• Journal of the Korean Wood Science and Technology
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• v.30 no.3
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• pp.1-11
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• 2002

This study was conducted to investigate the effects of reaction pH conditions and hardener types on the reactivity, chemical structure and adhesion performance of UF resins. Three different reaction pH conditions, such as traditional alkaline-acid (7.5 → 4.5), weak acid (4.5), and strong acid (1.0), were used to synthesize UF resins which were cured by adding three different hardeners (ammonium chloride, ammonium citrate, and zinc nitrate) to measure adhesion strength. Fourier transform infrared (FT-IR) and carbon-13 nuclear magnetic resonance (¹³C-NMR) spectroscopies were employed to study chemical structure of the resin prepared under three different reaction pH conditions. Adhesion strength of the resins cured with three different hardeners was determined with lap shear specimens in tension. The gel time of UF resins decreased with an increasing in the amount of both ammonium chloride and ammonium citrate added in the resins. However, the gel time increased for zinc nitrate. Both FT-IR and ¹³C-NMR spectroscopies showed that the strong reaction pH condition produce uronic structures in UF resin, while both alkaline-acid and weak acid conditions produce quite similar chemical species in the resins. The maximum adhesion strength was occurred with the resin prepared under strong acid pH condition. However, this study indicated that the weak acid reaction condition provide a balance between increasing resin reactivity and improving adhesion strength of UF resin. The measurement of formaldehyde emission from the panels bonded with the UF resins prepared is planned for future work.

• Journal of the Korean Wood Science and Technology
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• v.2 no.3
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• pp.3-16
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• 1974

One of the disadvantages of. wood and wood products is their hydroscopicity or dimensional instability. This is responsible for the loss of green volume of lumber as seasoning degrade. Dimensional stabilization is needed to substantially reduce seasoning defects and degrades and for increasing the serviceability of wood products. Recently, considerable world-wide attention has been drawn to the so-called Wood-Plastic Composites by irradiation-and heat-catalyst-polymerization methods and many research and developmental works have been reported. Wood-Plastic Composites are the new products having the superior mechanical and physical properties and the combinated characteristics of wood and plastic. The purpose of this experiment was to obtain the basic data for the improvement of wooden materials by manufacturing WPC. The species examined were Mulpurae-Namoo (Fraxinus, rhynchophylla), Sea-Namoo (Carpinus laxiflora), Cheungcheung-Namoo (Cornus controversa), Gorosae-Namoo (Acermono), Karae-Namoo(Juglans mandshurica) and Sanbud-Namoo (Prunus sargentii), used as blocks of type A ($3{\times}3{\times}40cm$) and type B ($5{\times}5{\times}60cm$), and were conditioned to about 10~11% moisture content before impregnation in materials humidity control room. Methyl methacrylate (MMA) as monomer and benzoyl peroxide (BPO) as initiator are used. The monomer containing BPO was impregnated into wood pieces in the vacuum system. After impregnation, the treated samples were polymerized with heat-catalyst methods. The immersed weights of monomer in woods are directly proportionated to the impregnation times. Monomer impregnation properties of Cheungcheung-Namoo, Mulpurae-Namoo and Seo-Namoo are relatively good, but in Karae-Namoo, it is very difficult to impregnate the monomer MMA. Fig. 3 shows the linear relation between polymer retentions in wood and polymerization times; that is, the polymer loadings are increasing with polymerization times. Furthermore species, moisture content, specific gravity and anatomical or conductible structure of wood, bulking solvents and monomers etc have effects on both of impregnation of monomer and polymer retention. Physical properties of treated materials are shown in table 3. Increasing rates of specific gravity are ranged 3 to 24% and volume swelling 3 to 10%. ASE is 20 to 46%, AE 14 to 50% and RWA 18 to 40%. Especially, the ASE in relation to absorption of liquid water increases approximately with increase of polymer content, although the bulking effect of the polymerization of monomer may also be influential. WPCs from Mulpurae-Namoo and Cheungcheung-Namoo have high dimensional stability, while its of Karae-Namoo and Seo-Namoo are-very low. Table 4 shows the mechanical properties of WPCs from 6 species. With its specific gravity and polymer loading increase, all mechanical properties are on the increase. Increasing rate of bending strength is 10 to 40%, compression strength 25 to 70%, ;impact bending absorbed energy 4 to 74% and tensile strength 18 to 56%. Mulpurae-Namoo and Cheungcheung-Namoo with high polymer content have considerable high increasing rate of strengths. But incase of Karae-Namoo with inferior monomer impregnation it is very low. Polymer retention in cell wall is 0.32 to 0.70%. Most of the polymer is accumulated in cell lumen. Effective. of polymer retention is 58.59% for Mulpurae-Namoo, 26.27% for Seo-Namoo, 47.98% for Cheungcheung-Namoo, 25.64% for Korosae-Namoo, 9.96% for Karae-Namoo and 25.84% for Sanbud-Namoo.

