• Title/Summary/Keyword: 2단계 열처리

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소결한 $(Bi_xLa_{1-x})Ti_3O_{12}$ 강유전체에서 조성 및 첨가물질에 따른 미세구조 및 전기적 특성 평가

  • Kim, Yeong-Min;Gang, Il;Ryu, Seong-Rim;Gwon, Sun-Yong;Jang, Geon-Ik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.279-279
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    • 2007
  • 비휘발성 메모리 Fe-RAM은 빠른 정보처리 속도와 전원공급이 차단되었을 때도 계속 정보를 유지할 수 있는 비휘발성 특징과 더불어 저전압, 저전력 구동의 장점이 있어서, 차세대 메모리로 많은 주목을 받고 있다. FeRAM에 사용되는 강유전체는 주로 Pb(Zr,Ti)$O_3$가 적용되었는데, 최근에는 비납계 강유전체의 연구도 활발히 이루어지고 있다. 이러한 비납계 강유전체 중에서 가장 특성이 우수한 물질은 $(Bi,La)_4Ti_3O_{12}$ (BLT) 이다. 그런데 BLT는 결정 방향에 따른 강한 이방성의 강유전 특성을 나타내기 때문에 BLT 박막을 이용하여 Fe-RAM 소자 등을 제작하기 위해서는 결정의 방향성을 세심하게 제어하는 것이 매우 중요하다. 지금까지 연구된 BLT 박막의 방향성 조절결과를 보면, BLT 박막을 스핀 코팅 법 (spin coating method)으로 증착하고, 핵생성 열처리 단계를 조절하여 무작위 방향성을 갖는 박막을 제조하는 방법이 일반적이었다. 그런데 이러한 스핀 코팅법에서의 핵생성 단계의 제어는 공정 조건 확보가 너무 어려운 단점이 있다. 이러한 어려움을 극복할 수 있는 대안은 스퍼터링 증착법(sputtering deposition method), PLD (pulsed laser deposition)법 등과 같은 PVD (physical vapor deposition) 법의 증착방법을 적용하는 것이다. PVD 법으로 증착하는 경우에는 이미 박막 내에 무수한 결정핵이 존재하기 때문에 핵생성 단계가 필요가 없게 된다. PVD 증착법의 적용을 위해서는 타겟의 제조 및 평가 실험이 선행되어야 한다. 그런데 벌크 BLT 재료의 소결공정 조건과 전기적 특성에 관한 연구 결과는 거의 발표가 되지 않고 있다. 본 실험에서는 $Bi_2O_3,\;TiO_2,\;La_2O_3,\;Nb_2O_5\;and\;Al_2O_3$ 분말들을 이용하여 최적의 조성을 구하기 위하여 $Nb^{+5}$$Al^{+3}$$Ti^{+4}$ 자리에 소량 치환시켜 제조하였다. 혼합된 분말을 하소 후 pellet 형태로 성형하여 소결을 실시하였다. 시편을 1mm 두께로 연마하고, 양면에 silver 전극을 인쇄하여 전기적 특성을 측정하였다. 측정결과 $Ti^{+4}$ 자리에 $Nb^{+5}$를 치환하여 제조한 시편에서 $2P_r{\sim}31\;{\mu}c/cm^2$정도의 매우 우수한 특성을 얻었다.

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Modification of glass fiber bundle with functionalized coupling agents and phenolic resin (기능성 커플링제와 페놀수지에 의한 유리섬유 다발의 표면개질 연구)

  • Lee, Soo
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.1
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    • pp.168-175
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    • 2016
  • The surface of glass fiber bundle was modified with functionalized silanes and phenolic resin to improve the tensile strength as well as the adhesion of glass fiber to matrix phenolic resin. The surface modification of reinforcing glass fiber can play a significant role in controlling whole composite characteristics. We applied surface modification of glass fiber with two different functionalized silanes, such as glycidyltrimethoxysilane(G-silane) and aminopropyltriethoxysilane (A-silane), and phenol formaldehyde(PF) resin in one pot or separated process under different coating compositions and temperatures. Thermal treatment temperature is very important factor to improve the mechanical properties of modified glass fiber. Modified glass fiber bundle treated at $170^{\circ}C$ showed the highest tensile strength of $10.05g_f/D$. Surface analyses by scanning electron microscope(SEM) and FT-IR spectroscopy were used to characterize the surface coatings on glass fiber bundles. Mechanical property changes as functions of treatment conditions and coupling agent types were also explained.

