• Title/Summary/Keyword: 흡수기 효율

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Ammonia Removal Characteristics in Membrane Contactor System Using Tubular PTFE Membrane (관형 PTFE 분리막을 이용한 막 접촉기(Membrane Contactor) 시스템에서 암모니아의 제거 특성)

  • Ahn, Yong-Tae;Hwang, Yu-Hoon;Shin, Hang-Sik
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.5
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    • pp.353-358
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    • 2011
  • In this study, ammonia removal characteristics in membrane contactor system under various operating conditions were evaluated. The mass transfer coefficient was used to quantitatively compare the effect of various operation conditions on ammonia removal efficiency. Effective removal of ammonia was possible with the tubular PTFE membrane contactor system at all tested conditions. Among the various operation parameters, contact time and solution pH showed significant effect on ammonia removal mechanism. Overall ammonia removal rate was not significantly affected by influent suspended solution concentration unlike other pressure driven membrane filtration processes. Also the osmotic distillation phenomena which deteriorate the mass transfer efficiency can be minimized by preheating of strip solution. Membrane contactor system can be a possible alternative to treat high strength nitrogen wastewater by optimizing operation conditions such as stripping solution flow rate, influent wastewater temperature, and influent pH.

Absorption Characteristics of Sulfur Dioxide in Jet Bubbling Reactor (가스분사반응기에서의 SO2 흡수 특성)

  • Choi, Byung-Sun;Park, Seung-Soo;Kim, Yung-whan
    • Applied Chemistry for Engineering
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    • v.5 no.5
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    • pp.836-842
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    • 1994
  • The optimum design conditions of gas sparger pipe and the effects of operating variables on $SO_2$ removal efficiency have been examined in Jet Bubbling Reactor. Geometry of gas sparser pipe of Jet Bubbling Reactor is a very important factor to obtain a effective gas-liquid contact. Test results revealed that Reynolds numbers at sparger and slot have to be kept greater than 12,000 identically at a given gas velocity. $SO_2$ removal efficiency was a function of ${\Delta}P$, pH, inlet $SO_2$ concentration and particle size of limestone and was more sensitive to the change of ${\Delta}P$ than to the changes of others. The ${\Delta}P$ of at least 230mmAq must be maintained to acheive the above 90% $SO_2$ removal at pH of 4.0 which is considered as adequate operating pH. Higher $SO_2$ removal efficiency was obtained even at lower pH ranges, which resulted from the complete oxidation of the absorbed $SO_2$ to sulfates by adding air and consequently from the reduction of $SO_2$ equillibrium partial pressure in the gas-liquid interface The 99.5% of the limestone utilization was attained in pH range from 3.0 to 5.0 with regardless to the particle size of limestone employed.

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Efficiency of Soil and Fertilizer Nitrogen in Relation to Rice Variety and Application Time, Using ^{15}N$ Labeled $Fertilizer_{1)}$ -V. ^{15}N$ Point application in fields- (중질소(重窒素)를 이용(利用)한 수도품종(水稻品種) 및 시용시기(施用時期)에 따른 토양(土壤) 및 시비(施肥) 질소(窒素)의 효율(效率) -V 포장(圃場)에서 ^{15}N$의 국지시용(局地施用)-)

  • Park, Hoon;Mok, Sung-Kyun;Seok, Sun-Jong
    • Applied Biological Chemistry
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    • v.25 no.4
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    • pp.232-238
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    • 1982
  • From ^{15}N$ labelled nitrogen experiments on 13 fields use efficiency by difference method was higher than that by labelling method in 80% of fields tested indicating augmentation of soil nitrogen uptake by fertilizer nitrogen. Both methods showed very similar trend among fields. Sulfur coated urea(SCU) and point application increased fertilization efficiency(yield increment per fertilizer nitrogen applied, Fe) to 23 from 15 of split application through the increase of fertilizer use efficiency from 29(Eu) to 50 but tended to decrease efficiency of absorbed fertilizer nitrogen(yield increment per nitrogen derived from fertilizer, Ef) from 50. to 46 High yielding capacity of Tongil line appears to be attributed to the higher Ef, translocation efficiency and soil nitrogen preference index(soil nitrogen increment in plant per the increment of fertilizer nitrogen in plant, PI). This studies confirmed that yield under fertilizer application system depends on Fe which is the multiplication of Eu and Ef and that the improvement of fertilizer management(form, application method and time) increases principally Eu, the limit of which is controlled by Ef that is attributed mainly to varietal characteristics.

