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A Study on the Fabrication and Physical Properties of $Ca_2SiO_4$:La Thermoluminescent Phosphors ($Ca_2SiO_4$: La 열형광체 제작과 물리적 특성에 관한 연구)

  • Kim, Choung-Mi;Seo, Mi-Kyong
    • Journal of the Korean Society of Radiology
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    • v.4 no.4
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    • pp.5-10
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    • 2010
  • The $Ca_2SiO_4$ phosphors doped by La with 0.1 wt%, 0.3 wt%, 0.5 wt%, and 1.0 wt% concentration were prepared by sintering at $1000^{\circ}C$ for 90 minutes in N2 atmosphere. The phosphors were ground in powdered form and were grouped in $100{\mu}m$ size, then the samples had been exposed to low energy X-ray and UV light. The TL glow curves were measured by heating the phosphors at $10^{\circ}C/s$ rate. There was no significantly meaningful correlation between the TL intensity and the doping level. The intensities of the TL peak measured from X-ray irradiated samples doped with 0.1 wt% were relatively strong. The activation energy and the frequency factor were 0.434 ~ 0.516 eV and 0.5 ~ 0.56, respectively. The intensities of the TL peak measured from UV irradiated samples doped with 0.3 wt% were relatively strong. The activation energy and frequency factor were 0.415 ~ 0.477 eV and 0.5 ~ 0.53, respectively. The TL process were found to be the 2nd order for both X-ray and UV irradiation. The TL intensity was increased linearly with the increase of the radiation dose. In summary, the $Ca_2SiO_4 phosphors developed in this study showed good TL characteristics at low energy X-ray and UV light. We believe they will be used as TLDs in near future for personal and environmental radiation detection dosimetry.

Preparation of Ceramic Paper Containing Zeolites and Its Characterization (제올라이트를 함유하는 세라믹종이의 제조 및 이의 특성평가)

  • Yoo, Yoon Jong;Kim, Hong Soo;Jeon, Sang Ho;Jang, Gun Eik
    • Journal of the Korean Ceramic Society
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    • v.42 no.10 s.281
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    • pp.654-659
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    • 2005
  • The ceramic paper, which could adsorb VOC's effectively, was made by paper-making method with zeolite and ceramic fiber as main constituents. By this experiment, the optimal composition of the slurry for the ceramic paper formation was established. SEM observation showed that zeolite powder was uniformly dispersed and adhered to the paper by applying inorganic binder. The two type zeolites content in the ceramic paper was 26 wt$\%$ and its BET surface area was 131 $m^{2}$/g. The thickness and the basis weight of the ceramic paper were 0.2 mm and 130 g/$m^{2}$ respectively, and it had sufficient tensile characteristics to withstand tensile stress without tearing during corrugation. The total inorganic content of the paper was 78 wt$ \% $ and organic content was 22 wt$\%$. The equilibrium loading amount of toluene at the toluene at the toluene partial pressure of 0.2 mmHg was 3.2 wt$\%$.

Study on the preparation of low loss Mn-Zn-Fe ferrite (저손실 Mn-Zn-Fe 페라이트의 제조에 관한 연구)

  • 문현욱;서강수;최희태;신용진
    • Electrical & Electronic Materials
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    • v.3 no.3
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    • pp.205-214
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    • 1990
  • 본 논문은 저손실 Mn-Zn-Fe 페라이트 제조에 관하여 연구한 것이다. Mn-Zn-Fe 페라이트는 16mol% Xno, 31mol% MnO 및 53mol% Fe$_{2}$O$_{3}$로 조성하였으며 0.1wt% $Na_{2}$SiO$_{3}$ 0.05wt% $Na_{2}$SiO$_{3}$ 0.1%wt% CaO 0.05% SiO$_{2}$ 및 0.05wt% SiO$_{2}$ 및 0.05wt% $Na_{2}$SiO$_{3}$ 0.1% CaO 0.05wt% $Al_{2}$O$_{3}$를 미량 첨가하였다. 그리고 하소와 분쇄과정을 거친 분말은 충진성을 높이기 위하여 과립화하였다. 소결 1250, 1300 및 1350.deg.C에서 이루어졌고, 평형 산소분압은 소오킹 시 PO$_{2}$는 6%부터 시작하여 점차 감소시켰으며 900.deg.C에서 순수한 질소 분위기로 냉각시켰다. 초투자율, 손실계수 및 고유저항 등의 자기적인 특성은 1300.deg.C에서 소결했을 경우의 것이 가장 우수하였다. 즉, 초투자율은 2*$10^{3}$~$10^{3}$의 높은 값을 얻을 수 있었으며 tan.delta./.mu.i값은 100KHz~ 400KHz의 고파수대에서 9*10$_{-6}$~21*10$_{-6}$이었으며 고유저항 값은 485~680 .OMEGA.-cm의 높은 값을 나타내어 중간주파수대의 자심재료에 적합한 페라이트임을 확인하였다.

