• Title/Summary/Keyword: 흡수 spectrum

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Research on Far-Infrared Optical Spectra of Blood Substances using FTIR-spectrometer (FTIR Spectrometer를 이용한 혈중성분의 원적외선 분광 스펙트럼에 관한 연구)

  • 김건식;최우석;박승한;전계진;윤길원
    • Proceedings of the Optical Society of Korea Conference
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    • 2000.08a
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    • pp.122-123
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    • 2000
  • 혈중 성분, 또는 생체 시료와 빛의 상호작용에 관한 연구는 비침습적 정량분석, 또는 생체 조직의 상태 분석의 가능성을 의미하므로 많은 분야에서 연구가 진행되고 있다. 최근에는 원적외선 검출소자가 급속히 개발됨에 따라 원적외선(8~15$mu extrm{m}$)영역에서의 생체 시료 및 성분들의 정량적인 분석과 영상에 관한 연구가 큰 주목을 받고 있다. 그중 혈중 Glucose 성분의 정량분석에 관한 연구는 여러가지 분광법-특히 NIR 영역에서 흡수, 투과, ATR, NMR 등-으로 활발히 연구되고 있으며$^{1)}$ , 최근에는 FIR 영역에서 혈중 성분들이 특정한 흡수 봉우리를 가지고 있음이 확인되어 이 영역에서의 분광법과 정량 분석에 대한 관심이 고조되고 있다. 본 연구에서는 혈중 성분들의 원적외선 영역에서 빛과의 상호작용인 흡수 spectrum을 측정하여 정량분석에 대한 가능성을 확인하였다. 생체를 이루는 가장 기본인 물에 대한 흡수 spectrum의 연구를 먼저 수행하였고, 혈중 성분중 Glucose, Hb, Albumin 등의 수용액을 농도별로 흡수 spectrum측정을 하였다. (중략)

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A study on the temperature dependence of electrical conductivity and optical absorption spectrum of poly(3-alklythiophene) in phase transition states (상전이상태에 있어서 poly(3-alkylthiophene)의 전기전도도와 광학흡수 spectrum의 온도의존성에 관한 연구)

  • 박복기
    • Electrical & Electronic Materials
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    • v.5 no.1
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    • pp.52-70
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    • 1992
  • Poly(3-alkythiophene)은 온도에 따라 전기적 광학적인 성질의 현저한 변화가 관측되었다. poly(3-alkylthiophene)의 전기전도도는 온도가 상승함에 따라 증가하지만 최대치를 유지한 후 용융점에서 단게적으로 감소한다. 가열과 냉각과정 동안 전기전도도의 온도의존성에서 hysteresis가 관측되었다. 이 변칙은 carrier확산에 따른 분자구조 변화의 강한 영향인 것으로 생각된다. 흡수 spectrum 또한 상전이에서 급격히 변화한다. poly(3-alkylthiophene)의 흡수 peak는 액체상태에서 가열하면 energy는 높게 이동한다. 그러나 흡수 edge의 이동은 비교적 작다. 그렇지만 고체-액체 상전이에서 흡수 edge는 energy가 높은 쪽으로 이동한다. 이러한 현상은 고체-액체 상전이에서 poly(3-alkylthiophene)의 구조가 현저하게 변화하고 있는 것으로 설명되며 공역 길이가 짧게되는 것은 큰 구조 변화에 의해 공역계의 평면성 감소에 의한 결과로 생각한다.

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Saturated absorption spectroscopy of 13C2H2 in the 1550 nm region (1550 nm 영역에서 아세틸렌 분자의 포화흡수분광)

  • 문한섭;이원규;서호성
    • Korean Journal of Optics and Photonics
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    • v.15 no.2
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    • pp.177-182
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    • 2004
  • We have observed the saturated absorption spectrum of the P(16) line of the V$_1$+V$_3$ band of $^{13}$ C$_2$H$_2$ molecule by using the external cavity spectroscopy method. The frequency of laser has been stabilized to the saturated absorption spectrum. The relative contrast of the saturation spectrum is about 7 % with respect to the linear absorption and the linewidth is about 1.8 MHz. The frequency fluctuation of the stabilized LD is about $\pm$20 KHz during the sampling time 100 S.