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A Thermodynamic Study on Suction Cooling-Steam Injected Gas Turbine Cycle (吸氣冷却-蒸氣噴射 가스터빈 사이클에 관한 열역학적 연구)

  • 박종구;양옥룡
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.1
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    • pp.77-86
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    • 1992
  • This paper discusses the thermodynamic study on the suction cooling-steam injected gas turbine cycle. The aim of this study is to improve the thermal efficiency and the specific output by steam injection produced by the waste heat from the waste heat recovery boiler and by cooling compressor inlet air by an ammonia absorption-type suction cooling system. The operating region of this newly devised cycle depends upon the pinch point limit and the outlet temperature of refrigerator. The higher steam injection ratio and the lower the evaporating temperature of refrigerant allow the higher thermal efficiency and the specific output. The optimum pressure ratios and the steam injection ratios for the maximum thermal efficiency and the specific output can be found. It is evident that this cycle considered as one of the most effective methods which can obtain the higher thermal efficiency and the specific output comparing with the conventional simple cycle and steam injected gas turbine cycle.

Designing FMH Impact-Absorbing Structure by Using Subcomponent Collapse Simulation (단품 압궤 시뮬레이션을 이용한 FMH 충격흡수부재의 설계방법에 관한 연구)

  • Kim, Ji-Hun;Jun, In-Ki;Choi, Jae-Min;Kim, Sung-Hun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.8
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    • pp.1113-1118
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    • 2010
  • It is requested that the interior compartment of a passenger vehicle must be satisfied with the FMVSS201U regulation, FMH impact test. It is needed the design methodology to find the appropriate structure about the FMH impact. When designing the impact-absorbing structure for the FMH impact test, it is to be noted that the impact absorber must have different performance considering the stiffness of the vehicle as the impact position and approach angle of FMH. In this study, an efficient design methodology was developed by using subcomponent collapse simulation instead of conducting full-vehicle simulation, thereby reducing the time and resources spent. Further, this unit-model simulation helps optimize the impact absorbing structure.

Reaction Characteristics of Simultaneous Removal of $SO_{x}/NO_{x}$ from flue gas with $CuO/{\gamma}-Al_2O_3$ sorbent/catalyst (산화구리가 담지된 알루미나 흡수제/촉매를 이용한 배연 탈황/탈질 동시제거 반응특성)

  • 유경선;김상돈
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1994.11a
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    • pp.97-100
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    • 1994
  • 산화구리가 담지된 알루미나 흡수제/촉매를 이용하여 유황산화물과 질소산화물의 제거반응 특성을 고정층 반응기를 이용하여 고찰하였다. 반응온도가 증가할 수록 $350^{\circ}C$까지 탈질 효율이 증가하였으며 그 이상의 온도에서는 암모니아의 산화에 의하여 탈질효율이 감소하였다. 암모니아의 $NO_{x}$ 선택성은 $SO_{x}$ 가 존재하지 않는 경우에 $NH_3/NO_{x}$mole 비 1.0 까지 유지되었으나 $SO_{x}$ 가 존재하면 선택성은 매우 감소하였다. 동시제거 반응의 경우 $400^{\circ}C$ 이상에서 효과적이었으며 $350^{\circ}C$ 이하에서는 암모늄 염의 생성으로 인하여 탈질효율의 감소가 반응시간이 증가함에 따라서 감소하였다.

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Performance Evaluation of K-based Solid Sorbents Depending on the Internal Structure of the Carbonator in the Bench-scale CO2 Capture Process (벤치급 CO2 포집공정에서 흡수반응기의 내부구조에 따른 K-계열 고체흡수제의 성능평가)

  • Kim, Jae-Young;Lim, Ho;Woo, Je Min;Jo, Sung-Ho;Moon, Jong-Ho;Lee, Seung-Yong;Lee, Hyojin;Yi, Chang-Keun;Lee, Jong-Seop;Min, Byoung-Moo;Park, Young Cheol
    • Korean Chemical Engineering Research
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    • v.55 no.3
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    • pp.419-425
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    • 2017
  • In this study, the performance characteristics of the K-based sorbents (KEP-CO2P2, KEPCO RI, Korea) has been studied in relation with the heat exchanger structure and shape in a mixing zone of the carbonator in the bench-scale dry $CO_2$ capture process. Two types of heat exchangers (different structure and shape) were used in the carbonator as CASE 1 and CASE 2, in which the experiment has been continuously performed under the same operating conditions. During the continuous operation, working temperature of carbonator was 75 to $80^{\circ}C$, that of regenerator was 190 to $200^{\circ}C$, and $CO_2$ inlet concentration of the feed gas was 12 to 14 vol%. Especially, to compare the dynamic sorption capacity of sorbents, the differential pressure of the mixing zone in the carbonator was maintained around 400 to 500 mm $H_2O$. Also, solid samples from the carbonator and the regenerator were collected and weight variation of those samples was evaluated by TGA. The $CO_2$ removal efficiency and the dynamic sorption capacity were 64.3% and 2.40 wt%, respectively for CASE 1 while they were 81.0% and 4.66 wt%, respectively for CASE 2. Also, the dynamic sorption capacity of the sorbent in CASE 1 and CASE 2 was 2.51 wt% and 4.89 wt%, respectively, based on the weight loss of the TGA measurement results. Therefore, It was concluded that there could be a difference in the performance characteristics of the same sorbents according to the structure and type of heat exchanger inserted in the carbonator under the same operating conditions.

