• Title/Summary/Keyword: 회전형 반응기

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Gas phase temperature profile measurement of an upflow OMVPE reactor by laser Raman spectroscopy (레이저 라만 분광법을 이용한 도립형 OMVPE 반응기의 기상 온도 분포 측정)

  • ;Timothy J. Anderson
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.3
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    • pp.448-453
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    • 1998
  • An inverted, stagnation point flow OMVPE reactor was studied by laser Raman spectroscopy. Pure rotational Raman scattering by the carrier gas $(N_2; or; H_2)$ was used to determine the axial centerline temperature profile in the reactor as a function of the inlet flow velocity and the rector aspect ratio. A larger temperature gradient normal to the susceptor surface was obtained with higher gas glow velocity, larger aspect ratio, and the use of a $N_2$ carrier gas.

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Photocatalytic Cr(VI) Reduction with a Photoanode for Hydrogen Production (수소제조용 광전극을 활용한 Cr(VI) 환원처리에 관한 연구)

  • Shim, Eun-Jung;Park, Youn-Bong;Bae, Sang-Hyun;Yoon, Jae-Kyung;Joo, Hyun-Ku
    • Transactions of the Korean hydrogen and new energy society
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    • v.18 no.4
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    • pp.452-457
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    • 2007
  • Titanium foil and mesh(anodized tubular $TiO_2$ electrode, ATTE) were anodized in a bath at $5^{\circ}C$ with 20V external bias applied, then annealed at different temperatures($450^{\circ}C{\sim}850^{\circ}C$) to obtain tubular $TiO_2$ on the Ti substrate. The prepared sample was used to investigate rate of hydrogen production as well as Cr(VI) reduction. The ATTEs annealed at relatively lower temperatures showed higher activity than those at relatively higher temperatures. In particular, the Cr(VI) reduction was pH-dependent. To improve photocatalytic Cr(VI) reduction with the ATTEs, two configurations, fixing foil type and rotating mesh type, were also compared. As a result, the rotating mesh type was much more effective for Cr(VI) reaction than the former due to the more efficient use of the light. In the rotating type reactor, as the rotating speed increased, the rate of the Cr(VI) reduction was getting faster.

Ammonia Removal by using RBC in Recirculating Aquaculture System (RBC를 이용한 양어장수 암모니아 제거)

  • KIM Byong-Jin;LIM Sung-Il;SUH Kuen-Hack
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.31 no.5
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    • pp.622-630
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    • 1998
  • Rotating Biological Contactor (RBC) was tested for the removal of total ammonia nitrogen (TAN) by using simulated aquaculture system. RBC performance was evaluated by controlling revolution rate of disk and hydraulic residence tile (HRT). The optimum revolution rate of disk was 4 rpm, As HRT of RBC was increased, TAN removal efficiency of RBC and TAN concentration of rearing water were increased. HRT for maintaining lowest TAN concentration of rearing water was 9.5 minutes and at that condition TAN concentration of rearing tank was $1.03 g/m^3$

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Investigation of the pyrolysis of GaN OMVPE precursors by Raman spectroscopy (Raman 분광법에 의한 GaN OMVPE 전구체들의 열분해에 관한 연구)

  • 이순애;김유택;신무환;신건철;박진호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.2
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    • pp.116-121
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    • 2000
  • The temperature profiles of gas phase and the concentration profiles of GaN precursors in an inverted OMVPE reactor have been carried out by in-situ Raman spectroscopy. Pure rotational Raman scattering from the carrier gas (rd) was used to determine the temperature profiles in the reactor, and a large temperature gradient perpendicular the susceptor surface was observed. The homogeneous gas phase decompositions of the OMVPE precursors were investigated by the vibrational Raman spectra, and it was found that the pyrolyses of $NH_3$ and TMGa begin above 800 K and 650 K, respectively, but a noticeable amount of precursors remain undecomposed even in the region very close to the susceptor.

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Design and Analysis of A New Type of the Motor-Driven Blood Pump for Artificial Heart (인공심장용 전동기구동형 혈액 펌프의 설계 및 해석에 관한 연구)

  • 천길정;김희찬
    • Journal of Biomedical Engineering Research
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    • v.10 no.2
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    • pp.139-150
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    • 1989
  • A new motor-driven blood pump for artificial heart was developed. In this blood pump, a small size, high torque brushless DC motor was used as an energy converter and the motor rolls back and forth on a circular track. This movement of the "rolling-cyliner" causes blood ejection by alternately pushing left or right polyurethane blood sacs. This moving-actuator mechanism could be eliminate two potential problems of other motor-driven artificial hearts such as large size and poor anastomosis for the implantation. Theoretical analyses on the pump efficiency, the temperature rise, and the inflow mechanism were also performed. In a series of mock circulation tests, the theoretical analyses were compared to the measured hemodynamic and mechanical values. The pump system was shown to have sufficient cardiac output (upto 9 L/min), sensitivity to preload, and mechanical stability to be tested as an implantable total artificial heart.ial heart.

