• Title/Summary/Keyword: 1,4-Addition

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Studies on the Manufacture of Adlay Yoghurt II. The Volatile Flavour Compounds and the Sensory Properties of Adlay Yoghurt (율무 Yoghurt 제조에 관한 연구 II. 율무 Yoghurt의 휘발성 향미성분 및 관능적 특성)

  • 김상범;임종우
    • Food Science of Animal Resources
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    • v.20 no.1
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    • pp.64-71
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    • 2000
  • The volatile flavour compounds such as acetaldehyde, acetone, ethanol, diacetyl and acetoin were detected by gas chromatography in adlay yoghurt during fermentation and storage period at 4 $pm$1$^{circ}C$, but acetoin was trace. The contents of acetaldehyde of adlay yoghurt showed maximum immediately after fermentation and decreased significantly(P<0.05) with storage period and were in order of adlay yoghurt fermented with YC-380, ABT-D and ABT-4. The contents of acetone were shown similar trend to acetaldehyde and those of adlay yoghurt fermented with YC-380, ABT-4 and ABT-D, decreased rapidly from 6 days, 9 days and 12 days of storage, respectively. The contents of ethanol increased during the storage period and those were significant differences(p<0.05) between 6 days and 9 days of storage period in control and treatments. The contents of diacetyl were detected in control and treatments at 9 days of storage and increased slightly during the storage period. The contents of volatile flavour compounds of T1 showed similar to that of control and slightly high compared to those of treatments, and decreased gradually with increasing the level of addition of adlay in treatments. The taste, flavour and texture of T1 immediately after fermentation and during the storage period at 4$\pm$1$^{\circ}C$ were slightly higher than those of control and treatments. The scores of sensory evaluation of treatments except T1 were lowered significantly(p<0.05) with increasing level of addition of adlay. Adlay yoghurt fermented with YC-380 and ABT-4 and ABT-D were superior to both of taste and flavour, and texture, respectively. From the results mentioned above, the addition of taste and flavour, and texture, respectively. From the results mentioned above, the addition of adlay at 1% (w/v) level in skim milk substrate were suitable for quality of adlay yoghurt such as volatile flavour compounds and sensory property.

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The Stereospecific Synthesis of Abscisic Acid

  • Park, Oee-Sook;Lee, W.Y.;Park, J.C.
    • Korean Journal of Pharmacognosy
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    • v.17 no.1
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    • pp.67-72
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    • 1986
  • A stereospecific synthesis of 3-methyl-5-(1-hydroxy-4-oxo-2,6,6-trimethyl-2-cyclohexen-1-yl)-cis, trans-2,4-pentadienoic acid (abscisic acid) from ${\alpha}-ionone$ has been investigated. Ethyl 5-(2,6,6-trimetyl-2-cyclohexen-1-yl)-trans-4-penten-2-ynoate $({\alpha},{\beta}-acetylenic\;ester)$, which was synthesized from alpha-ionone in two steps, was stereospecifically converted in good yield into ethyl 3-methyl-5-(2,6,6-trimethyl-2-cyclohexen-1-yl)-cis, trans-2, 4-pentadienoate $({\alpha}-ionylideneacetate)$ by the conjugate addition of lithium dimethylcuprate at $-78^{\circ}C$. Basic hydrolysis of the ethyl ${\alpha}-ionylideneacetate$ gave an abscisic acid precursor, 3-methyl-5-(2,6,6-trimethyl-2-cyclohexen-1-yl)-cis, trans-2,4-pentadienoic acid, which can be oxidized to yield abscisic acid.

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Effect of Pb based flux on the Microwave Dielectric Properties of PCFN-PZW System (PCFN-PZW계의 마이크로파 유전 특성에 미치는 Pb계 Flux의 영향)

  • 강동헌;설충의;차훈주;김영호;길상근;조봉희
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.12
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    • pp.1027-1032
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    • 2002
  • (Pb$\_$0.4/Ca$\_$0.6/)(Fe$\_$1/2/Nb$\_$1/2/)O$_3$ system was modified by 10 mol% Pb(Zn$\_$1/2/W$\_$1/2/)O$_3$ addition and their sinterability and microwave properties were investigated as a function of the amount of flux (0.975PbO-0.025SnO$_2$). With increasing flux content, single perovskite phase was maintained up to 3 wt% flux addition and further addition led to the presence of Pb-rich second phase which was confirmed by EDS analysis. The apparent densities of PCFN-PZW specimen increased and showed maximum values at 2.5 wt% flux addition for the Ts=1000$^{\circ}C$ and 2.0wt% flux addition for the Ts=1050$^{\circ}C$, respectively. The dielectric constant and Q$.$f values strongly depended on the variation of density and microstructure, where the optimum values of $\varepsilon$$\_$r/ = 91.95, Q$.$f = 5938GHz, TCF = +8.15ppm/$^{\circ}C$ were obtained for the 2.5wt% flux added PCFN-PZW specimen sintered at 1000$^{\circ}C$ for 4h.

