• Title/Summary/Keyword: 흡수제 구조

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Structural characterization and degradation efficiency of degradation products of iopromide by electron beam irradiation (전자선 처리 후 생성된 Iopromide의 분해산물 구조 규명 및 분해 효율)

  • Ham, Hyun-Sun;Myung, Seung-Woon
    • Analytical Science and Technology
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    • v.27 no.6
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    • pp.292-299
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    • 2014
  • Iopromide is an X-ray contrast agent that has been detected frequently with high concentration level in surface waters. Structural characterization of degradation products and measurement of degradation efficiency of iopromide by an electron beam irradiation were performed. For the fortified sample with iopromide, electron beam irradiation (UELV-10-10S, klysotrn, 10 MeV, 1 mA and 10 kW) was performed. The chemical structures of I_D_665 and I_D_663, which are degradation products of iopromide, were proposed by interpretation of mass spectra and chromatograms by LC/ESI-MS/MS. The mass fragmentation pathways of mass spectra in tandem mass spectrometry were also proposed. Iopromide was degraded 30.5~98.4% at dose of 0.3~5 kGy, and 97.8~30% in the concentration range $0.5{\sim}100{\mu}g/kg$ at electron beam dose of 0.3 kGy, respectively. Thus, increased degradation efficiency of iopromide by electron beam irradiation was observed with a higher dose of electron beam and lower concentration.

Studies on the Anthocyanins in Wild Vines (Vitis amurensis Ruprecht) - (Part 2) Identification of Anthocyanins in Wild Vines - (머루(Vitis amurensis Ruprecht) Anthocyanin에 관(關)한 연구(硏究) - [제 2 보(第 2 報)] 머루 Anthocyanin의 구조(構造) 확인(確認) -)

  • Hwang, In-Kyeong;Ahn, Seung-Yo
    • Applied Biological Chemistry
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    • v.18 no.4
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    • pp.188-193
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    • 1975
  • The studies on the structure of anthocyanins in wild vines have beer carried out. The pigments were extracted with 0.5% HCl in methanol from the wild vines which were wildly grown in the mountain area of Korea and purified with Amberlite IRC-50 canon exchange resin. The individual pigments were separated by paper chromatography. Sever. pigments were identified by partial acid hydrolysis, sugar moiety, alkaline degradation, $R_f$ values of paper chromatography in various solvents and absorption spectra in the visible region. The identified pigments were delphinidin 3-monoglucoside, petunidin 3-monoglucoside, cyanidin 3-monoglucoside, delphinidin 3, 5-diglucoside, malvidin 3-monoglucoside, petunidin 3, 5 diglucoside and malvidin 3, 5-diglucoside.

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Effect of Nonionic Surfactant Solutions on Wetting and Absorbency of Polyethylene Terephthalate(PET) Fabrics (Part II) -Surfactants Characteristics and Fabric Properties- (비이온계 계면활성제 수용액이 PET직물의 습윤특성에 미치는 영향 (제2보) -계면활성제와 직물의 특성-)

  • Kim, Chun-Hee
    • Journal of the Korean Society of Clothing and Textiles
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    • v.29 no.12 s.148
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    • pp.1546-1553
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    • 2005
  • The wetting behavior and liquid transport of nonionic surfactant solutions; Span 20 and Tween 20, 40, 60, 80, 21, 61, 81, 65 & 85: in polyethylene terephthalate(PET) fabrics are reported. Five different PET fabrics are used in this study. PET 1, 2 & 3 have different compactness in structure. PET 4 & 5 have similar physical properties to PET 2, however, PET 4 has heat set finish and PET 5 with rewetting agent. The wetting and water retention properties of PET fabrics are greatly improved by addition of nonionic surfactants. The aqueous liquid retention(W) vs. cosq and W vs. adhesion tension has positive linear relationship. Hydrophilic surfactants which have short hydrophobes and surfactants with unsaturated hydrophobe structures are more efffctive in improving the wetting properties of PET fabrics. PET fabric which has larger thread spacing shows greater value of water retention ratio(W/H) than PET fabric with smaller thread spacing if there are no surfactants present in the system, however, W/H values become very similar among these PET fabrics when the surfactants are added. If there are no surfactants present in the system, PET with heat set finish has smaller value and PET with rewetting agent has greater value of W/H than PET without finish even though the fabrics have the similar physical properties.