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Study on the Superplasticity in Al-Li Alloy Systems (AI-Li계 합금의 초소성에 관한 연구)

  • Jin, Y.C.;Kook, J.S.;Kim, Y.S.;Hong, E.S.;Lee, M.S.;Lee, M.H.;Yoo, C.Y.
    • Journal of the Korean Society for Heat Treatment
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    • v.5 no.1
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    • pp.41-49
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    • 1992
  • The effects of alloying elements on the superplastic properties of Al-Li based alloys had been investigated. The intermediate thermo-mechanical treated (ITMT) Al-2.0wt%Li, Al-2.0wt%Li-1.0wt%Mg, Al-2.0wt%Li-0.12wt%Zr and Al-2.0wt%Li-1.2wt%Cu-1.0wt%Mg-0.12wt%Zr alloys were tested in tension at various temperature (400, 450, 500 and $550^{\circ}C$) and strain rate($6.7{\times}10^{-3}$, $1.0{\times}10^{-2}$, $1.6{\times}10^{-2}$ and $5.0{\times}10^{-2}/sec$). The results were as follows : The superplasticity in binary, ternary and pentanary alloys appeared at 500 to $550^{\circ}C$, and good strain rate for superplasticity. $1.6{\times}10^{-2}/sec{\sim}1.0{\times}10^{-2}/sec$ for a binary alloy and $1.0{\times}10^{-2}/sec{\sim}6.7{\times}10^{-3}/sec$ for ternary and pentanary alloys. A Zr-added ternary alloy had best value of elongation (730%) in four alloys at $550^{\circ}C$ of tension temperature and $1.0{\times}10^{-2}/sec$ of strain rate. The strain rate was greatly dependent on tension temperature and true strain rate was more than 1.0 at all test temperature and strain rate. In binary and Mg-added teranry alloys. the necks were slightly formed and their fracture surface had lips shape, but Zr-added ternary and pentanary alloy fractured along the grain boundary without necking. Their dislocations moved to grain boundary during superplasticity deformation and arranged perpendicular to grain boundary. Super plastic deformation was made by grain boundary slip of dislocation slip creep and model of core and mantle.

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Effect of Lubricant with Nanodiamond Particles in Sliding Friction

  • Adzaman, M.H.;Rahman, A.;Lee, Y.Z.;Kim, S.S.
    • Tribology and Lubricants
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    • v.31 no.4
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    • pp.183-188
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    • 2015
  • This paper presents the experimental effects of lubricant with nanodiamond particles in sliding friction. In order to improve the performance of lubricants many additives are used, such as MoS2, cadmium chloride, indium, sulfides, and phosphides. These additives are harmful to human health and to the environment, so alternatives are necessary. One such alternative is nanodiamond powder, which has a large surface area. In order to investigate the effect of nanodiamonds in lubricants under sliding friction, they are dispersed in the lubricant at a variety of concentrations (0 wt%, 0.1 wt%, 0.3 wt%, 0.5 wt%, and 1 wt%) using the matrix synthesis method. Friction and wear tests are performed according to the ASTM G99 method using a pin-on-disc tester at room temperature. The specimens used in this experiment are AISI 52100 ball bearings and AISI 1020 steel discs. During the test, lubricant mixed with nanodiamond is supplied constantly to keep the two bodies separated by a lubricant film. To maintain boundary lubrication, the speed is set to 0.18 m/s and a load of 294 N is applied to the disc through the pin. Results are recorded by using workbench software over the test duration of 10 minutes. Experimental results show that when the concentration of nanodiamond increases, the coefficient of friction decreases. However, above a nanodiamond concentration of 0.5 wt%, both the coefficient of friction and wear volume increase. From this experiment, the optimum concentration of nanodiamond showing a minimum coefficient of friction of 0.09 and minimum wear volume of 0.82 nm2 was 0.5 wt%.

