• Title/Summary/Keyword: 2상 분무

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A Study on the Improvement of Potassium Based Sorbent for Flue Gas Carbon Dioxide(CO2) (배가스 이산화탄소(CO2)용 Potassium계 흡수제의 성능 향상 연구)

  • Wi, Young Ho;Ryu, Chong Kul;Choi, Dong Hyeok
    • Journal of Climate Change Research
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    • v.2 no.2
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    • pp.107-113
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    • 2011
  • In this research, we described the experimental results for the improvement of Potassium based sorbents. These sorbents have been actually used in the 0.5 MW $CO_2$ capture plant located in Hadong #3 Power Plant. Firstly, we had shaped two kinds of sorbents using a spray dryer. These sorbents applied magnetite & copper oxide as an additive. And the magnetite sorbent was evaluated more excellent relatively in the attrition index. Secondly, We had obtained TGA multicycle experimental results of the improved Potassium based sorbent which applied magnetite as an additive. Consequently, $CO_2$ sorption capacity had been sustained 5.5 wt% after 2nd cycle and attrition index was very excellent as 0.5%. Finally, we had investigated the characteristics of the sorbent following in properties of supporters. As a result, the sorption capacity of the KMO sorbent used base material as a supporter was appeared as 7.2 wt%.

Development of NO2/NOx Ratio Estimation Model for Urea-SCR System Application on Non-road Diesel Engine (비도로용 디젤엔진의 Urea SCR system 적용을 위한 NO2/NOx ratio 예측모델 개발에 관한 연구)

  • Kang, Seokho;Kim, Hoonmyung;Kang, Jeongho;Park, Eunyong;Kwon, Ohyun;Kim, Daeyeol
    • Journal of ILASS-Korea
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    • v.25 no.4
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    • pp.178-187
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    • 2020
  • The current emission regulations, US Tier-4 and EU Stage-V, are only able to satisfy the regulations when all currently mass-produced emission reduction technologies such as EGR, DOC, DPF, and SCR are applied. Therefore, in this study, for the application of the Urea-SCR system to non-road diesel engines, the database was established by measuring the NO, NO2 concentration and calculating the NO2/NOx ratio based on the catalyst temperature and exhaust mass flow rate. Also, based on the measured NO2/NOx ratio data, a mathematical model was proposed to predict the NO2/NOx ratio at SCR catalyst, and the suitability of the model was verified through steady-state and transient mode. As a result of comparing the NO2/NOx ratio measured at the DOC outlet under the steady-state condition to two model values separately, the R2 was 0.9811 for the 3D map model and 0.9303 for the mathematical model. And in the case of the NO2/NOx ratio measured at the DPF outlet, the R2 was 0.9797 for the 3D map model and 0.935 for the mathematical model. It was confirmed that the R2 with the model value of the 3D Map of the mathematical model in the transient mode is 0.957, which shows high reliability.

Corelation between crystalline phase and corrosion resistance of Mg alloy with different PEO conditions. II. Corrosion resistance (Mg 합금의 PEO 공정 조건에 따른 산화피막 결정상과 내부식성에 대한 연구 II. 내부식성)

  • Kim, Bae-Yeon;Kim, Yong-Nam;Jeon, Min-Seok;Ham, Jae-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.28 no.2
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    • pp.80-84
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    • 2018
  • Mg alloys AZ31 and AZ91 were Plasma-Electrolytic-Oxidized in Na-P and Na-Si system electrolyte at various concentration, applied voltage and time. Thickness and surface roughness of PEO coating were examined. Salt spraying test were carried out to compare their corrosion resistances. Generally, corrosion resistances rate were increased as thickness and crystallinity increasing. Size of pore being larger, long term corrosion resistance decreased. It is turned out that $Mg_2SiO_4$ and other crystalline phase rather than MgO might be increase corrosion resistance dramatically.

Effects of Annealing of Gas-atomized Fe-Si-Cr Powder (Fe-Si-Cr 분말합금의 열처리 효과)

  • Jang, Pyungwoo
    • Journal of the Korean Magnetics Society
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    • v.26 no.1
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    • pp.7-12
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    • 2016
  • Effects of annealing of the gas-atomized Fe-9%Si-2%Cr powder which is suitable for high frequency application in mobile devices because of its high electrical resistivity were studied with an emphasis on the order-disorder phase transition. The formation of B2 ordered phase could not be suppressed during atomization process. When the powder was annealed at a temperature higher than $550^{\circ}C$ the peak diffracted from $DO_3$ phase could be detected. With increasing annealing temperature lattice parameter and coercivity decreased. An interesting phenomenon was an abrupt increment of coercivity in the powder annealed at $450^{\circ}C$. Highest permeability could be shown in the powder annealed at a relative low temperature of $150^{\circ}C$ and then the permeability decreased with annealing temperature. The above-mentioned results could be successfully explained by both the formation of $DO_3$ ordered phases and the change of electrical resistivity of the Fe-Si-Cr powder which was also originated from the phase transition.

