• Journal of the Korean Society of Propulsion Engineers
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• 제24권4호
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• pp.66-72
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• 2020

In this report, the post-curing and chemical aging ratio of propellants are described according to several aluminum contents. Under the same curing conditions, it was confirmed that the post-curing period of propellant having the aluminum content of 18 wt% was longer than the propellant having the 2 wt% of aluminum. On the other hand, in the chemical aging ratio analysis including post-curing, the propellant having the 18 wt% of aluminum was confirmed that the chemical aging proceeds slowly compared to the propellant having an aluminum content of 2 wt%.

• Journal of Dental Rehabilitation and Applied Science
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• 제38권4호
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• pp.233-241
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• 2022

Purpose: The purpose of this study was to assess the dimensional change of 3D-printed dentures after post-curing. Materials and Methods: The upper and lower dentures were designed in Exocad DentalCAD software and exported as STL files. The upper and lower dentures were printed from 10 STL files using a DLP-type dental 3D printer. The printed upper and lower dentures were cleaned, and a scan file was created using a model scanner before and after post-curing. The dimensional change was evaluated by superimposing the scanned denture files before and after post-curing and measuring the distance between measurement points on the denture. SPSS was used for statistics, and the level of significance was 5%. Results: The maxillary denture reduced in size during post-curing, with the most notable color change occurring in the posterior palatal region. The reduction in anteroposterior maxillary denture length (A-D, A-E, A-F), as well as the distance between the first molars on both sides (B-C), was statistically significant. After post-curing, the mandibular denture showed more noticeable color change in the posteriorly buccal and lingual region. The decrease of length on the posterior (A-M, A-D, A-E, A-L, A-H, A-I, H-I) and lingual (J-K, L-M) sides of the denture were statistically significant. Conclusion: There was significant dimensional change in both the length and width of the 3D-printed maxillary and mandibular dentures after post-curing in this experiment. Consequently, it is seemed necessary to develop post-curing techniques and materials that reduce such denture deformation.

• Transactions of the Korean Society of Mechanical Engineers A
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• 제36권9호
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• pp.1041-1046
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• 2012

In this study, we performed experimental tests on five SP-100 aluminum powder epoxy specimens with several after-curing conditions in order to estimate their hardness with temperature and compressive strength. In the surface hardness test, it was found that the higher the after-curing temperature, the higher was the hardness. In particular, it was found that the hardness of the specimens in cases 3 and 4 was much higher than in the other cases. In addition, in the compression tests carried out to evaluate the compressive strength, it was found that the specimens showed relatively similar stiffness and strength with after-curing, and specimens with no after-curing showed compression stress-strain curves similar to those of thermoplastic resins.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• 제21권6호
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• pp.976-981
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• 2012

In this study, hardness, microstructure and temperature of glass transition are measured respectively by using SEM (Scanning electron microscope) and DSC (Differential scanning calorimeter) to analyze the effects on material properties by after-curing in the epoxy resin. As the result of hardness test according to the after-curing conditions, the higher the temperature of after-curing, hardness and heat resistance are, the higher hardness is. As a result of microstructure for each specimen by SEM, it could be confirmed that the specimen with after-curing has more dense fracture surface. It is also found that temperatures of glass transitions by DSC are comparatively higher in the specimens with after-curing, and the differences between after-curing conditions are negligible.

• Journal of the Korean Society of Propulsion Engineers
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• 제23권3호
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• pp.51-57
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• 2019

Post curing effects are estimated by specimen tests. Propellant specimen accelerated aging tests are performed when post curing is estimated to be complete and the coefficients of Arrhenius aging equations are acquired. Simulated motors with cylindrical grain are designed and fabricated to confirm the application. Accelerated aging tests are conducted, and aged properties are measured and estimated for the inner bore, center and bond parts of the grain. The measured aging ratios of the modulus are compared with the ones predicted by the equations. As the results, the accelerated aging equations predict well the propellant aging trends; however, some differences are observed at the bond part. Therefore, the specimen extraction part must be carefully chosen to suit the test purpose when a rocket motor grain is used for the aging test.