Discriminant and predictive validity of TUG, F8WT, FSST, ST for community walking levels in chronic stroke survivors (만성 뇌졸중 환자들의 지역사회 보행 수준 구별을 위한 일어나 걸어가기 검사, 8자 모양 경로 보행 검사, 네 막대 스텝 검사, 스텝 검사의 변별력과 예측 타당도)

  • Lee, DongGeon;An, SeungHeon;Lee, GyuChang
    • Journal of Korean Physical Therapy Science
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    • v.27 no.2
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    • pp.25-35
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    • 2020
  • Background: There are many situations where walking in an actual community needs to change direction along with walking on a straight path, and this situation needs to be reflected in assessing walking ability of the community. Therefore, in this study, we tried to determine whether the assessments can distinguish the level of walking in the community. Design: Retrospective cohort study. Methods: Fifty-two survivors with chronic stroke have participated in the study. According to the evaluation result of 10mWT, the subjects of 0.8m/s and above were classified as the group who could walk in the community (n=22), and the subjects of 0.4m/s~0.8m/s were classified into the group who could not walk in the community (n=30). Modified Rivermead Mobility Index, Postural Assessment Scale for Stroke, Fugl-Meyer Assessment, Berg Balance Scale, 10-meter Walk Test (10mWT) were used to evaluate the motor skills. Furthermore, Activities-specific Balance Confidence Scale was used to evaluate psychological factors, and Timed Up & Go Test (TUG), Figure-of-Eight Walk Test (F8WT), Four Square Step Test (FSST), Step Test (ST) were applied to evaluate dynamic balance and mobility. Results: As a result for distinguishing walking levels in the community, TUG was 14.25 seconds, F8WT was 13.34 seconds, FST was 19.43 seconds, and ST of affected side and non-affected side were 6.5 points and 7.5 points, respectively. TUG (AUC=0.923), F8WT (AUC=0.905), and FST (AUC=0.941) were highly accurate, but the ST of affected side and non-affected side (AUC=0.806, 0.705) showed the accuracy of the median degree, respectively. Conclusion: To distinguish walking levels in the community of survivors with chronic stroke, TUG and FSST have been found to be the best assessment tool, and in particular, FSST could be very valuable in clinical use as the most important assessment tool to distinguish walking levels in the community.

Thermal Performance of the Microencapsulated PCM

  • Lee, Hyo-Jin;Lee, Jae-Goo
    • International Journal of Air-Conditioning and Refrigeration
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    • v.10 no.1
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    • pp.31-39
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    • 2002
  • Microencapsulated pcm (MPCM) particles are mixed with distilled water and utilized to evaluate its characteristics and performance as a thermal storage medium transporting heat. For the present study, tetradecane ($C_14$$H_30$, $T_m$=5.5$^{\circ}C$) is capsulated in the core, coated with the melamine for their surface. The size of particles is well-controlled under 10$\mu$m in the process of in-situ polymerization with melamine-formaldehyde resin. For the experiment, the concentractions of slurries are prepared for 20 wt%, 30 wt%, and 40 wt%. The results are compared with those of water and 100% tetradecane oil. The pure water and tetradecane start solidifying within 20 minutes after introducing cooling water into the thermal storage tank whose flow rates are varied by 125 cc/min, 250 cc/min, and 500 cc/min. However, MPCM slurries are required relatively longer period of time for their phase change than pure phase change materials. That is, the entrained MPCM particles restrict their heat transfer in terms of natural convection and conduction to them.

