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Ultrahigh Molecular Weight Polyethylene Hybrid Films with Functionalized-MWNT: Thermomechanical Properties, Morphology, Gas Permeability, and Optical Transparency (기능화된 탄소나노튜브를 이용한 초고분자량 폴리에틸렌 복합체 필름: 열적 기계적 성질, 모폴로지, 전기적 성질 및 기체 투과도)

  • Ko, Jeong-Ho;Kim, Jeong-Cheol;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.33 no.2
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    • pp.97-103
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    • 2009
  • Ultra-high molecular weight polyethylene (UHMWPE)/functionalized-MWNT hybrid films were prepared by the solution intercalation method, using 4-cumylphenol-MWNT (CP-MWNT) as the functionalized-MWNT. The variation of the thermomechanical properties, morphology, gas permeability, and optical transparency of the hybrid films with CP-MWNT content in the range of 0$\sim$2.00 wt% were examined. The newly synthesized UHMWPE/functionalized-MWNT hybrid films were characterized by using differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and a universal tensile machine (UTM). It was found that the addition of only a small amount of functionalized-MWNT was sufficient to improve the thermomechanical properties of the UHMWPE hybrid films, with maximum enhancement being observed in the CP-MWNT loading in the range 0.50 to 1.00 wt%. The maximum enhancement in the oxygen gas barrier was also found at the functionalized MWNT content of 1.00 wt%. In this work, the thermomechanical properties and gas permeability of the hybrid films were found to be better than those of pure UHMWPE.

Preparation of $M_xZn_{0.22}Fe_{2.78-x}O_4(M=Mn, Ni)$ Films by the Ferrite Plating and Their Magnetic Properties (페라이트 도금법에 의한 $M_xZn_{0.22}Fe_{2.78-x}O_4(M=Mn, Ni)$ 박막의 제조와 자기적 성질)

  • 하태욱;유윤식;김성철;최희락;이정식
    • Journal of the Korean Magnetics Society
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    • v.10 no.3
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    • pp.106-111
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    • 2000
  • The magnetic thin films can be prepared without vacuum process and under the low temperature (<100 $^{\circ}C$) by ferrite plating. We have performed ferrite plating of M $n_{x}$Z $n_{0.22}$F $e_{2.78-x}$ $O_4$(x=0.00~0.08) films and N $i_{x}$Z $n_{0.22}$F $e_{*}$2.78-x/ $O_4$(x=0.00~0.15) films on cover glass at the substrate temperature 90 $^{\circ}C$. The crystal structure of the samples has been identified as a single phase of polycrystal spinel structure by x-ray diffraction technique. The lattice constant in the M $n_{x}$Z $n_{0.22}$F $e_{2.78-x}$ $O_4$films increases but in the N $i_{x}$Z $n_{0.22}$F $e_{*}$2.78-x/ $O_4$films decrease with the composition parameter, x. The saturation magnetization in the M $n_{x}$Z $n_{0.22}$F $e_{2.78-x}$ $O_4$films does not greatly change, in agreement with observations on bulk samples.k samples.k samples.

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Development of Bacillus thuringensis var. kurstaki NRD 6-Stu 1 by Site-Directed Mutagenesis (위치지정 변이기법을 이용한 Bacillus thuringiensis var. kurstaki NRD 6-Stu 1의 육성)

  • Lee, Jong-Su
    • The Journal of Natural Sciences
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    • v.6 no.1
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    • pp.41-48
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    • 1993
  • A cloned delta-endotoxin gene from Bacillus thuringiensis var. kurstaki NRD 6 was mutated at N-terminal toxic portion of the protoxin by site-directed mutagenesis. A Stu 1 restriction site was created in protoxin region of the mutant B.t.kurstaki NRD 6-Stu 1 which changed A to C in 177 region of the protoxin(silent mutation). Antigenic property of crystalline inclusion (delta-endotoxin) of the mutant was no difference to intact strain by the western blot analysis and its toxidity threshold value was also showed 0.015~0.030ng against Choristoneura femiferana-1 insect, similar with 0.01~0.024ng of parent strain, but stronger than that of B.t.kurstaki NRD 5 (500~1000ng) and B.t.kurstaki NRD 4(none toxic).