A Study on Adhesion Characteristics and Physical Properties of Animal Glue Added Genipin (제니핀을 첨가한 아교의 접착 특성과 물성 변화 연구)

  • Lee, Jun Ho;Yu, Ji A;Chung, Yong Jae
    • Journal of Conservation Science
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    • v.34 no.3
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    • pp.157-166
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    • 2018
  • In this study, gelatin binding ability was increased by adding cross linking agent to improve adhesive characteristic of animal glue. Animal glue added genipin measured gel strength and viscosity, the structural analysis, the color retention degree, elution degree, and rupture strength. And the water resistance and ultraviolet light resistance with the addition of genipin were compared. As a result of the study, the gel strength and viscosity increased with the amount of genipin. As a result of the structural analysis, in gelatin, the absorption peak of the triple structure of collagen structurally stabilized was observed. As a result of the color retention degree, the film was observed because of the lowered brightness. The amount of elution glue was increased with addition of genipin at $50^{\circ}C$ distilled water condition and rupture strength has increased with the amount of genipin. In the water resistance and light fastness, there was no appearance before and after deterioration due to the addition of genipin. Based on the results of this study, it confirmed the adhesive characteristics of animal glue added genipin and examined the experimental method applicable for animal glue. After the addition of genipin, flexibility, re-solving, adhesive force, and curing speed, which are unique characteristics of glue, can be improved without disappearing, so it is expected that it will be applicable to production of animal glue and conservation of cultural heritage when homogeneous glue is secured.

Charactericstics of Glass-Ceramic having High Efficiency Diffuse Reflectance and Fabrication of Laser Cavity (MAS계 결정화유리를 이용한 레이저 여기용 공진기의 제작 및 특성분석)

  • Park, Yong-Bae;Byun, Woo-Bong;Kim, Yo-Hee
    • Proceedings of the KIEE Conference
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    • 2002.07c
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    • pp.1559-1561
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    • 2002
  • 적외선 확산반사형 결정화유리를 응용한 레이저 여기용 공진기를 제작하여 미세구조 분석 및 레이저 여기 효율특성을 조사하였다. 출발물질로는 Cordierite를 주결정상으로 하는 MAS(MgO, $Al_2O_3$, $SiO_2$) 3성분계 조성에 결정화 유도용 조핵제로 $TiO_2$를 첨가하였으며, 형성된 유리 용융물을 흑연제 몰드에 부어 공진기를 제조하였다. 용융물 중 일부를 2단계 열처리를 행하여 상분석을 실시한 결과 Cordierite($2MgO{\cdot}2Al_2O_3{\cdot}5SiO_2$)와 Rutile($TiO_2$)이 주결정상으로 관찰되었으며, 열처리 온도를 변화시켜 생성된 입자의 크기에 따른 확산반사율간의 관계를 조사한 결과, $1100{\sim}1200nm$에서 열처리된 시편의 경우 $500{\sim}2200nm$의 영역에서 95% 이상의 확산반사율을 나타내었다. 대표적인 고체레이저인 Nd:YAG의 경우, $700{\sim}900nm$ 파장이 주흡수대이며, 이를 결정화유리로 제조된 공진기의 레이저 효율특성실험에 이용하였다. 수냉 및 단일 펄스의 조건에서 $1.7{\sim}1.9%$의 효율을 나타내었다.

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Development of Polymer-Concrete Composite(I) - Physical Properties of Polymer-Cement Concrete Composites - (폴리머-콘크리트 복합재료 개발(I) - 폴리머-시멘트 콘크리트의 물성 -)

  • Hwang, Eui-Hwan;Kil, Deog-Soo;Oh, In-Seok
    • Applied Chemistry for Engineering
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    • v.8 no.6
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    • pp.979-984
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    • 1997
  • Test specimens of polymer-cement concrete composites were prepared using styrene-butadiene rubber(SBR) latex, ethylenevinyl acetate(EVA) and polyacrylic ester(PAE) emulsions as polymer dispersions in cement modified system at constant slump($10{\pm}0.5cm$), then compressive and flexural strengths water absorption, pore size distribution, and microstructures were investigated. Compressive and flexural strengths of these composites were remarkably improved with an increase of polymer-cement ratio. These composites had a desirable pore size distribution against frost damage due to a small capillary pore volume. Continuous polymer film was able to form in higher than 15% of polymer cement ratio.

