• Proceedings of the Mineralogical Society of Korea Conference
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• 2003.05a
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• pp.33-36
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• 2003

• The Journal of the Petrological Society of Korea
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• v.8 no.2
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• pp.81-91
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• 1999

The area of the study is located in Ogcheon district, middle part of Ogcheon Fold Belt. The area is covered by metasedimentary rocks of Ogcheon Supergroup at northern, eastern and southern part. Jurassic Ogcheon granite which intruded into Ogcheon Supergroup at central part, was intruded by Cretaceous quartz porphyry at western part. The granite consists of quartz, plagioclase, alkali feldspar, biotite, sphene, apatite, epidote, opaque and so on. It is generally characterized by grey to light grey, medium-grained, mafic enclave and partly weak foliation. In terms of geochmical compositions, the granite is felsic, peraluminous, subalkaline and calc-alkaline, and it was differentiated from single granitic magma. It shows parallel LREE enrichment and HREE depletion patterns with 0.84 Eu negative anomaly, which has REE variation trend and anomaly value similar to Jurassic granites in Korea. From charactristics of petrology, mineralogy and geochmistry, it may be interpreted that the Ogcheon granite body was derived from melting of I-type crustal material related to syn-collisional tectonic setting and emplaced more or less rapidly into the Ogcheon Supergroup.

• The Journal of Engineering Geology
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• v.18 no.1
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• pp.103-115
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• 2008

The purposes of this study are to understand characteristic water-rock interaction mechanisms of groundwater in the granite area of Geochang and Hapcheon areas, Gyeongnam-do and to clarify the origin of fluoride. The possible water-rock interaction process and the source of fluorine were studied using water chemistry, rock chemistry, mineralogy by XRD, and microtexture analysis by backscattered electron image of the electron microprobe. No clear relationships between F and hardness was found. But the fluorine content increases to some extent with pH and well depth. Preferential alteration due to water-rock interaction took place along edges or cleavage, or margins of biotite. Because biotite is highly subject to alteration in granite aquifer, fluorine in groundwater is originated from the leaching of biotite.

• Economic and Environmental Geology
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• v.36 no.6
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• pp.407-413
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• 2003

The geology of the Apdong Nb-Ta deposit, is hosted by alkali metasomatites, consist of Upper Proterozoic sedimentary rocks, alkali syenites(Hoamsan intrusive) of Phyonggang Complex(late Paleozoic to early Mesozoic), Jurassic granite and Quaternary basalt. Alkali syenites are distinguished as alkali amphibole-pyroxene syenite, alkali amphibole-biotite syenite, biotite-nepheline syenite, biotite syenite, and quartz-alkali amphibole-pyroxene syenite. Alkali metasomatites are the products of intense post-magnatic metasomatism, and form the Nb-Ta ore bodies as the belt, irregular vein and lenticular types in the southern part of Hoamsan intrusive. The ore mineralization is characterized by the occurrence of pyrochlore, zircon, and small amounts of columbite, fergusonite. magnetite, fluorite, molybdenite, ilmenite, titanite, apatite, and monazite. Pyrochlore is one of the niobium/tantalum oxides and contains substantial amounts of rare earths and radioactive elements. The compositional varieties of pyrochlore can be defined: (1) enriched in tantalum, uranium and cerium, (2) substantially tantalum- and fluorine-poor, and (3) enriched in thorium or barium. The geochemical characteristics, ore textures and mineral occurrences indicate that alkali metasomatism of the mineralizing fluid was the dominant ore-forming process.

• The Journal of Engineering Geology
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• v.28 no.4
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• pp.593-603
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• 2018

The most of groundwater with high U-concentration occur in the Jurassic granite of Gyeonggi massif and Ogcheon belt, and some of them occur in the Cretaceous granite of Ogcheon belt. On the contrary, they do not occur in the Jurassic granite of Yeongnam massif and the Cretaceou granite of Gyeongsang basin. The Jurassic and Cretacous granite, the host rock of high U-groundwater, were resulted from parental magma with high ratio of crustal material and highly differentiated product of fractional crystalization. These petrogenetic characteristics explain the geological evidence for preferential distribution of uraniferous groundwater in each host rock. It were reported recently that high U-content, low Th/U ratio and soluble mineral occurrence of uraninite in the two-mica granite of Daejeon area which have characteristics of S-type peraluminous and highly differntiated product. It is the mineralogical-geochemical evidences supporting the fact that the two-mica granite is the effective source of uranium in groundwater. The biotite granite and two-mica granite of Jurassic age were reported as biotite granite in many geological map even though two-mica granite occur locally. This fact suggest that the influence of two-mica granite can not be ignored in uraniferous groundwater hosted by biotite granite.