Fabrication of Low Temperature Cofiring Substrate Containing Fluorine by Water Swelling (Water Swelling을 이용한 Fluorine함유 저온소결 기판의 제조)

  • 윤영진;최정헌;이용수;강원호
    • Journal of the Microelectronics and Packaging Society
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    • v.9 no.2
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    • pp.19-25
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    • 2002
  • Glass composed of $Li_2$O.MgO. $MgF_2$.$SiO_2$.$B_2O_3$ for the fabrication of green sheet was prepared by melting process, and glass ceramics was prepared by the process of nucleation and grystal growth for the glass of $Li_2$O.MgO. $MgF_2$.$SiO_2$.$B_2O_3$ system with Lithium fluorhectorite and Lithium boron fluorphlogopite crystal phase. Powderization of the glass ceramics was carried out by water swelling. The average particle size at this point was 2.574 $\mu\textrm{m}$. Slurry was prepared for green sheet using high viscous sol fabricated by water swelling, which shows cleavage phenomenon in prepared glass ceramics. The optimum ratio of powder to water for the tape casting was 18:100, and its viscosity was 11,000~14,000 cps.

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Lipid Oxidation in Roasted Fish Meat II. Rancidity in Roasted and/or Reheated White Musled Fish (어육의 배소에 의한 지질산화에 관한 연구 II. 백색육어의 배소 및 재가열에 의한 지질의 산패)

  • LEE Kang-Ho;CHO Ho-Sung;LEE Jong-Ho;SHIM Ki-Hwan;RYU Hong-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.30 no.5
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    • pp.714-718
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    • 1997
  • The tendency of rancidity in roasted and/or reheated yellowfin sole and yellow croaker was investigated as typical white muscled fish. In fatty acid composition of the total lipid, saturated fatty acid was $27.4\%,\;33.4\%$; monoenoic acid, $36.5\%,\;38.7\%$ and polyenoic acid, $34.5\%,\;26.5\%$ in yellowfin sole and yellow croaker, respectively. The ratio of unsaturated fatty acid (UFA)/saturated fatty acid (SFA) were 2,6, 2.0 and content of total lipid was $1.4\%,\;0.8\%$, respectively. Peroxide content decreased after heating in yellowfin sole while decreased after heating and tended to increase after reheating in yellow croaker. Thiobarbituric acid value increased during roasting and heating in all the samples but decreased after reheating. Acid value increased after roasting, heating and reheating in all samples, particularly higher in yellowfin sole which have a high content of UFA. Conjugated dienes continuously increased during the repeats of heating, showing more increase in the fillet with Skin than the skinless.

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Nutritive and Antioxidative Properties of Eggplant by Cooking Conditions (조리조건에 따른 가지(Solanum melongena L.)의 영양 및 항산화 특성 연구)

  • Ko, Hyun-Jung;Sun, Tian Yu;Han, Jung-Ah
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.45 no.12
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    • pp.1747-1754
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    • 2016
  • The nutritive and antioxidative properties of eggplant by cooking conditions based on hardness range were evaluated. Three cooking methods (boiling, microwaving, and steaming) with three different times were used, and cooked eggplant was freeze-dried for analysis. For color of peel, fading was most observed during boiling and least during steaming. Although raw eggplant showed high free radical scavenging activity based on 1,1-diphenyl-2-picrylhydrazyl and total polyphenol contents, both were further increased upon steaming but significantly decreased upon boiling. The amount of chlorogenic acid in eggplant increased upon steaming and decreased upon boiling or microwaving. Notable cell wall collapse was observed in the microwaved sample compared to the other two cooking methods. Calcium elution from tissues or the cell wall was observed in all samples, and the amount significantly increased with cooking time, especially by steaming.

Texture and Plastic Strain Ratio Changes during a 2 Step Asymmetric Rolling and Annealing of AA5083 Al Alloy Sheet (2단계 비대칭 압연과 열처리한 AA5083 Al 합금판재의 집합조직과 소성변형비 변화)

  • Jeong, H.B.;Lee, J.H.;Kim, G.H.;Nam, S.K.;Kim, I.
    • Transactions of Materials Processing
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    • v.23 no.2
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    • pp.82-87
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    • 2014
  • The plastic strain ratio is one of the factors that affect the deep drawability of Al alloy sheet. The deep drawability of Al alloy sheet is limited because of its low plastic strain ratio. Therefore an increase in the plastic strain ratio to improve the deep drawability of Al alloy sheet is needed. The current study investigated the increase of the plastic strain ratio and the change in texture of AA5083 Al alloy sheet after a 2 step asymmetric rolling with heat treatments. The average plastic strain ratio of initial AA5083 Al alloy sheets was 0.83. After the first asymmetric rolling step of 88% deformation and subsequent heat treatment at $320^{\circ}C$ for 10 minutes the value was still 0.83. After the second asymmetric rolling of 14% reduction and subsequent heat treatment at $330^{\circ}C$ for 10 minutes the plastic strain ratio rose to 1.01. The average plastic strain ratio after the 2 step asymmetric rolling and heat treatment is 1.2 times higher than that of initial AA5083 Al alloy sheet. This result is related to the development of ND/<111> texture component after the second asymmetric rolling and heat treatment.