• Journal of the Korean Wood Science and Technology
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• v.16 no.3
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• pp.48-64
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• 1988

This study was carried out to investigate the free vibrational properties of traditional and replaceable species for sounding board, using piezoelectrical accelerometer and signal analyzer. In the study, the frequency equations of free-free beam carrying a concentrated mass in the transverse vibration and of free-mass beam in the longitudinal vibration were used. The results obtained were as follows. 1. Average values of dynamic modulus of rigidity of Korean commercial species measured were as follows. Paulownia tomatosa (Thunb.) Steudel: $5.590\times10^9\;dyne/cm^2$ Tilia amurensis Rupr.: $5.414\times10^9\;dyne/cm^2$ Macckia amurensis Rupr.: $10.044\times10^9\;dyne/cm^2$ Fraxinus mandshurica Rupr.: $8.876\times10^9\;dyne/cm^2$ Ulmus davidiana var.japonica Nakai: $8.677\times10^9\;dyne/cm^2$ Pinus rigida Miller: $6.33\times10^9\;dyne/cm^2$ Fraxinus rhynchophylla Hance: $4.666\times10^9\;dyne/cm^2$ 2. The ratio of dynamic transverse Young's modulus to dynamic modulus of rigidity, $E_T/G_{LT}$, was 24.922 for Fraxinus rhynchophylla Hance, which was the highest, 7.317 for Paulownia tomentosa (Thunb.) Steudel, which was the lowest among Korean commercial species measured. 3. The value of longitudinal dynamic Young's modulus was about 3.7% and 19.8%, respectively, higher than those of transverse dynamic and static Young's modulus. The value of transverse dynamic Young's modulus was about 15.5% higher than that of static Young's modulus. 4. Predicted value of MOR in terms of correlation coefficient by transverse dynamic Young's modulus was slightly higher than that of static Young's modulus, but no significance was found out. 5. Transverse dynamic Youne's modulus was $(2.002\pm0.288)\times10^{11}\;dyne/cm^2$ for Fraxinus mandshurlca Rupr., which was the highest, $(0.601\pm0.100)\times10^{11}\;dyne/cm^2$ for Paulownia tomentosa (Thunb.) Steudel, which was the lowest among Korean commercial species measured. The sound velocity of sitka spruce was 5,685 m/sec, which was the highest. 6. Internal friction of Paulownia tomentosa (Thunb.) Steudel was shown the lowest value among Korean commercial species, $(8.795\pm1.795)\times10^{-3}$, but was higher than that of sitka spruce, $(7.331\pm0.991)\times10^{-3}$. Internal friction was shown negative correlation with density and dynamic Young's modulus, respectively. 7. K value was affected largely by internal friction and was the highest, $2.225\times10^8$ for Paulownia tomentosa (Thunb.) Steudel and was the lowest, $0.550\times10^8$ for Fraxinus rhynchophylla Hance. K value of Paulownia tomentosa (Thunb.) Steudel was higher than that of sitka spruce and K values of melapi and cottonwood, which have been considered to be replaceable species with sitka spruce in the piano industry, were lower than those of Paulownia tomentosa (Thunb.) Steudel and mill amurensis Rupr.