Corrosion and Surface Mechanical Properties of Fe-Gd-B Alloys (Fe-Gd-B 합금의 내식성과 표면 물성 평가)

  • Baek, Yeol;Choe, Yong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.119.1-119.1
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    • 2017
  • Fe-(10, 24 wt.%) Gd-B 합금을 진공 주조하고 상분석과 내식성 평가 및 표면 경도를 측정하였다. 주조된 Fe-10 wt.% Gd-B 합금의 상은 주로 $Fe_2Gd$, $Fe_3Gd$, $B_4FeGd$, $GdB_2$이었으며, Fe-24 wt.% Gd-B 합금은 주로 $Fe_2Gd$, $Fe_3Gd$, $Fe_9Gd$, $Fe_{17}Gd_2$, $B_4FeGd$, $GdB_2$이었다. 인공해수 분위기에서의 부식 속도와 부식 전위는 각각 2.771, 2.914 [$mA/cm^2$]과 -623.9, -607.8 [$mV_{SHE}$]이었다. 표면 경도는 각각 220, 208 [Hv] 이었다. Gd 함량이 증가할수록 부식 속도는 증가하였고 표면 경도는 감소하는 경향을 보였다.

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Fabrication and Physical Properties of ZrO2(m)-Al2O3ZrO2(t)-Al2O3 Structural Ceramics (ZrO2(m)-Al2O3ZrO2(t)-Al2O3 세라믹스의 제조와 물리적 특성)

  • Park, Jae-Sung;Park, Ju-Tae;Park, Jung-Rang
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.4
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    • pp.140-148
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    • 2010
  • The effects of the addition of either monoclinic $ZrO_2(ZrO_2(m))$ or tetragonal $ZrO_2(ZrO_2(t))$ containing 5.35[wt%] $Y_2O_3$ on the physical properties and electrical conductivity of $Al_2O_3$ were investigated. The addition of $ZrO_2$(m) and $ZrO_2$(t) increased sintered density of $Al_2O_3$. The Vickers hardness also increased as addition of $ZrO_2$(t) increased going through a maximum at 20[wt%] and the hardness of the specimens was found to be dependent on the sintered density. The addition of $ZrO_2$(t) improved the hardness of $Al_2O_3-ZrO_2$ systems and the $ZrO_2$(m) addition showed the better effect on the thermal shock property of $Al_2O_3-ZrO_2$ systems than that of the $ZrO_2$(t) addition. Above 15[wt%] addition of $ZrO_2$(t), the electrical conductivity is gradually increased with increasing applied voltage but not effects by addition of $ZrO_2$(m).

Liquid Phase Sintered SiC-30 wt% TiC Composites by Spark Plasma Sintering (스파크 플라즈마 소결에 의한 액상소결 SiC-30 wt% TiC 복합체)

  • 조경식;이광순;송진호;김진영;송규호
    • Journal of the Korean Ceramic Society
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    • v.40 no.8
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    • pp.751-757
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    • 2003
  • Rapid densification of a SiC-30 wt% TiC powder with additive 10 wt% A1$_2$O$_3$-Y$_2$O$_3$-CaO was conducted by Spark Plasma Sintering(SPS). The fully-densified materials can be obtain through the SPS process with very fast heating rate and short holding time. In the present work, the heating rate and applied pressure were kept to be $100^{\circ}C$/min and 40 MPa, while sintering temperature varied from $1600^{\circ}C$ to $1800^{\circ}C$ for 10 min. The full densification of SiC-30 wt% TiC composites with the addition of $Al_2$O$_3$, $Y_2$O$_3$ and CaO was achieved at the temperature above $1700^{\circ}C$ by spark plasma sintering. The XRD found that 3C-SiC and TiC were maintained the entire SPS process temperature, without phase transformation of SiC and formation of YAG phase to $1800^{\circ}C$. The microstructures of the rapidly densified SiC-30 wt% TiC composites consisted of smaller equiaxed SiC grains and larger TiC grains. The biaxial strength of 635.2 MPa and fracture toughness of 6.12 MPaㆍ$m^{1/2}$ were found for the specimen prepared at $1750^{\circ}C$.