• Title/Summary/Keyword: 회수기술

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Recovery of High Purity Sn by Multi-step Reduction of Sn-Containing Industrial Wastes (건식 환원 공정을 이용한 고순도 주석 회수)

  • Lee, Sang-Ro;Lee, Man-Seung;Kim, Hyun You
    • Resources Recycling
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    • v.24 no.3
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    • pp.11-15
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    • 2015
  • In order to develop a technology for the recovery of pure tin from the Sn containing industrial wastes (SIWs), a process consisted of high temperature reduction and electrorefining was investigated. The tin which exists as oxide in SIWs was successfully reduced by two consecutive high temperature treatments and 92.7% of the tin was recovered. The purity of the tin thus obtained was increased to 99.87% by electrorefining. By applying the results obtained in this work, a commercial process can be developed to produce pure tin metals from domestic spent resources, which can reduce the amount of tin imported from abroad.

Recent Trends and Future Perspectives of the Magnesium Recovery based on Electrolysis (전해 기반 마그네슘 회수 기술의 관련 동향 및 향후 전망)

  • Sang-hun Lee
    • Resources Recycling
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    • v.33 no.2
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    • pp.16-23
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    • 2024
  • The electrolysis for extracting magnesium from seawater or brine primarily involves recovery of magnesium via precipitation as the form of magnesium hydroxide. The technology is classified into cation-exchange membranes (CEM), anion-exchange (AEM) membranes, electrodialysis, and membraneless methods. Recent research has focused on enhancing the efficiency and selectivity of magnesium recovery from seawater or brine containing magnesium, with expectations of effective magnesium recovery even with normal seawater. In a future, the optimization of the selective and efficient recovery of magnesium and various valuable substances through long-term operation of scaled-up systems is crucial with enhancing economic and environmental viability. It is essential to realistically estimate operational costs considering the membrane's lifespan and replacement cycle. Also, detailed and practical process models should be developed based on monitoring data on various factors.

Development of Simulation Model for Waste Heat Recovery from Automotive Engine Exhaust Using Thermoelectric Generator (열전소자를 이용한 자동차 엔진 배기 폐열 회수 시스템 해석 모델 개발)

  • Kim, Ki-Bum
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.3
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    • pp.1022-1026
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    • 2013
  • Recently, the waste heat recovery technique using thermoelectric generator (TEG) in automotive engine has emerged to improve thermal efficiency in commercial vehicle. It is not difficult to recognize the numerous attempts that have been made to develop the TEG simulation model, but it is hard to find the model in conjunction with a particular heat engine system. In this study, 1-D commercial software AMESim was used to develop a computational model that can assess waste heat recovery from a diesel engine exhaust using TEG. The developed TEG simulation model can be used for evaluating the TEG performance of various types of TE module, and the diesel engine model can simulate any type of on and off-road diesel engines. The simulation results demonstrated that approximately 544.75W could be recovered from the engine exhaust and 40.4W could be directly converted into electricity using one TE module. The models developed in this study can be easily coupled with each other in the same computational program; thus, the models are expected to provide a viable tool for developing and optimizing a TEG waste heat recovery system in an automotive diesel engine.

Development of Technology for Recovering Valuable Metals in Detoxified Waste Asbestos-Containing Waste (무해화된 폐석면에 함유된 유가금속 회수 기술 개발)

  • Kim, Dong Nyeon;Yang, Dong Hyeon;Kim, Seok Chan
    • Applied Chemistry for Engineering
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    • v.31 no.4
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    • pp.438-442
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    • 2020
  • Studies on the recovery conditions and optimization process for valuable metal recovery through chemical treatment from detoxified asbestos-containing waste composed of calcium silicate, larnite, merwinite, and akermanite were conducted. The main components, Si, Ca, and Mg, of detoxified asbestos-containing waste (DACW) were separated and recovered in the form of SiO2, CaSO4, and Mg(OH)2 compounds, respectively. Each separated component was confirmed through X-ray diffraction (XRD) and inductively coupled plasma spectrometer (ICP) analysis. The recovery conditions for each component were first treating them with an acid to separate SiO2 and subsequently with H2SO4 to recover Ca in the form of sulfate, CaSO4. The remaining Mg was recovered by precipitation with Mg(OH)2 under strong basic conditions. This study suggested that it is possible to convert existing treatment process of asbestos waste by landfill through recovering the components into a resource-recycling green technology.

Comparison of Genetic Responses Using Reproductive Techniques of MOET and In Vitro Fertilization in Cattle Populations (다배란과 수정란이식 및 체외수정기술을 이용한 소의 유전적 개량량 비교)

  • 전광주
    • Journal of Embryo Transfer
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    • v.11 no.1
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    • pp.1-6
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    • 1996
  • 다배란 수정란이식(MOET)과 체외수정(IVF)기술을 이용한 육종체계에서 예상되는 유전적 개량량을 여러 집단의 크기에서 비교한 결과 체외수정기술이 MOET육종기술보다 특히 개량대상 유전력이 낮을때 훨씬 효율적으로 나타났다. 그러나 유전력이 높아지면 (h$^2$=0.3, 0.5), MOET와 IVF간의 상대적 차이는 미진하게 나타났다. 체외수정을 이용한 육종기술에서 암컷의 선발 강도는 대단히 높일 수 있는 반면 난자의 회수율이 많을수록 상대적으로 수컷에 대한 선발 강도는 낮아진다. 그 이유는 한 가계에서 근친을 피하기 위해 한 마리의 수컷만 선발해야 하므로 수소의 선발강도는 난자의 회수율이 높을수록 상대적으로 낮아진다. 여러 수준의 난자회수율(10, 20, 30, 50, 100)중에서 30일 때 가장 높은 유전적 개량을 나타내었다. (Key word: MOET, IVF,selection responses)