Fabrication of Nano-Sized Complex Oxide Powder from Waste Solution Produced during Shadow Mask Processing by Spray Pyrolysis Process (새도우마스크 제조 공정중 발생되는 폐액으로부터 분무열분해 공정에 의한 복합산화물 나노 분말 제조)

  • Yu Jae-Keun
    • Resources Recycling
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    • v.12 no.6
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    • pp.38-46
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    • 2003
  • In this study, nano-sized Ni-ferrite and $Fe_2$$O_3$+NiO powder was fabricated by spray pyrolysis process in the condition of 1kg/$\textrm{cm}^2$ air pressure using the Fe-Ni complex waste acid solution generated during the manufacturing process of shadow mask. The average particle size of the produced powder was below 100 nm. The effects of the reaction temperature, the concentration of raw material solution and the nozzle tip size on the properties of powder were studied. As the reaction temperature increased from $800 ^{\circ}C$ to $1100^{\circ}C$, the average particle size of the powder increased from 40 nm to 100 nm, the structure of the powder gradually became solid, yet the distribution of the particle size appeared more irregular. Along with the increase of the reaction temperature, the fraction of the Ni-ferrite phase were also on the rise, and the surface area of the powder was greatly reduced. As the concentration of Fe in solution increased from 20g/l to 200g/l, the average particle size of the powder gradually increased from 30 nm to 60 nm, while the distribution of the particle size appeared more irregular. Along with the increase of the concentration of solution, tie fraction of the Ni-ferrite phase was on the rise, and the surface area of the powder was greatly reduced. Along with the increase of the nozzle tip size, the distribution of the particle size appeared more irregular, yet the average particle size of the powder showed no significant change. As the nozzle tip size increased from 1 mm to 2 mm, the fraction of the Ni-ferrite phase showed no significant change, while the surface area of the powder slightly reduced. As the nozzle tip size increased to 3 mm and 5 mm, the fraction of the Ni-ferrite phase gradually reduced, and the surface area of the powder slightly increased.

Flow characteristics of supersonic twin-fluid atomizers (초음속 2유체 분무노즐의 유동 특성)

  • Park, Byeong-Gyu;Lee, Jun-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.7
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    • pp.2267-2276
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    • 1996
  • Twin-fluid atomization has been widely used in combustors and process industries because of its high performance and simple structure. Flow visualization and pressure measurements were conducted to investigate the effects of gas flow in twin-fluid atomization. Schlieren photographs showed that changes in atomizing gas pressure, altered the wave patterns, and the lengths of both recitrculating toroid (impinging stangnation point) nad supersonic flow region in the jet. A longer supersonic wave pattern like net-shape wqas observed as atomizing gas pressure increased. The disintegration phenomenon of liquid delivery tube. The variation of spray angles with gas pressures were obtained by visualization using laser sheet beam. Suction pressuresat the nozzle orifice exit and recirculating region are shown to be used to estimate the stable atomization condition of a twin-fluid atomizer.

Hydroponic Culture System for Wasabi Leaf Production (고추냉이 잎 생산을 위한 수경재배)

  • Choi, Ki-Young;Lee, Yong-Beom;Lee, Joo-Hyun;Nasangargale, T.
    • Journal of Bio-Environment Control
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    • v.16 no.1
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    • pp.1-6
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    • 2007
  • This experiment was conducted to possibility for leaf production of wasabi using hydroponics system. When they were grown in aeroponics and soiless culture such as saprolite and Coir, photosynthesis and transpiration rate were high and marketable yield $(leaf\;width\;11{\sim}13cm)$ showed $11.2{\sim}11.7$ of leaf number per plant and $52{\sim}53.8g$ fresh weight. In spring periods, the highest yield was 25.7 of leaf number per plant in nutrient solution of Yamasaki's solution developed in Japan in deep culture during 130 days. It showed be possibility that marketable leaves harvested one leaf every $2{\sim}4$ days though spring and fall culture periods using hydroponics controlled in environmental culture.

