• Proceedings of the Optical Society of Korea Conference
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• 2002.07a
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• pp.252-253
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• 2002

원적외선 영역에서 혈중성분들의 분광 특성이 존재함이 확인되면서 이 영역의 빛을 이용한 혈중 성분의 정량 분석을 통한 진단기술 개발이 활발히 진행되고 있다1). 특히 원적외선 영역에서 특정 파장에서의 반응성을 이용한 여러 방법들 중 photo-Acoustic을 이용한 방법이 여러 가지로 연구되어지고 있다. (2) 현재 수용액 상태의 혈중 성분들의 원적외선 분광 특성을 연구하였으며, 이를 이용한 혼합 성분들의 흡수 spectrum 정량-정성 분석이 가능하며, 이러한 특성을 이용하여 non-invasive로 이용 가능한 분광법을 연구 진행 중이다. (중략)

• 보존과학연구
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• s.18
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• pp.74-81
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• 1997

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.49 no.11
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• pp.893-900
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• 2021

In this study, air density in a narrow test section is measured using a laser absorption spectroscopy system that detects oxygen absorption lines. An absorption line pair at 13156.28 and 13156.62 cm^-1 are detected. A gas chamber with a height of 40 mm is used as a narrow test section. A triangular spiral-shaped laser path is applied in the gas chamber to amplify absorption strength by extending laser beam path length. A well-known logarithm amplifier and a secondary amplifier are used to electrically amplify absorption signal. An AC-coupling is applied after the logarithm amplifier for signal saturation prevention and noise suppression. Procedure of calculating spectral absorbance from output signal is introduced considering the logarithm amplifier circuit configuration. Air density is determined by fitting the theoretically calculated spectral absorbance to the measured spectral absorbance. Test conditions with room temperature and a pressure range of 10~100 kPa are made in a gas chamber using a Bourdon pressure gauge. It is confirmed that air density in a narrow test section can be measured within a 16 % error through absorption signal amplification using a triangular spiral-shaped beam path and a logarithm amplifier.

• Journal of the Korean Chemical Society
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• v.33 no.3
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• pp.315-320
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• 1989

A method was presented for the analysis of trace metals in iron oxide ore. The method utilized ammonium pyrrolidinedithiocarbamate (APDC)-methyl isobutyl ketone (MIBK) extraction procedure and analysis by atomic absorption spectroscopy (AA). Citrate at pH $8{\sim}10$ for the determination of Co, Ni and Cu or tiron at pH $6{\sim}7$for the determination of Mn and Cu was added as a masking agent to prevent extraction of Fe(III) into the organic phase. Reduction of solubility of MIBK in water was achieved by addition of NaCl as a salting-out agent. Back extraction of the MIBK extracts with aqueous $HNO_3$ was also studied to increase the stability of metal extracts.

• Journal of the Korean Chemical Society
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• v.29 no.3
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• pp.220-225
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• 1985

An attempt was made to determine some trace metals in highly concentrated samples using micro sampling technique in flame atomic absorption spectrophotometry. Major instrumental parameters and optimun analytical conditions investigated were the measuring time of instrument (the speed of electronics), sample volume, burner height, aspiration rate, and fuel to oxidant ratio. Advantages of the present technique are not only rapid, simple, and sensitive with good precision but also capability of analyzing small volume of sample and ability to handle highly concentrated samples without serious burner clog-up problem compared to conventional flame atomic absorption.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.329.2-329.2
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• 2014

