• Title/Summary/Keyword: 흡수스펙트럼

Search Result 567, Processing Time 0.021 seconds

Absorbed Spectrum Comparison of Lead and Tungsten in Continuous X-ray Energy using Monte Carlo Simulation (몬테카를로 시뮬레이션을 통한 연속 엑스선 에너지에서 납(Pb)과 텅스텐(W)의 흡수 스펙트럼 비교 연구)

  • Kim, Kyotae;Kang, Sangsik;Noh, Sicheul;Jung, Bongjae;Cho, Changhoon;Heo, Yeji;Park, Jikoon
    • Journal of the Korean Society of Radiology
    • /
    • v.6 no.6
    • /
    • pp.483-487
    • /
    • 2012
  • In 1895, the discovered X-ray is used for not only in this field of medicine wide but also field. The detection of radiation after, people realized the risk of the radiation exposured recommended the principle about the protection of radiation by the part of the effort for lowering the radiation exposure. In this recommendation, all unnecessary radiation exposure have to be prevented by All doses include the protection of radiation, general idea of applicable two kinds of that it has to low maintain. Presently, in the General X-ray room of the clinical, the lead (Pb) was used for the shielding, However, because it had the problem of the lead poisoning which is fatal in the human body, the alternatives was showed. and Among them, the material that it is the tungsten was presented. in this research, the absorbed spectrum according to the thickness in the continuous X-ray energy of the tungsten which is not harmful to the human body through the Monte Carlo simulation, tried to compare with the absorbed spectrum of the lead (Pb). The tungsten confirmed that simulation presumption than result lead in the whole domain that absorbed probability was higher and it is considered that tungsten shows the absorbed efficiency higher than the lead in particularly, 70 keV ~ 90 keV and the tungsten is more useful to the X-ray energy cover of the high energy diagnostic area.

Displacement Properties of Nano Structure Functional Organic Thin Films (나노구조 기능성 유기박막의 변위특성)

  • Song, Jin-Won;Lee, Kyung-Sup;Lim, Jung-Yoel
    • Proceedings of the Korea Contents Association Conference
    • /
    • 2004.11a
    • /
    • pp.554-557
    • /
    • 2004
  • Monolayers of lipids on a water surface have attracted much interest as models of thin films, also as precursors of multilayer systems promising many technical applications. Photoisomerization in monolayers of a novel azobenzene compound, azobenzene dendrimer, was investigated for the first time by means of the absorption spectrum and Maxwell displacement current (MDC) technique. Dendrimers are well-defined macromolecules exhibiting a tree-like structure, first derived by the cascade molecule approach. According to the absorption spectrum, trans-to-cis conversion ratio was estimated to azobenzene dendrimer deposited onto a glass substrate. As a result, It's photoisomerization progressed by dendrimer.

  • PDF

A study on CIGS thin film characteristic with composition ratio change (조성비 변화에 의한 CIGS박막 특성에 관한 연구)

  • Chu, Soon-Nam;Park, Jung-Cheul
    • Journal of the Korea Institute of Information and Communication Engineering
    • /
    • v.16 no.10
    • /
    • pp.2247-2252
    • /
    • 2012
  • In this paper, we produced CIGS thin film by co-evaporation method. During the process, substrate temperature and Ga/(In+Ga) composition ratio was altered to observe the change of resistivity and absorbance spectra measurements. As substrate temperature increased, resistivity decreased and as Ga/(In+Ga) composition ratio increased from 0.30 to 0.72, band gap also increased with the range of 1.26eV, 1.30eV, 1.43eV, 1.47eV. With the constant condition of composition ratio, resistivity decreased with increased thickness of the thin film. On this experiment, we assumed that optical absorbance ratio and optical current will be increased with CIGS thin film fabrication.

