• Title/Summary/Keyword: 흡수제

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Test Bed Studies with Highly Efficient Amine CO2 Solvent (KoSol-4) (고효율 습식 아민 CO2 흡수제(KoSol-4)를 적용한 Test bed 성능시험)

  • Lee, Ji Hyun;Kwak, No-Sang;Lee, In Young;Jang, Kyung Ryoung;Jang, Se Gyu;Lee, Kyung Ja;Han, Gwang Su;Oh, Dong-Hun;Shim, Jae-Goo
    • Korean Chemical Engineering Research
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    • v.51 no.2
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    • pp.267-271
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    • 2013
  • Test bed studies with highly efficient amine $CO_2$ solvent (KoSol-4) developed by KEPCO research institute were performed. For the first time in Korea, evaluation of post-combustion $CO_2$ capture technology to capture 2 ton $CO_2$/day from a slipstream of the flue gas from a coal-fired power station was performed. Also the analysis of solvent regeneration energy was conducted to suggest the reliable performance data of the KoSol-4 solvent. For this purpose, we have tested 5 campaigns changing the operating conditions of the solvent flow rate and the stripper pressure. The overall results of these campaigns showed that the $CO_2$ removal rate met the technical guideline ($CO_2$ removal rate: 90%) suggested by IEA-GHG and that the regeneration energy of the KoSol-4 showed about 3.0~3.2 GJ/$tCO_2$ which was, compared to that of the commercial solvent MEA (Monoethanolamine), about 25% reduction of regeneration energy. Based on these results, we could confirm the good performance of the KoSol-4 solvent and the $CO_2$ capture process developed by KEPCO research institute. And also it was expected that the cost of $CO_2$ avoided could be reduced drastically if the KoSol-4 is applied to the commercial scale $CO_2$ capture plant.

The Study on the Realtime Evaluation of NH3 Absorption Efficiency Using Chemical Gas Sensor (가스센서를 활용한 암모니아 가스의 실시간 흡수 효율 평가에 관한 연구)

  • Lim, Jung-Jin;Kim, Han-Soo;Kim, Sun-Tae
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.4
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    • pp.233-239
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    • 2013
  • This study was carried out to develop the realtime evaluation system of $NH_3$ absorption efficiency with gas sensors which were installed on the inlet and outlet of lab-scale scrubber system. The $NH_3$ absorption amount, calculated by sensor outcomes for 3 hr, 6 hr, and 12 hr of absorption process, was compared with the results analysed by Indo-phenol method for the absorption solution. Even though the difference between two methods was about 20%, the correlation coefficient between the two results was very high, more than 0.99. In addition, we could find very good correlation between pH, absorption amount and reaction time. Also we could find out the breakthrough time in the middle of absorption process. With more diverse experiment in the future, we can make gas sensor system for the realtime evaluation of the odor and/or air pollution treatment efficiency.

The Effect of Designing Washing Column in Post Combustion CO2 Capture Plant on the Losses of Amine Solvent (습식아민 CO2 포집설비의 물 세정 단 설계에 따른 흡수제 손실 영향 평가)

  • Han, Sun-Gu;Ko, Hyun-Shin;Kim, Sung-Kyu;Choi, Si-Mook
    • Plant Journal
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    • v.13 no.2
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    • pp.34-38
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    • 2017
  • To reduce global warming, there are so many studies, investments and efforts. The Post Combustion $CO_2$ Capture technology is one of these efforts. But the technologies are having trouble with reducing operating prices. And CCS technology which is using amine solvent uses high price amine solvent. There is solvent losses naturally when operating plant. The solvent loss makes operating and maintenance price higher. In this study, how the washing column of treated flue gas affects the losses of amine solvent and operating was studied.

