• Proceedings of the Materials Research Society of Korea Conference
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• 2003.11a
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• pp.112-112
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• 2003

은분말은 전자 산업에 있어 후막 도체 페이스트의 제조를 위해 사용되어지고 있다. 후막 페이스트는, 기재상에 스크린 프린트되고, 전도성의 회로 패턴을 형성한다. 이러한 회로는, 다음에 건조, 소성되고 액체 유기 비이클을 휘발 시키고, 그리고 은 입자를 소결시킨다. 프린트 회로 기술은 점점 고밀도이면서 더욱 정밀한 전자 회로를 요구하고 있다. 이러한 요건에 적합하기 위하여 도선은 폭이 점점 좁아지고, 선의 사이의 거리가 점점 작아지고 있다. 고밀도가 조밀하게 꽉 찬 좁은 선을 위하여 은 분말은 가능한 크기가 단일하고 구형의 형태를 가져야 한다. 현재 금속 분말을 제조하는 방법으로는 화학적 환원법, 무화 또는 분쇄, 열분해법등의 물리적 과정 및 전기 화학적 과정 등이있다. 본 연구에서는 입도 분포가 좁은 구형의 은 분말을 제조하기 위하여 기상법의 하나인 분무열분해법을 도입하였다. 또한 싸이클론을 사용하므로 큰 액적들을 걸러 입도 분포를 줄였다. 은 분말의 프리커서로써는 AgNO$_3$를 사용하였고 반응기의 온도는 $700^{\circ}C$에서 100$0^{\circ}C$까지 변화시켰으며 운반기체로써는 5%H$_2$ 혼합가스로 20L/min에서 80L/min 변화시켜 은 분말을 제조하였다. 또한 용액의 농도는 0.2M에서 1.0M까지 변화시켰다. 용액의 농도가 0.2M이고 운반기체의 유랑이 40L/min일 경우 완전한 은 상이 관찰되었고, 입자의 크기는 약 600nm였다.

• Journal of the Korean Society of Propulsion Engineers
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• v.16 no.5
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• pp.1-9
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• 2012

The gas jet from a coaxial porous injector for two-phase flows is discharged from the porous surface, which encloses the center liquid jet, and the gas and liquid jet interact with each other physically. The wall injected gas jet transfers the radial momentum effectively while the radial gas jet develops to axial jet, and the performance of atomizing and mixing can be improved. In this study, the Weber number and the ratio of momentum flux were controlled by changing the gas injection area and the mass flow rate of the gas jet, and a study on the spray characteristics at the cold-flow test using water and air simulant was performed. It is concluded that the radial momentum transfer concept of a coaxial porous injector gives a positive effect on the atomization and mixing of the two-phase spray.

• Journal of ILASS-Korea
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• v.14 no.1
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• pp.1-7
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• 2009

This study carried out numerical analysis of flow field of combustion gas and sorbent to test sorbent efficiency of DSI process. To provide rapid mixing for increase utilization rate of sorbent, streamwise vorticity can be introduced into the flowing streams by other means; for example, by installing vortex generators immediately downstream of the wavy trailing edge. Computing results show that the degree of sorbent dispersion depends strongly on duct structure. Highest dispersion efficiency received when vortex generator was installed inside of duct. The results presented in this study a optimum condition for the development of practical DSI process.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.29 no.1
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• pp.6-11
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• 2019

Methylammonium lead halide ($MAPbX_3$, X = I, Br) thin films, used as the light absorber of perovskite solar cells, were prepared using the dual feed ultrasonic spray method. Going through a deposition at a substrate temperature of below $60^{\circ}C$ and then a final heat treatment at $75^{\circ}C$ for 5 minutes using dual feed ultrasonic spray method, $MAPbI_3$ single phase could be formed. Whereas undergoing a deposition at temperatures above $80^{\circ}C$, the spheroidal grains could be changed into rod-shaped fractal structures due to the decomposition of the perovskite phase. Furthermore, using the same method at a higher heat treatment temperature of $100^{\circ}C$, $MAPbI_{3-x}Br_x$ thin films could also be formed from $MAPbI_3$ and $MAPbIBr_2$ solution.

• Journal of Energy Engineering
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• v.4 no.3
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• pp.394-401
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• 1995

본 연구는 중심부에 액체, 외주부에 산화제가 흐르는 기액 동축분류의 유동장에 대한 것이다. 기액 동축 분사기는 연료의 분사량이 적은 소형 연소시스템을 고려하여, 실험은 연공비(W1/Wa)가 0.6 이하를 대상으로, 물과 공기를 사용하여 분사조건에 따른 분무특성과 기액 2상 분무류의 기본구조를 조사하여 액적의 확산, 기액혼합특성에 대하여 검토하여 다음과 같은 결론을 얻었다. 반경방향 기상속도분포 및 액적유속분포는 분구직경 및 분사조건에 관계없이 정규분포에 가까운 형태를 취하고 있으며, 각각 식 (2) 및 (3)으로 나타낼 수 있다. 기상속도는 반치폭은 축방향에 따라 일정한 구배 (≒4.6)로서 증가하며, 기상만의 단상분류의 구배(≒6)에 비해서 완만하다. 액적유속 반치폭은 축방향에 따라 더욱 완만한 구배(≒3.1)로서 증가한다. 무차원 액적유속분포는 축방향에 따라 일정한 구배(n≒1.5)로서 감소한다. 액적의 확산은 상대적으로 기액유량비가 클수록 효과적으라고는 말할 수 없고, 최대 확산을 이루는 최적의 기액유량비가 존재한다.