Studies on the Enzyme of Rhizopus oryzae - Part I. Production of Acid Protease and Enzymatic Characteristics - (Rhizopus oryzae의 효소(酵素)에 관(關)한 연구(硏究) - 제(第)1보(報), 산성(酸性) Protease 생산(生産) 및 효소(酵素)의 특성(特性) -)

  • Hou, Won-Nyong;Chung, Man-Jae
    • Applied Biological Chemistry
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    • v.22 no.3
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    • pp.135-141
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    • 1979
  • These experiments were conducted to investigate the conditions of the acid protease production by Rhizopus oryzae and the characteristics of crude enzyme. The results obtained were as follows: 1. The optimum culture time and the optimum amount of added water to the wheat bran medium were about 48 hrs and $80{\sim}120%$, respectively. 2. The addition of $(NH_4)_6Mo_7O_{24},\;(NH_4)_2SO_4,\;NH_4NO_3$, casein, and albumin, respectively, as nitrogen sources to the wheat bran medium was effective. Of these, the optimum concentrations of addition of $(NH_4)_6Mo_7O_{24}$ and casein which were the most effective were 0.1% and 1.0%, respectively. 3. The addition of glucose, galactose, maltose, lactose, and soluble starch, respectively, as carbon sources to the wheat bran medium was effective. Of these, the optimum concentration of addition of glucose which was the most effective was 3.0%. 4. The addition of $KH_2PO_4$ as a phosphate salt to the wheat bran medium was effective. The optimum concentration of addition of $KH_2PO_4$ was 0.3%. 5. The optimum pH for the enzyme action was 2.4, the optimum temperature about $40^{\circ}C$, and the stable pH range $2.0{\sim}5.0$. The enzyme was stab1e below $40^{\circ}C$. 6. The enzyme activity increased rapidly for 10 minutes after addition, thereafter it increased slowly. 7. The enzyme activity increased rapidly to 2 ml of addition, but nearly did not increase at the amounts greater than 2ml.

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Study on Moisture Variation in Light Frame Wall with Different Wall Assemblies (II) - Moister Transfer of Light Frame Wall in Field Test - (벽체구성에 따른 목조벽체 내 수분변화에 대한 연구(II) - 외기에 노출된 목조벽체의 수분이동 -)

  • Kim, Se-Jong;Yeo, Hwan-Myeong;Lee, Jun-Jae
    • Journal of the Korean Wood Science and Technology
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    • v.38 no.1
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    • pp.56-65
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    • 2010
  • The purpose of this study was finding out proper wall assembly to reduce moisture accumulation in light frame wall under outdoor air conditions. For the purpose, moisture transfer and accumulation in a wall were evaluated for five types of wall assembly; typical wall (T), addition of a vapor retarder (P1), addition of two vapor retarders (P2), addition of an open air gap for ventilation behind the siding (P3), and shift of vapor retarder with proposed wall 'P3' (P4). The moisture transfer and accumulation in the all walls were evaluated after applying the typical and proposed walls to the field test house. Performances of the typical and proposed walls were compared according to the season. Rank for effective wall on reducing moisture accumulation in wall was 1) shift of vapor ratarder and addition of open air gap (P4), 2) addition of vapor retarder (P1), 3) typical wall (T), 4) addition of open air gap (P3), and 5) the other (P2).

Microwave Dielectric Properties of Ca(Li1/4Nb3/4)O3-CaTiO3 Ceramics added with Zinc-borosilicate Glass Frit (Zinc-borosilicate Glass Frit 첨가에 따른 Ca(Li1/4Nb3/4)O3-CaTiO3 세라믹스의 마이크로파 유전 특성)

