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Experimental Study on Improving Compressive Strength of MWCNT Reinforced Cementitious Composites (MWCNT 보강 시멘트 복합체의 압축강도 향상에 대한 실험적 연구)

  • Kang, Su-Tae;Park, Soon-Hong
    • Journal of the Korea Concrete Institute
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    • v.26 no.1
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    • pp.63-70
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    • 2014
  • This experimental study was intended to improve the compressive strength of multi-walled CNT reinforced cementitious composites with efficiency. The variables considered are the degree of sonication, the amount of surfactant, the replacement ratio of silica fume, etc. Optical microscope informed that fiber dispersion of CNT was improved with the increase of sonication time, and the compressive strength was proved to be enhanced as the degree of sonication increased. When superplasticizer as a surfactant had SP/CNT ratio of 4~6, the best improvement in strength was obtained. Silica fume was shown to produce the highest compressive strength at 10% replacement. Microstructure of CNT composites was also analyzed; XRD and SEM results indicated that CNT addition hardly changed hydration products and microstructure, and MIP analysis found the reduction of total porosity as well as the increase of nano-pores with the size of tens of nm instead of the decrease of pore distribution in the region of around 10 ${\mu}m$ and 100 nm. The results of microstructure analysis explains that the strength improvement is closely related to physical contribution rather than chemical influence by adding CNT.

The Combustion Gas Hazard Assessment of Main Building Materials (주요 건축 재료별 연소가스 유해성 평가)

  • Kim, Jong-Buk;Lee, Si-Young
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.5
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    • pp.639-654
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    • 2016
  • This study building materials by relates to human hazard assessment in accordance with the combustion gas SEM, the flame-retardant foam FTIR and cone calorimeter to configure the Forest products of MDF and preservative treated Lauan two kinds of Retardant styrofoam, Styrofoam, Urethane foam and gypsum board four kinds of plastics material by the combustion gas were each analyzed. MDF was burned to the structure of the wood and the glue evenly mixed combustion area preservative treated Lauan, kept constant even in the form of high heat to penetrate deep into the wood flame retardant agents. Retardant styrofoam is due to feed my Dropped dissolved inorganic flame retardant without the fire-stick and confirmed that the weak form of gypsum board, but keep the column. In MDF ammonia ($NH_3$), lethal concentration (750 ppm) compared to 795 ppm, preservative treated Lauan is carbon dioxide ($CO_2$) that was greater than 2.5 times the lethal concentration (100,000 ppm) to 256,965 ppm, the lethal concentration (500 ppm) of hydrogen chloride (HCl). The Urethane greater than 697 ppm, 434 ppm also greatly exceeding the nitrogen dioxide ($NO_2$) lethal concentration (250 ppm) in Retardant styrofoam and 398 ppm was released. It is confirmed that the human body is extremely harmful gas emitted from most of the materials to be utilized as basic data for evaluating the hazard-specific human future building material.

Classification of Fall in Sick Times of Liver Cirrhosis using Magnetic Resonance Image (자기공명영상을 이용한 간경변 단계별 분류에 관한 연구)

  • Park, Byung-Rae;Jeon, Gye-Rok
    • Journal of radiological science and technology
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    • v.26 no.1
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    • pp.71-82
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    • 2003
  • In this paper, I proposed a classifier of liver cirrhotic step using T1-weighted MRI(magnetic resonance imaging) and hierarchical neural network. The data sets for classification of each stage, which were normal, 1type, 2type and 3type, were obtained in Pusan National University Hospital from June 2001 to december 2001. And the number of data was 46. We extracted liver region and nodule region from T1-weighted MR liver image. Then objective interpretation classifier of liver cirrhotic steps in T1-weighted MR liver images. Liver cirrhosis classifier implemented using hierarchical neural network which gray-level analysis and texture feature descriptors to distinguish normal liver and 3 types of liver cirrhosis. Then proposed Neural network classifier teamed through error back-propagation algorithm. A classifying result shows that recognition rate of normal is 100%, 1type is 82.3%, 2type is 86.7%, 3type is 83.7%. The recognition ratio very high, when compared between the result of obtained quantified data to that of doctors decision data and neural network classifier value. If enough data is offered and other parameter is considered, this paper according to we expected that neural network as well as human experts and could be useful as clinical decision support tool for liver cirrhosis patients.

