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http://dx.doi.org/10.5806/AST.2011.24.6.421

Analysis of volatile aroma compounds from vanilla perfume using headspace disk type monolithic material sorptive extraction  

Son, Hyun-Hwa (Department of Chemistry, Seoul Women's University)
Lee, Dong-Sun (Department of Chemistry, Seoul Women's University)
Publication Information
Analytical Science and Technology / v.24, no.6, 2011 , pp. 421-428 More about this Journal
Abstract
In this study, headspace disk type monolithic material sorptive extraction (HS-MMSE) was developed, validated and applied to the analysis of volatile aroma compounds from vanilla perfume by gas chromatography -mass spectrometry (GC/MS). HS-MMSE uses monolithic material (MonoTrap) based on silica bonded with octadecyl silane (ODS) and activated carbon as a sorbent. Aroma compounds was adsorbed onto the MonoTrap in headspace and extracted by only 100 ${\mu}L$ of solvent. Total 12 volatile compounds from vanilla perfume were successfully analyzed using HS-MMSE. The influence of extractive parameters was investigated and optimized, using benzyl acetate, linalyl acetate, vanillin, ethyl vanillin as target compounds. Under the optimum condition, the limit of detection (S/N = 3) and the limit of quantification (S/N = 10) of proposed method for the target compounds were obtained within the range of 8.35~13.76 ng and 27.82~45.88 ng, respectively. The method showed good linearity with correlation coefficient more than 0.9888, satisfactory recovery and reproducibility. These results showed that HS-MMSE using disk type MonoTrap is a new promising technique for the analysis of volatile aroma compounds from vanilla perfume.
Keywords
monolithic material; MonoTrap; GC/MS; vanilla perfume; aroma;
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