지난 수년간 태양전지의 광전변환효율을 높이기 위해 자가 조립된 InAs 또는 GaSb와 같은 양자점을 GaAs 단일 p-n 접합에 적용하는 연구를 개발해 왔다. 그러나 양자점의 흡수 단면적에 의한 광 흡수도는 양자점층을 수십 층을 쌓으면 증가하지만 활성층에 결함을 생성시킨다. 생성된 결함은 운반자트랩으로 작용하여 태양전지의 광전변환효율을 감소시킨다. 본 실험에서는 양자점이 적용된 태양전지와 적용되지 않은 태양전지의 광전변환 효율을 비교하고, 깊은준위 과도용량 분광법을 이용하여 결함상태를 측정 및 비교함으로써, 활성층 내부에 생성된 결함이 광전변환 효율에 미치는 영향을 분석하였다. 소자구조는 분자선 증착 방법을 이용하여, 먼저 n+-형 GaAs기판위에 n+-형 GaAs를 250 nm 증착한 후, 도핑이 되지 않은 GaAs활성층을 $1{\mu}m$ 두께로 증착하였다. 마지막으로 n+ 와 p+-형 GaAs를 각각 50, 750 nm 증착함으로써 p-i-n구조를형성하였다. 여기서, n+-형 GaAs 과 p+-형 GaAs의 도핑농도는 동일하게 $5{\times}1018cm-3$로 하였다. 또한 양자점을 태양전지 활성층에 20층을 형성하였다. 이때 p-i-n 태양전지 와 양자점 태양전지의 광전변환 효율은 각각 5.54, 4.22 % 를 나타내었다. p-i-n 태양전지의 개방 전압과 단락전류는 847 mV, 8,81 mA이며 양자점 태양전지는 847 mV, 6.62mA로 확인되었다. 태양전지의 전기적 특성을 측정하기 위해 소자구조 위에 Au(300nm)/Pt(30nm)/Ti(30nm)의 전극을 전자빔증착장치로 증착하였으며, 메사에칭으로 직경 $300{\mu}m$의 태양전지 구조를 제작하였다. 정전용량-전압 특성 및 깊은준위 과도용량 분광법을 이용하여 태양전지의 결함분석 및 이에 따른 광전변환 특성인자와의 상관관계를 논의할 것이다.

• Journal of the Korean Chemical Society
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• v.37 no.7
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• pp.662-671
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• 1993

New Ni(II) and Pd(II) complexes of isonitrosomethylacetoacetate imine derivatives, Ni(IMAA-NH)(IMAA-NH'), Ni(IMAA-NH)(IMAA-NR), $Pd(IMAA-NH)_2\;and Pd(IMAA-NR)_2(R=CH_3,\;C_2H_5,\;n-C_3H_7,\;n-C_4H_9,\;or\;CH_2C_6H_5)$, where H-IMAA-NH and H-IMAA-NR represent isonitrosomethylacetoacetate imine and N-alkylisonitrosomethylacetoacetate imine derivative, respectively, have been prepared and the structures of the complexes have been studied by elemental analyses, electronic, infrared, and $^1H-\;and\;^{13}C-NMR$ spectroscopies.

• Journal of the Korean Chemical Society
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• v.44 no.3
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• pp.212-219
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• 2000

An absorption spectrometry coupled with flow injection analysis has been developed and tested for the analysis of the Cr$_2O_7^{2-}$/Nn$O_4^-$ mixtures. Even though one has to inject the sample twice into the FIA system and the process of the sample treatment is required to completely destroy the Mn$O_4^-$ ion for the analysis of the Cr$_2O_7^{2-}$ ion, the new method has definite advantages over the current method. It utilizes only a single analytical wavelength (570 nm) and enables one to construct calibration curves which accurately follow the Beer's law over wide ranges of analytical concentrations of both ions ($2.0{\times}10^{-6}$M∼$8.0{\times}10^{-3}$M for Cr$_2O_7^{2-}$ ion, $2.0{\times}10^{-6}$M∼$4.0{\times}10^{-3}$M for MnO4- ion).

• Korean Journal of Optics and Photonics
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• v.10 no.5
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• pp.357-363
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• 1999

A frequency domain spectroscopic system was constructed to investigate the optical properties of multiple scattering media. The alternating current (AC) and phase lag components of backscattered light were measured by using the heterodyne detection method. Absorption and transport scattering coefficients were computed from the values based on diffusion theory. Predictions showed excellent matches in comparison with actual values of absorption and scattering. Predictable ranges of the optical coefficients were analyzed in terms of the distance between light source and detector, and modulation frequencies. A proposed compact experimental set-up using laser diodes can be utilized to estimate non-invasively the optical properties of multiple scattering media such as biological tissues.

• Korean Journal of Optics and Photonics
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• v.9 no.4
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• pp.240-244
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• 1998

Cavity ring-down spectroscopy (CRDS) is a high-sensitive laser spectroscopic technique capable of measuring concentrations of trace gases. We have demonstrated a new design of the CRDS spectrometer with a continuous wave (CW) laser. The ring-dwon signal is produced through blocking the incident CW laser by scanning the cavity length fast toward off-resonance iwth PZT (piezoelectric transducer). We have also measured an absorption spectrum of acetylene overtone transitions near 570 nm at the pressure of 2700 Pa, and the minimum detectable absorption coefficient has been found to be about $3{\times}10^{-9}\cm^{-1}$.