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COMPARISON OF THE CHRONOLOGY OF ROOT RESORPTION OF DECIDUOUS TEETH BETWEEN EARLY 1990S AND EARLY 2000S (1990년대 초와 2000년대 초의 유치 치근 흡수의 연령 비교)

  • Lee, Keun-Hye;Nam, Dong-Woo;Kim, Hyun-Jung;Nam, Soon-Hyeun;Kim, Young-Jin
    • Journal of the korean academy of Pediatric Dentistry
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    • v.31 no.3
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    • pp.362-371
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    • 2004
  • It is essential to have adequate knowledge of the timing of root resorption of deciduous teeth for diagnosis and treatment planning in pediatric and orthodontic dentistry. Dental development is also influenced by hereditary characteristics, environmental factors, race, sex, endocrine reaction, nutrition, socioeconomic condition and secular factor. The aims of the present study were to determine the mean age of root resorption of deciduous teeth in contemporary Korean children and to compare the mean age of root resorption time of deciduous teeth between early 1990s and early 2000s. The study population was made up of Korean children attending the pediatric dentistry ward of Kyungpook National University Hospital. One thousand thirty seven children's panoramic radiograph (girls: 528 persons, boys: 509 persons) in $1990{\sim}1992$ and one thousand sixty five children's panoramic radiograph (girls: 394 persons, boys: 671 persons) in $2001{\sim}2003$ were examined. This study utilized a cross-sectional design. Due to the problems of imaging in the maxillary region and the mandibular incisor region, the mandibular deciduous canine, the mandibular deciduous first molar and the mandibular deciduous second molar were chosen for examination. The results were as follows. 1. There is a tendency for the teeth to resort earlier in the early 2000s group than the in early 1990s group. At the Res c stage, the difference of the mean age was 0.4 years. 2. At the Res c stage, the order of difference of the mean age from smaller to larger for the girls was the mandibular deciduous canine, the mandibular first deciduous molar, and the mandibular second deciduous molar. On the other hand, for the boys, the order was the mandibular second deciduous molar, the mandibular first deciduous molar, and the mandibular deciduous canine. The difference was larger with aging in girls and smaller with aging in boys. 3. There is a tendency for the teeth to resort earlier in girls in both the early 1990s group and the early 2000s group. The difference of the mean age between girls and boys was 0.3 year. 4. The commencement of root resorption of the mandibular deciduous canine was slower than that of the mandibular first deciduous molar. However, the completion of root resorption of the mandibular deciduous canine is faster than that of the mandibular first deciduous molar. The total elapsed time of root resorption from commencement to completion was shortest in the mandibular deciduous canine. 5. For each of the teeth in the early 1990s and the early 2000s groups, the speed of root resorption was in the later stage faster than in the earlier stage. In order to know about the exact timing of root resorption of deciduous teeth, periodic and longitudinal studies preferably covering the entire period of growth, is required.

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흡수식 고효율화 방안

  • 문인식
    • The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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    • v.33 no.3
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    • pp.29-32
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    • 2004
  • 이중효용 흡수냉동기의 고효율화 방안과 당사(한국 캐리어)에서 개발한 흡수식 냉동기를 소개 하고자 한다. 흡수냉동기는 1777년 영국의 NAIRNE에 의해 흡수냉동기 이론을 발표한 이후 1945년 미국 CARRIER사가 냉매로서 물, 흡수제로서 리튬브로마이드(LiBr)를 이용한 일중 효용 흡수냉동기가 세계 최초로 상용화되면서 공조용 및 산업용 냉방기기로서 보급되기 시작하였다. 이러한 흡수식 기술은 일본에서 이중효용 흡수냉동기 및 냉온수기를 개발하면서 공조용 및 산업용 냉. 난방기기로서 널리 보급되기 시작하였으며, 최근에는 고 효율 이중효용 흡수냉동기 및 냉온수기(COP 1.2-l.3)를 개발하여 제작. 판매하고 있으며 또한 삼중효용 흡수냉온수기(COP 1.6)를 개발하고 있다. 그리고 세계 흡수냉동기 시장은 일본 및 중국을 중심으로 고 효율 흡수냉동기 시장으로 재편되고 있다. 그러나, 우리나라에는 아직 일본기술에 의존한 표준 COP 이중효용 흡수냉동기 및 냉온수기(COP 1.01)를 제작 판매하고 있는 실정이다. 따라서 본 고에서는 이중효용 흡수냉동기의 고효율화 방안과 당사(한국 캐리어)에서 개발한 흡수식 냉동기를 소개하고자 한다.

