and vinyl group with indium trihalides at room temperature in $CH_2Cl_2$.