• The Journal of the Acoustical Society of Korea
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• v.30 no.8
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• pp.436-445
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• 2011

In this paper, equivalent properties of 2-2 mode piezocomposites were studied. Variation of the properties of 2-2 mode piezocomposites was analyzed by the finite element method, and the result was compared with experimental measurement data to confirm the validity of the analysis. The equivalent properties of a single phase material to represent the piezocomposite composed of PZT-5H and polymer were derived by the asymptotic averaging method. Accuracy of the derived equivalent properties was enhanced by minimizing the discrepancy between the impedance spectra of full 2-2 piezocomposite and equivalent single phase material resonators of various vibration modes by the least square method. The equivalent properties of 2-2 piezocomposites derived in this study can be utilized to the design of diverse acoustic sensors.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.11a
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• pp.346-346
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• 2007

압전세라믹 재료는 현재 압전 변압기, actuator, transducer, sensor, speaker 등에 광범위하게 이용이 되고 있다. 이 중에서 압전세라믹 소결체를 이용한 스피커의 제조는 가공이 까다롭고, 대형의 크기로 제작 시 소자가 깨지는 등의 많은 제약을 받고 있으며, 저음 특성이 떨어져 응용 범위가 한정되어 있다. 따라서 최근에는 이러한 단점을 극복하기 위하여 세라믹/고분자 복합체를 이용한 필름 스피커를 제작하고자 시도하고 있다. 이러한 세라믹/고분자 0-3형 압전 복합체를 이용할 경우, 제품의 경량화를 실현할 수 있고, 크기나 환경의 영향을 거의 받지 않으므로, 고기능성 스피커로의 응용에 적합할 것으로 보인다. 따라서 본 연구에서는 PZT계의 세라믹와 PVDF, PVDF-TrFE, Polyester, acrylic resin 등의 여러 고분자 물질과의 복합체를 제조하여 압전특성을 평가하였다. 본 실험은 먼저 $(Pb_{1-a-b}Ba_aCd_b)(Zr_xTi_{1-x})_{1-c-d}(Ni_{1/3}Nb_{2/3})_c(Zn_{1/3}Nb_{2/3})_dO_3$ (이하 PZT라 표기)의 최적화 조성을 선택하여, $1050^{\circ}C$에서 소결된 분말을 48시간 ball milling방법 로 약 $1{\mu}m$ 크기로 분쇄하였다. 고분자 물질들은 알맞은 용제들을 선택하여 녹였다. 그 다음 소결된 PZT분말과 고분자를 50:50, 60:40, 65:35, 70:30등의 무게 분율로 혼합하고, 분산제, 소포제 등을 첨가하여 3단 roll mill을 이용하여 충분히 분산시켜 페이스트 (Paste)를 제조하였다. 제조된 페이스트를 ITO가 코팅된 PET필름 위에 스크린 프린팅 법을 사용하여 인쇄하여 $120^{\circ}C$에서 5분간 건조하였다. 코팅된 복합체의 두께는 약 $80{\mu}m$ 정도로 측정되었다. Ag 페이스트를 이용한 상부 전극 형성에도 스크린 프린팅 법을 적용하였다. 이를 $120^{\circ}C$에서 4 kV/mm의 DC 전계로 분극 공정을 수행한 후 전기적 특성을 평가하였다. 유전특성을 조사하기 위해서 LCR meter (EDC-1620)를 사용하였고, 시편의 결정구조는 XRD (Rigaku; D/MAX-2500H)을 통해 분석하였으며, 전자현미경(SEM)을 이용하여 미세구조를 분석하였다. 압전 전하상수$(d_{33})$ 값은 APC 8000 모델을 이용하여 측정하였다. PZT의 혼합비가 증가할수록 비유전율 및 압전 전하 상수 등의 전기적 특성이 증가되었다. 또 여러 고분자 물질 중에서 PVDF-TrFE 수지가 가장 우수한 특성을 보였다. 이는 PVDF-TrFE 수지가 압전성을 나타내기 때문인 것으로 판단되었다.

• Proceedings of the Korean Ceranic Society Conference
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• 2003.04a
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• pp.184.1-184
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• 2003

• Electrical & Electronic Materials
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• v.25 no.4
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• pp.20-27
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• 2012

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.11a
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• pp.85-85
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• 2009

본 연구에서는 압전 세라믹과 고분자를 혼합한 복합체를 제작하고 이러한 재료로부터 발생될 수 있는 미소 전력량을 조사하였다. 압전 세라믹으로는 0.2(PbMg1/3Nb2/3O3)-0.8(PbZr0.475Ti0.525O3)와 고분자는 PVPF-TrFE (6:4)를 사용하였다. 고분자와 압전 세라믹 분율을 1%, 5%, 10%, 30%, 50%로 변화하였으며, 구조는 0-3 복합재료 및 1-3 재료를 제작하였다. 제작한 결과 0.3 복합재료에서는 분율이 10%에서 가장 큰 전력량이 발생되었고, 1-3 복합재료에서는 분율이 30%에서 최대 값을 나타내었다. 이러한 결과들을 간단한 식을 이용하여 분석을 하였다.

