• Title/Summary/Keyword: 18-crown-6

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Analysis of Morphological Characteristics and Variation among Six Populations of Pourthiaea villosa (Thunb.) Decne. var. villosa in Korea (국내 윤노리나무 6개 집단의 형태적 특징과 변이조사)

  • Nam, Jae-Ik;Choi, Go-Eun;Kim, Young-Me;Park, Jae-In
    • Korean Journal of Plant Resources
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    • v.28 no.1
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    • pp.26-34
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    • 2015
  • This study was conducted to examine the morphological characteristics and variations of the 6 populations of Pourthiaea. villosa (Thunb.) Decne. var. villosa in Korea. The ANOVA results showed that the populations were significantly different in 18 of the 21 quantitative characteristics that were analyzed. In the results of principal component analysis, 6 principal components (PC) represented 68.28% for the total variations. 'Petiole length' (0.764), 'Leaf shape' (0.834), 'Leaf length' (0.753), 'Crown diameter' (0.663), 'Inflorescence width' (0.492), and 'Leaf base shape' (0.721) showed the highest contribution to PC1, PC2, PC3, PC4, PC5, and PC6, respectively. According to the results of cluster analysis, one cluster comprised only 'Goesan-gun Ssanggok Valley' population. 'Namhae-gun Mijori Evergreen Forest' population was grouped with 'Hamyang-gun Sang Forest' population, which was the nearest subgroup. Further, 'Namhae-gun Geum Mountain' population, 'Jindo-gun Cheomchal Mountain' population, and 'Jeju-si Barimae Parasitic volcano' population were placed in the same cluster.

Mechanical Properties and Microstructure of the Leucite-Reinforced Glass-Ceramics for Dental CAD/CAM

  • Byeon, Seon-Mi;Song, Jae-Joo
    • Journal of dental hygiene science
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    • v.18 no.1
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    • pp.42-49
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    • 2018
  • The computer-aided design/computer-aided manufacturing (CAD/CAM) system was introduced to shorten the production time of all-ceramic restorations and the number of patient visits. Among these types of ceramic for dental CAD/CAM, they have been processed into inlay, onlay, and crown shapes using leucite-reinforced glass-ceramics to improve strength. The purpose of this study was to observe the mechanical properties and microstructure of leucite-reinforced glass-ceramics for dental CAD/CAM. Two types of leucite-reinforced glass-ceramic blocks (IPS Empress CAD, Rosetta BM) were prepared with diameter of 13 mm and thickness of 1 mm. Biaxial flexural testing was conducted using a piston-on-three-ball method at a crosshead speed of 0.5 mm/min. Weibull statistics were used for the analysis of biaxial flexural strength. Fracture toughness was obtained using an indentation fracture method. Specimens were observed by field emission scanning electron microscopy to examine the microstructure of the leucite crystalline phase after acid etching with 0.5% hydrofluoric acid aqueous solution for 1 minute. The results of strength testing showed that IPS Empress CAD had a mean value of $158.1{\pm}8.6MPa$ and Rosetta BM of $172.3{\pm}8.3MPa$. The fracture toughness results showed that IPS Empress CAD had a mean value of $1.28{\pm}0.19MPa{\cdot}m^{1/2}$ and Rosetta BM of $1.38{\pm}0.12MPa{\cdot}m^{1/2}$. The Rosetta BM sample exhibited higher strength and fracture toughness. Moreover, the crystalline phase size and ratio were increased in the Rosetta BM sample. The above results are expected to elucidate the basic mechanical properties and crystal structure characteristics of IPS Empress CAD and Rosetta BM. Additionally, they will help develop leucite-reinforced glass-ceramic materials for CAD/CAM.

