• Korean Journal of Materials Research
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• v.6 no.12
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• pp.1257-1262
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• 1996

1.0Cr-1.0Mo-0.25V강 용접부의 크립 파단 시험시 파단 발생 원인에 관한 연구가 시행되었다. 파괴는 Intercritical Heat Affected Zone에서 발생하였으며 파단면에서 구상의조대한 M6C탄화물이 발견되었다. 모재는 molybdenum 주성분의 M2C, vanadium 주성분의 M4C3 및 chromium 주성분의 M23C6와 M7C3 탄화물이 존재하였다. 모의 실험 결과 준안정 상태인 M2C 탄화물은 85$0^{\circ}C$, 10oh에서 안정한 M6C탄화물로 변태하였다. M6C 탄화물은 주변의 molybdenum 농도를 떨어뜨려 강도의 저하를 가져오며 크립 기공의 발생 원인을 제공하였다.

• Journal of the Korean Ceramic Society
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• v.33 no.12
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• pp.1421-1425
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• 1996

Sintered Si3N4 and Inconel composed of Ni(58-63%) Cr(21-25%) Al(1-17%) Mn(<1%) fe(balance) were pressurelessly joined by using Ag-Cu-Ti brazing filler metal at 950℃ and 1200℃ under N2 gas atmosphere of 1atm and their interfacial structures were investigated. In case that the reaction temperature was low as 950℃ its interfacial structure was "Inconel metal/Ti-rich phase layer/brazing filler metal layer/Si3N4 " Ti used as reactive metal existed in between inconel steel and brazing metal and moved to the interface of between brazing filler metal nd Si3N4 according as reaction temperature increased up to 1200℃. The interfacial structure of inconel steel-Si3N4 reacted at 1200℃ was ' inconel metal/Ni-rich phase layer containing of Fe. Cr and Si/Cu-rich phase layer containing of Mn and Si/Si3N4 " Cr Mn, Ni and Fe diffused to the interface of between brazing filler metal and Si3N4 and reacted with Si3N4 The most reactive components of ingredients of inconel metal were Cr and Mn. On the other hand Ti added as reactive components to Ag-Cu eutectic segregated into Ni-rich phase layer,.

• Proceedings of the KOSOMBE Conference
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• v.1994 no.12
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• pp.175-177
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• 1994

The wear corrosion behaviour of a nitrogen ion implanted super stainless steel (S.S.S, 22Cr - 20Ni - 6Mo - 0.25N) was compared with those of S.S.S, 316L SS and TiN coated 316L SS. The Cr and Ni amounts won out from the materials were investigated using an electrothermal atomic absorption spectrometry. We observed that the Cr dissolution rate of the S.S.S was similar to that of 316L SS, however, the Ni release of the S.S.S was feater than 316L SS. The metal ions released from the nitrogen ion implanted S.S.S surface were significantly reduced. The wear corrosion behaviour of the stainless steels was not correlated with the results shown by a static metal ion release test.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2000.11a
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• pp.12-12
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• 2000

This paper investigated the effect of the film deposition rate for $CrN_x$ microstructure and mechanical properties. For these purpose, pure Cr an stoichiometric CrN films were deposited with various target power density on Si hardened M2 tool steel. The variation of ni trogen concentration in $CrN_x$ f analyzed by AES and deposition rate was calculated by measuring of thickness using ${\alpha}-step$ profilometer. The microstructure was analyzed by X-Ray Diffract and Scanning Electron Microscopy(SEM), and mechanical properties were evalua residual stress, microhardness and adhesion tests. Deposition rate of Cr and CrN increased as an almost linear function of target power density from $0.25\mu\textrm{m}/min$ and $0.15\mu\textrm{m}/min$ to $0.43\mu\textrm{m}/min$. Residual stresses of Cr and CrN films were from tensi Ie to compressive stress with an increase of deposi tion rate a compressive stresses were increased as more augmentation of deposition r maximum hardness value of $2300kg/\textrm{mm}^2$ and the best adhesion strength correspond HF 1 were obtained for CrN film synthesized at the highest target densitY($13.2W/\textrm{mm}^2$) owing to high residual compressive stress and increasing mobility.