The evaluation of electrical properties for $LiNi_xMn_{2-x}O_4$ Nano powders by Ultra sonic pyrolysis (초음파 분무연소법에 의한 $LiNi_xMn_{2-x}O_4$ 분말의 전기적 특성 평가)

  • Oh, Hyo-Jin;Lee, Nam-Hee;Yoon, Cho-Rong;Czoska, Anna;Nam, Sang-Chul;Park, Kyeong-Soon;Lee, Nae-Sung;Kim, Sun-Jae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.05a
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    • pp.113-116
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    • 2006
  • 자발착화 연소반응법 (Glycine Nitrate Process)을 응용한 초음파분무열분해장치를 이용하여 이차전지의 양극재료인 Ni치환형 $LiMn_2O-4$ 분말을 합성하였고, 각각의 하소온도에 따른 분말의 특성을 평가하였다. 전구용액은 산화제로 $Mn(NO_3)_2{\cdot}6H_20$EX>, $LiNO_3$, $Ni(NO_3)_2{\cdot}6H_20$를 사용하였고, 자발착화 에너지를 공급하기 위한 연료로는 glycine를 사용하였다. 분말의 결정상을 확인하기 위해 X-선 회절 시험을 시행하였으며, 각각의 조성별로 ICP측정결과 여러 조성들($LiNi_xNm_{2-x}O_4\;0{\leq}x{\leq]0.5$) 중 $LiNi_{0.3}Nm_{1.7}O_4$의 분말이 비교적 우수한 특성을 나타내었지만, 전기화학적 특성 평가 결과 이론용량값에 미치지 못하는 용량값을 나타내었다. 이것은 분말 합성 시 미량의 미 반응된 유기물들이 분말 표면에 피복되어 전기적 성질을 변화시키고 있기 때문임을 확인하였다. 이러한 특성을 개선하고자 추가적으로 하소 공정을 실시하여 전지의 성능를 평가 하였다. 분말의 미세구조와 형태, 크기, 전기 화학적 특성을 관찰하여 하소 전 후의 분말을 비교하였다.

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Investigation of Spherical LiMn2O4 Cathode Materials by Spray-drying with Different Electrochemical Behaviors at High Rate (분무건조법으로 제조한 구형 스피넬계 LiMn2O4 양극소재의 합성 조건에 따른 고출력 거동에 대한 연구)

  • Song, Jun Ho;Cho, Woosuk;Kim, Young Jun
    • Journal of the Korean Electrochemical Society
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    • v.19 no.2
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    • pp.50-56
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    • 2016
  • Spherical lithium manganese oxide spinel, $Li_{1.10}Mn_{1.86}Al_{0.02}Mg_{0.02}O_4$ was prepared by wet-milling, spray-drying, and sintering process. In the spray-drying process, solid content in slurry was varied from 20 to 30 wt%. In the sintering process, the precursors have been sintered under air or $O_2$ atmosphere. While the as-prepared samples exhibit excellent electrochemical properties at room temperature, the discharge voltage profiles at 5.0C are very different one from another. The origin for the difference especially at initial state of discharge is oxygen defect. The sample prepared in air has larger capacity related to the plateau at 3.3 V (vs. $Li/Li^+$) which is caused by the oxygen defects than the one prepared in $O_2$. The difference of discharge voltage profiles especially at the final state of discharge comes from different diffusion rate of $Li^+$ ions. The sample prepared from 30 wt% solid content of slurry shows twice higher diffusion rate than the samples prepared from 20 wt% solid content, which is attributed to better compactness between primary particles for the sample prepared from 30wt % solid content than the one prepared by 20 wt%.

Making Process for Magnetite Powder (Magnetite 분말의 제조)

  • Ho-Sang Lee;Kyu-Jin Kim
    • Resources Recycling
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    • v.9 no.5
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    • pp.28-32
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    • 2000
  • In this study, the new processing method to produce magnetite for mono-component black toner was studied using spray roaster. The produced magnetite is compared with TMB 125 made by Magnox, USA. When the weight ratio of the ferrous chloride and the ferric chloride is varied from 3:7~7:3 under $N_2$ atmosphere, the 100% major phase of magnetite is obtained. However, when the content of he ferrous chloride is higher than 70wt%, the content of FeO is increased. The phase of $\Gamma-Fe_2O_3$ is shown in th range of over 70wt% of the ferric chloride. The magnetite produced by spray roasting has a saturation magnetization of 80~85 emu/g and a coercivity of 110~130 Oe. The shape of the particle is irregular sphere and hte size of the magnetite is the range of $0.3~0.5\mu\textrm{m}$. It is shown that the magnetite made by spary roasting is enough to apply to the magnetic material of toner.

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