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Development and Evaluation of the Attrition Coupled Bioreactors for Enzymatic Hydrolysis of Biomass ; Horizontal Paddle Type Bioreactor for Enzymatic Hydrolysis of Cellulose (Biomass의 고효율 효소당화에 적합한 Attrition Coupled Bioreactor 개발에 관한 연구;Horizontal Paddle Type Bioreactor를 활용한 섬유소 당화)

  • 이용현;박진서
    • KSBB Journal
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    • v.4 no.3
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    • pp.215-220
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    • 1989
  • To develop an attrition coupled enzyme reactor with high efficiency-low energy consumption for saccharification of insoluble biomass, a 5L horizontal paddle type bioreactor was constructed and its performance was evaluated. The optimal condition for saccharification of 50g $\alpha$ -cellulose/L was found to be 200rpm with 500g of 3mm glass bead. Especially, the horizontal paddle type bloreactor was very effective for saccharification of high concentration of insoluble cellulose, in which around 72% of $\alpha$ -cellulose was saccharified for 75g $\alpha$ -cellulose/L, and even up to 70% for 100g of $\alpha$ -cellulose/L after 24hours. Under the optimal condition, the power consumption was measured to be around 1.7watth/g. Horizontal paddle type bioreactor seems to have an appropriated structural feature for industrial scale operation and to be an effective and energy saving attrition coupled enzyme reactor.

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Non-explosive separation device using screw jack mechanism (나사잭 메커니즘을 이용한 비폭발식 분리장치)

  • Park, Hyun-Jun;Lee, Min-Su;Jo, Jae-Wook;Kim, Byung-Kyu
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.38 no.4
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    • pp.321-326
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    • 2010
  • The non-explosive release device using jack mechanism is designed and fabricated for the small satellite. As a triggering actuator for the release device, a piezo rotory motor with torque of more than $1.7kgf{\cdot}cm$ is employed to guarantee stable activation. For performance tests of separation device, we conducted release time test, preload test and shock test. The device was operated within 1.172sec and activated stably under load of 45kgf. Maximum shock was measured as 18G that is much less than the pyro-separation device produces. We confirmed the possibility as a satellite separation device through above presented tests.

A Study on Quality Improvement and Verification of Recycled Coarse Aggregate for Concrete Using an Impact Crusher with Radial Rotation (방사형 회전이 추가된 임팩트 크러셔를 이용한 콘크리트용 순환굵은골재 품질향상 및 검증 연구)

  • Jeon, Duk-Woo;Kim, Yong-Seong;Jeon, Chan-Soo;Choi, Won-Young;Cho, Won-Ig
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.2
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    • pp.133-142
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    • 2022
  • The purpose of this study is to develop an impact crusher with a radial rotating plate installed at the bottom, which is a shock absorber that can produce high-quality recycled coarse aggregate for concrete and to verify the effect of improving the quality performance of recycled coarse aggregate and its applicability through concrete tests. As a result, it showed improved quality in all items such as absolute dry density, absorption rate, abrasion resistance, Particle shape judgment rate, amount lost in the 0.08 mm sieve passing test, alkali aggregate reaction, clay mass, stability, and impurity content, and it was found to meet the criteria of recycled aggregate quality standards. In addition, the air volume and slump of concrete to which recycled coarse aggregate is applied meet all domestic standards. According to the test results of the compressive strength characteristics by age of concrete according to the mixing ratio of the recycled coarse aggregate, it was confirmed that the mixing ratio of the recycled coarse aggregate was applicable up to 60 %.

Parallel clustering technology for real-time LWIR band image processing (실시간 LWIR 밴드 영상 처리를 위한 병렬 클러스터링 기술)