• Journal of the Korean Society of Propulsion Engineers
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• 제24권6호
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• pp.101-107
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• 2020

In this paper, step-curing, which includes the change of curing temperature on the curing process, was applied to reduce curing day of HTPB/AP based propellant. This study targets the improvement of productivity of HTPB/AP based solid rocket motor. Comparison of mechanical properties of propellant resulted in the change of normal curing condition (60℃, 5 days) to step-curing condition (60℃, 1 day / 65℃, 3 days). Post-cure test was conducted to determine the impact on the shelf life of the solid rocket motor. The aging characteristics of propellants were analyzed by measuring mechanical properties and thermal expansion factor. To step-cured propellant, accelerated aging test was performed for 12 weeks, followed by tensile test. Sm(bar) and Em(%) were higher than 8 bar and 40% each, showing excellent mechanical properties.

• Korean Chemical Engineering Research
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• 제51권2호
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• pp.279-284
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• 2013

The phenolic beads in macrosize range were obtained by suspension polymerization at $98^{\circ}C$ from phenol and formaldehyde in the presence of basic catalyst with a phenol to formaldehyde (P/F) range of 1:1~1:4, and they were carbonized to spherical carbon beads under nitrogen at $700^{\circ}C$. Thermal analysis on spherical phenolic beads obtained by suspension polymerization showed that the postcuring process is essential. In order to optimize the suspension polymerization, the effects of the P/F molar ratio, the pH of catalyst, and the molecular weight of stabilizer on the size distribution and yield of spherical phenol beads were examined separatively. The particle size was increased whereas the yield was decreased with P/F molar ratio. The increasing basicity of catalyst made the particle size to increase, while the molecular weight of stabilizer had more effect on the yield rather than on the particle size distribution. The thermal stability of the spherical phenolic beads obtained through postcure was also examined by TGA. The phenol beads of high P/F ratio still showed the weight loss at $220^{\circ}C$ even after postcure due to the high possibility of dibenzyl ether, while those of low P/F ratio showed the steady decrease in weight during $220^{\circ}C$ to $400^{\circ}C$, which showed that the optimal P/F ratio was 1:2.

• Polymer(Korea)
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• 제30권6호
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• pp.492-497
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• 2006

The epoxy composites are prepared with mixing temperature of epoxy/montmorillonite (MMT) melt master batch and the dielectric properties of the composites are also compared with intercalation of MMT. The exfoliation mainly occurrs iii the low content of MMT composites, while in the composites with high content of MMT the interspacing distance increases as the mixing temperature of epoxy/MMT master batch is increased. Class transition temperature of the composite which the MMT are effectively exfoliated is increased with the appropriate postcuring condition. Since the orientation polarization of dipoles in the epoxy molecules is restricted by the clay nanolayers exfoliated, the dielectric constant and dielectric loss of the composites are reduced. Furthermore, the dielectric properties could be improved by controling the mixing temperature and time of epoxy/MMT master batch as well as postcuring condition.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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• pp.240-241
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• 2006

변류기의 제조공법에는 conventional 방식이 있다. Conventional 방식은 부분적으로 불규칙한 경화에 의한 굴곡형태, 단기간에 금형의 손상이 많이 가고, 제한된 생산량으로 금형이 많아야하고 또한 금형의 예열이 필요한 단점을 가지고 있다. 이를 개선한 APG(Automatic Pressure Gelation) 주형방식은 제품의 외관을 매끄럽게 하고, 자동화에 따른 금형수명을 연장하고, 1일 생산량이 conventional 방식보다 8배나 많고 제품의 후경화 설비만 필요한 장점이 있다. 생산성 향상 및 제조원가 절감을 위하여 새로운 제조공법인 APG 방식의 제조공법에 맞는 원재료 및 작업조건을 표준화하고 한국전기연구원이 보유하고 있는 고가장비인 내후성시험기, 성분분석시험기, 충격시험기, 단락시험설비 등을 이용하여 시제품에 대한 평가 시험을 하여 제품의 품질을 향상하고 안정성을 확보함으로써 국내 기업의 기술 경쟁력을 향상하고자 하였다.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 한국대기환경학회 2008년도 춘계학술대회 논문집
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• pp.414-415
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• 2008