• Journal of ILASS-Korea
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• v.22 no.2
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• pp.87-95
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• 2017

Recently, as the interest in environmental issues have increased around the world, the regulation on vehicle exhaust have been tightened in each country. To satisfy such tightened exhaust regulation, automotive manufactures are forced to equipped Diesel Particulate Filter (DPF) at Diesel vehicles. If DPF is used for a long time, DPF regeneration should be performed. The objective of this study is to research on post injection for DPF regeneration. The result of the study was that it was desired that retarding post injection timing, lower load of engine and smaller the amount of main fuel injection, for DPF regeneration. Oil dilution was tended to increase as load was lower, amount of post injection was increased, and post injection timing was retarded.

• Korean Chemical Engineering Research
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• v.53 no.5
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• pp.620-626
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• 2015

$Ho^{3+}$ doped $SrAl_2O_4$ upconversion phosphor powders were synthesized by spray pyrolysis, and the crystallographic properties and luminescence characteristics were examined by varying activator concentrations and heattreatment temperatures. The effect of organic additives on the crystal structure and luminescent properties was also investigated. $SrAl_2O_4:Ho^{3+}$ powders showed intensive green emission due to the $^5F_4/^5S_2{\rightarrow}^5I_8$ transition of $Ho^{3+}$. The optimal $Ho^{3+}$ concentration in order to achieve the highest luminescence was 0.1%. Over this concentration, emission intensities were largely diminished via a concentration quenching due to dipole-dipole interaction between activator ions. According to the dependence of emission intensity on the pumping power of a laser diode, it was clear that the upconversion of $SrAl_2O_4:Ho^{3+}$ occurred via the ground state absorption-excited state absorption processes involving two near-IR photons. Synthesized powders were monoclinic as a major phase, having some hexagonal phase. The increase of heat-treatment temperatures from $1000^{\circ}C$ to $1350^{\circ}C$ led to crystallinity enhancement of monoclinic phase, reducing hexagonal phase. The hexagonal phase, however, did not disappear even at $1350^{\circ}C$. When both citric acid (CA) and ethylene glycol (EG) were added to the spray solution, the resulting powders had pure monoclinic phase without forming hexagonal phase, and led to largely enhancement of crystallinity. Also, N,N-Dimethylformamide (DMF) addition to the spray solution containing both CA and EG made it possible to effectively reduce the surface area of $SrAl_2O_4:Ho^{3+}$ powders. Consequently, the $SrAl_2O_4:Ho^{3+}$ powders prepared by using the spray solution containing CA/EG/DMF mixture as the organic additives showed about 168% improved luminescence compared to the phosphor prepared without organic additives. It was concluded that both the increased crystallinity of high-purity monoclinic phase and the decrease of surface area were attributed to the large enhancement of upconversion luminescence.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.33 no.6
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• pp.454-460
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• 2009

To analyze the mixture formation process of evaporating diesel spray is important for emissions reduction in actual engines. Then the effects of change in density of ambient gas on spray structure in high temperature and pressure field have been investigated in this study. The ambient gas density was changed from ${\rho}_a=5.0kg/m^3$ to ${\rho}_a=12.3kg/m^3$ with CVC(Constant Volume Chamber). Also, simulation study by modified KIVA-II code was conducted and compared with experimental results. The ambient temperature and injection pressure are kept as 700K and 72MPa, respectively. The images of liquid and vapor phase in the evaporating free spray were simultaneously taken by exciplex fluorescence method. As experimental results, with increasing ambient gas density, the tip penetration of the evaporating free spray decreases due to the increase in the drag force from ambient gas. The spatial structure of a diesel spray can be verified as 2-regions consisted of liquid with momentum decrease and vapor with large-scale vortex. The calculated results obtained by modified KIVA-II code show good agreements with experimental results.

• Journal of ILASS-Korea
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• v.12 no.1
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• pp.65-70
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• 2007

This paper is to investigate the characteristics of exhaust emissions and nano-particle emission from diesel passenger vehicle according to using biodiesel fuel as an alternative fuel. In this work, the particulate matters (PM) of exhaust emissions in diesel engine were investigated by number of particles and mass measurement. The mass of the total PM was measured using the standard gravimetric measurement method, the total number concentrations were measured on a ECE15+EUDC driving cycle using Condensation Particle Counter (CPC). Total PM emission was reduced $2{\sim}38%$ and number concentration was reduced $1{\sim}27%$ according to increasing blended ratio of biodiesel with diesel fuel. Total PM emission was reduced more than particle number emission because volatile particles were measured in total PM but were not measured in particle number emissions.

• Journal of ILASS-Korea
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• v.9 no.1
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• pp.15-20
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• 2004

The post injection effect to enhance aftertreatment devices' performance is essential to meet future stringent emission standards by controlling exhaust gas temperature and emission pollutants. The test has been made with commercial common rail diesel engine by post injection manipulation, to optimize exhaust gas temperature while guarantee low fuel penalty. The optimization was done at 1500, 2000 and 2500[rpm] for 2, 4[bar] condition which show low exhaust gas temperature. The main purpose of this test is dedicated to understand mechanism of exhaust gas temperature rise while optimizing