  • Cho, Yongjin;Lee, Kyou-seung;Hong, Seongha;Oh, Jong-woo;Lee, DongHoon
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2017.04a
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    • pp.158-158
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    • 2017
  • 비닐포장 하부에 위치한 콩의 생장 초기에 발생한 초엽을 인식하기 위한 연구를 수행중이다. 선행 연구에서 비닐포장에 접촉한 콩 초엽으로 인해 비닐포장 상부 표면의 열 반응 분포에 변화가 있음을 발견하였다. 현장에서 주행 중에 콩 초엽의 위치를 실시간으로 인식하고 연동된 선형 또는 회전형 엑츄에이터를 제어하여 정확한 위치에 천공을 수행하기 위해서는 계측 시스템과 제어 시스템간의 시간적 차이를 최소할 수 있는 실시간 신호 처리 기술이 필수적이다. 선행 연구에서 사용한 다중 IR 센서의 분해능은 $16{\times}4pixel$이며 주파수는 3 Hz로, 폭이 30cm 내외인 비닐포장 상부의 정밀 분석에 한계가 있음을 발견하였다. 이를 해결하기 위하여 분해능과 계측 주기를 개선할 수 있는 초소형 ($1cm{\times}1cm{\times}1cm$) 열화상 센서를 이용하였다. LWIR(Longwave infrared)영역에 해당하는 $8{\mu}m{\sim}14{\mu}m$의 영역에서 $0.05^{\circ}C$의 분해능을 보이는 $ Lepton^{TM}$ (500-0690-00, FLIR, Goleta, CA)모델을 사용하였다. 프레임당 $80{\times}60$ 픽셀의 정보가 2 Byte의 단위로 계측이 되며 9 Hz의 주파수로 대상면의 열 분포를 측정할 수 있다. 이론적으로 초당 정보 전송량은 86,400 Byte ($80{\times}60{\times}2{\times}9$)이며, 1 m를 진행하는 주행형 천공기에 적용할 경우 1 프레임당 10cm 정도의 면적을 측정하므로, 최대 위치 판정 분해능은 약 10 cm / 60 pixel = 0.17 cm/pixel로 상대적으로 정밀한 위치 판별이 가능하다. $80{\times}60{\times}2Byet$의 정보를 0.1초 이내에 분석해야 하는 기술적 과제를 해결하기 위하여 천공 작업기에 적합한 상용 SBC(Single board computer)의 클럭 속도(1 Ghz)로 처리 가능한 공간 분포 분석 알고리즘을 개발하였다. 전체 이미지 도메인을 한 번에 분석하는데 소요되는 시간을 최소화하기 위하여 공간정보 행렬을 균등히 배분하고 별도의 프로세서에서 Feature를 분석한 후 개별 프로세서의 결과를 경합식으로 판정하는 기술을 연구하였다. 오픈 소스인 MPICH(www.mpich.org) 라이브러리를 이용하여 개발한 신호 분석 프로그램을 클러스터링으로 연동된 개별 코어에 설치/수행 하였다. 2D 행렬인 열분포 정보를 공간적으로 균등 분배하여 개별 코어에서 행렬의 Spatial domain analysis를 수행하였다. $20{\times}20$의 클러스터링 단위를 이용할 경우 총 12개의 코어가 필요하였으며, 초당 10회의 연산이 가능함을 확인하였다. 병렬 클러스터링 기술을 이용하여 1m/s 내외의 주행 속도에 대응이 가능한 비닐포장 상부 열 분포 분석 시스템을 구현하였다.

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Kinetics and Mechanism of Alkalie Hydrolysis of Cinnamonitrile (II) (Cinnamonitrile의 알카리 가수분해(加水分解) 반응(反應)메카니즘 (II))

  • Sung, Nack Do;Chung, Woo Jin;Kwon, Ki Sung;Park, Byung Kwan
    • Korean Journal of Agricultural Science
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    • v.10 no.2
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    • pp.354-364
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    • 1983
  • Confonmation of (Z)-cinnamonitrile have been studied by molecular orbital theoretically using extended Huckel theory(EHT) and CNDO/2 molecular orbital calculation methods. The results indicate that the stability of conformation is(Z)-gauch>(Z)-planar. The rate constants for alkalie hydrolysis of cinnamonitrile at pH 7.0-14.0 range have been determined by ultra-violet spectrophotometry in 50% methanol at $25^{\circ}C$ and the following rate equation which can be applied over wide pH range was obtained; $${\therefore}k=({\frac{1.41{\times}10^{-14}+1.21{\times}10^7/[H_3O^+]}{2.65{\times}10^{-7}+1.64/[H_3O^+]})+9.14{\times}10^9/[H_3O^+]$$ The rate equation reveals that, at pH 7.0-10.0, the reaction is initiated by the addition of water molecule to unsaturated cabon-carhon double bond of cinnamonitrile and ${\alpha}C-{\beta}C$ bond scission follow subsequently in neutral and alkalie media. At pH 12.0-14.0, in strong alkalie solution, that so-called Michael type nucleophilic addition that the over-all rate constants is only dependent upon the concentration of hydroxide ion occurs competitively and are very complicated. Hence, the reaction mechanism of alkalie hydrolysis of cinnamonitrile which did not carefully before can be fully explained.

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