Kinetic Study on Nucleophilic Substitution Reaction of 5-Nitro-8-quinolyl Benzoate, Picolinate, Nicotinate and Isonicotinate with Alkali Metal Ethoxide: Effect of Nonleaving Group on Reactivity and Transition State Structure

  • Lee, Jieun;Kim, Min-Young;Um, Ik-Hwan
    • Bulletin of the Korean Chemical Society
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    • v.35 no.6
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    • pp.1789-1793
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    • 2014
  • Pseudo-first-order rate constants ($k_{obsd}$) have been measured spectrophotometrically for the reactions of 5-nitro-8-quinolyl nicotinate (4) and 5-nitro-8-quinolyl isonicotinate (5) with alkali metal ethoxides (EtOM; M = K, Na and Li) in anhydrous ethanol at $25.0{\pm}0.1^{\circ}C$. The plots of $k_{obsd}$ vs. [EtOM] curve slightly upward for the reactions with EtOK and EtONa but are linear for the reactions with EtOLi and for those with EtOK in the presence of 18-crown-6-ether. Dissection of $k_{obsd}$ into $k_{EtO^-}$ and $k_{EtOM}$ (i.e., the second-order rate constants for the reactions with the dissociated $EtO^-$ and ion-paired EtOM, respectively) has revealed that the reactivity increases in the order $EtO^-{\approx}EtOLi$ < EtOK < EtONa for the reactions of 4 and EtOLi < $EtO^-$ < EtOK < EtONa for the reactions of 5. Comparison of the kinetic results for the reactions of 4 and 5 with those reported previously for the corresponding reactions of 5-nitro-8-quinolyl benzoate (2) and picolinate (3) has revealed that the esters possessing a pyridine ring (i.e., 3-5) are significantly more reactive than the benzoate ester 2 due to the presence of the electronegative N atom (e.g., 2 << 3 < 4 < 5). It has been concluded that $M^+$ ion catalyzes the reactions of 3-5 by increasing the electrophilicity of the reaction center through a five-membered cyclic transition state (TS) for the reaction of 3 and via a four-membered cyclic TS for the reactions of 4 and 5.

Full mouth rehabilitation on the patient with severe tooth wear and tooth fracture using reestabilishment of occlusal vertical dimension (심한 치아 마모 및 파절 환자의 수직고경거상을 동반한 전악 수복 증례)

  • Lee, Ho-Sun;Joo, Se-Jin;Jin, Soo-Yoon;Kang, Dong-Wan;Lee, Gyeong-Je
    • Journal of Dental Rehabilitation and Applied Science
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    • v.32 no.3
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    • pp.224-231
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    • 2016
  • Severe dental attrition causes pathological changes of the tooth, imbalanced occlusion, and functional and aesthetic complications and can also result in a decrease in occlusal vertical dimension that can incur temporomandibular joint and muscular complications. Before restoring the vertical dimension with full-mouth prosthetic restorations, it is important to determine the amount of vertical lifting through complete diagnosis. In this study, a 59 year-old male patient with generalized attrition and fracture of teeth was treated with full-mouth zirconia prosthetic restoration in order to recover vertical dimension and aesthetics. Through the analysis of physiologic rest position and inter-canine distance, the treatment was planned for lifting 3 mm in vertical dimension. Interim crown were fabricated after full-mouth wax up, having the patient use for 6 months. The final monolithic and bilayered zirconia restorations were completed. The patient showed satisfaction in function and aesthetics for 18 months of follow-up since delivering the final restorations.

Plant Community Structure of Pinus densiflora S. et Z. Forest in the Geumjeongsan (Mt.), Busan Metropolitan City (부산광역시 금정산 소나무림 식생구조 연구)