• Journal of Ocean Engineering and Technology
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• v.12 no.2 s.28
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• pp.71-78
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• 1998

In this report for the assessment of creep properties of high-temperature tube materials in power plants, the long-time($10^4$~105h) creep life prediction by ISM for 2.25Cr1Mo steel was studied. It was clarified experimentally and quantitatively that the newly developed long-time creep life prediction equation was very coincident with the actual experimental data with high confidence, and the model was $t_r=\alpha\varepsilon_0^{\beta}\sigma^{-1}$.

• Journal of the Korean Society for Nondestructive Testing
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• v.17 no.1
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• pp.23-30
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• 1997

Recently high frequency ultrasonic transducers to employ polyvinylidene fluoride(PVDF) or polyvinylidene fluoride trifluoroethylene P(VDF-TrFE) have been used to detect small flaws in immersion testing. The detection field depending on the water path between the transducer and a specimen and the path in a tested specimen was measured using a PVDF transducer with nominal frequency 80MHz. Also, C-scan and B-scan were performed for the specimens made of Cr-Ni steel with the artificial flaws, the flat-bottom holes with diameter ranging from $50{\mu}m$ to $560{\mu}m$ at 12mm depth. As the result, the flaws with diameter larger than $280{\mu}m$ were detected, but the flaws with the ratio of diameter to wavelength smaller than about 0.48 were not detected. That the smaller flaws could not be detected was attributed to the attenuation of high frequency components in the steel specimens.

• Journal of the Korean institute of surface engineering
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• v.25 no.2
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• pp.66-72
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• 1992

Magnetite film on iron surface could be coated in strongly alkaline solution (12M NaH\OH) which contained additives such as NaHCO3, KCl and NaNO2, Iron plate was immersed in boiling solution ($130^{\circ}C$) contained above mentioned additives for 1 hour. There are some microcracks and these cracks proved to be the sites for the initiation of corrosion when immersed in 3% NaCl solution. To improve corrosion resistance of the coated steel plate, chromating was done as a post treatment. Chromate film was formed on magnetite oxide film potentiostatically at-918mV/SCE for five minutes at temperature of $70^{\circ}C$ in the alkaline solution containing 5g/l Na2Cr2O7.2H2O.Cr3O4 was electrodeposited on magnetite oxide film and Cr2O3 was electrodeposited on iron surface which was assumed as surface revealed due to microcracks. Increased corrosion resistance of chromated magnetite oxide film was proved in salt spray test & immersion test.

• Korean Journal of Materials Research
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• v.14 no.1
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• pp.78-82
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• 2004

In this study, the degree of creep damages on the weldment accelerated creep degradation was nondestructively evaluated by replica method. The frequency of creep cavities occurrence has been observed highly at the intercritical HAZ. The life fraction of weldment damaged by creep has shown from 0.25(damage grade: 2) to 0.75(damage grade: 4) when it reptured. The degree of creep damages is considered to be evaluated by the metallographic replica method which is one of nondestructive evaluation methods.

• Transactions of the Korean Society of Mechanical Engineers
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• v.18 no.12
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• pp.3136-3148
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• 1994

This paper proposed the method of fracture integrity evaluation for semi-elliptical crack. Plane strain fracture toughnesses are used to compare with the thermal shock stress intensity factors for semi-elliptical crack obtained by Vainshtok weight function method. The method is applied to the finite Cr Mo V and 2.25Cr Mo steel plates with semi-elliptical crack under the thermal shock. For the purpose, tensile property and fracture toughness with respect to the temperature are measured. To verify the method, thermal shock experiments are carried. The theoretical predictions are in good agreement with the experiments.

• Proceedings of the KIEE Conference
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• 1998.11c
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• pp.861-863
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• 1998

As-casted high nitrogen alloys (Fe-25%Mn-12%Cr-1%Ni) have been investigated to study core material. Nitrogen concentration in molten alloys was increased with increasing the square root of nitrogen gas pressure in melting chamber. This result can be explained by Sievert's law. Nitrogen that dissolved as a interstital solid solution element in austenite stainless steel increased lattice parameter and hardness. Electric resistivity($\rho$) was increased with increasing nitrogen concentration and was about $80{\mu}{\Omega}cm$ at room temperature. Coefficient of linear thermal expansion of the nitrogen steel was about $22{\times}10^{-6}/^{\circ}C$.