• Proceedings of the Mineralogical Society of Korea Conference
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• 2001.06a
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• pp.115-115
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• 2001

경주시 양남면의 4기 단층으로 추정되는 수렴단층에 의해 절단되는 해안단구 퇴적층 풍화단면에서 저결정질 광물인 앨로패인 교결층을 기재하였다. 이들은 자갈퇴적층 내에 협재하는 수조의 모래층에 한정되어 형성되어 있으며, 3-17 cm 두께로 연장성이 매우 좋다. 편광현미경 관찰에 의하면 모래층에는 사장석편들이 다량 함유되어 있으며 앨로패인은 광학적 등방성의 치밀한 점토집합체들로서 사장석 입자를 선택적으로 교대하거나 자갈과 모래입자들을 피복하고 있다. 앨로패인은 광학적 이방성인 상하위층의 고령토질 점토피복물과 명확히 구분된다. 앨로패인의 전자현미분석에 의하면, Al/Si 원자비가 1.3-1.7 범위이고 평균값은 1.5이다. X선회절분석 결과 3.49$\AA$과 2.26$\AA$에서 두 개의 넓은 회절대가 관찰된다. 주사 및 투과전자현미경관찰에 의하면 앨로패인을 특정한 입자형태 없이 치밀한 겔상태를 이루고 있다. 열분석에 의하면 96$^{\circ}C$에서 큰 흡열피크와 992$^{\circ}C$에서 발열피크가 관찰되며, 총 45% 정도의 중량감소를 보인다. 사장석의 평균조성은 An$_{87}$이며, 사장석내 유리포유물의 전자현미분석결과는 화산암 화학분류도에서 현무암 영역에 도시된다. 이 지역의 기반암은 현무암질 라필리응회암이나 사장석편을 제외하고 벤토나이트화되어 있다. 따라서 해빈환경에서 사장석이 벤토나이트에서 분리되어 퇴적한 것으로 보인다. 앨로패인 교결층은 해수면 강하로 단구퇴적층이 지표로 노출된 후, Al의 함량이 높고 비교적 풍화에 약한 사장석이 선택적으로 풍화되어 생성되었다. 앨로패인으로 피복된 모래층 내의 자갈은 풍화반응이 지체되어 상하위층의 자갈과 비교하여 풍화도에 있어서 현저한 차이를 보인다.. 파이프 중심에서 외곽부로 갈수록 전기석의 함량은 줄어들고 있고 장석들이 알바이트ㆍ칼스베드 쌍정을 보이며, 흑운모가 각섬석보다는 우세하게 나타나고 있다. 전기석은 주상 결정, 자형 내지 반자형의 입자로 다색성을 보이며, 결정 중심에서 가장자리로 갈수록 파란색과 황갈색의 광학적 누대구조를 관찰할 수 있다. 일광광산에서 산출되는 전기석에 대한 현미경 관찰은 열수기원임을 지시하고 있다. 야외조사와 현미경 관찰의 예비조사에 의하면 일광광산의 전기석이 형성된 환경은 다른2가지 화학적인 저장소의 혼합 효과의 결과로 생성되어진 것으로 예상된다. 일광의 화강암류를 만든 마그마는 전기석을 형성할 만큼의 Fe-Mg성분이 충분하지 않았을 것이다. 화강암 내에 흑운모와 각섬석의 결정작용에 의해 마그마의 Fe-Mg성분이 고갈되어지고 이로 인해 그 함량이 감소하며 상대적으로 마그마 내에 남은 붕소(B$_2$O$_3$)는 열수로 용리되고 흑운모, 각섬석과 평형을 유지하며 열수에 남아있게 된다. 잔류용융체에 남은 붕소의 함량은 전기석을 만들기에 충분함에도 불구하고, Fe-Mg 함량이 부족하여 마그마 기원의 전기석 결정을 만들 수가 없다가 광맥이 형성된 시기에 또 다른 열수가 공급되면서 이전의 평형이 깨지고 기존의 흑운모와 같은 염기성 광물이 붕소(B)를 함유한 새로운 열수와 반응하여 전기석을 형성한 것으로 예상한다. 앞으로 전암과 광물에 대해 지화학적 연구를 통해 화강암류와 전기석과의 지화학적 연관성, 주성분 원소와 열수의 특성과의 상관관계, 전기석의 기원(마그마 기원인지 열수기원인지)이 보다 정확하게 파악될 것이다. 마그마 진화에 따른 전기석의 성분변화와 기원을 이용하여 일광광산의 동광화대를 형성한 마그마 계에서 열수계로 이어지는 지질학적 과정을 이해할 수 있을 것이며, 암석 성인론적 지시자로서

• Journal of the Mineralogical Society of Korea
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• v.15 no.1
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• pp.69-77
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• 2002

Margarite, which occurs in the Unkyori Formation of Miwon area, Chungcheongbukdo, South Korea, was investigated using the petrographic microscope, back-scattered electron images (BSEI), and electron probe microanalyzer (EPMA) to characterize the alteration textures and mineral chemistries. Most margarite crystals are inhomogeneous, and chlorite was commonly observed to occur at the boundaries parallel to the rim of margarite. Cracks occur across the basal plane of the margarite, and margarite is partly replaced by chlorite along the cracks. In additon, muscovite and biotite are intergrown in margarite and chlorite crystals, suggesting that margarite was partially altered to chlorite as well as to muscovite and biotite. Chemical analysis data show that paragonite solid solution in the margarite is approximately 19.6 mol%, but clintonite solid solution is negligible. Margarite crystals in the Unkyori Formation cut or penetrate other metamorphic minerals In the same thin sections and are oriented randomly without any relationship with the foliation of host rocks, indicating that formed as a secondary mineral after peak metamorphism. Furthermore, it seems that hydrothermal fluids associated with the Mesozoic intrusions developed near the sample are closely related to the margarite formation.