  • Lee, Kyoung-Jae;Kwak, Jeong-In;Kwak, Nam-Hyun;Jang, Jong-Soo
    • Korean Journal of Environment and Ecology
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    • v.27 no.4
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    • pp.462-472
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    • 2013
  • This study was carried out to provide a basic data for preservation of Pinus desiflora forest as cultural landscape forest by analyzing characteristics of plant community of P. desiflora forest in Geumjeongsan(mountatin) in Busan city. In order to analyze plant community of P. densiflora in Geumjeongsan, we set up 10 study plots inside and 8 plots outside of Geumjeongsansung(mountain fortress, hereinafter 'Sansung')(unit area: $400m^2$), a total of 18 plots. TWINSPAN analysis divided these 18 study plots into 6 communities which are Querqus serrata-P. desiflora community, P. desiflora community, P. desiflora-Q. serrata community, P. thunbergii-P. densiflora community, P. densiflora-P. thubergii-Q. acutissima community, and P. densiflora-Platycarya strobilacea community. Importance Percentage (I.P.) of each area and DBH class distribution of main species showed that P. densiflora community would succeed to Q. serrata community or C. tschonoskii community. Analysis on tree age found out that communities in the Sansung were 32~37 years old and those outside the Sansung were 44~57 years old. Shannon's species diversity index ranged from 0.4826 to 1.2499. Regarding correlation between species, P. densiflora had negative correlation with Styrax japonica. Based on abovementioned result we expected ecological succession from P. densiflora community to Q. serrata community inside of the Sansung. Outside the Sansung, succession from P. densiflora-P. thunbergii community to C. tschonoskii-Q. serrata community was expected. In order to manage P. densiflora forest as cultural landscape forest, Q. spp in the understory and shrub layer and deciduous broad-leaved arboreal trees should be managed. Tree crown management of deciduous broad-leaved trees in competition with P. desiflora, is also required.

Estimation of Gestational Age by Measurement of Fetal and Extra-fetal Structures in Miniature Schnauzer Bitches

  • Kim, Bang-Sil;Son, Chang-Ho
    • Journal of Veterinary Clinics
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    • v.25 no.6
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    • pp.501-505
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    • 2008
  • Serial ultrasonographic examinations were performed on 9 Miniature Schnauzer bitches from day 15 of gestation until parturition to determine the ultrasonographic measurement of gestational structures. Ovulation was designated the day that plasma progesterone concentration exceeded 4.0 ng/ml (day 0). Extra-fetal structures were measured from day 17 or 18 to 60. Outer uterine diameter (OUD) increased from $6.50{\pm}1.06mm$ ($Mean{\pm}SD$) to $50.89{\pm}5.62mm$, inner chorionic cavity diameter (ICCD) increased from $2.10{\pm}0.15mm$ to $37.15{\pm}4.36mm$, and length of placenta (PL) increased from $7.50 {\pm}1.41mm$ to $40.62{\pm}3.27mm$. OUD and ICCD were significantly and linearly relative to gestational age especially through day 37, whereas PL was not significantly relative to gestational age. Of the extra-fetal structures, ICCD was the most accurate for estimation of gestational age before day 38 of gestation. Fetal structures increased at a linear rate to parturition. Fetal crown-rump length (CRL) increased from $2.55{\pm}0.07mm$ on day 22 to $85.25{\pm}9.89mm$ on day 48. Fetal head diameter (HD) increased from $3.43{\pm}0.64mm$ on day 27 to $25.06{\pm}0.41mm$ on day 63. Fetal body diameter (BD) increased from $ 5.96{\pm}0.84mm$ on day 30 to $43.76{\pm}3.36mm$ on day 63. Of the fetal structures, HD was the most accurate for estimation of gestational age after day 38 to parturition.

Three-dimensional analysis of tooth movement in Class II malocclusion treatment using arch wire with continuous tip-back bends and intermaxillary elastics

