• Title/Summary/Keyword: 12Cr steel

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Leaching and Acute Toxicity Test of Steel-making Slags for Media Contact Recycling (제강슬래그의 매체접촉형 재활용에 따른 중금속 용출특성 및 물벼룩 생태독성 평가)

  • Donghyun Kim;Bong Seok Cho;Won Sik Shin
    • Journal of Soil and Groundwater Environment
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    • v.29 no.1
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    • pp.72-83
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    • 2024
  • Most of the slags generated from steel-making industry in Korea are recycled into media-contact aggregates such as fill and cover materials. For their use as media-contact aggregates, the slags must meet not only the waste quality criteria, but also the Daphnia magna acute toxicity test criteria. In this study, Korean Leaching Test ES 06150.e (Korea), Japanese Leaching Test JIS K 0058-1(Japan), Detuch Leaching Test DIN 19529 (Germany), Toxicity Characteristic Leaching Procedure (USA) were conducted for batch leaching test of slags from 6 Korean steel-making companies. In addition, Korean Standard up-flow percolation test (ES 06151.1) mimicking field conditions was conducted to assess the impact of the slag leachate on the surrounding environment indirectly. Heavy metals such as Cr6+ and Zn2+ were detected from both extractant and leachate samples, but all of them did not exceed waste quality criteria of each country. However, Daphnia magna acute toxicity tests using the leachate samples from up-flow percolation test with slag alone and slag/natural soil conditions exceeded ecotoxicity standard (TU=2) due to their high pH (11.3-12.5). After neutralizing the pH of the slag leachate to 6.5~8.5, the Daphnia magna mortality and immobilization were reduced to satisfy ecotoxicity standard. As the reducing pH of slag leachate would be extremely difficult, appropriate recycling management considering the physicochemical characteristics of he slags should be stuided further.

Environmentally Conscious Machining Technology of Aircraft Material(12Cr steel) (항공기소재(고크롬강)의 환경친화적 가공기술)

  • 강명창;김정석;이득우;황윤호;송준호
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2002.05a
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    • pp.1051-1054
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    • 2002
  • Environmentally conscious machining and technology have been taking more and more important position in machining process. Since cutting fluid has some impact on environment, many researches are being carried out to minimize the use of cutting fluid. It can be Increased the environmental pollution through not using coolant any more or minimizing it. In this study, the cooling effects of cutting methods using the compressed cold air, dry cutting and cutting fluid will investigate in the blade machining. In order to examine the characteristics of cutting and tool in the environmentally conscious machining, this work investigates experimentally the degree of tool wear, cutting force and characteristics of surface roughness in relation to machining conditions and cooling methods.

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A Study on Fracture Mechanism of Torsion-Mounted Type Turbine Blade (비틀림 마운트형 터빈 블레이드의 파괴기구에 관한 연구)

  • Hong, Soon-Hyeok;Lee, Dong-Woo;Jang, Deuk-Yul;Cho, Seoks-Woo;Joo, Won-Sik
    • Proceedings of the KSME Conference
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    • 2001.06a
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    • pp.585-590
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    • 2001
  • Turbine blade is subject to torsional load by torsion-mount, centrifugal load by rotation of rotor and repeated bending load by steam pressure. Turbine with partially cracked blade has normal working condition at initial repair time but vibratory working condition at middle repair time due to crack growth. Finite element analysis on turbine blade indicates that repeated bending load out of all loads is the most important factor on fatigue strength of turbine blade. Therefore, this study shows root mean square roughness has linear relation with stress intensity factor range in 12% Cr steel and can predict loading condition of fractured turbine blade.

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A Study on Failure Analysis of Turbine Blade Using Surface Roughness and FEM (표면거칠기와 유한요소법을 이용한 터빈 블레이드의 파손해석에 관한 연구)

  • 홍순혁;이동우;이선봉;조석수;주원식
    • Transactions of the Korean Society of Automotive Engineers
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    • v.9 no.6
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    • pp.170-177
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    • 2001
  • Turbine blade is subject to torsional load by torsion-mount, centrifugal load by rotation of rotor and repeated bending load by steam pressure. Turbine with partially cracked blade has normal working condition at initial repair time but vibratory working condition at middle repair time due to crack growth. Finite element analysis on turbine blade indicates that repeated bending load out of all loads is the most important factor on fatigue strength of turbine blade. Therefore, this study shows root mean square roughness has linear relation with stress intensity factor range in 12% Cr steel and can predict loading condition of fractured turbine blade.