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Study on the Application of Miwon Organic Fertilizer (Byproduct of Amino Acid Fermentation) to the Ginseng Cultivation I. The Application Effect of Miwon Organic Fertilizer on the Germination rate of Ginseng Seed, Growth of Ginseng Plant and Physicochemical Properties of Soil (미원유기질비료(味元有機質肥料)(아미노산발효부산비료박(酸醱酵副産肥料粕)) 시용(施用)에 의(依)한 인삼재배(人蔘栽培)에 관(關)한 연구(硏究) I. 미원유기질비료(味元有機質肥料) 시용(施用)이 인삼(人蔘)의 발아(發芽)와 생육(生育) 및 토양(土壤)의 이화학적(理化學的) 성질(性質)에 끼치는 영향(影響))

  • Uhm, Dai-Ick;Han, Kang-Wan
    • Korean Journal of Soil Science and Fertilizer
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    • v.16 no.3
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    • pp.274-279
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    • 1983
  • In order to find out the application effect of commercial organic fertilizer on the germination rate of ginseng seed, growth of ginseng plant and changes of the physicochemical properties of soils, a Miwon organic fertilizer, byproduct of amino acid fermentation, was applied to the ginseng nursery bed. The application rates of Miwon organic fertilizer were 0kg-N from organic fertilizer and 30kg-N from wild grass compost per 10a as control(namely 0kg-N/10a), 2.5kg-N and 27.5kg-N/ 10a(2.5kg-N/10a) 5.0kg-N and 25kg-N/10a(5.0kg-N/10a), 10kg-N and 20kg-N/10a(10kg-N/10a), 15kg-N and 15kg-N/10a(15kg-N/10a) respectively, The obtained results are as follows: 1. The germination rate of ginseng seed were better in the plots that received 2.5kg, 5.0kg and 10kg-N/10a as compared with control plot. However no difference was found on germination rate between control and 15kg-N/10a, 2. The higher rate of missing plant was found in the 15kg-N/10a plot that showed poor growth. However control and 10kg-N/10a plot showed similar rate of missing plant. The best result, lower rate of missing plant, was obtained in the order of 5kg-N and 2.5kg-N/10a respectively. 3. The significant heavier ginseng root weight was obtained in 5kg-N/10a and 10kg-N/10a plot. However the root weight was decreased in the order of 2.5kg-N/10a, control, 15kg-N/10a. 4. In the physicochemical changes of soils between control and organic fertilizer treated soil before and after harvesting the increment of pH, C.E.C. and organic matter content along with the rate of organic fertilizer application were found. There were significant correlation between nitrate nitrogen and the rate of organic fertilizer application. 5. In the view points of germination rate, missing rate of plant and yield of ginseng root, it can be stated that the best result could be obtained from the plot that received 10kg-N/10a from Miwon commercial organic fertilizer and 10kg-N/10a from wild grass compost.

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A Study on the Magnetic Properties of Amorphous Fe-Co-RE-B (RE=Nd, Sm, Gd, Tb) Alloys (비정질 Fe-Co-Re-B(RE=Nd, Sm, Gd, Tb) 합금의 자기적 성질)

  • 김경섭;유성초;김창식;김종오
    • Journal of the Korean Magnetics Society
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    • v.1 no.2
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    • pp.55-59
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    • 1991
  • The temperature-dependent magnetization curves of amorphous Fe-Co-(Nd, Sm, Gd, Tb)-B alloys were measured using a vibrating sample magnetometer from 77 K up to 900 K. The spin wave stiffness constants and the range of the exchange interaction were calculated from the saturation magnetization values at 0 K. Curie temperatures and the Bloch coefficients estimated from the saturation magnetization curves. The low temperature dependence of magnetization is in good agreement with Bloch relation, $M_{s}(T)=M_{s}(O)(1-BT^{3/2}-CT^{5/2})$. The spin wave stiffness constant and the range of exchange interaction are decreased by substitution of heavy rare earth (Tb, Gd).

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The effects of heat-treatment on the mechanical properties of the Cu-bearing HSLA steels (Cu를 함유한 저합금 고장력강의 기계적 성질에 미치는 열처리의 영향)

  • Park, Tae-Won;Sim, In-Ok;Kim, Yeong-U;Gang, Jeong-Yun
    • Korean Journal of Materials Research
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    • v.5 no.3
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    • pp.333-344
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    • 1995
  • Cu를 함유한 2종의 저합금 고장력강(HSLA-A, HSLA-B)\ulcorner 기계적 성질에 미치는 시효처리의 영향을 조사하였다. 탄소량이 적음에도 불구하고 Cu첨가로 석출물을 생성시킴으로서 2합금 모두 $650^{\circ}C$에서 시효한 경우 양호한 강도(HSLA-A:Y.S 703Mpa, E.L 22.6% HSLA-B:Y.S 810 Mpa, E.L 23.8%)와 인성(HSLA-A:271.4J, HSLA-B:197.5J at -5$0^{\circ}C$)의 조합을 나타내었다. 50$0^{\circ}C$에서 시효할 때 가장 높은 항복 강도를 나타내나 인성은 아주 낮은 값을 나타내었다. 50$0^{\circ}C$이상 시효 온도가 증가하면 강도는 감소하고 인성은 증가하였다. HSLA-B강의 강도가 HSLA-A 강보다 높은데, \ulcorner칭 상태에서의 강도 차이는 경화능을 증가시키는 원소인 Ni, Mn, Mo, Cu의 첨가량 차이에 의한 기지 조직의 차이에 의한 것이며, 시효한 상태에서의 강도 차이는 기지 조직과 석출 강화에 기여하는 Cu량의 차이에 의한 것으로 판단된다. 시효 경화 곡선에서 $700^{\circ}C$에서의 경도 증가는 오스테나이트-페라이트 2상 영역으로부터 냉각시 생성된 “M-A constituents”에 의한 것이다. HSLA-A강과 HSLA-B강의 충격 천이 온도는 각각 -1$25^{\circ}C$와 -145$^{\circ}C$이었다.