  • Lee, Ji-Yea;Choi, Sung-Kwon;Kwon, Tae-Hoon;Kang, Kyung-Hwa;Kim, Sang-Cheol
    • The korean journal of orthodontics
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    • v.49 no.6
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    • pp.349-359
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    • 2019
  • Objective: The aim of this study was to analyze three-dimensional (3D) changes in maxillary dentition in Class II malocclusion treatment using arch wire with continuous tip-back bends or compensating curve, together with intermaxillary elastics by superimposing 3D virtual models. Methods: The subjects were 20 patients (2 men and 18 women; mean age 20 years 7 months ${\pm}$ 3 years 9 months) with Class II malocclusion treated using $0.016{\times}0.022-inch$ multiloop edgewise arch wire with continuous tip-back bends or titanium molybdenum alloy ideal arch wire with compensating curve, together with intermaxillary elastics. Linear and angular measurements were performed to investigate maxillary teeth displacement by superimposing pre- and post-treatment 3D virtual models using Rapidform 2006 and analyzing the results using paired t-tests. Results: There were posterior displacement of maxillary teeth (p < 0.01) with distal crown tipping of canine, second premolar and first molar (p < 0.05), expansion of maxillary arch (p < 0.05) with buccoversion of second premolar and first molar (p < 0.01), and distal-in rotation of first molar (p < 0.01). Reduced angular difference between anterior and posterior occlusal planes (p < 0.001), with extrusion of anterior teeth (p < 0.05) and intrusion of second premolar and first molar (p < 0.001) was observed. Conclusions: Class II treatment using an arch wire with continuous tip-back bends or a compensating curve, together with intermaxillary elastics, could retract and expand maxillary dentition, and reduce occlusal curvature. These results will help clinicians in understanding the mechanism of this Class II treatment.

EARLY DEVELOPMENT OF THE TOOTH IN THE STAGED HUMAN EMBRYOS AND FETUSES (한국인 배자 및 태아에서 유치 발생의 조직학적 변화)

  • Lim, Hee-Sik;Park, Hyoung-Woo;Oh, Hyeon-Joo;Kim, Hee-Jin;Choi, Byung-Jai
    • Journal of the korean academy of Pediatric Dentistry
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    • v.25 no.2
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    • pp.383-399
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    • 1998
  • Tooth development is usually described in four stages such as bud stage, cap stage, bell stage and crown stage. Exact time of appearance of tooth primordia is different among reports, and up to now there is no timetable regarding initial tooth development. To understand the congenital malformations and other disorders of the orofacial region, there is a need to establish a standard timetable on early tooth development. Till now, studies on the tooth development were mainly on later fetuses, and only few reports on early stage. Also, there were no reports on the time when bud stage turns to cap stage, and cap stage to bell stage. In this study, external morphology of face and the early development of the tooth, and transition of bud stage to cap stage, cap stage to bell stage were studied using 27 staged human embryos and 9 serially sectioned human fetuses. The results are as follows: 1. Mandibular region was formed by union of both mandibular arch at stage 15, and maxillary region by union of maxillary arch, medial nasal prominence, and intermaxillary segment at stage 19. 2. Ectodermal thickening which represents the primordia of tooth appeared in mandibular region at stage 13, and maxillary region at stage 15. 3. Bud stage began from mandibular primary central incisor at stage 17, and maxillary primary central incisor at stage 18. And the sequence of appearance was in the mandibular primary lateral incisor at stage 19, maxillary primary lateral incisor at stage 20, mandibular primary canine at stage 22, maxillary primary canine and primary first molar at stage 23, madibular primary first molar and maxillary primary second molar at 9th week, and mandibular primary second molar at 10th week of development. 4. Cap stage began from the primary anterior teeth at 9th week, and primary second molar still had the characteristics of cap stage at 12th week of development. 5. Transition to bell stage started from the primary anterior teeth at 12th week, and primary second molar started at 16th week of development. 6. Trnasition to crown stage started from primary anterior teeth at 16th week, and primary second molar at 26th week of development.