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Characteristics of $SF_6$ Gas Recycling Processes ($SF_6$가스 회수 공정들의 특성 연구)

  • Cho, Hoon;Woo, Dae-Sik;Choi, Yu-Mi;Han, Myung-Wan
    • Clean Technology
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    • v.17 no.4
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    • pp.329-335
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    • 2011
  • $SF_6$ gas is well known as a global warming gas. Global warming potential of $SF_6$ gas is 22,000 times higher than that of $CO_2$. Recycling of $SF_6$ gas is an essential technology for the sake of the environment and the economy. The recovery processes of $SF_6$ gas studied in this work were liquefaction, distillation, and crystallization processes because these processes were thought to be easily carried to the fields for recycling waste $SF_6$ gas. The processes were simulated and optimized using Aspen plus. The optimization problems were formulated to minimize energy consumption with satisfying product specification and desired recovery. The performance of the processes was compared based on the optimization results. Effects of major process variables on the recovery performance were investigated and optimal operation guide for changing product specification and product recovery was provided.

Recovery of Copper from Waste Printed Circuit Boards by High-temperature Milling Process (고온 밀링 공정을 통한 폐인쇄회로기판으로부터 구리 회수)

  • Woo-chul Jung;Byoungyong Im;Dae-Geun Kim
    • Resources Recycling
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    • v.33 no.4
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    • pp.22-28
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    • 2024
  • Waste PCBs contain a large amount of valuable resources, including copper, and technology to recover them is constantly being developed. Generally, to recycle waste PCBs, a physical pretreatment process such as shredding and crushing is required. However, during this stage, the loss rate of metals is high and the sorting efficiency is low, indicating a need for a more efficient recycling pretreatment process. In this study, a high-temperature milling process, which simultaneously employs heat treatment and ball milling, was utilized to efficiently recover copper from waste PCBs. An experiment was conducted at 350 ℃ with milling time, milling speed, and the weight of the balls as variables. The results showed a copper recovery rate of over 90% under the conditions of a ball weight of 500 g, a milling speed of 70 RPM, and a milling time of 5 hours. The purity of the recovered copper was approximately 93%, and through post-processing after the high-temperature milling process, the feasibility of reusing the recovered copper as a high-purity material was confirmed.

$CO_2$ Separation in IGCC plant using Principles of Gas hydrate Formation (가스 하이드레이트 형성 원리를 이용한 IGCC 공정에서의 $CO_2$ 분리 연구)

  • Lee, Hyun Ju;Kim, Soo Min;Lee, Eun Kyung;Lee, Ju Dong;Kim, Yang Do
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.215.2-215.2
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    • 2010
  • 지구온난화의 주범으로 알려진 $CO_2$의 대기 중 농도는 산업혁명 이전 280ppm에서 산업 혁명 이후 375ppm으로 증가하였다. 정부 간 기후변화패널(IPCC)의 기후변화 시나리오에 의하면, 지금부터 다양한 감축노력을 한다 할지라도 $CO_2$ 증가추세는 계속되어 2100년경에는 대기 중 $CO_2$농도가 600~950ppm에 이를 것으로 예측하고 있다. 현재까지 화력발전부분은 온실가스($CO_2$)의 최대 배출 원으로 알려져 있으며 이 분야의 $CO_2$ 회수기술은 연소 후 포집(Post-combustion), 순산소 연소(Oxy-fuel combustion), 연소 전 탈탄소화(Pre-combustion) 3가지로 크게 구분된다. 이중 석탄가스화복합발전(IGCC)기술과 연계하여 $CO_2$를 회수할 수 있는 방법이 연소 전 탈탄소화 기술이다. 핵심기술은 $CO_2$ 분리공정으로 적용 될 수 있는 기술로서는 흡착 흡수법, 막분리법 그리고 가스 하이드레이트가 있으나 아직까지 우리나라의 가스 하이드레이트 기술은 전무한 형편이다. 본 연구에서는 가스 하이드레이트 형성원리를 이용하여 정온 정압 조건에서 $CO_2/H_2$ 하이드레이트를 제조하였으며 특히, 하이드레이트 형성 촉진제인 TBAB(Tetra-n-butyl ammonium bromide)를 첨가하여 TBAB 농도에 따른 상평형 및 속도론 실험을 수행 하였다. 또한 라만 분석을 통하여 $CO_2$ 회수 분리에 대한 연구도 병행하였다.

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Brief Review on Microbial Enhanced Oil Recovery (미생물을 이용한 원유 회수증진법에 대한 동향연구)

  • Oh, Kyeongseok
    • Journal of the Korean Applied Science and Technology
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    • v.38 no.4
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    • pp.1010-1019
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    • 2021
  • Petroleum oil in reservoir has been acquired by primary, secondary and tertiary oil recoveries. Microbial enhanced oil recovery (MEOR) classified to tertiary oil recovery has been evaluated in two ways of in-situ and ex-situ options. In-situ MEOR injects microbes into a depleted oil reservoir and stimulates those to generate metabolites. Among metabolites, biosurfactants play an important role to make heavy residues flow. Ex-situ MEOR injects microbial metabolites instead of microbes into a reservoir to recover oil. Even though both in-situ MEOR and ex-situ MEOR are eco-friend processes, in-situ MEOR can be preferred because it is more economic. Even though MEOR have been evaluated for a long time, it is still in the state of evaluating in a pilot-scale. Among microbes, bacteria have been widely evaluated in MEOR purpose. In this paper, bacteria for MEOR were summarized and their metabolites were qualitatively evaluated.