• Journal of the Korean Wood Science and Technology
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• v.43 no.5
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• pp.591-599
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• 2015

Cercidiphyllum japonicum leaves were collected, air-dried and extracted with 70% aqueous acetone, then concentrated and sequentially fractionated using n-hexane, methylene chloride ($CH_2Cl_2$), ethylacetate (EtOAc), and $H_2O$. A portion of EtOAc fraction (10 g) was chromatographed on a Sephadex LH-20 column, by the successively elution with various aqueous $MeOH-H_2O$ (1:9, fraction $1-2{\rightarrow}3:7$, fraction $3-5{\rightarrow}1:1$, fraction $6-9{\rightarrow}7:3$, fraction $10-13{\rightarrow}9:1$, fraction 14-16). Compound 2 was isolated from fraction 6 and compound 1 was separated from fraction 11 and 12. Compound 3 and 4 were purified from fraction 13. The isolated compounds were elucidated as quercetin-3-O-${\alpha}$-L-rhamnopyranoside (1), chlorogenic acid (2), quercetin-3-O-${\alpha}$-L-arabinofuranoside (3) and quercetin-3-O-${\beta}$-D-xylopyranoside (4) by the spectral and literature data, and by comparison with the authentic samples. These compounds were reported, for the first time, from the extracts of C. japonicum leaves. Also chlorogenic acid (2) has never been reported before in domestic tree species and can be used as an index compound for C. japonicum.

• Journal of Korean Society of Forest Science
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• v.83 no.4
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• pp.540-544
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• 1994

Equilibrium moisture contents(EMC) were calculated based on temperature and relative humidity of atmosphere and actual EMCs were measured at intervals of ten days in previous air-dried wood samples for seven different species including Douglas fir and oaks in four indoor locations in central region for one year. Mean annual air temperature and relative humidity were $23.3^{\circ}C$ and 54.9% in bedroom, $22.4^{\circ}C$ and 59.5% in living room of apartment, $20.1^{\circ}C$ and 57.0% in office room and 19.4 and 64.0% in living room of tile-roofed house, respectively. Mean annual calculated and actual EMCs were 10.2 and 9.7% in bedroom, 11.1 and 10.2% in living room of apartment, 10.7 and 10.4% in office room, and 12.1 and 12.5% in living room of tile-roofed, house, respectively. Actual EMC of kasai were higher than average value of EMC for seven species. However, those of sycamore and apitong were lower than average value.

• Journal of Mushroom
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• v.14 no.2
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• pp.51-58
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• 2016

Basidiomycetous fungi are one of the most potent biodegraders because many of its species grow on dead wood or litter, in environments rich in lignocellulose. For the degradation of lignocellulose, basidiomycetes utilize their lignocellulytic enzymes, which typically include laccase (EC 1.10.3.2), lignin peroxidase (EC 1.11.1.14), xylanase (EC 3.2.1.8), and cellulase (EC 3.2.1.4). In recent years, the practical applications of basidiomycetes have ranged from the textile to the pulp and paper industries, and from food applications to bioremediation processes and industrial enzymatic saccharification of biomass. Recently, spent mushroom substrates of edible mushrooms have been used as sources of bulk enzymes to decolorize synthetic dyes in textile wastewater. In this review, the occurrence, mode of action, general properties, and production of lignocellulytic enzymes from mushroom species will be discussed. We will also discuss the potential applications of these enzymes.

• Mycobiology
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• v.46 no.4
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• pp.349-360
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• 2018

Whole-genome sequencing of Flammulina ononidis, a wood-rotting basidiomycete, was performed to identify genes associated with carbohydrate-active enzymes (CAZymes). A total of 12,586 gene structures with an average length of 2009 bp were predicted by the AUGUSTUS tool from a total 35,524,258 bp length of de novo genome assembly (49.76% GC). Orthologous analysis with other fungal species revealed that 7051 groups contained at least one F. ononidis gene. In addition, 11,252 (89.5%) of 12,586 genes for F. ononidis proteins had orthologs among the Dikarya, and F. ononidis contained 8 species-specific genes, of which 5 genes were paralogous. CAZyme prediction revealed 524 CAZyme genes, including 228 for glycoside hydrolases, 21 for polysaccharide lyases, 87 for glycosyltransferases, 61 for carbohydrate esterases, 87 with auxiliary activities, and 40 for carbohydrate-binding modules in the F. ononidis genome. This genome information including CAZyme repertoire will be useful to understand lignocellulolytic machinery of this white rot fungus F. ononidis.