• Journal of Ocean Engineering and Technology
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• v.22 no.2
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• pp.65-71
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• 2008

Recently, many researches in relation to data transmission with faster speed and greater volume, many researches have been carried out on sonar systems for underwater communication. According to these researches, an acoustic transducer for underwater communication requires wide bandwidth properties. In domestic researches for underwater communication sonar, an operating frequency in the range of $20{\sim}40\;kHz$ is used. In this paper, we propose anon-resonance type acoustic transducer for underwater communication. The TVR (transmitting voltage response) characteristics increased linearly as the frequency increased, and the RVS (receiving voltage sensitivity) characteristics were constant as the frequency increased. Traditional techniques for wide bandwidth transducershave a limit and a transmission loss difference at lower and higher frequency operating ranges. In this paper, the new transducer proposed decreased the transmission loss under some conditions. It was optimized with the FE analysis tool (ATILA) and evaluated using the TVR and the RVS characteristics in the range of $10{\sim}90\;kHz$. The value of TVR was 138 dB at 20 kHz and 148 dB at 40 kHz, and the differences was 12 dB. The value of RVS was $195{\pm}2\;dB$ and nearly constant. From theseresults, it is certain that the developed transducers can be used for an underwater communication network in the 1.3 km range with both a 20 kHz bandwidth and 30 kHz center frequency.

• Journal of Powder Materials
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• v.26 no.2
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• pp.119-125
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• 2019

Piezoelectric energy harvesting technology is attracting attention, as it can be used to convert more accessible mechanical energy resources to periodic electricity. Recent developments in the field of piezoelectric energy harvesters (PEHs) are associated with nanocomposites made from inorganic piezoelectric nanomaterials and organic elastomers. Here, we used the $BaTiO_3$ nanoparticles and piezoelectric poly(vinylidene fluoride) (PVDF) polymeric matrix to fabricate the nanocomposites-based PEH to improve the output performance of PEHs. The piezoelectric nanocomposite is produced by dispersing the inorganic piezo-ceramic nanoparticles inside an organic piezo-polymer and subsequently spin-coat it onto a metal plate. The fabricated organic-inorganic piezoelectric nanocomposite-based PEH harvested the output voltage of ~1.5 V and current signals of ~90 nA under repeated mechanical pushings: these values are compared to those of energy devices made from non-piezoelectric polydimethylsiloxane (PDMS) elastomers and supported by a multiphysics simulation software.

• Proceedings of the KIEE Conference
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• 2006.07c
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• pp.1392-1393
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• 2006

In this paper dielectric and piezoelectric properties were measured for 2 phase - dispersed composite system consisting of ferroelectric ceramic PZT particles and polymer PVC. The results were analyzed and the validity of composite theories for experimental results were discussed. And also in high temperature where ionic conductivity is dominated, linear and nonlinear permittivites were measured and discussed.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2003.07b
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• pp.710-713
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• 2003

The PZT(KP12) powder was synthesized by sintering at $1250^{\circ}C$ for 2hrs and wet milling for 24 hrs. The PZT composite mixed with PVdF was fabricated into bulk, sheet, and plate type and the characteristics of three types were estimated. The bulk type which has PZT volume percent of 70 showed the best piezoelectric constant. Dielectric constant increased exponentially as an increase of PZT volume percent. The figure of merit of bulk and plate type was better than pure PZT over PZT volume percent of 50.

• Journal of the Korean Ceramic Society
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• v.25 no.2
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• pp.125-130
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• 1988

The characteristics of the PZT/PMM and PZT/Butadiene composites with 3 dimensional network structure have been investigated as a function of the PZT volume fraction. The dielectric constants of the PZT composites increased linearly as the PZT volume fraction increased. However, they are not significantly affected by the polymer compliance. The piezoelectric d33 coefficients of the PZT/Butadiene are largest than the PZT/PMM because of the high elastic compliance which promotes stress transfer. The values of the mechanical quality factor adn frequency factor of the PZT/PMM composite are slightly larger, while the planar coupling factor is smaller, than the PZT/Butadiene composite. These results are due to strong interaction and mechanical coupling between PZT and PMM.