The Q-switched $1.3\mum$ Nd:YAG laser using sautrable absorber Nd:LSB (포화흡수체 Nd:LSB를 이용한 $1.3\mum$ Q-스위칭 Nd:YAG 레이저)

  • 지명훈;이재명;오세용;이영우
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2001.05a
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    • pp.329-332
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    • 2001
  • In this paper, it's shown that the saturable absorber Nd:LSB has a capability as a saturable absorber in Q-switching system. In the passively Q-switched 1.3${\mu}{\textrm}{m}$ Nd:YAG laser with saturable absorber, we theoretically investigated the optimized output mirror, peak power, output power, pulse width and output efficiency. The passively Q-switched Nd:YAG laser with saturable absorber Nd:LSB gives peak power of 30MW and pulse width of 6.23 ps at 30cm resonator length and output mirror reflectivity 98%. Consequently the output energies are 143, 200 and 209 $\mu$J at loss of 2.2%, 2.1% and 1.5%, respectively.

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Reaction Characteristics of Desulfurization Sorbents for Warm Syngas Cleanup (석탄 합성가스 정제용 탈황제의 흡수/재생 온도 변화에 따른 황흡수 특성)

  • Baek, Jeom-In;Ryu, Jungho;Lee, Joong Beom;Eom, Tae-Hyoung;Lee, Kisun;Wi, Yong-Ho;Ryu, Chong Kul
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.107.1-107.1
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    • 2010
  • 고체 흡수제를 이용한 석탄합성가스 중의 황제거 기술은 습식 스크러빙 방식에 비해 고온에서 운전가능하므로 석탄가스화복합발전의 효율 향상을 가져올 수 있다. 고체탈황제는 서로 연결된 두 개의 유동층 반응기를 순환하면서 흡수탑에서는 합성가스 중의 $H_2S$로부터 황을 흡수하고 재생탑에서는 공기 중의 산소와 흡수된 황이 반응하여 $SO_2$를 배출하고 재생된다. 따라서 고체 황 흡수제는 유동층 공정에 응용가능한 물성과 함께 높은 황흡수능과 빠른 반응성이 요구된다. 본 연구에서는 기존 개발된 고체 탈황제가 가졌던 소성시 수축 현상, 낮은 내마모도 등을 개선하기 위해 지지체 조성을 변경하여 개발한 분무성형 탈황제의 흡수 재생 온도에 따른 황흡수 특성 변화를 조사하였다. $H_2S$ 1 vol. %를 함유한 모사 합성가스를 이용하여 흡수온도 450, $500^{\circ}C$, 재생온도 500, 550, 600, $650^{\circ}C$에서 황 흡수능을 열중량분석기를 이용하여 측정하였다. 개발된 흡수제는 유동층 공정 적용에 적합한 훌륭한 물성(형상, 밀도, 강도 등)과 함께 $500^{\circ}C$ 흡수와 $650^{\circ}C$ 재생을 기준으로 10 wt% 이상의 높은 황흡수능을 보여주었다. 흡수온도 변화는 황 흡수능 변화에 큰 영향을 미치지 않았으나, 재생온도가 $600^{\circ}C$ 이하인 경우 황흡수능이 5 wt% 이하로 크게 떨어져 재생온도를 $650^{\circ}C$ 이상 유지시키는 것이 중요함을 알 수 있었다.

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Mineral nutrition of field-grown rice plant. -III. Uptake, efficiency and percent translocation of N.P.K. and Si at various yield classes (포장재배수도(圃場栽培水稻)의 무기영양(無機營養) -III 수량등급별(收量等級別) 양분(養分)(N. P. K Si) 흡수량(吸收量), 양분효율(養分効率) 및 전이율(轉移率))

  • Park, Hoon
    • Korean Journal of Soil Science and Fertilizer
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    • v.7 no.2
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    • pp.119-125
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    • 1974
  • Uptake amount, percent translocation to grain and grain yield efficiency of N. P. K. Si were investigated with N. P. K simple trials (countrywide, 1967~69) and other nitrogen fertiltzer field trials in relation to yield class. 1) Uptake rate with yield increase were similar in all nutrients but silica showed greater yearly variation. 2) In N. P. K simple trials showing very low nitrogen efficiency(46kg grain/ nitrogen uptake kg) it and percent translocation increased with yield increase. 3) Nitrogen efficiency deacreased with the increase of nitrogen uptake and the decreasing rate depends greatly on fertilizer forms and variety. Nitrogen efficiency was greater in sandy loam where yield was higher than in clay loam. 4) Nitrogen efficiency positively correlated with percent translocation. 5) In high yielding fields yield was attributed only to the increase of nitrogen uptake, keeping efficiency around 50. 6) Major factor for high yield is considered as the increase of nitrogen efficiency rather than nitrogen uptake. 7) Phosphorus efficiency in N. P. K. simple trials was considerably low, suggesting too much uptake due to soil reduction.

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