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The Tooth Size RelaTionship Between Crowding Patients and Normal Subjects in Korean (총생치열을 갖는 교정환자와 정상인의 치아크기 비교)

  • Han, Man-Deuk;Jeon, Eun-Sook
    • Journal of dental hygiene science
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    • v.6 no.1
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    • pp.29-34
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    • 2006
  • This study was undertaken to compare the tooth and arch size between crowding patient and normal subjects. Two group of dental casts were selected on the basis of crowding patients and normal subjects. One group, consisting of 40 pair of dental casts(20 male and 20 female), exhibited noncrowded dentitions. A second group, consisting of 40 pairs of dental cast(21 male and 21 female), exhibited remarkably crowding need for orthodontic treatment. Tooth width measurements were made with a sliding digital caliper with Vernier scale neared 0.01 mm. Mean, standard deviation, T-test of the following parameters were used to compare two group : individual mesiodistal crown widths, arch width and arch length. The following result were obtained. In the mesiodistal crown widths, normal subjects had generalized larger teeth than Wheeler's results(human tooth size index), except for maxillary central incisor, maxillary 2nd premolar, mandibular canine, and mandibular 1st molar. In the orthodontic patients with crowded dentitions, the mesiodistal tooth crown widths were generalized larger teeth than noncrowded normal subjects. In the arch width and arch length, the crowded dentition group had smaller arch width and arch length than the normal group.

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Crown Shape Control of Pinus koraiensis S. et Z. (VII) - The Influence of Thinning and Stem Pruning on Seed Component(The First Report) - (잣나무의 수형조절(VII) - 잣나무의 간벌과 수형조절이 종자의 성분에 미치는 영향(제1보) -)

  • Song, Jae-Mo;Shim, Tae-Heum;Yi, Jae-Seon
    • Journal of Forest and Environmental Science
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    • v.18 no.1
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    • pp.87-96
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    • 2001
  • In order to investigate the influence of increased seed production of Korean white pine(Pinus koraiensis S. et Z.), component of seeds, produced from trees in the thinned stand and the stem-pruned trees in the seed orchard, were analyzed. The results obtained were as follows: 1. General component analysis of seed There is no significant influence of thinning on the seed component in moisture content (thinned- 4.10%, unthinned- 3.74% ), ash (thinned- 2.95%, unthinned- 2.94%), crude lipid (thinned- 67.62%, unthinned- 71.94%), and crude protein (thinned- 17.27%, unthinned- 17.50%). There is no significant influence of stem-pruning on the seed component in moisture content (unpruned- 4.26%, 1m stem-pruned- 4.10%, and 2m stem-pruned- 3.99%), ash (unpruned- 2.08%, 1m stem-pruned- 2.09%, and 2m stem-pruned- 2.15%) crude lipid(unpruned- 68.59%, 1m stem-pruned- 69.52%, and 2m stem-pruned- 72.53%), and crude protein (unpruned- 18.13%, 1m stem-pruned- 17.96%, and 2m stem-pruned- 17.56%) 2. Fatty acid analysis Seeds of tree from thinned and unthinned stands contained two essential fatty acids, i.e., linoleic acid (18:2) (thinned- 54.92%, unthinned- 55.40%) and linolenic acid (18:3) (thinned- 0.19%, and unthinned- 0.23%). Over 94% of fatty acids consisted of linoleic acid (18:2)(55%), oleic acid (18:1) (32%), and palmitic acid (16:0)(7%). T-test showed difference of content at 1% significance level for palmitoleic acid (16:1), stearic acid (18:0) and 8.11, 14-eicosatrienoic acid (20:3) and at 5% for linolenic acid (18:3), but no significant difference for three major fatty acids mentioned above, between two types of trees. Thus thinning may give no influence in fatty acid content. Seeds of three types of trees contained two essential fatty acids, i.e., linoleic acid (18:2)(unpruned- 55.25%, 1m stem-pruned- 54.74%, and 2m stem-pruned- 55.00%), and linolenic acid (18:3)(0.21% for three kinds of trees). Linoleic acid (18:2)(55%), oleic acid (18:1) (32%), and palmitic acid (16:0)(6%) consisted of more than 93% of all fatty acid content. At 5% significance level in F-test, difference was observed in the content of palmitoleic acid (16:1) and 8.11, 14-eicosatrienoic acid (20:3), but not in three major types of fatty acids above mentioned. It is observed that stem-pruning gave no significant influence in fatty acid content in general.

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