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Corrosion and mechanical properties of hot-rolled 0.5%Gd-0.8%B-stainless steels in a simulated nuclear waste treatment solution

  • Jung, Moo Young;Baik, Youl;Choi, Yong;Sohn, D.S.
    • Nuclear Engineering and Technology
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    • v.51 no.1
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    • pp.207-213
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    • 2019
  • Corrosion and mechanical behavior of the hot-rolled 0.5%Gd-0.8%B-stainless steel to develop a spent nuclear fuel storage material was studied in a simulated nuclear waste treatment condition with rolling condition. The austenite and ferrite phases of the 0.5%Gd-0.8%B-stainless steels are about 88:12. The average austenite and ferrite grain size of the plane normal to rolling, transverse and normal directions of the hot rolled specimens are about 5.08, 8.94, 19.35, 23.29, 26.00 and 18.11 [${\mu}m$], respectively. The average micro-hardness of the as-cast specimen is 200.4 Hv, whereas, that of the hot-rolled specimen are 220.1, 204.7 and 203.5 [$H_v$] for the plane normal to RD, TD and ND, respectively. The UTS, YS and elongation of the as-cast and the hot-rolled specimen are 699, 484 [MPa], 34.0%, and 654, 432 [MPa] and 33.3%, respectively. The passivity was observed both for the as-cast and the hot rolled specimens in a simulated nuclear waste solution. The corrosion potential and corrosion rate of the as-casted specimens are $-343[mV_{SHE}]$ and $3.26{\times}10^{-7}[A/cm^2]$, whereas, those of the hot rolled specimens with normal to ND, RD and TD are -630, -512 and -620 [$mV_{SHE}$] and $6.12{\times}10^{-7}$, $1.04{\times}10^{-6}$ and $6.92{\times}10^{-7}[A/cm^2]$, respectively. Corrosion tends to occur preferentially Cr and B rich area.

Effect of $N_2$ and $O_2$ Properties of STS304 Stainless Steel Films Synthesized by Unbalanced Magnetron Sputtering Process (비대칭 마그네트론 스퍼터링법에 의해 합성된 STR304 스테인리스강 박막에서의 질소와 산소의 첨가 효가)

  • 김광석;이상율;김범석;한전건
    • Journal of Surface Science and Engineering
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    • v.34 no.2
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    • pp.89-96
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    • 2001
  • N- or O-doped STS304 stainless films were synthesized by an unbalanced magnetron sputtering process with various argon and reactive gas ($N_2$, $O_2$) mixtures. These films were examined by scanning electron microscopy (SEM), X-ray diffraction (XRD), Auger electron spectroscopy (AES) and Knoop microhardness tester. The Results from X-ray diffraction (XRD) analysis showed that a STS304 stainless steel film synthesized without reactive gas using a bulk STS304 stainless steel target had a ferrite bcc structure ($\alpha$ phase), while the N-doped STS304 stainless film was consisted of a nitrogen supersaturated fcc structure, which hsa a strong ${\gamma}$(200) phase. In the O-doped films, oxide Phases ($Fe_2$$O_3$ and $Cr_2$$O_3$) were observed from the films synthesized under an excess $O_2$ flow rate of 9sccm. AES analysis showed that nitrogen content in N-doped films increased as the nitrogen flow rate increased. Approximately 43 at.%N in the N-doped film was measured using a nitrogen flow rate of 8sccm. In O-doped film, approximately 15 at.%O was detected using a $O_2$ flow rate of 12sccm. the Knoop microhardness value of N-doped film using a nitrogen flow rate of 8 sccm was measured to be approximately $H_{ k}$ 1200 and this high value could be attributed to the fine grain size and increased residual stress in the N-doped film.

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Reliability Improvement of Offshore Structural Steel F690 Using Surface Crack Nondamaging Technology

  • Lee, Weon-Gu;Gu, Kyoung-Hee;Kim, Cheol-Su;Nam, Ki-Woo
    • Journal of Ocean Engineering and Technology
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    • v.35 no.5
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    • pp.327-335
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    • 2021
  • Microcracks can rapidly grow and develop in high-strength steels used in offshore structures. It is important to render these microcracks harmless to ensure the safety and reliability of offshore structures. Here, the dependence of the aspect ratio (As) of the maximum depth of harmless crack (ahlm) was evaluated under three different conditions considering the threshold stress intensity factor (Δkth) and residual stress of offshore structural steel F690. The threshold stress intensity factor and fatigue limit of fatigue crack propagation, dependent on crack dimensions, were evaluated using Ando's equation, which considers the plastic behavior of fatigue and the stress ratio. ahlm by peening was analyzed using the relationship between Δkth obtained by Ando's equation and Δkth obtained by the sum of applied stress and residual stress. The plate specimen had a width 2W = 12 mm and thickness t = 20 mm, and four value of As were considered: 1.0, 0.6, 0.3, and 0.1. The ahlm was larger as the compressive residual stress distribution increased. Additionally, an increase in the values of As and Δkth(l) led to a larger ahlm. With a safety factor (N) of 2.0, the long-term safety and reliability of structures constructed using F690 can be secured with needle peening. It is necessary to apply a more sensitive non-destructive inspection technique as a non-destructive inspection method for crack detection could not be used to observe fatigue cracks that reduced the fatigue limit of smooth specimens by 50% in the three types of residual stresses considered. The usefulness of non-destructive inspection and non-damaging techniques was reviewed based on the relationship between ahlm, aNDI (minimum crack depth detectable in non-destructive inspection), acr N (crack depth that reduces the fatigue limit to 1/N), and As.