Theoretical Study on the Absorption Spectrum of a Chromophore in Liquid (용액상 색소분자의 흡수스펙트럼에 대한 이론적 연구)

  • Woo, Jung-Moon;Yang, Min-O
    • Journal of the Korean Chemical Society
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    • v.52 no.1
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    • pp.7-15
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    • 2008
  • Molecular motion influencing the absorption spectrum of a chromophore in liquid is theoretically described by a quantum mechanical time correlation function. In the present paper, we developed a theoretical method to calculate such a quantum mechanical time-correlation function from a classical time-correlation function using semi-classical approximations. The calculated time-correlation function was combined with the second order cumulant expansion method to calculate the absorption spectrum of nile blue in acetonitrile. Reasonably good agreement with experimental spectrum was obtained. From the comparison with experimental spectrum, we concluded that the time scale of solvation dynamics of the system should be longer then 1ps and the first shell of solvent is the major contribution to the solvation dynamics.

Wide-Band Ultrasonic Spectroscopy in Albumin Aqueous Solution (단백질 알부민 수용액의 광대역 초음파 스펙트로스코피)

  • Kim, Jeong-Koo;Bae, Jong-Rim
    • Journal of radiological science and technology
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    • v.30 no.2
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    • pp.161-165
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    • 2007
  • Ultrasonic absorption spectrum in bovine serum albumin aqueous solutions have been measured at $20^{\circ}C$ over the broad frequency range $0.2{\sim}1,000\;MHz$ at pH 7. The absorption spectrum observed at neutral pH was successfully analyzed with the distribution of relaxation time assuming a mirror-image curve of the Davidson-Cole function. This distribution function suggests that hydration of BSA molecules is responsible for the absorption.

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Absorption Spectra of a Methylene blue-Tetraphenylborate Ion Pair (Methylene Blue-Tetraphenylborate 이온쌍의 흡수스펙트럼)

  • Hyung-Soo Song;Young Joon Park;Kang-Jin Kim
    • Journal of the Korean Chemical Society
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    • v.28 no.6
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    • pp.355-360
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    • 1984
  • A new absorption spectrum observed from dilute aqueous solutions of methylene blue$(MB^+)$ and tetraphenylborate(TPB$^-$) ions was investigated by spectrophotometry. The species responsible for the spectrum can be a charge-transfer complex formed between the two, univalent, and poorly hydrated ions in order to minimize the disturbance to the water structure. However, as the absorption band of MB$^+$ is split into two bands with exciton splitting of about 2,000 cm$^{-1}$, the formation of double ion-pair, (MB-TPB)$_2$ appears to be more favorable than the charge transfer complex.

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Deconvolution of UV Spectrum for Selective Measurement of $ClO_2$ Concentration Quantitatively in Solution Containing Various Chlorine Species (다양한 염소 종이 함유된 수용액에서 자외선 흡수 파장 분해법을 이용한 이산화염소 선별 정량 분석)

  • Byun, Youngchul;Kim, Jaehoon;Jang, Yumi;Lee, Kiman;Lee, Jae Myeong;Shin, Dong Nam
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.11
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    • pp.743-750
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    • 2012
  • An ultraviolet (UV) absorption method has a difficulty to analyze $ClO_{2(aq)}$ in solutions containing various chlorine species because UV spectrum of $ClO_{2(aq)}$ overlaps with other chlorine-containing species. This study has proposed the deconvolution method of UV spectrum to analyze $ClO_{2(aq)}$ concentration quantitatively in solution containing various chlorine species. We compared results obtained from UV deconvolution method with titration method. Good agreement of $ClO_{2(aq)}$ concentration between them has been shown in about 10%. This result informs us that the deconvolution method of UV spectrum could be a feasible for the analysis of $ClO_{2(aq)}$ in solution containing various chlorine species.