Mössbauer and Infrared Absorption Spectroscopy of Tourmaline Minerals (전기석 광물의 뫼스바우어 및 적외선 흡수 분광학)

  • Kim, Hee Jong;Kim, Soo Jin
    • Journal of the Mineralogical Society of Korea
    • /
    • v.6 no.2
    • /
    • pp.105-115
    • /
    • 1993
  • $M{\ddot{o}}ssbauer$ and Infrared absorption spectra of the iron-bearing tourmaline minerals show that the ferrous and ferric ions occupy the Y and Z octahedral sites. The Fe ions are almost ferrous, predominantly partitioning into Y site and partly take in Z site. The $Fe^{2+}$ content of the Z sites in brownish black tourmaline minerals are higher than that in blue/green tourmaline minerals. Therefore, 720 nm peak of brownish black samples is broader than that of blue/green samples in optical spectra. All of the blue/green tourmaline minerals used in experiment have only $Fe^{2+}$ ion. The IR spectra of tourmaline depend on the cation environments around OH groups, as also evidenced by their chemical analyses. There appear no difference in IR spectrum between O(1)H and O(3)H binding characters in the heat-treated samples. But the characteristic $3565cm^{-1}$ peak appears in the ferrous hydroxyl bearing silicates, where dehydroxylation temperature for OH coordinated to $Fe^{2+}$ is $700{\sim}800^{\circ}C$.

  • PDF

Ferrimagnetic Resonance Studies of Poly-crystalline $Mn_x$ Ferrites (Mn-Zn 훼라이트의 자기공명 특성연구)

  • 김정렬;박명희;박윤창
    • Journal of the Korean Magnetics Society
    • /
    • v.2 no.2
    • /
    • pp.105-113
    • /
    • 1992
  • 조성이 Mn$_{x}$Zn$_{1-x}$ Fe$_{2}$O$_{4}$ 훼라이트(x=0.75, 0.52)를 pusher type 연속 전기로를 이용하여 질소 분위기하에서 1360 .deg. C 로 3시간 동안 소결하여 얻어냈다. 본 연구에서는 스피넬 구조인 Mn-Zn 훼라이트의 FMR(Ferrimagnetic Resonance) 스펙트럼 특징과 초기투자율과의 상관성을 조사하고자 EPR X-band 스펙 트로미터를 이용 9.50 GHz의 microwave frequency에서 FMR 실험을 수행하였다. FMR 공명흡수선은 주 자기공명 흡 수선외에 낮은 자기장에서 약한 subsidiary 공명흡수선을 나타내는데 온도변화에 따른 주 자기공명 흡수선과 sub- sidiary 공명흡수선(제2, 제3 공명흡수선)의 세기, 공명선폭, g값 등의 온도 의존성을 연구함으로써 제2 공명흡수 선이 나타나는 원인을 분석하였으며, 자기공명 흡수선의 g값, 자기공명선 세기, 그리고 공명선폭과 초기투자율의 상관성을 연구하였다. 실험 결과 주 자기공명 흡수선의 g값, 자기공명선 세기, 공명선폭은 초기투자율 값과 밀접 한 관련이 있음을 확인할 수 있었다.었다.

  • PDF

Spectral Analysis for Non-Invasive Total Hemoglobin Measurement in the Region from 400 to 2500nm (총헤모글로빈 농도를 비침습적으로 측정하기 위한 400-2500nm 대역의 흡수 스펙트럼 분석)

  • Jeon, Kye-Jin;Kim, Yoen-Joo;Kim, Su-Jin;Kim, Hong-Sig;Yoon, Gil-Won
    • Journal of Sensor Science and Technology
    • /
    • v.10 no.6
    • /
    • pp.273-278
    • /
    • 2001
  • Absorption spectra of blood components have been measured for the purpose of predicting the total hemoglobin concentration. We obtained absorption spectra of major blood components from the visible to near-infrared of $400{\sim}2500nm$ region. In the near-infrared, water is the main absorbing constituent. The amount of water in the sample cell varies depending on the volume of solute concentration(water displacement). We acquired water-compensated spectra by considering the variation of water volume depending on the variation of analyze concentration. Those spectra show inherent absorption peaks of analyzes and linearity with respect to concentration. We selected wavelengths for non-invasive measurement of hemoglobin concentration considering the scattering effect of tissue and the interference of other blood components.