Effects of pulsed laser surface remelting on microstructure, hardness and lead-bismuth corrosion behavior of a ferrite/martensitic steel

  • Wang, Hao;Yuan, Qian;Chai, Linjiang;Zhao, Ke;Guo, Ning;Xiao, Jun;Yin, Xing;Tang, Bin;Li, Yuqiong;Qiu, Shaoyu
    • Nuclear Engineering and Technology
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    • v.54 no.6
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    • pp.1972-1981
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    • 2022
  • A typical ferritic/martensitic (F/M) steel sheet was subjected to pulsed laser surface remelting (LSR) and corrosion test in lead-bismuth eutectic (LBE) at 550 ℃. There present two modification zones with distinct microstructures in the LSRed specimen: (1) remelted zone (RZ) consisting of both bulk δ-ferrite grains and martensitic plates and (2) heat-affected zone (HAZ) below the RZ, mainly composed of martensitic plates and high-density precipitates. Martensitic transformation occurs in both the RZ and the HAZ with the Kurdjumov-Sachs and Nishiyama-Wassermann orientation relationships followed concurrently, resulting in scattered orientations and specific misorientation characteristics. Hardnesses of the RZ and the HAZ are 364 ± 7 HV and 451 ± 15 HV, respectively, considerably higher than that of the matrix (267 ± 3 HV). In oxygen-saturated and oxygen-depleted LBE, thicknesses of oxide layers developed on both the as-received and the LSRed specimens increase with prolonging corrosion time (oxide layers always thinner under the oxygen-depleted condition). The corrosion resistance of the LSRed F/M steel in oxygen-saturated LBE is improved, which can be attributed to the grain-refinement accelerated formation of dense Fe-Cr spinel. In oxygen-depleted LBE, the growth of oxide layers is very low with both types of specimens showing similar corrosion resistance.

A study on the crack initiation of SCM 4 (SCM4 의 크랙開始点 에 관한 硏究)

  • 옹장우;박찬국;김재훈
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.9 no.2
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    • pp.135-139
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    • 1985
  • A J$_{IC}$ test procedure by ultrasonic method performed to observe the crack opening behavior of fatigue precrack and detect the initiation of crack propagation of compact tension specimen in this paper. Pulse-echo method with 5 MHz transducer was used on the Cr-Mo steel quenched and tempered at 593.deg. C. We obtained the following results in the elastic-plastic fracture toughness test by ultrasonic method. Echo height is a little increased linearly and rapidly at the early stage of loading . Then it is decreased considerably, finally at the unstable crack growth stage, it is rapidly increased at an unpredictable rae. The initiation of crack propagation is supposed to be at the stage deviated from linearly decreased region and then blunted. J$_{IC}$ value(10.15-12.15 Kgf/mm) by ultrasonic method is lower than that(12.2 Kgf/mm) by R-curve method. But, it is required that the research for the more exact evaluation about correlation between echo height and the crack opening behavior of precrack tip will be continued. continued.ued.

Performance and Thermal-Flow Characteristics in a Planar Type Solid oxide Fuel Cell with Single Channel and Multi-Channel (단일채널 및 다채널을 포함한 평판형 고체산화물연료전지의 열유동 해석 및 성능평가)

  • Ahn, Hyo-Jung;Cha, Suk-Won
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.12
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    • pp.1033-1041
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    • 2007
  • This paper studied the characteristics of performance and temperature in a unit cell of a planar type SOFC under various conditions by employing computational fluid dynamics (CFD). In order to derive thermal stress distribution and performance characteristics, the 3-D model simulation for a single channel was performed in various conditions which include interconnect materials $(LaCrO_3/AISI430)$, gas flow direction (co-flow/counter-flow) and inlet temperature (923 K/1173 K). From these results of a single channel, the most effective conditions were applied to the unit stack with multi-channel and the temperature distribution is displayed. Considering both thermal stress and performance, the best combination is 923 K inlet temperature, counter-flow and interconnector of stainless steel. As the end results, flow, thermal and current density distributions were found in the model with multi-channel applied to the best combination and were concentrated in the middle of channels than in the edge.