  • Yoon Sang-Ok;Kim Kwan-Soo;Jo Tae-Hyun;Shim Sang-Heung;Park Jong-Guk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.6
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    • pp.524-530
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    • 2006
  • $xCa(Li_{1/4}Nb_{3/4})O_{3}-(1-x)CaTiO_{3}$ ceramics were sintered under the presence of zinc-borosilicate(ZBS) glass and resultant microwave dielectric properties were investigated with a view to applying the composition to low-temperature co-fired ceramic(LTCC) technology. The addition of $5{\sim}15wt%$ ZBS glass ensured successful sintering below $900\;^{\circ}C$. In general, increased addition of ZBS glass increased sinterability but it decreased the quality factor($Q{\times}f_{0}$) significantly due to the formation of an excessive liquid and second phases. As for the addition of $CaTiO_3$, the dielectric constant(${\epsilon}_r$) and temperature coefficient of resonant frequency(${\tau}_f$) increased, while the quality factor($Q{\times}f_{0}$) did not show an apparent change. The sintered $0.9Ca(Li_{1/4}Nb_{3/4})O_{3}-0.1CaTiO_{3}$ specimen at $900\;^{\circ}C$ with 10 wt% ZBS glass demonstrated 39.6 in dielectric constant(${\epsilon}_r$), 4,400 in quality factor$(Q{\times}f_{0}),\;and\;-11ppm/^{\circ}C$ in temperature coefficient of resonant frequency(${\tau}_f$).

Effects of glycerol and seminal plasma in characteristics of preserved canine spermatozoa (개 정액의 보존시 glycerol 첨가 및 정장제거가 정자의 성상에 미치는 영향)

  • Kim, Kye-seong
    • Korean Journal of Veterinary Research
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    • v.33 no.2
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    • pp.345-350
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    • 1993
  • Multiple ejaculates were collected from four male mongrel dogs. The second fraction and the small volume of third fraction from the ejaculates were divided and treated as follows : control; addition of the egg-yolk Tris extender to the semen at $37^{\circ}C$. group I; Removal of seminal plasma, group II; addition of the glycerolated extender at $4^{\circ}C$, group III Removal of seminal plasma and addition of glycerolated extender at $4^{\circ}C$. The semen cooled to $4^{\circ}C$ was equlibrated for 2hrs and preserved in refrigerator at $4^{\circ}C$. The preserved semen was evaluated for kinetics, morphology, motility and thermoresistance daily for 3 days. 1. The kinectics after preserved days 2 and 3 of group I was significantly higher than that of control(p<0.05). 2. There were no significant difference in abnormal morphology of each group between the periods of storage. 3. The motility after preserved day 1 and days 3 of group I was significantly higher than that of others(p<0.05), and the molity after preserved days 2 of group I and III was signficantly higher than that of others(p<0.05). 4. When the molity of preserved semen was measured during incubation at $37^{\circ}C$, the motility of four groups was declined at similar rates. There was no effect of removal of seminal plasma and glycerol addition on thermoresistance.

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A Study on the Microstructural Control of LAS Ceramics (II): Influence of L$Li_2O{cdot}4B_2O_3$ Frit Addition on the Microstructure and Thermal Expansion of ${\beta}$-Spodumene (LAS계 내열충격성 재료의 미세구조 제어(II): $Li_2O{cdot}4B_2O_3$ 프릿트 첨가가 ${\beta}$-Spodumene의 미세구조 및 열팽창특성에 미치는 영향)

  • 박정현;김현민;이화선
    • Journal of the Korean Ceramic Society
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    • v.29 no.7
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    • pp.533-538
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    • 1992
  • Effect of Li2O.4B2O frit on the microstructural and thermal expansion behaviour of $\beta$-spodumene ceramics was investigated. With 4.0~8.0 wt.% frit addition, sintering temperature range was enlarged and densification was enhanced through liquid phase sintering. As the amount of frit addition was increased, thermal expansion coefficient was increased to 1.72$\times$10-6$^{\circ}C$-1 of its highest value, which indicated that the increment of thermal expansion coefficient due to the second phase was constrained.

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The effect of g1ass frit arid BaWO$_4$ Addition Microwave Dielectric Prperties of BaTiO$_3$-3TiO$_2$ Ceramics (Glass 첨가 및 BaWO$_4$ 첨가에 따른 BaTiO$_3$-3TiO$_2$ 세라믹스의 고주파 유전 특성)

  • 윤중락;김지균;이헌용
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.335-338
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    • 1998
  • The effect of glass flit addition on microwave dielectric properties of BaTiO$_3$-3TiO$_2$ ceramic was studied. Addition of glass frit to this system obtained sintered sample below sintering temperature 105$0^{\circ}C$. At BaTiO$_3$-3TiO$_2$+ g1ass frit 3wt% + BaWO$_4$6 wt%m, this ceramic showed excellent microwave properties of dielectric constant 34, Q$\times$f 8,100, temperature coefficient of resonant frequency 4 ppm/$^{\circ}C$ .

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