• The Journal of the Petrological Society of Korea
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• v.19 no.4
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• pp.283-292
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• 2010

The Suljeongri east three-story stone pagoda in Changnyeong (National Treasure No. 34) has been damaged mainly by lots of cracks. The stones used for this pagoda are medium-granied equigranular pinkish biotite granite. Measured magnetic susceptibility values are of from 2 to 9 (${\times}10^{-3}$ SI unit). From the ${\gamma}$-ray spectrometer mesurement K, eU, and eTh contents of the stones are 3 to 7%, 8 to 19 ppm, and 11 to 35 ppm, respectively. Comparing the petrographical and chemical characteristics between the stones of the pagoda and the country rocks near Suljeongri, it is suggested that the most similar rock could be equigranular biotite granite in the western slope of the Mt. Hwawangsan. Vertical, horizontal and diagonal cracks are intensely developed at the lower part of the stone pagoda. Biotite granite has intrinsic microcracks defined as rift and grain rock cleavages. Both rock cleavages are assumed to have led to the crack growth and consequent mechanical damage of the pagoda. It seems that vertical cracks have been grown parallel to the principal compressional stress, and that horizontal cracks to the reacting tensional stress. Diagonal cracks seems likely to have been resulted from conjugate rift and grain rock cleavages.

• Economic and Environmental Geology
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• v.42 no.3
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• pp.247-259
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• 2009

This study is focused on the relationship between whole rock boron contents and metamorphic P-T conditions of metasedimentary rocks from northeastern Yeongnam massif around Samcheok area, Korea. Metamorphic P-T conditions of sillimanite and garnet zones based on the Ti-biotite geothermometer is 553-687$^{\circ}C$ and 582-722$^{\circ}C$ at 4-6 kbar, respectively. In the metasedimentary rocks, boron contents in whole rock decrease with increasing metamorphic grade, from sillimanite zone (9.60-189 ppm B) to garnet zone (2.63-15.97 ppm B), except one sample (90.9 ppm B) from garnet zone containing graphites. Boron depletion in garnet zone has relation with mode of tourmaline which are broken down with increasing metamorphic temperature. Boron contents are indirectly proportional to major and trace elements such as $Al_2O_3$, MgO, $Fe_2O_3$, $K_2O$, Li, Ba, Sc, Co, Cr, Rb and Cs that are abundant in tourmalines. In conclustion, tourmalines and graphite are modulator of boron contents in metasedimentary rocks. In the biotite granitic gneisses, boron contents (2.62-12.2 ppm B) are similar or lower than those of metasedimentary rocks and have no relation with metamorphic P-T conditions.

• Economic and Environmental Geology
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• v.35 no.1
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• pp.75-95
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• 2002

The Andong pluton in the Andong Batholith is composed of comagmatic plutonic rocks, in which the lithofacies comprise hornblende biotite tonalite in the central paft biotite granodiorite in the marginal paft and porphyritic biotite granite at the topside (noJthea~tern paft) of the pluton. The pluton is petrographically and petrochemically zoned, having more mafic center than margin and topside. Distribution pallern of the lithofacies represents a reverse zoning in the pluton. Modal and chemical data in the pluton show progressive and gradual compositional variations from the centrer via the margin to the topside. Quartz and K-teldspar increase toward the topside of the pluton, whereas hornblende, biotite and color index increase toward the center. The bulk composition in the pluton is also reversely zoned, with high $Si0_2$ and $K_{2}O$ in the topside facies, and high MnO, CaO, $Ti0_2$, $Fe_{2}O_{3}$t, MgO and $P_{2}O_{5}$ in the central facies. The reverse zoning is also evident in higher Cr. V, Ni, Sc and Sr of the more mafic tonalite in the interior. The reversely zoned pluton results from remobilization (resurgence) of the lower more mafic compositional zone into the upper more felsic zones of the pluton modified by thennogravitational diffusion and fractional crystallization. In the initial stages of evolution, the pluton was a petrochemical system that fonned chemical compositional zonation with mafic tonalitic magma in the lower. granodioritic one in the middle and granitic one in the upper paft of the magma chamber. Periodic influxes of more mafic magma from the ba~e resulted in mingling of liquids and redistribution of minerals, and may have triggered the remobilil.ation of the lower compositional zone into the upper more felsic zones.