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Analysis of volatile aroma compounds from vanilla perfume using headspace disk type monolithic material sorptive extraction (시료상층부 원판 형태 단일 다공성 물질을 이용한 바닐라 향수의 휘발성 아로마 성분 추출 분석)

  • Son, Hyun-Hwa;Lee, Dong-Sun
    • Analytical Science and Technology
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    • v.24 no.6
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    • pp.421-428
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    • 2011
  • In this study, headspace disk type monolithic material sorptive extraction (HS-MMSE) was developed, validated and applied to the analysis of volatile aroma compounds from vanilla perfume by gas chromatography -mass spectrometry (GC/MS). HS-MMSE uses monolithic material (MonoTrap) based on silica bonded with octadecyl silane (ODS) and activated carbon as a sorbent. Aroma compounds was adsorbed onto the MonoTrap in headspace and extracted by only 100 ${\mu}L$ of solvent. Total 12 volatile compounds from vanilla perfume were successfully analyzed using HS-MMSE. The influence of extractive parameters was investigated and optimized, using benzyl acetate, linalyl acetate, vanillin, ethyl vanillin as target compounds. Under the optimum condition, the limit of detection (S/N = 3) and the limit of quantification (S/N = 10) of proposed method for the target compounds were obtained within the range of 8.35~13.76 ng and 27.82~45.88 ng, respectively. The method showed good linearity with correlation coefficient more than 0.9888, satisfactory recovery and reproducibility. These results showed that HS-MMSE using disk type MonoTrap is a new promising technique for the analysis of volatile aroma compounds from vanilla perfume.

Micromachined pH Sensor Using Open Well Structures (개방형 우물 구조를 이용한 마이크로머신형 pH 센서)

  • Kim, Heung-Rak;Kim, Young-Deog;Jeong, Woo-Cheol;Kim, Kwang-Il;Kim, Dong-Su
    • Journal of the Korean Society for Nondestructive Testing
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    • v.22 no.4
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    • pp.347-353
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    • 2002
  • A structure of a glass electrode-type pH sensor for measuring any concentration of $H^+$ in an aqueous solution was embodied with bulk micromachining technology. Two open well structures were formed, and a reference electrode was secured by the Ag/AgCl thin film in the sloped side of the etched structure. A sensitive membrane of an indicator electrode for generating a potential by an exchange reaction to $H^+$ was made with a glass containing Na 20% or more finely so that its thickness might be $100{\mu}m$ or so, and then it was bonded to one pyramidal structure. A liquid junction for a current path was formed by filling an agar in the anisotropically etched part of the Si wafer, which had a size of $50{\mu}m{\times}50{\mu}m$, and then bonded it to the other. After complete fabrication of each part, it was filled with a 2M KCl reference solution and encapsulated the sensor structure with a cold expoxy. The potential value of fabricated pH sensor was about 90mV/pH in the standard pH solutions.

A pilot study on measuring the human cortisol using an electronic device (전자소자를 이용한 인간 감성지표 코티졸 검출에 관한 기초연구)

  • Lee, Hee-Jo;Lee, Jung-Hyun;Hwang, Yoo-Sun;Jung, Hyo-Il
    • Science of Emotion and Sensibility
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    • v.14 no.4
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    • pp.531-536
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    • 2011
  • The precise measurement of human emotion is of pivotal importance in the field of emotion science. Based on the perspective of psychoneuroimmunoendocrinology, human emotion is now considered to be measurable by body fluid. The biological molecule cortisol, which is known for the stress hormone, has been widely investigated to help researchers to estimate the stress loaded on human body. Until now, several measurement techniques such as High Performance Liquid Chromatography (HPLC), fluorometric assay, and reverse phase chromatography have been developed. However, since these measurements are expensive, take relatively long time for an operation, and they are not portable, they are not appropriate for POCT (point of care testing). In this paper we demonstrate the performance of a miniaturized-microwave resonant device in the measurement of cortisol. Our method has many advantages in that it requires a small volume of sample, has fast response time, is easy to operate and needs no labeling process. Besides, it will shed a light on the measurement techniques for emotion science.

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Application of Texture Features algorithm using Computer Aided Diagnosis of Papillary Thyroid Cancer in the Ultrasonography (초음파영상에서 갑상선 결절의 컴퓨터자동진단을 위한 Texture Features 알고리즘 응용)

  • Ko, Seong-Jin;Lee, Jin-Soo;Ye, Soo-Young;Kim, Changsoo
    • The Journal of the Korea Contents Association
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    • v.13 no.5
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    • pp.303-310
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    • 2013
  • Thyroid nodular disease is the most frequently appeared in thyroid disease. Thyroid ultrasonography offers location of nodules, size, the number, information of internal echo characteristic. Thus, it makes possible to sort high-risk nodule containing high possibility about thyroid cancer and to induct precisely when take a Fine Needle Biopsy Aspiration. On thyroid nodule, the case which is diagnosed as malignant is less than 5% but screening test is very important on ultrasound and also must be reduced unnecessary procedure. Therefore, in this study an approach for describing a region is to quantity its texture content. We applied TFA algorithm on case which has been pathologically diagnosed as papillary thyroid cancer. we obtained experiment image which set the ROI on ultrasound and cut the $50{\times}50$ pixel size, histogram equalization. Consequently, Disease recognition detection efficiency of GLavg, SKEW, UN, ENT parameter were high as 91~100%. It is suggestion about possibility on CAD which distinguishes thyroid nodule. In addition, it will be helpful to differential diagnosis of thyroid nodule. If the study on additional parameter algorithm is continuously progressed from now on, it is able to arrange practical base on CAD and it is possible to apply various disease in the thyroid US.