Layout of Long-pass-edge Filter Correspond with the Optical Transmission in Crystalline (수정체 광투과에 대응하는 LPE Filter 설계)

  • Kim, YongGeun
    • Journal of Korean Ophthalmic Optics Society
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    • v.4 no.2
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    • pp.57-63
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    • 1999
  • The optical absorption and transmittance of cow' crystalline were measured by spectrophotometer in the 200~800nm wavelength regions. The optical absorptions of crystalline composed of a high absorption band in the UV-A, UV-B, and appeared the light transmittance edge in the 400nm wavelength region, and completely transmitted without the absorption in the high wavelength regions than 400nm. Also, the optical absorption and transmittance had no temperature dependence. The optical transmittance spectrum of crystalline concord with the thin film structure of $n_0/(0.5H)L(LH)^6(0.5H)/n_s$ and $n_0{\mid}(0.5LH0.5L)^kL/1.25{\mid}4.0$ of long-pass edge filter form. In the artificial crystalline and inter lens layout, long-pass edge filter layout can UV cut off.

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Consideration of Electromagnetic Induction through the coupling spectrum and the probe spectrum (결합광과 조사광의 스펙트럼을 통한 전자기 유도의 고찰)

  • Kim, Sook-Yung;Moon, Han-Sub;Lee, Chung-Hee;Kim, Kyung-Dae;Kim, Haeng-Hwa;Lee, Rim;Kim, Joong-Bok
    • Proceedings of the Optical Society of Korea Conference
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    • 2002.07a
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    • pp.120-121
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    • 2002
  • 결맞음 광원과 원자의 상호작용으로 원자의 에너지 준위간에 원자결맞음(atomic coherence)이 발생하고, 이러한 원자결맞음으로 많은 새로운 현상들이 나타난다. 흥미로운 원자결맞음 현상의 대표적인 예가 전자기 유도 투과(EIT)와 전자기 유도 흡수 (EIA) 현상이다. 특히, F'=F+1 의 축퇴된 2준위 원자와 레이저가 상호 작용할 때 공명주파수에서 조사광의 흡수신호가 급격히 증가하는 전자기 유도 흡수 현상을 관측할 수 있다. (중략)

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Absorbed Spectrum Comparison of Lead and Tungsten in Continuous X-ray Energy using Monte Carlo Simulation (몬테카를로 시뮬레이션을 통한 연속 엑스선 에너지에서 납(Pb)과 텅스텐(W)의 흡수 스펙트럼 비교 연구)

  • Kim, Kyotae;Kang, Sangsik;Noh, Sicheul;Jung, Bongjae;Cho, Changhoon;Heo, Yeji;Park, Jikoon
    • Journal of the Korean Society of Radiology
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    • v.6 no.6
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    • pp.483-487
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    • 2012
  • In 1895, the discovered X-ray is used for not only in this field of medicine wide but also field. The detection of radiation after, people realized the risk of the radiation exposured recommended the principle about the protection of radiation by the part of the effort for lowering the radiation exposure. In this recommendation, all unnecessary radiation exposure have to be prevented by All doses include the protection of radiation, general idea of applicable two kinds of that it has to low maintain. Presently, in the General X-ray room of the clinical, the lead (Pb) was used for the shielding, However, because it had the problem of the lead poisoning which is fatal in the human body, the alternatives was showed. and Among them, the material that it is the tungsten was presented. in this research, the absorbed spectrum according to the thickness in the continuous X-ray energy of the tungsten which is not harmful to the human body through the Monte Carlo simulation, tried to compare with the absorbed spectrum of the lead (Pb). The tungsten confirmed that simulation presumption than result lead in the whole domain that absorbed probability was higher and it is considered that tungsten shows the absorbed efficiency higher than the lead in particularly, 70 keV ~ 90 keV and the tungsten is more useful to the X-ray energy cover of the high energy diagnostic area.