• Journal of the Korean Wood Science and Technology
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• v.47 no.6
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• pp.674-691
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• 2019

The aim of this study was to evaluate the anti-inflammatory effects of essential oils extracted from the wood of Chamaecyparis obtusa, Pinus densiflora, Pinus koraiensis, and Larix kaempferi. Essential oils were extracted by hydrodistillation, and their chemical components were determined by GC/MS. Major chemical components of these essential oils were ${\alpha}$-cadinol (19.25%), ${\tau}$-muurolol (14.20%), and ${\alpha}$-pinene (13.74%) in C. obtusa; ${\alpha}$-pinene (47.16%), longifolene (14.31%), ${\beta}$-phellandrene (11.78%), and ${\beta}$-pinene (11.02%) in P. densiflora; ${\alpha}$-pinene (13.49%) and longifolene (10.79%) in P. koraiensis, and geranyl linalool (23.58%) and ${\alpha}$-pinene (18.57%) in L. kaempferi. To evaluate the anti-inflammatory effects of essential oils, lipopolysaccharide (LPS)-induced RBL-2H3 mast cells were treated with these essential oils; then, the changes in the mRNA expression level of the cytokines IL-4 and IL-13 were examined. Further, degranulation was evaluated by measuring ${\beta}$-hexosaminidase release. After LPS-induced RBL-2H3 mast cells were exposed to $10^{-7}%$ of all types of essential oils, the gene expression levels of IL-4 and IL-13 within the cells remarkably decreased. The relative mRNA expression level of IL-4 was 69.6% in P. densiflora, 63.2% in P. koraiensis, 55.1% in C. obtusa, and 45.8% in L. kaempferi compared with that in the group treated with LPS. The mRNA expression level of L-13 should a similar trend. The inhibitory rate of IL-13 mRNA expression of P. densiflora, P. koraiensis, C. obtusa, and L. kaempferi was 57.8%, 57.1%, 51.1%, and 34.5%, respectively. ${\beta}$-Hexosaminidase release significantly decreased following the treatment with the four types of essential oils. The rate of ${\beta}$-hexosaminidase release were 38.1% C. obtusa; 33.0% P. densiflora; 27.4% P. koraiensis; and 9.1% L. kaempferi. Among all types of essential oils, that extracted from P. densiflora wood showed the highest anti-inflammatory activity. These results show that the tested essential oils exert an anti-inflammatory effect through the inhibition of degranulation and expression of cytokines.

• Journal of the Korean Wood Science and Technology
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• v.10 no.3
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• pp.52-67
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• 1982

We have relatively heavy stocks of hardwood which consist of inferior and nonproductive natural hardwood species in Korea. As conception above to develope these forest resources, the study was carried out to obtain the basical data for the reasonable and efficient utilization of hardwoods. The sample trees were selected 11 natural hardwood species grown in Kangwon-do region and Kwangnoong Experimental Forest. We have investigated anatomical, physical and mechanical properties of them. Especially, Quercus species which is a major species in the forests was investigated on qualities of trees, logs and lumbers, recevery of bucking and lumber yield, etc.

• Journal of Forest and Environmental Science
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• v.31 no.4
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• pp.241-254
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• 2015

This study attempts to examine farmers' preference and perception towards cropland agroforestry (CAF) and its economic benefits in Bangladesh. It surveys 84 farmers of two sub-districts named Manirampur and Bagherpara under Jessore district of Bangladesh to address the study objectives with the help of a questionnaire during the period of June to July 2013. We follow a multistage random sampling procedure for selecting respondents of the survey. A total of 27 plant species under 19 families are identified in the surveyed crop fields, among which 11 are tree species and 1 is shrub from 8 families and 15 species are agricultural crops from 11 families. According to the survey findings, most of the farmers prefer multipurpose tree species like Swietenia macrophylla (67 percent), Phoenix sylvestris (48 percent), Mangifera indica (48 percent) and Cocos nucifera (43 percent). We also find that Curcuma longa (92 percent), Oryza spp. (56 percent), Solanum melongena (43 percent) and Amorphophallus campanulatus (33 percent) are the available agriculture crops which are grown in association with trees in the study area. The surveyed farmers report that they practice CAF to get fuel wood, fodder, juice, fruit and food for family consumption and revenue earnings. About 76 percent of the surveyed farmers endorse the existence of a positive interaction between trees and agriculture crops, while the rest 24 percent endorse the existence of a negative interaction between trees and agriculture crops. This study finds that CAF farmers on an average earn US$ 1,410 per farm per year and the yearly average revenue difference between CAF and non-cropland agroforestry (NCAF) farmers is US$ 214. Overall, CAF needs to develop through scientific intervention in the study area to conserve the biodiversity and to enhance farmers' sustainable livelihood.