  • PDF

Determination of Pu Oxidation states in the HCl Media Using with UV-Visible Absorption Spectroscopic Techniques (UV-Visible 흡수분광학법을 이용한 염산매질내 Pu 산화상태 측정)

  • Lee, Myung-Ho;Suh, Mu-Yeol;Park, Kyoung-Kyun;Park, Yeong-Jae;Kim, Won-Ho
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
    • /
    • v.4 no.1
    • /
    • pp.1-7
    • /
    • 2006
  • The spectroscopic characteristics of Pu (III, IV, V, VI) in the HCl media were investigated by measuring Pu oxidation states using a UV-Vis-NIR spectrophotometer (400-1200 nm) after adjusting Pu oxidation states with oxidation/reduction reagents. Pu in stock solution was reduced to Pu(III) with $NH_2OH$ HCl, and oxidized to Pu(IV) and Pu(VI) with $NaNO_2$ and $HClO_4$, respectively. Also, Pu(V) was adjusted in the Pu(VI) solution with $NH_2OH$ HCl. The major absorption peaks of Pu (IV) and Pu(III) were measured in the 470 m and 600 nm, respectively. The major absorption peaks of Pu (VI) and Pu(V) were measured in the 830 nm and 1135 nm, respectively. There was not found to be significant changes of UV-Vis absorption spectra for Pu(III), Pu(IV) and Pu(VI) with aging time, except that an unstable Pu(V) immediately reduced to Pu(III).

  • PDF

Investigation of Absorption Cross-Section Effects on the Formaldehyde Column Density Retrieval from Direct Sun Measurement (태양 직달광 관측 자료로부터 포름알데히드 연직 농도 산출 시 흡수단면적이 미치는 영향 연구)

  • Gyeong Park;Jeonghyeon Park;Hanlim Lee
    • Korean Journal of Remote Sensing
    • /
    • v.39 no.5_1
    • /
    • pp.551-561
    • /
    • 2023
  • In this study, we investigated the effects of the spectral fitting window and absorption cross-section on the retrieval of the formaldehyde (HCHO) slant column density (SCD) from the direct-sun measurement of pandora spectrometer system using differential optical absorption spectroscopy (DOAS). Pandora Level 1 data observed at Yonsei University in Seoul from October 12 to 31, 2022 were used. The HCHO column density was retrieved under eight ranges including the spectral fitting window used in the Second Cabauw Intercomparison campaign for Nitrogen Dioxide measuring Instruments (CINDI-2) and seven types of absorption cross-section composition. The spectral fitting window was selected from 336.5 to 359.0 nm with minimum residual and HCHO SCD error. When the nitrogen dioxide (NO2) absorption cross-section at 220 K was added to the cross-section composition used in the CINDI-2 campaign among seven types, the residual and HCHO SCD error were the smallest and the HCHO column density wasstably retrieved. The average HCHO SCD with the highest retrieval accuracy and the values retrieved under other conditions differed from a minimum of 4% to a maximum of 40%.

A Study on the Rearrangement of 1,3-Oxathiolane Sulfoxides (1,3-옥사티올란술폭시드의 전위에 관한 연구)

  • Wha Suk Lee;Hoh Gyu Han;In Kyu Kim
    • Journal of the Korean Chemical Society
    • /
    • v.33 no.2
    • /
    • pp.238-246
    • /
    • 1989
  • 1,3-Oxathiolane sulfoxide 4 in which the sulfoxide oxygen and the 2-methyl group are on the same face of the oxathiolane ring undergoes a sigmatropic rearrangement to produce a ring expansion product. The structure of this product would be dihydro-1,4-oxathiin 6 or isomeric exo compound 7. This paper describes physical and chemical methods to determine the correct structure of the two alternatives. Thus, $^1HNMR$, UV spectroscopies, and mass spectrometry showed that the product actually obtained had the structure 6. It was also found that from deuteration reactions of the product the compound 7 was initaly formed and then tautomerized to endo compound 6.

  • PDF

Detection of Dimer of Rhodamine 6G Perchlorate Doped in Ormosil (Ormosil에 침투된 Rhodamine 6G Perchlorate의 이중합체의 검출)

  • Kim, Goo-Dae;Lee, Dong-A;Moon, Ji-Woong;Park, Kyung-Su
    • Analytical Science and Technology
    • /
    • v.10 no.3
    • /
    • pp.225-229
    • /
    • 1997
  • The stability of Rhodamine 6G Perchlorate(Rh6GP) doped in organically modified silicate(Ormosil) was investigated after the Ormosil was synthesized by sol-gel process. The composition of the Ormosil which makes organic dye molecules stable and dimer-free was decided from comparing absorption peaks of dye molecules in sol state, in wet gel and in completely dried gel. The stable and dimer-free Rh6GP doped in the Ormosil was achieved in the 0.1 molar ratio of HCl/TEOS.

  • PDF