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Enzymatic Properties of Extracellular Cytosine Deaminase (세포외 Cytosine Deaminase의 효소학적 성질)

  • 유대식;김대현;박정문;송형익;정기택
    • Korean Journal of Microbiology
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    • v.26 no.4
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    • pp.368-374
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    • 1988
  • Enzymological proprties of an extracellular cytosine deaminase from Bacellus polymyxa YL 38-3 were investigated. The extracellular enzyme was very stable, and optimum pH and temperature for the enzyme activity were found to be near pH 6.0 in 0.2M potassium phosphate buffer and at $30^{\circ}C$, respectively. 5-Fluorocytosine was converyed to 5-fluorouracil by the enzyme, but 5-methylcytosine was not to thymine by it. The enzyme activity was completely inhibited by some heavy metal ion such as 1mM of $Cd^{2-}$ and $Hg^{2+}$, and by 1mM of p-chloromercuribenzoate, respectively. The enzyme activity was inactivated about 75% by 1mM of o-phenanthroline and monoiodoacetate. But the enzyme activity was stimulated up to 200% by 1mM of 2-mercaptoethanol.

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Rheological Properties of Arrowroot Statch Suspension (칡전분 현탁액의 리올로지적 성질)

  • Kim, Kwan;Yoon, Han-Kyo;Kim, Sung-Kon;Lee, Shin-Young
    • Korean Journal of Food Science and Technology
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    • v.18 no.2
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    • pp.114-117
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    • 1986
  • The rheological properties of arrowroot starch suspension (2-6%) were investigated with a tube viscometer. The starch suspensions of less $t^1$, 4% showed a dilatant behavior with no yield stress at the temperature range of $30-65^{\circ}C$. However, the starch suspension of 6% concentration showed a pseudoplastic behavior at $65^{\circ}C$. The consistency index was exponentially increased with the increase of the starch concentration. The activation energy of flow of the starch suspensions was 0.370-0.399 kcal/mole at $30^{\circ}-60^{\circ}C$ and 28-60 kcal/mole at $65^{\circ}C$.

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The Multiferroic Properties Study of YMn2-xFexO5 (x=0.00, 0.01) by Neutron Diffraction (고 분해능 중성자 회절 실험에 의한 YMn2-xFexO5 (x = 0.00, 0.01)의 다강체 특성 연구)

  • Kim, Dong-Hyun;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.17 no.5
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    • pp.183-187
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    • 2007
  • Compounds of multiferroic materials $YMn_{2-x}Fe_xO_5$ (x = 0.00, 0.01) were prepared using the sol-gel method. The crystallographic, magnetic and electric properties are studied using x-ray diffraction (XRD), neutron diffraction, vibrating sample magnetometer (VSM) and physical property measurement system (PPMS). The crystalline structure of $YMn_2O_5$ was found to be orthorhombic (Pbam) at room temperature. The lattice constants of $YMn_2O_5$ were determined to be $a_0=7.275\;{\AA},\;b_0=8.487\;{\AA},\;c_0=5.674\;{\AA}$. The lattice constants not changed with Fe concentrations. Our data demonstrate the correlation of magnetic and electric properties in $YMn_2O_5$ materials.

Enzymatic Properties of Pectin Esterase from Aspergillus sp. (Aspergillus속(屬)이 생성(生成)하는 Pectin Esterase의 효소학적(酵素學的) 성질(性質))

  • Song, Hyung-Ik;Yu, Tae-Shick;Chung, Ki-Taek
    • The Korean Journal of Mycology
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    • v.9 no.1
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    • pp.39-43
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    • 1981
  • The enzymatic properties of pectin esterase from Aspergillus sp. were studied. The optimum conditions for the enzyme reaction were pH 4.2 and temperature of $45^{\circ}C$. The crude enzyme was very stable at pH range of $2.2{\sim}4.6$, but about 20 percent of activity was lost at the range of pH $5.4{\sim}8.0$. The crude enzyme was very stable at $50^{\circ}C$ for one hour, however almost 100 percent of enzyme activity was lost at $70^{\circ}C$ for 30 minutes. The pectin esterase activity of crude enzyme was greatly inhibited by addition of sodium chloride at lower pH range. That is, the inhibition rates of enzyme activity at pH 3.0 and 4.0 were 47% and 28% in concentration of 1M sodium chloride, respectively. The enzyme activity was not affected by sodium chloride at pH 7.0 at different concentration of sodium chloride. Although the enzyme activity was not affected by addition of sucrose, it was slightly inhibited at higher concentration of sucrose.

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