• 제목/요약/키워드: 1-D Organic molecular line

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Directionality of ο-Phthalaldehyde adsorbed onto H-passivated Si(100) Surface Characterized by NEXAFS and HRPES

  • Kim, Ki-Jeong;Yang, Sena;Kang, Tai-Hee;Kim, Bong-Soo;Lee, Hang-Gil
    • Bulletin of the Korean Chemical Society
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    • 제31권7호
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    • pp.1973-1975
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    • 2010
  • The electronic and adsorption structure of o-phthalaldehyde (OPA) on the H-Si(100) surface was investigated by using Near Edge X-ray Fine Structure (NEXAFS) and high resolution photoemission spectroscopy (HRPES). We confirmed that the OPA grown on the H-Si(100) surface showed good dependency with about 60 degree tilting angle using NEXAFS and a single O 1s peak by using HRPES. Hydrogen atom passivated on the Si(100) surface was found to be a seed for making one dimensional organic line that uses a chain reaction as the H-Si(100) surface was compared with the hydrogen free Si(100) surface.

유기플라스틱 결정체의 PMR 연구 (제 1 보). 피발산 (PMR in Organic Plastic Crystals (I). Pivalic Acid)

  • 최종권;잔 그레함
    • 대한화학회지
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    • 제19권3호
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    • pp.149-155
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    • 1975
  • 플라스틱 결정체인 피발산의 temperature-dependent wide-line NMR line width, second monent 및 spin-lattice relaxation times 의 결과는 이 결정체의 특이한 운동학적 성질 및 수소결합에 기인된 것으로 해석된다. 이 분자의 운동학적 성질은 $C_3-C_3'$ reorientation 및 self-diffusion 으로 구성 되었음을 확인했다. Wide-line NMR 연구결과는 또한 Pople-Karasz 융해설과 비교검토되었고, 이 이론과의 차이점은 피발산의 수소결합에 기인되었음을 알아냈다.

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