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The Preparation and Properties of Petroleum Sulfonate Dispersant (열분해 잔유를 원료로 한 분산제의 제조 및 특성)

  • Choi, Sang-Won;Kim, Eun-Young;Chang, Woo-Seok;Kim, Viktor;Moon, Jang-Soo
    • Applied Chemistry for Engineering
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    • v.18 no.5
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    • pp.490-494
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    • 2007
  • Dispersants were prepared from petroleum pyrolysis residual oil (PPRO) through sulfonation. Without employing a conventional polynaphthalene sulfonate formaldehyde condensate (PNS) process, the dispersants (NPS) were synthesized by a simpler process only in 2 h. The chemical structure of new dispersant, which has various naphthalene derivative groups, was similar to PNS conformed by UV-visible spectroscopy curves. The new dispersants demonstrated high dispersing ability in inorganic suspension ; cement, $Fe_2O_3$, and $CaCO_3$.

Performance Improvement of Government R&D Investments Through Creating Open Innovation Conditions (개방형 혁신여건 조성을 통한 정부 R&D투자의 성과 제고)

  • Kim, Jae-Hong
    • Journal of Digital Convergence
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    • v.8 no.2
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    • pp.29-42
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    • 2010
  • To improve the performance of R&D investments, government has taken great efforts for advancing the structure and process in R&D systems. However, due to the drastic internal/external changes in the technological environment and the steady increase of investment scale, the necessity for a innovative approach which accomplishes returns to scale through the utilization of various external resources is emerging. In this regard, open innovation approach can minimize the possibility of government failures by strengthening the absorptive capacity of external resources and enhancing the cooperation and participation of diverse innovative participants within the R&D system. This paper evaluates the previous researches and government policies concerning the performances of government R&D investments, and presents the connectivity between open innovation and its possible contribution to the improvement of R&D investment performances.

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Studies on the Molybdenum Complexes with Tetradentate Schiff Base Ligand (I). N,N'-bis (Salicylaldehyde)-ethylene Diimine (네자리 Schiff Base 리간드의 몰리브덴착물에 관한 연구 (제1보))

  • Jo, Gi Hyeong
    • Journal of the Korean Chemical Society
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    • v.18 no.4
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    • pp.267-271
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    • 1974
  • The tetradentate schiff base, N,N'-bis(salicylaldehyde)-ethylene diimine has been reacted with a series of Mo(IV), Mo(V), Mo(IV), and Mo(III) oxidation states to form new Complexes; $[MoO_2(C_{16}H_{14}O_2N_2)], (MoO(C_{16}H_{14}O_2N_2)]_2O, (Mo(SCN)(C_{16}H_{14}O_2N_2)]_2O, and (Mo(H_2O)(C_{16}H_{14}O_2N_2)]_2O.$ These complexes have hexa coordinated configurations and the mole ratio of these ions to the ligand was 1:1. These complexes have been identified by visible spectra, infrared specra, T.G.A., D.T.A., and elemental analysis.

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An Empirical Study on Effects of Global Alliance Networks' Motives on Firm's Capabilities, Partner's Capabilities, Operating Structures, and Performances of Korean Companies (글로벌 제휴네트워크 추진 동기가 기업 역량, 파트너 역량, 운영구조, 제휴 성과에 미치는 영향에 관한 실증연구)

  • Jeong, Jong-Sik
    • International Commerce and Information Review
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    • v.14 no.2
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    • pp.249-269
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    • 2012
  • The focus of our work is to identify and understand the drivers of alliance performance so that businesses can maximize their chances of a successful alliance-an area that has received little attention in empirical modeling. Although both conceptual and applied research on alliances has increased, an empirically tested comprehensive theoretical model that explains alliance performance has yet to be developed. Using five salient perspective, namely market power theory, transaction cost theory, the resource-based view, institutional theory, real option theory, this paper attempts to provide a theoretical rationale linking motives of global alliance networks on firm's capabilities, partner's capabilities, operating structures, and performances of Korean companies. The key contribution of this study is that it paints a picture of what matters in driving alliance performance. Our work shows the complex nature of driving performance and the interplay of firm's capabilities, partner's capabilities, and operating structures for understanding alliance performances. This study has given us a small but significant step forward towards understanding the intricacies of alliance performance. We are now better able to understand the respective roles played by various alliance factors and derive insights that lead to improved alliance performance.

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