Speciation Analysis of Arsenic Species in Surface Water (수중의 비소 종 분리 분석)

  • Jeong, Gwan-Jo;Kim, Dok-Chan
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.6
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    • pp.621-627
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    • 2008
  • In this study, a technique of speciation and determination of the trace inorganic arsenic(As(III) and As(V)) in water sample using HPLC-DRC-ICP-MS has been developed. Isocratic mobile phase of 10 mM ammonium nitrate and 10 mM ammonium phosphate monobasic was used and methanol(5 v/v%) was used as flushing solvent. Selection of the best flow rate of reaction gas, O$_2$, and optimization of the parameters such as pH and flow rate of mobile phase, and injection volume of sample for the separation and detection of arsenic species were carried out. The oxygen flow rate of 0.5 mL/min, pH of 9.4 and flow rate of 1.5 mL/min of mobile phase, and injection volume of sample of 100 $\mu$L were found to be the best parameters for the speciation and determination of arsenic species. The analytical features of the method were detection limit 0.10 and 0.08 $\mu$g/L, precision(RSD) 4.3% and 3.6%, and recovery 95.2% and 96.4% for As(III) and As(V), respectively. Analysis time was 4 minutes per sample. Linear calibration graphs with r$^2$ = 0.998 were obtained for both As(III) and As(V). Speciation analysis of arsenic species in the raw water samples collected from the tributary streams to Han River and main stream of Paldnag were performed by the proposed method. The concentrations of As(III) ranged from 0.10 to 0.22 $\mu$g/L and As(V) concentrations ranged from 0.44 to 1.19 $\mu$g/L, and 93.5% of total arsenic was found to be As(V).

A Study on Analysis of Characteristics Combustion of Floor Covering Materials (바닥내장재의 연소특성 분석에 관한 연구)

  • Park, Young-Ju;Lee, Hae-Pyeong;Kim, Hyun-Ju
    • Journal of the Korean Society of Hazard Mitigation
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    • v.10 no.3
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    • pp.77-83
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    • 2010
  • In this study, we analyzed the combustion characteristics of four different floor covering materials(wood, monorium, laminatedpaper, and varnish-laminated paper) with regard to their ignitibility, thermal characteristics and flame retardancy by using an ignition temperature tester, a dual cone calorimeter, a thermogravimetric analyzer and limited oxygen index, for their fire risk assessment. According to the result, monorium had the lowest ignition temperature of $325^{\circ}C$ and the laminated paper and the varnish-laminated paper promptly ignited before 7s. Further, the wood showed the largest total heat release of $100MJ/m^2$, and the varnish-laminated paper showed the highest peak heat release rate. From the thermogravimetric analysis, it was shown that all specimens underwent rapid weight loss at $300{\sim}400^{\circ}C$. The limit oxygen indices of the laminated paper and the varnish-laminated paper were in the range of 20~21%, while it was 34% for wood. This study enabled us to confirm that wood, laminated paper and varnish-laminated paper have a relatively short ignition time and are easy to burn but they all have low heat release. In contrast, wood showed the lowest fire risk among them and had excellent flame retardancy but with high heat release.

Rheological Characteristics and Debris Flow Simulation of Waste Materials (광산폐석의 유변학적 특성과 토석류 흐름특성 분석)

  • Jeong, Sueng Won
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.34 no.4
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    • pp.1227-1240
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    • 2014
  • Abandoned mines often cause environmental problems, such as alteration of landscape, metal contamination, and landslides due to a heavy rainfall. Geotechnical and rheological tests were performed on waste materials corrected from Imgi waste rock dump, located in Busan Metropolitan City. Debris flow mobility was examined with the help of 1-D BING model which was often simulated in both subaerial and subaqueous environments. To determine flow curve, we used a vane-penetrated rheometer. The shear stress (${\tau}$)-shear rate (${\dot{\gamma}}$) and viscosity(${\eta}$)-shear rate (${\dot{\gamma}}$) relationships were plotted using a shear stress control mode. Well-known rheological models, such as Bingham, bilinear, Herschel-Bulkley, Power-law, and Papanastasiou concepts, were compared to the rheological data. From the test results, we found that the tested waste materials exhibited a typical shear shinning behavior in ${\tau}$-${\dot{\gamma}}$ and and ${\eta}$-${\dot{\gamma}}$ plots, but the Bingham behavior is often observed when the water contents increased. The test results show that experimental data are in good agreement with rheological models in the post-failure stage during shearing. Based on the rheological properties (i.e., Bingham yield stress and viscosity as a function of the volumetric concentration of sediment) of waste materials, initial flowing shape (5 m, 10 m, and 15 m) and yield stress (100 Pa, 200 Pa, 300 Pa, and 500 Pa) were input to simulate the debris flow motion. As a result, the runout distance and front velocity of debris flow are in inverse propositional to yield stress. In particular, when the yield stress is less than 500 Pa, most of failed masses can flow into the stream, resulting in a water contamination.