A New Process for a High Performance $I^2L$ (고성능 $I^2L$을 위한 새로운 제작공정)

  • Han, Cheol-Hui;Kim, Chung-Gi;Seo, Gwang-Seok
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.18 no.1
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    • pp.51-56
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    • 1981
  • A new I2L process for a high performance I2L structure is proposed. The modifiedstructure consists of a heavily doped extrinsic base and lowly doped intrinsic base where the collector regions are self-alignment with the intrinsic base regions. The proposed process untilizes spin-on sources as the diffusion sources and the self-alignment of collectors is achieved by using the hardened spin-on source as a diffusion mask. Test devices including a 13-stage ring oscillator have been fabricated by the proposed process on n/n+ silicon wafers with 6.5$\mu$m epitaxial layer. The maximum upward current gain of npn transistors is 8 for a three collector I2L cell. The speed-power product and minimum propagation delay for a one collector structure are 3.5 pJ and 50 ns, respectively.

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Co/Ti Bilayer Silicidation on the $\textrm{p}^{+}$-Si Region Implanted with High Dose of $\textrm{BF}_2$ ($\textrm{BF}_2$가 고농도로 이온주입된 $\textrm{p}^{+}$-Si 영역상에 Co/Ti 이중막 실리사이드의 형성)

  • Jang, Ji-Geun;Sin, Cheol-Sang
    • Korean Journal of Materials Research
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    • v.9 no.2
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    • pp.168-172
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    • 1999
  • We have studied the formation of Co/Ti bilayer silicide with low resistivity and good thermal stability on the heavily boron doped $\textrm{p}^{+}$-Si region. In this paper, Co/Ti bilayer silicides were fabricated by depositing Co($150\AA$)/Ti($50\AA$) films on the clean $\textrm{p}^{+}$-Si substrates in an E-beam evaporator and performing the two step RTA process (first annealing: 650$50^{\circ}C$/20sec, second annealing: $800^{\circ}C$/20sec) in a $N_2$ambient with the pressure of $\textrm{10}^{-1}$atm. Co/Ti bilayer silicides obtained from our experiments exhibited the low resistivity of about $18\mu\Omega$-cm and the uniform thickness of about $500\AA$ without change of sheet resistance and agglomeration under the long post0annealing time up to $1000^{\circ}C$.

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Analysis of Irradiation Growth Behavior for the Zircaloy-4 Cladding used in the KOFA Fuel (국산 핵연료에 사용되는 Zircaloy-4 피복관의 조사성장 거동 해석)

  • Kim, Gi-Hang;Lee, Chan-Bok;Kim, Gyu-Tae
    • Korean Journal of Materials Research
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    • v.4 no.3
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    • pp.357-363
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    • 1994
  • The irradiation growth of the Zircaloy-4 cladding in the KOFA fuel loaded in the Kori-2 nuclear plant was measured to evaluate the irradiation growth behavior and to be compared with that of the Siemens cladding having different manufacturing process. Due to the partial recrystallization by final heat treatment, the KOFA Zircaloy-4 cladding showed a two step irradiation growth behavior such as the growth saturation and the accerlation which is typical of the fully annealed Zircaloy cladding. The difference in the measured irradiation growth rate between the KOFA and the Siemens cladding could be explained by the difference in the cladding texture which depends on the manufacturing process. From the measured irradiation growth data of Kori-2 KOFA fuel, a two-step irradiation growth model of the KOFA Zircaloy-4 cladding was derived, the accuracy of which can be more clearly verified as the measured data of the irradiation growth are accumulated in the future.

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Changes to the Anti-oxidative Activity and Amino Acid Content of Arctium lappa Tea by Heat Treatment (열처리 조건에 따른 우엉차의 항산화 활성과 아미노산 함량의 변화)

  • Im, Do-Youn;Lee, Kyoung-In
    • Journal of Life Science
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    • v.29 no.12
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    • pp.1358-1363
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    • 2019
  • In this study, the effect on the free amino acid content and anti-oxidative activity of Arctium lappa samples by heat treatment were compared to obtain data on the conditions required for properly processing the root as a raw material for tea. The results of DPPH and ABTS radical scavenging activity assays showed that 180℃-4 min and 200℃-3 min treatments retained relatively high activity. All heat treatment conditions showed increased polyphenol content compared to the initial sample value of 42.72 mg/l, and the 180℃-4 min and 200-3 min treatments were higher than the others at 60.09 mg/l and 62.74 mg/l, respectively. In the free amino acid analysis of the A. lappa root tea, the tendency of the initial content was confirmed to decrease as temperature and time increased. Changes in phenylalanine, histidine, leucine, and isoleucine were found to be high, while aspartic acid and proline changes were relatively low. Overall, amino acid content decreased significantly under heating conditions above 180℃-3 min and 200℃-2 min. From these results, heat treatment of A. lappa root at 180℃-4 min was deemed optimal based on anti-oxidative activity and free amino acid content.