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A Study on the Improvement of Potassium Based Sorbent for Flue Gas Carbon Dioxide(CO2) (배가스 이산화탄소(CO2)용 Potassium계 흡수제의 성능 향상 연구)

  • Wi, Young Ho;Ryu, Chong Kul;Choi, Dong Hyeok
    • Journal of Climate Change Research
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    • v.2 no.2
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    • pp.107-113
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    • 2011
  • In this research, we described the experimental results for the improvement of Potassium based sorbents. These sorbents have been actually used in the 0.5 MW $CO_2$ capture plant located in Hadong #3 Power Plant. Firstly, we had shaped two kinds of sorbents using a spray dryer. These sorbents applied magnetite & copper oxide as an additive. And the magnetite sorbent was evaluated more excellent relatively in the attrition index. Secondly, We had obtained TGA multicycle experimental results of the improved Potassium based sorbent which applied magnetite as an additive. Consequently, $CO_2$ sorption capacity had been sustained 5.5 wt% after 2nd cycle and attrition index was very excellent as 0.5%. Finally, we had investigated the characteristics of the sorbent following in properties of supporters. As a result, the sorption capacity of the KMO sorbent used base material as a supporter was appeared as 7.2 wt%.

Evaluation of Solution Mediator in Irrigation System Controlled by Drainage Level Sensor (배액전극제어법 적용시 배액 이동매개체 선발)

  • Kim, Sung-Eun;Sim, Sang-Youn;Lee, Sang-Don;Kim, Young-Shik
    • Journal of agriculture & life science
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    • v.44 no.6
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    • pp.23-26
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    • 2010
  • Commercial fibers such as two kinds of micro-fiber, flannel, and cotton were analyzed for their nutrient solution absorption capacity to select hydrophilic mat used for the irrigation management by drainage level sensor in perlite bag culture. The selected mat was evaluated in terms of absorption capacity. Cotton had the highest absorption capacity and was revealed to be the most appropriate for the control system.

Efficiency Characteristics by Mixed Absorbents for the Removal of Odor Compounds in the Wet Scrubber (습식세정탑 내 악취가스 제거를 위한 복합흡수제의 효율 특성)

  • Park, Young G.;Kim, Jeong-in
    • Applied Chemistry for Engineering
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    • v.22 no.1
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    • pp.48-55
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    • 2011
  • It was found that the absorbent mixed with 2-aminoethanol and others has been applied to remove them via chemical neutralization. The absorbent of natural second metabolites was achieved by a removal efficiency of 20~30% by itself depending on treatment conditions, but the complex absorbent mixed with 0.2% amine chemical provides the removal efficiency of over 98%. Optimal removal efficiencies have been examined against two major parameters of the temperature and pH to remove ammonia and hydrogen sulfide gases. The chemical analysis was also performed to analyze the composition of an essential oil by GC-MS. The monoterpenes in an essential oil reacted with odorous compounds by neutralization and their reaction mechanism was partially elucidated.

Solubility Measurement of Carbon Dioxide in Alkylcarbonates and Triacetin at High Pressure (고압에서 알킬카보네이트와 트리아세틴의 이산화탄소 용해도 측정)

  • Kim, Ji Won;Hong, Won Hi;Hong, Yeon Ki
    • Clean Technology
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    • v.21 no.2
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    • pp.124-129
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    • 2015
  • The constant-volume method was used to determine the solubility of CO2 in various physical absorbents such as DMPEG (dimethyl ether of polyethylene glycol), DEC (diethyl carbonate), DMC (dimethyl carbonate), and TAT (triacetin) in the total pressure range from 5 to 30 bar. The Peng-Robinson equation of state has been used to describe the equilibrium behavior of these mixtures. It was found that the solubility of absorbents was in the of DMPEG250 > TAT > DEC > DMC at the same temperature. Futhermore, the solubiity of blended absorbent of DMPEG250 and DEC is higher than that of DMPEG 250 alone. Therefore, blended absorbent of DMPEG250 and DEC is expected to be an effective and low cost absorbent for physical absorption in precombustion CO2 capture.